1. Introduction
In the textile industry, solid waste causes severe environmental problems. As a result, there has been a considerable amount of research into recycling and reclaiming textile waste. With the increasing awareness of the importance of environmental protection, enterprises have a social duty to help to protect the environment. The best solution is to have materials that cause zero pollution. For example, selvages can be recycled for the production for geotextiles [
1], penetration resistant planks, or far infrared emissive or electromagnetic interference shielding (EMI SE) functional fiber composites [
2,
3,
4,
5,
6,
7,
8].
Using recycled FIR fiber conforms to eco-friendly concepts, and FIR rays activate water molecules, which increases body temperature and attains the added value of thermal insulation. FIR rays boost the circulation and metabolism rates for the human body and provide substantial health-care effects [
9,
10,
11].
Low-melting-point polyester (LPET) fiber has different components, structure, and functions from those of common fibers. LPET fiber has a sheath-core structure that is composed of common polyester and modified polyester multi-filaments. Unlike common PET fibers, the sheath of LPET fiber can be melted at a lower temperature, as its melting point is 110 °C. It can serve as an adhesive to bond fibers, and thus replace the commonly used glues. Therefore, LPET fiber is suitable for use in nonwoven fabrics, which meets economical and environmentally protective requirements [
12,
13].
For this study, recycled far infrared polyester (FPET) fiber that accounts for the majority of industrial waste was collected from textile waste. They have the function of emitting FIR rays. Moreover, three-dimensional crimped, hollow, flame-retarding (TPET) fiber and LPET fiber were added during the production of nonwoven fabrics in order to evaluate the influence of these materials on the properties of the nonwoven. The properties of nonwoven fabrics were evaluated and compared, examining the influence of hot pressing.
2. Experimental
2.1. Materials
Three-dimensional crimped, hollow flame-retarding (TPET) fiber (Far Eastern New Century Corporation, Taipei, Taiwan) has a fineness of 7D, a length of 51 mm, and a melting point of 259–269 °C [
14,
15]. Low melting point polyethylene terephthalate (LPET) fiber (Far Eastern New Century Corporation) has a fineness of 4D, and a length of 51 mm. The sheath of LPET fiber has a melting temperature of 110 °C [
16]. Recycled far infrared (FPET) fiber (True Young Co., Ltd., Tainan, Taiwan) has a fineness of 6D, 2% far infrared powder, and a length of 64 mm.
2.2. Preparation of Nonwoven Fabrics
FPET, TPET, and LPET fibers are respectively scattered via an opening process using a porcupine in order to make them loose and fluffy, which facilitates their mixture. The fibers at ratios of 0/80/20, 20/60/20, 40/40/20, 60/20/20, and 80/0/20 are processed with mixing and carding. The webs are folded and needle punched in order to form nonwoven matrices. These matrices are then processed with a roller-type hot pressing with a gauge distance of 1 mm, allowing the LPET fibers to create bonding points that toughen the connection between fibers. These samples are evaluated using different tests, examining the influence of the fiber blending ratios.
3. Tests
3.1. Air Permeability Test
A TEXTEST FX3300 (GO-IN International Co., Ltd., Munich, Germany) was used to measure the air permeability of samples, as specified in ASTM D737. Nonwoven fabrics were composed of five different fiber blending ratios, and 20 samples for each specification were taken for the test. Air permeability is defined as the air volume (cm3) that passes through per 1 cm2 of a sample, and is represented as cm3/(s·cm2).
3.2. Stereomicroscopic Observation
A stereomicroscope (SMZ-10A, Nikon Instruments Inc., Shinagawa, Japan) was used to observe the surface of the samples. Afterwards, Motic Images Plus 2.0 software (Motic Group Co., Ltd., Barcelona, Spain, 2012) was used to analyze the photographs.
3.3. Tensile Test
Samples are trimmed along the cross machine direction (CD) and the machine direction (MD) into 2.54 cm × 18 cm strips. The distance between clamps was 7.5 cm and the tensile rate was 300 mm/min.
3.4. Tear Strength Test
Tear strength along the CD and MD of nonwoven fabrics was measured as specified in CNS 12915. Ten samples were taken along the CD and MD for each specification. The sample size was 7.6 cm × 20.3 cm. The test rate was 300 mm/min.
3.5. Far Infrared Emissivity Test
A far infrared emissivity (TSS-5X, Desunnano Co., Ltd., Tokyo, Japan) test measures the far infrared emissivity of 10 spots of nonwoven fabrics as specified in FTTS-FA-010. The fabrics release heat radiation when being measured with far infrared emissivity.
4. Results and Discussion
4.1. The Effect of Content of Recycled Fiber on Air Permeability of Nonwoven Fabrics
The data in
Figure 1a show that air permeability decreases as a result of increasing the amount of FPET fiber. FPET fiber and TPET fiber account for 80 wt % of the nonwoven fabrics, while LPET fiber was used at a specified amount of 20 wt %. TPET fiber is three-dimensional, crimped, hollow, and fire-retardant, which enables it to hold more air. Moreover, the sheath of LPET fiber melts during hot pressing, which creates a compact structure between fibers. That is, a lower amount of pores is presented in the nonwoven fabrics, as indicated in
Figure 1c, and the nonwoven fabrics have a smaller thickness. The air permeability of hot pressed nonwoven fabrics is higher by 20 cm
3 (cm
2/s) than that of non-hot-pressed nonwoven fabrics.
4.2. The Effect of Content of Recycled Fibers on the Tensile Strength of Nonwoven Fabrics
Figure 2a shows that more FPET fiber causes the tensile strength of nonwoven fabrics to decrease. The needle punching process results in the entanglement and cohesion of fibers. As the barbed needles repeatedly pierce the fabric, they pull the fiber from the bottom through to the upper surface. The repetitive needle punch provides nonwoven fabrics with a higher density, which is conducive for tensile strength. However, recycled fibers often have a poor strength. When recycled fibers are repeatedly needle-punched, they exhibit fiber breakage. Therefore, the tensile strength of nonwoven fabrics is in inversely proportional to the amount of recycled fiber. Moreover, the tensile strength along the CD is higher than that along the MD. This result is ascribed to the carding process, which laminates the webs along the CD, as illustrated in
Figure 2b and good arrangement of the fiber wed in
Figure 1b. Therefore, nonwoven fabrics exhibit a higher tensile strength along the CD.
4.3. Effect of Content of Recycled Fibers on the Tear Strength of Nonwoven Fabrics
That the nonwoven fabrics exhibit lower tear strength when they contain more FPET fiber, is illustrated by the data presented in
Figure 3, the trend observed for tensile strength. This result indicates that the recycled fibers have a decreased physical properties as a result of being recycled. In the recycling process, the recycled fibers are processed via melting, granulating, or spinning. In addition, the presence of the LPET fiber can mechanically improve the compact structure of nonwoven fabrics due to the fusion swing presence of hot pressing. The tear strength of nonwoven fabrics is assumed to be primarily due to the three-dimensional crimped, hollow, flame-retardant TPET fiber. The end user can thus adjust the tear strength according to their requirements.
4.4. Effect of Content of Recycle Fibers on the Far Infrared Emissivity of Nonwoven Fabrics
Using more FPET fiber stabilizes the slightly increased far infrared emissivity of nonwoven fabrics, as shown in
Figure 4. All thermally treated nonwoven fabrics exhibit far infrared emissivity of above 0.8, which is qualified for health care and is 8% greater than the non-thermally treated samples. The recycled FPET fiber contains 2% far infrared powder. It is difficult for these powders to be evenly dispersed in fluffy nonwoven fabrics. In performing the far infrared emissivity test, there is a high potential for black body to detect the air inside the fabrics. Moreover, the test is highly influenced by external environment conditions in terms of humidity, temperature, or people’s interference and creates a high variation coefficient. In contrast, the thermally treated fabrics not only have a smaller thickness, but also allow the powder to be evenly dispersed, which leads to an efficient far infrared emissivity. In particular, using 40 wt % FPET fiber helps to yield a stabilized far infrared emissivity, indicating that this specified amount of FPET fiber is suitable for applications relating to far infrared emissivity for health care.
5. Conclusions
In this study, the influence of FPET fiber on the properties of nonwoven fabrics was examined in terms of air permeability, tensile strength, tear strength, and far infrared emissivity of FPET/TPET/LPET nonwoven fabrics. The air permeability increases by 6% when the TPET fiber is increased from 40 to 60 wt % and from 60 to 80 wt %. When the content of FPET fiber is increased by 20 wt %, the mechanical properties along the CD of nonwoven fabrics decrease by 9%, while those along the MD decrease by 5%. The recycled far infrared fiber can be adjusted in view of the application field. For thermally treated FPET/TPET/LPET nonwoven fabrics, the far infrared emissivity shows an increasing trend when the content of the FPET fiber is increased from 0 to 40 wt %, and it is then stabilized at 0.85ε when the content of the FPET fiber is increased from 60 to 80 wt %.
Acknowledgments
The authors would especially like to thank the Ministry of Science and Technology of Taiwan for financially supporting this research under Contract MOST 105-2622-E-034-001-CC2.
Author Contributions
In this study, the concepts and designs for the experiment, all required materials, and the processing and assessment instruments were provided by Jia-Horng Lin, and Ching-Wen Lou. Data were analyzed and experimental results were examined by Wen-Hao Hsing, Chien-Teng Hsieh, and Yi-Jun Pan. Experiment were conducted and tests were carried out by Yan-Lan Hsing.
Conflicts of Interest
The authors declare no conflict of interest.
Abbreviations
The following abbreviations are used in this manuscript:
PET | polyester |
FPET | far-infrared polyester |
TPET | three-dimensional crimped hollow flame-retarding polyester |
LPET | low-melting-point polyester |
FIR | far infrared |
CD | cross machine direction |
MD | machine direction |
References
- Broda, J.; Gawlowski, A.; Laszczak, R.; Mitka, A.; Przybylo, S.; Grzybowska-Pietras, J.; Rom, M. Application of innovative meandrically arranged geotextiles for the protection of drainage ditches in the clay ground. Geotext. Geomembr. 2017, 45, 45–53. [Google Scholar] [CrossRef]
- Ise, N.; Kaysuura, T.; Kikuchi, Y.; Miwa, E. Effect of far-infrared radiation on forearm skin blood flow. Ann. Physiol. Anthropol. 1987, 6, 31–32. [Google Scholar] [CrossRef] [PubMed]
- Li, T.T.; Wang, R.; Lou, C.W.; Huang, C.H.; Lin, J.H. Mechanical and physical properties of puncture-resistance plank made of recycled selvages. Fibers Polym. 2013, 14, 258–265. [Google Scholar] [CrossRef]
- Lou, C.W.; Chen, A.P.; Chuang, Y.Y.; Lin, J.Y.; Lin, M.C.; Lin, J.H. Manufacturing techniques and mechanical properties of recycle Kevlar®/PET composite nonwoven. Adv. Mater. Res. 2012, 627, 831–834. [Google Scholar] [CrossRef]
- Lou, C.W.; Lin, C.M.; Hsing, W.H.; Chen, A.P.; Lin, J.H. Manufacturing techniques and electrical properties of conductive fabrics with recycled polypropylene nonwoven selvage. Text. Res. J. 2011, 81, 1331–1343. [Google Scholar]
- Ozen, M.S.; Sancak, E.; Akalin, M. The effect of needle-punched nonwoven fabric thickness on electromagnetic shielding effectiveness. Text. Res. J. 2015, 85, 804–815. [Google Scholar] [CrossRef]
- Rengasamy, R.S.; Wesley, D.S. Study on dynamic needle thread tensions in a single needle lock stitch (SNLS) sewing machine. II. Effect of sewing speed, thickness of fabric plies, thread linear density and pre-tensions of threads. Fibers Polym. 2014, 15, 1773–1778. [Google Scholar] [CrossRef]
- Ghosh, S.; Chapman, L. Effects of fiber blends and needling parameters on needlepunched moldable nonwoven fabric. J. Text. Inst. 2002, 93, 75–87. [Google Scholar] [CrossRef]
- Toyokawa, H.; Matsui, Y.; Uhara, J.; Tsuchiya, H.; Teshima, S.; Nakanishi, H.; Kwon, A.H.; Azuma, Y.; Nagaoka, T.; Ogawa, T. Promotive effects of far-infrared ray on full-thickness skin wound healing in rats. Exp. Biol. Med. 2003, 228, 724–729. [Google Scholar]
- Lou, C.-W.; Huang, C.-H.; Tai, K.-C.; Lin, C.-W.; Lin, J.-H. Recycling polypropylene nonwoven selvages to create far-infrared composite plates. J. Thermoplast. Compos. Mater. 2012, 25, 561–571. [Google Scholar] [CrossRef]
- Tsai, I.J.; Lin, C.W.; Lee, Y.C.; Lou, C.W.; Lei, C.H.; Lin, J.H. Manufacturing process evaluating of pet loose-filled nonwoven thermal insulation. J. Hwa Gang Text. 2007, 14, 1–9. [Google Scholar]
- Yoo, H.; Park, C.M.; Oh, T.J. Investigation of jewelry powder radiating farinfrared rays and the biological effect on human skin. J. Consmet. Sci. 2002, 53, 175–183. [Google Scholar]
- Park, Y.M.; Shin, J.W. Surface properties studies of MPCMs containing fabrics for thermo-regulating textiles. Fibers Polym. 2011, 12, 384–389. [Google Scholar] [CrossRef]
- Leshchinsky, D.; Dechasakulsom, M.; Kaliakin, V.N.; Ling, H.I. Creep and stress relaxation of geogrids. Geosynth. Int. 1997, 4, 463–479. [Google Scholar] [CrossRef]
- Vashi, J.M.; Desai, A.K.; Solanki, C.H. Assessment of reinforced embankment on soft soil with PET and PP geotextile. Int. J. Civ. Struct. Eng. 2012, 2, 828–837. [Google Scholar]
- Hsieh, J.C.; Li, J.H.; Lou, C.W.; Hsieh, C.T.; Hsing, W.H.; Pan, Y.J.; Lin, J.H. Influence of immersion conditions on the tensile strength of recycled Kevlar®/polyester/low-melting-point polyester nonwoven geotextiles through applying statistical analyses. Appl. Sci. 2016, 6, 133. [Google Scholar] [CrossRef]
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