Fabrication of PA-PEI-MOF303(Al) by Stepwise Impregnation Layer-by-Layer Growth for Highly Efficient Removal of Ammonia
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis Method
2.2.1. Synthesis PA Substrate and the Modified Material
2.2.2. Synthesis of PA-PEI-MOF303(Al)
2.3. Characterization Methods
2.4. NH3 Adsorption Performance Test
2.4.1. Adsorption Isotherms
2.4.2. Adsorption Thermodynamics
2.4.3. Dynamic Adsorption Performance Measurements
2.5. In Situ FTIR Spectroscopy Study and Two-Dimensional Correlation Spectroscopic Analysis
3. Results
3.1. Synthesis of PA and PA-PEI
3.2. Synthesis of PA-PEI-MOF303(Al)
3.3. Characterization of PA-PEI-MOF303(Al)
3.3.1. Microstructure
3.3.2. BET Analysis
3.3.3. Thermal Stability
3.4. NH3 Adsorption Tests
3.4.1. Adsorption Isotherms
3.4.2. Adsorption Thermodynamics
3.4.3. Breakthrough Tests
3.5. NH3 Adsorption Mechanism
3.5.1. NH3 Adsorption Stage
3.5.2. NH3 Heating−Desorption Stage
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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BET Specific Surface Area | Micropore Volume | Total Pore Volume | Micropore Size Distribution | |
---|---|---|---|---|
SBET [cm2·g−1] | Vm [cm3·g−1] | Vt [cm3·g−1] | D [nm] | |
PA-PEI | 24.2 | / | 0.22 | / |
PA-PEI-MOF303(Al) | 302.8 | 0.10 | 0.28 | 0.45–0.80 |
Material Type | Sample | NH3 Adsorption Capacity (mmol·g−1) | Regeneration Condition | Reference |
---|---|---|---|---|
MOF | M(NA)2 (M = Zn, Co, Cu) | 6.00–17.50 (298 K) | 423 K for 70 min under vacuum | [73] |
MOF | M-2(INA) (M = Cu, Co, Ni, Cd) | 12.00–13.00 (298 K) | 423 K for 50 min | [74] |
MOF | MOF303(Al) | 19.70 (298 K) | 423 K for 2 h under vacuum | [25] |
COF | COF-10 | 15.00 (298 K) | 473 K for 12 h under vacuum | [15] |
Zeolite | Zeolite-A | 8.39 (295 K) | Vacuum | [75] |
Zeolite | Zeolite-13X | 9.00–9.30 (room temperature) | Not mentioned | [76] |
Activated carbon | Activated carbon | 6.36 (298 K) | 323 K for 5 h under vacuum | [77] |
MOF composite | PA-PEI-MOF303(Al) | 16.07 (298 K) | 423 K for 2 h under vacuum | This work |
Sample | Langmuir | Freundlich | ||||
---|---|---|---|---|---|---|
R2 | R2 | |||||
298 K | 16.07 | 0.2558 | 0.9611 | 4.4901 | 0.3455 | 0.9889 |
313 K | 10.53 | 0.3132 | 0.9637 | 3.0802 | 0.3430 | 0.9950 |
353 K | 7.28 | 0.1815 | 0.9745 | 1.6296 | 0.4042 | 0.9984 |
Temperature (K) | |||
---|---|---|---|
298 | −10.77 | −130.50 | −49.49 |
313 | −8.54 | ||
353 | −3.55 |
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Lan, L.; Yang, X.; Kang, K.; Song, H.; Xie, Y.; Zhou, S.; Liang, Y.; Bai, S. Fabrication of PA-PEI-MOF303(Al) by Stepwise Impregnation Layer-by-Layer Growth for Highly Efficient Removal of Ammonia. Nanomaterials 2023, 13, 727. https://doi.org/10.3390/nano13040727
Lan L, Yang X, Kang K, Song H, Xie Y, Zhou S, Liang Y, Bai S. Fabrication of PA-PEI-MOF303(Al) by Stepwise Impregnation Layer-by-Layer Growth for Highly Efficient Removal of Ammonia. Nanomaterials. 2023; 13(4):727. https://doi.org/10.3390/nano13040727
Chicago/Turabian StyleLan, Liang, Xuanlin Yang, Kai Kang, Hua Song, Yucong Xie, Shuyuan Zhou, Yun Liang, and Shupei Bai. 2023. "Fabrication of PA-PEI-MOF303(Al) by Stepwise Impregnation Layer-by-Layer Growth for Highly Efficient Removal of Ammonia" Nanomaterials 13, no. 4: 727. https://doi.org/10.3390/nano13040727