Study on Green Controllable Preparation of Coal Gangue-Based 13-X Molecular Sieves and Its CO2 Capture Application
Abstract
:1. Introduction
2. Experiment
2.1. Materials
2.2. Methods
2.2.1. Synthesis of Gangue-Based 13-X Molecular Sieve
2.2.2. Characterization
3. Results and Discussion
3.1. Processing and Analysis of Raw Materials
3.1.1. Treatment of Raw Material Gangue
3.1.2. Orthogonal Experimental Design for the Synthesis of 13-X Molecular Sieve
3.2. Evaluation of the Synthesized 13-X Zeolite
3.2.1. X-ray Diffraction Analysis
3.2.2. SEM-EDS Analysis
3.2.3. Specific Surface Area Analysis
3.3. Measured Characteristics of CO2 Adsorption by Gangue-Based 13-X Molecular Sieve
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Oxide | CaO | MgO | SiO2 | Al2O3 | Fe2O3 | TiO2 | K2O | Na2O | Loss |
---|---|---|---|---|---|---|---|---|---|
wt% | 0.82 | 1.57 | 61.39 | 23.76 | 4.14 | 0.79 | 2.82 | 1.62 | 2.11 |
Serial Number | Influence Factor | |||
---|---|---|---|---|
Si/Al (PCG/NaAlO2 Mass Ratio) | Alkalinity (CNaOH(aq))/mol·L−1 | Crystallization Temperature/°C | Hydrothermal Time/h | |
Y1 | 4 | 0.3 | 100 | 8 |
Y2 | 4 | 0.4 | 120 | 10 |
Y3 | 4 | 0.5 | 80 | 12 |
Y4 | 5 | 0.5 | 100 | 10 |
Y5 | 5 | 0.3 | 120 | 12 |
Y6 | 5 | 0.4 | 80 | 8 |
Y7 | 6 | 0.4 | 100 | 12 |
Y8 | 6 | 0.5 | 120 | 8 |
Y9 | 6 | 0.3 | 80 | 10 |
Sample | BET-Specific Surface Area (m2/g) | Average Pore Size (Å) | Pore Volume (m3/g) |
---|---|---|---|
Coal Gangue | 2.04 | — | — |
Y9 | 377.02 | 20.87 | 0.20 |
Commercial 13-X molecular sieve | 523.88 | 18.62 | — |
Temperature (°C) | Langmuir Model | Dual-Site Langmuir Model | ||||||
---|---|---|---|---|---|---|---|---|
qA (mmol/g) | bA (kPa−1) | R2 | qA (mmol/g) | bA (kPa−1) | qB (mmol/g) | bB (kPa−1) | R2 | |
0 | 1.91 | 0.13 | 0.9799 | 1.48 | 0.04 | 0.64 | 0.84 | 0.9995 |
25 | 1.65 | 0.10 | 0.9796 | 1.29 | 0.03 | 0.65 | 0.48 | 0.9994 |
45 | 0.98 | 0.06 | 0.9988 | 0.49 | 0.06 | 0.49 | 0.06 | 0.9988 |
Sample | Adsorption Temperature (°C) | Adsorption Capacity (mmol/g) | References |
---|---|---|---|
zeolite 13-X | 0 | 1.8 | Present work |
Hierarchical melamine resin sponges | 0 | 1.7 | [40] |
β-zeolite | 30 | 1.8 | [39] |
Monolithic Ni/ZSM-5 | 35 | 2.4 | [42] |
Amine-impregnated Silica foam | 25 | 1.48 | [41] |
ZSM-5 | 0 | 2.37 | [43] |
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Yi, D.; Du, H.; Li, Y.; Gao, Y.; Liu, S.; Xu, B.; Huang, H.; Kang, L. Study on Green Controllable Preparation of Coal Gangue-Based 13-X Molecular Sieves and Its CO2 Capture Application. Coatings 2023, 13, 1886. https://doi.org/10.3390/coatings13111886
Yi D, Du H, Li Y, Gao Y, Liu S, Xu B, Huang H, Kang L. Study on Green Controllable Preparation of Coal Gangue-Based 13-X Molecular Sieves and Its CO2 Capture Application. Coatings. 2023; 13(11):1886. https://doi.org/10.3390/coatings13111886
Chicago/Turabian StyleYi, Dawei, Huiling Du, Yefei Li, Yimin Gao, Sifan Liu, Boyang Xu, Haoqi Huang, and Le Kang. 2023. "Study on Green Controllable Preparation of Coal Gangue-Based 13-X Molecular Sieves and Its CO2 Capture Application" Coatings 13, no. 11: 1886. https://doi.org/10.3390/coatings13111886