1. Introduction
Mineral fillers play an important role in improving the workability and stability of asphalt mixtures [
1,
2]. Various types of fillers have different effects on the performance of asphalt mixtures [
3,
4]. In recent years, the partial replacement of mineral powder by industrial waste has gained considerable research attention considering the long-term performance of asphalt pavements [
5,
6,
7,
8]. At present, the most common filler used in asphalt pavement is limestone ore [
9]. In China, the Technical Specifications for Construction of Asphalt Pavements [
10] stipulate that cement can be used instead of a part of the mineral powder, as a part of the filler to improve the adhesion of asphalt to acid stone, thereby improving the moisture stability. In recent years, it has become common practice to use cement instead of ore as a filler in asphalt pavements in hot and humid areas. It is also common worldwide to mix various filler materials for replacing mineral powder to improve the performance of asphalt mixtures [
11,
12,
13].
Cement–mineral composite fillers improve the anti-rutting performance and moisture stability of the asphalt mixture compared to single limestone powder fillers [
14]. This is mainly because the content of calcium oxide in cement is higher than that of mineral powder; therefore, its alkalinity is higher than that of mineral powder. In the preparation of an asphalt mixture, the alkaline component of cement reacts with the acidic component of asphalt to produce a substance with strong adhesion [
15,
16]. This results in strong binding of the aggregate and asphalt, thereby improving the water stability of the mixture. Ahmad et al. [
17] studied the effects of using two types of mineral fillers on the strength of asphalt mixtures in terms of the Marshall stability and retained strength, and showed that ordinary Portland cement (OPC) and pulverized limestone have a similar effect on the Marshall stability. Thus, the use of OPC resulted in higher values of retained strength. Because unaged asphalt mixtures were used in that study, the long-term moisture stability and low-temperature crack resistance were not evaluated. Wang [
18] found that the addition of cement and slaked lime can significantly improve the adsorption capacity of asphalt and improve the moisture stability of the asphalt mixture. However, the study did not consider the effect of aging on the test results, and the test data analysis tended to be qualitative. Zhi et al. [
19] found that the moisture stability improvement effect of the asphalt mixture after aging under all filler combinations was reduced. However, the study primarily focused on the improvement effect of cement fillers on the moisture stability of aged asphalt mixtures.
Thus, the effect of cement fillers on the performance of asphalt mixtures after aging is still debatable, and the effect of cement–mineral composite fillers on the performance of asphalt mixtures under long-term aging has not been definitively studied. In addition, moisture damage and low-temperature shrinkage occur mostly in the upper or middle layers of asphalt pavements, which usually consist of modified asphalt. However, previous studies have focused on samples mostly made of matrix asphalt. Therefore, this knowledge gap must be addressed.
Notably, some studies have applied colloidal theory to analyze the interaction between different types of fillers and asphalt [
20,
21,
22,
23]. The effects of different fillers on the rheological properties of asphalt cement were studied with asphalt mastic as the test object [
24,
25,
26]. For example, Movilla-Quesada et al. [
27] used Portland cement (CEM II/A-L 32.5 R) and calcium hydroxide as two different types of filler to study the stiffness of the corresponding bituminous mixture. According to colloidal theory, when active ore powders with a large specific surface area, high degree of irregularity, and high content of alkaline components are mixed with asphalt, the rheological properties of the asphalt cement significantly change because of the chemical properties and particle packing of the ore powder [
28]. The acidic component of the asphalt reacts with the ore fines so that the interface between the asphalt and the ore fines forms a strong bond [
29]. Cement is a more active alkaline material, and not only has the characteristics of a mineral powder but also has a pH of 12 after silicates C
3S\C
2S and water in the cement are digested; on the other hand, the pH of general limestone ore powder is only 9 [
30]. When the alkaline component of the cement reacts with the hydroxy acid in the asphalt, the resulting product has an improved adsorption performance [
31]. Moreover, when the asphalt reacts with the cement, the oil content (molecular weight MW ~300 to 1000) and asphaltene (MW ~2000 to 10,000) with a low molecular weight will enter the cement due to the irregularity of cement particles and presence of large open voids. The oil content refers to the saturated fraction and aromatic fraction. At this time, the consistency of the asphalt cement is also increased, thereby improving the temperature stability and water stability of the asphalt concrete.
Colloidal theory can be applied to analyze the interaction mechanism between different fillers and asphalt. However, the asphalt binder is a mix of asphalt and filler, and asphalt concrete is a mixture of asphalt after the dry mixing of filler and aggregate. That is, in the asphalt mortar, the filler is directly dispersed uniformly in asphalt to form a colloidal dispersion. In the asphalt mixture, the filler (e.g., cement) is not directly and uniformly dispersed in the asphalt but is present in the contact surface of the asphalt and aggregate and is dispersed in the structural asphalt film. Considering the difference in the production mode and filler distribution between asphalt cement and asphalt concrete, the influence of the filler on the rheological properties of asphalt cement cannot directly reflect its influence on the performance of the asphalt mixture. Therefore, when studying the effect of the filler on the mixture properties, the mixture must be selected as the test sample.
Based on the current research status, this study designed a performance test for styrene-butadiene-styrene- (SBS)-modified asphalt mixtures for three different aging procedures. The fillers were various cement–mineral powder combinations (five ratios). By analyzing the performance test results of the modified asphalt mixtures with the different cement–mineral powder composites under the three aging procedures, the effect of the cement–mineral composite filler with different blending ratios on the long-term performance of the asphalt mixture was determined.
3. Results and Discussion
3.1. High-Temperature Anti-Rutting Performance
For the modified asphalt mixture, the rutting test results under the conventional 60 °C test conditions tended to be high, resulting in a low degree of discrimination between the test results and high-temperature stability performance [
34,
35]. However, for asphalt mixtures, aging will inevitably lead to an increase in dynamic stability and high-temperature stability. Therefore, this study used the short-time-aged test piece for the 70 °C rutting test for five types of filler combinations to analyze the effect of adding cement on the high-temperature stability of the asphalt mixture. The test results are summarized in
Figure 3.
With an increase in cement content, the high-temperature stability of the modified asphalt mixture showed an overall increasing trend. That is, adding cement as a filler helped to increase the high-temperature stability of the asphalt mixture, which is consistent with previous experimental results. When the ratio of MPC/MMP was 3:1, the dynamic stability reached its highest value. When the ratio of MPC/MMP was 4:0, that is, after the cement completely replaces the mineral powder, the dynamic stability exhibited a decreasing trend. This implies that the addition of cement can significantly improve the high-temperature stability of the mixture up to a certain concentration; however, because the filler uses cement, it no longer achieves the best high-temperature stability.
3.2. Immersion Marshall Test Results
To comprehensively investigate the influence of the cement filler on the volumetric parameters of the asphalt mixture, this study measured the index and corresponding stability from asphalt mixture specimens for different cement/mineral ratios by the Marshall test [
10,
32]. The results are summarized in
Table 7.
From the volume index of the Marshall test piece, as the cement replacement ratio increased, the measured relative density of the asphalt mixture increased gradually, the void ratio and mineral gap ratio decreased gradually, and the asphalt saturation increased gradually. Because Portland cement has a higher density compared to limestone ore powder, incrementally increasing the cement content will inevitably lead to an increase in the density of the asphalt mixture. Because the filler accounts for a relatively small proportion of the total mass of the mixture, the change in the proportion of cement blending had little effect on the relative density of the overall mixture. From the test results, changing MPC/MMP did not significantly change the void ratio, mineral gap ratio, and asphalt saturation of the molded specimens, and the variation range was also small. This proves that the cement, when substituted for mineral powder, had no significant effect on the volumetric parameters of the asphalt mixture after compaction.
For the design of the asphalt mixture proportion, the Chinese standard uses the water-immersed Marshall test to evaluate the water stability of the asphalt mixture, and the residual stability ratio MS
0 is used as the evaluation index. The results of the residual stability test of the asphalt mixture for different aging degrees in this study are summarized in
Table 8.
With the addition of cement, the residual stability of the asphalt mixture was improved; however, when the cement blending ratio was in the range of 50%–75%, the residual stability reached a maximum. To compare and analyze the improvement effect of the cement filler on the water stability of the asphalt mixture for different aging degrees, the difference ΔMS
0 between the maximum and minimum values of residual stability in the same test group was calculated. By comparing the three aging levels of ΔMS
0, we found that after aging, the improvement in water stability due to the cement filler decreased. The improvement effect of the cement filler on water stability was 42% lower than that for the non-aging condition. To more clearly analyze the variation of residual stability for different aging degrees, the test results are plotted in
Figure 4.
3.3. Low-Temperature Crack Resistance
For the low-temperature crack resistance of asphalt mixtures, the maximum bending tensile strain of a trabecular beam specimen is generally evaluated when it is destroyed at −10 °C [
36]. The specific test results are shown in
Figure 5. Among them,
Figure 5a reflects the influence of the cement content on the bending strength of the specimen when it is damaged. The maximum bending strain of the specimen when it is damaged is shown in
Figure 5b, and the bending stiffness modulus of the specimen when it is damaged is shown in
Figure 5c. The plots for each parameter provide test results for three different aging conditions.
The test results demonstrate that with increasing M
PC/M
MP, the bending strength and bending stiffness modulus of the trabeculae specimens increased. Meanwhile, with increasing M
PC/M
MP, the maximum bending strain at damage is reduced. As for the bending strength index of the modified asphalt mixture, the influence of cement content on the unaged specimens exhibited an increasing trend, while that on the aged specimens was not considerable. The influence of the cement filler on the bending strength of the modified asphalt mixture will decrease with increasing aging degree.
Figure 5b shows that the test results of the unaged specimens varied gradually with increasing M
PC/M
MP. In the long-term aging test group, this curve exhibited a high slope and the maximum bending strain ε
B declined considerably. Therefore, the addition of cement would considerably decrease the maximum bending tensile strain for a damaged specimen, which would become more evident with prolonged aging.
Figure 5c shows that the bending stiffness modulus increased with the cement content and varied more with prolonged aging.
The low-temperature bending tests demonstrate that the low-temperature cracking resistance of asphalt mixtures with no aging or a small degree of aging varies slightly with an increase in the cement content, which is consistent with existing research results. However, when the asphalt mixture undergoes severe aging, adding cement will make the asphalt mixture brittle to a certain extent, thus reducing the low-temperature cracking resistance of the asphalt mixture.
3.4. Moisture Stability
Freeze–thaw split and water immersion tests are important for evaluating the water stability of asphalt mixtures. In this study, the freeze–thaw splitting strength ratio and the immersion water loss rate were used as the evaluation indices for analyzing the water stability of the asphalt mixture. The specific test results are shown in
Figure 6. Among them,
Figure 6a–c reflects the results of the freeze–thaw splitting test for three different aging conditions. The results of each set include the splitting strength before and after freezing and thawing (
RT1 and
RT2) as well as the TSR.
The freeze–thaw splitting strength ratio TSR serves as an evaluation index for the water stability of the asphalt mixture. The results of the TSR test indicate that the cement substitute mineral powder can improve the water stability of the asphalt mixture; however, its degree of influence is different for different aging conditions. Among them, TSR reached a maximum value when MPC/MMP was 3:1 in the unaged and short-term aging test groups. In the long-term aging test group, there was no difference between MPC/MMP powder in the range of 1:3 to 3:1. Simultaneously, TSR decreased when cement completely replaced the mineral powder. From the results for the long-term water stability of the mixture, MPC/MMP must not exceed 3:1.
The splitting tensile strength represents the breaking strength of the Marshall specimen when subjected to indirect stretching.
Figure 6a shows that the splitting tensile strengths of the unaged mixture (
RT1 and
RT2) reached the maximum value when M
PC/M
MP was 3:1.
Figure 6b,c show that the splitting tensile strengths
RT1 and
RT2 after aging reached the maximum value when M
PC/M
MP was 1:3. It has been corroborated that the aging of the mixture will make it hard and brittle. In this test, with the increase in aging time, the cement content increased, reducing the indirect tensile strength of the asphalt mixture and further aggravating the embrittlement of the mixture. In conclusion, combined with the test results in
Figure 6c, M
PC/M
MP must not exceed 2:2.
3.5. Mechanical Property
Asphalt pavement structures are subjected to driving load, while asphalt mixtures experience the alternating action of pressure and tension. In an engineer’s calculation of a pavement structure, the tensile fatigue failure of the asphalt surface layer is an ultimate failure state. Therefore, analysis of the mechanical properties of asphalt mixtures must be based on their tensile properties. In this study, the effects of different cement–mineral filler systems on the mechanical properties of asphalt mixtures were analyzed using two indices: bending stiffness modulus in the low-temperature bending test and indirect tensile strength in the freeze–thaw splitting test.
Figure 6c shows that the proportional increase of cement content with the aging level will increase the bending stiffness modulus of the mixture. For the long-term aging test group, when the ratio of M
PC/M
MP is higher than 2:2, the bending stiffness modulus of the specimen will increase sharply and directly enter the brittle failure state.
Figure 6c shows that the splitting tensile strength of the specimens before and after freezing–thawing treatment reaches the maximum within the range of M
PC/M
MP from 1:3 to 2:2, and the best resistance is obtained. Thus, for the asphalt mixture with AC-20 gradation and SBS modified asphalt, or another asphalt mixture with similar components and composition, it is suggested that the content of cement not exceed 50% when substituted for mineral powder.