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Separations, Volume 12, Issue 10

2025 October - 31 articles

Cover Story: The present study optimizes a targeted chromatographic method coupled to mass spectrometry, employing design of experiments, for the determination of 40 organic micro-contaminants with a wide range of polarities. Chromatographic separation was achieved on a pentafluorophenyl column, and a Face-Centered Design was applied for multivariate optimization. Mobile phase flow and temperature were chosen as the study factors, and retention time and peak width as the responses, as indicators of analytical performance. Two optimized runs (for positive and negative electrospray ionization modes) were obtained, enabling the analysis of all analytes in a total of 29 min. The method showed satisfactory sensitivity, precision and specificity and demonstrated to be suitable for routine monitoring of a broad range of emerging contaminants in seawater. View this paper
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Articles (31)

  • Article
  • Open Access
664 Views
12 Pages

19 October 2025

The Free Water Knock Out (FWKO) vessel is a critical device in the oil sands treatment process, responsible for separating water, oil, and gas. This study investigates the gas–oil interface within the FWKO and analyzes the flow characteristics...

  • Article
  • Open Access
1 Citations
728 Views
22 Pages

16 October 2025

A phosphogypsum flotation tailings-derived zeolite (PGTZ) was synthesized from the tailings produced during the reverse flotation of phosphogypsum through alkaline fusion and hydrothermal treatment. The response surface methodology (RSM) utilizing a...

  • Article
  • Open Access
1 Citations
1,255 Views
21 Pages

Vanadium, Titanium, and Iron Extraction from Titanomagnetite Ore by Salt Roasting and 21st-Century Solvents

  • Emmanuel Anuoluwapo Oke,
  • Johannes Hermanus Potgieter,
  • David Nkhoesa and
  • Lizelle Doreen van Dyk

15 October 2025

Vanadium is a strategic metal with critical applications in steel alloys, aerospace, chemical catalysis, and energy storage. However, conventional extraction methods such as high-temperature salt roasting are energy-intensive and environmentally chal...

  • Article
  • Open Access
678 Views
19 Pages

Adsorption of Platinum from Alkaline Glycine–Cyanide Solutions Using Activated Carbon: Leachates, Water, and Waste Treatment Applications

  • Caroline Rubina Acuna,
  • Elsayed A. Oraby,
  • G. A. Bezuidenhout,
  • Chau Chun Beh and
  • Jacques J. Eksteen

13 October 2025

Platinum’s unique properties, such as its high resistance to corrosion and high temperatures, are driving an increased use in modern technologies and advanced chemistry. However, the World Platinum Investment Council has projected, for the thir...

  • Review
  • Open Access
1,453 Views
28 Pages

Functionalized Carbon-Based Materials for Uranium Extraction: A Review

  • Maqbool Hussain,
  • Liang Zhao,
  • Xusheng Zhang,
  • Chen Yang,
  • Yi Cui,
  • Zhisheng Yu and
  • Jianzhong Zheng

13 October 2025

The development of effective materials for uranium extraction from seawater is vital for advancing sustainable energy solutions. However, the efficient recovery of uranium from seawater presents significant challenges due to its extremely low concent...

  • Article
  • Open Access
1,740 Views
20 Pages

Phenolic Compounds in Plant-Based Milk Alternatives from the Greek Market

  • Velisaria-Eleni Gerogianni,
  • Christiana Mantzourani,
  • Maria A. Theodoropoulou,
  • Antonia Chiou and
  • Maroula G. Kokotou

11 October 2025

Plant-based milk alternatives (PBMAs) are plant-based fluid products that are marketed as substitutes for regular milk. The nutrient composition of PBMA products can vary widely, depending on the plant source, processing methods, potential additives,...

  • Article
  • Open Access
497 Views
12 Pages

Study on the Emission Characteristics of Fine Particulate Matter in the White Mud Desulfurization Process

  • Changqing Wang,
  • Yongchao Feng,
  • Xin Wang,
  • Rongliang Xie,
  • Guanglei Li,
  • Li Yu and
  • Lingxiao Zhan

11 October 2025

White mud is a promising desulfurizing agent, but the risk of fine particulate emissions exists during its application. This study investigated the fine particulate emissions in the white mud desulfurization process and analyzed the effects of proces...

  • Review
  • Open Access
688 Views
18 Pages

11 October 2025

Artemisia frigida Willd. (A. frigida), a traditional medicinal herb widely distributed in northern China, Mongolia, and Siberia, has garnered increasing scientific interest due to its diverse phytochemical profile and extensive pharmacological potent...

  • Article
  • Open Access
1,259 Views
11 Pages

Ultrasound-Assisted Extraction Optimization and Flash Chromatography Fractionation of Punicalagin from Pomegranate Peel (Punica granatum L.)

  • Erick M. Raya-Morquecho,
  • Pedro Aguilar-Zarate,
  • Leonardo Sepúlveda,
  • Mariela R. Michel,
  • Anna Iliná,
  • Cristóbal N. Aguilar and
  • Juan A. Ascacio-Valdés

11 October 2025

Background: Pomegranate peel (Punica granatum L.) is a rich source of phenols, particularly ellagitannins, highlighting punicalagin, a bioactive compound with recognized antioxidant potential. However, efficient recovery and purification methods are...

  • Article
  • Open Access
927 Views
14 Pages

10 October 2025

This research presents the study of utilizing the cocoa husk biomass waste to obtain active carbon through carbonization method, followed by chemical–thermal activation. The activated carbon (CH) was characterized using BET, SEM–EDX, XPS,...

  • Article
  • Open Access
791 Views
22 Pages

10 October 2025

Biologically treated swine farm wastewater still contains high levels of refractory organics, humic substances and antibiotic residues, posing environmental risks and limiting opportunities for water reuse. Wastewater treatment by ozonation alone suf...

  • Article
  • Open Access
1,219 Views
10 Pages

Background: Histone post-translational modifications (PTMs) play a pivotal role in the regulation of chromatin structure and gene expression, making them key targets in structural and epigenetic research. Synthetic histone peptides bearing specific P...

  • Article
  • Open Access
869 Views
18 Pages

The development of efficient and sustainable advanced oxidation processes (AOPs) for organic pollutant removal is of great significance for water purification. In this study, a CoFeNi-layered double hydroxide (CoFeNi-LDH) catalyst was synthesized and...

  • Article
  • Open Access
797 Views
20 Pages

Process Design and Optimisation Analysis for the Production of Ultra-High-Purity Phosphine

  • Jingang Wang,
  • Yu Liu,
  • Jinyu Guo,
  • Shuyue Zhou,
  • Yawei Du and
  • Xuejiao Tang

With the increasing demand to scale the chip industry, attention is turning to the vital role that phosphanes and silanes play in semiconductor manufacturing processes such as chemical vapor deposition, plasma etching, and impurity doping. High-perfo...

  • Article
  • Open Access
1 Citations
2,593 Views
16 Pages

Since H2O and Ethylene Glycol Monomethyl Ether (EM) form a minimum-boiling azeotrope, 1-pentanol, 1-hexanol, and 1-heptanol are selected as entrainers to separate the azeotropic mixture (H2O/EM) using azeotropic distillation. The binary vapor liquid...

  • Article
  • Open Access
849 Views
16 Pages

Nitrous oxide (N2O), a potent greenhouse gas, is an important environmental concern associated with biological nitrogen removal in wastewater treatment plants. Anaerobic ammonium oxidation (anammox), recognized as an advanced carbon-neutral nitrogen...

  • Article
  • Open Access
490 Views
12 Pages

The Influence of Y2O3 Nanoparticles on the Permeation Properties of Polyethersulfone Membranes

  • Andreea Liliana Lazăr,
  • Adrian Cîrciumaru,
  • Gina Genoveva Istrate,
  • Eliza Dănăilă and
  • Ștefan Baltă

Y2O3 nanoparticles were used in a polyethersulfone (PES) as additives to increase the permeation properties of the polymeric membranes. Membranes were manufactured by diffusion-induced phase inversion in N-methyl-pyrrolidone (NMP) using a different c...

  • Article
  • Open Access
679 Views
17 Pages

Adsorption of Cr(III) by IRA-900 Resin in Sodium Phosphite and Sulfuric Acid System

  • Tingjie Xu,
  • Dahuan Gan,
  • Guowang Wei,
  • Yingjie Yang,
  • Qiankun Wei and
  • Chunlin He

Chromium (Cr), a toxic heavy metal, poses significant environmental and health risks when industrial effluents containing Cr are discharged untreated. Addressing this challenge, this study developed a selective chromium removal strategy using IRA-900...

  • Article
  • Open Access
2 Citations
800 Views
23 Pages

Ultrasound-Assisted Deep Eutectic Solvent Extraction of Flavonoids from Cercis chinensis Seeds: Optimization, Kinetics and Antioxidant Activity

  • Penghua Shu,
  • Shuxian Fan,
  • Simin Liu,
  • Yu Meng,
  • Na Wang,
  • Shoujie Guo,
  • Hao Yin,
  • Di Hu,
  • Xinfeng Fan and
  • Jihong Huang
  • + 6 authors

This study establishes an efficient and eco-friendly ultrasound-assisted extraction (UAE) method for total flavonoids present in Cercis chinensis seeds using natural deep eutectic solvents (NADES). Among nine NADES formulations screened, choline chlo...

  • Article
  • Open Access
2 Citations
1,350 Views
14 Pages

Variations in Quantitative Composition of Phenolic Compounds in Flowers, Leaves, and Fruits of Mespilus germanica L. During Harvesting Period

  • Jelena Nikolić,
  • Vesna Stankov Jovanović,
  • Jovana Pavlović,
  • Milica D. Nikolić,
  • Ana Barjaktarević,
  • Ksenija Obradović and
  • Milan Mitić

The medlar (Mespilus germanica) is a deciduous tree that belongs to the Rosaceae family. This plant has been valued throughout history for its culinary uses and medicinal applications. Medlar fruit contains a high amount of vitamin C, carbohydrates,...

  • Article
  • Open Access
2 Citations
630 Views
20 Pages

The application of microsphere molecularly imprinted materials for the targeted extraction and purification of flavonoids derived from agricultural waste has emerged as a prominent area of investigation. An innovative boronate affinity imprinted micr...

  • Article
  • Open Access
2 Citations
1,025 Views
33 Pages

Mineral Extraction from Mixed Brine Solutions

  • M. A. Salman,
  • M. Ahmed,
  • H. Al-Sairfi and
  • Y. Al-Foudari

Sulfate minerals (SMs), such as BaSO4, SrSO4, and CaSO4, precipitate when incompatible solutions from the oil industry, such as seawater (SW) and high-salinity brine solutions (HSBSs), are mixed during the oil production process. To investigate the p...

  • Article
  • Open Access
606 Views
22 Pages

Development of a Green Extraction Process from Residues of Assyrtiko Wine Production for Cosmetic Applications

  • Styliani Kalafateli,
  • Agni-Areti Freri,
  • Georgios Stavropoulos,
  • Andromachi Tzani and
  • Anastasia Detsi

30 September 2025

Vitis vinifera L. cultivar, “Assyrtiko”, is a famous grape variety native to Santorini island. Its wine production residues are rich in bioactive polyphenols, making them valuable for extraction and use in cosmetics. The aim of this work...

  • Article
  • Open Access
965 Views
15 Pages

Wastewater Sludge Dewatering Enhancement by Flocculant Selection and Electrochemical Pretreatment

  • Binbin Yang,
  • Yingxue Sun,
  • Quanze Liu,
  • Xiaobo Wang and
  • Xiaolei Zhang

27 September 2025

In wastewater treatment, sludge is generated during both the primary and secondary sedimentation processes. With the growing volume of wastewater, sludge production has increased accordingly. Prior to subsequent treatment or disposal, sludge dewateri...

  • Article
  • Open Access
789 Views
16 Pages

Bone Density Assessment Through Sodium Poly-Tungstate Gradient Centrifugation: A Preliminary Study on Decades-Old Human Samples

  • Barbara Di Stefano,
  • Chiaramaria Stani,
  • Giorgio Marrubini,
  • Barbara Bertoglio,
  • Solange Sorçaburu Ciglieri,
  • Serena Bonin,
  • Carlo Previderè,
  • Giovanni Birarda and
  • Paolo Fattorini

27 September 2025

Bone density is considered one of the many factors influencing bone structure and DNA preservation. For this reason, it is of interest in fields such as anthropology, palaeontology, and genetics. This study describes a method for bone density assessm...

  • Article
  • Open Access
720 Views
15 Pages

Enhanced Electro-Dewatering of Sludge Through Inorganic Coagulant Pre-Conditioning

  • Xiaoyin Yang,
  • Song Huang,
  • Yusong Zhang,
  • Hanjun Wu,
  • Yabin Ma and
  • Bingdi Cao

26 September 2025

Sludge electro-dewatering technology is an attractive dewatering technology, but its application is limited by high energy consumption and filter cloth clogging caused by the dissolution of extracellular polymeric substances (EPSs). Thus, the additio...

  • Article
  • Open Access
1,220 Views
14 Pages

24 September 2025

The inevitable ubiquity of natural organic matter (NOM) in all waters presents a challenge to the proper functioning of water treatment processes. Therefore, minimizing NOM in raw water is crucial to avoid operational issues in subsequent treatment s...

  • Article
  • Open Access
1,324 Views
14 Pages

24 September 2025

Chlorinated aliphatic hydrocarbons (CAHs) are some of the most widely distributed organic pollutants in underground environments and have high biological toxicity. This research aims to prepare an effective adsorbent comprising biochar and magnetite...

  • Article
  • Open Access
20 Citations
1,180 Views
14 Pages

Efficient Adsorptive Removal of Phosphonate Antiscalant HEDP by Mg-Al LDH

  • Changjin Guo,
  • Lejiaqi Zhang,
  • Qi Zhang,
  • Congcong Ni,
  • Ning Deng and
  • Xin Huang

24 September 2025

Phosphonate-based antiscalants such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP) are extensively employed in industrial water treatment but pose significant environmental challenges due to their persistence and phosphorus content. In this study, M...

  • Article
  • Open Access
1 Citations
671 Views
15 Pages

Eco-Friendly Dye Removal: Black Cumin Seed Press Cake for Toluidine Blue Adsorption

  • Galia Gentscheva,
  • Paunka Vassileva,
  • Christina Tzvetkova,
  • Aleksandar Pashev,
  • Ina Yotkovska,
  • Metodi Mladenov and
  • Tsvetan Vassilev

23 September 2025

This research investigates the potential of Seed Press Cake of Nigella sativa (SPCN) as a low-cost, eco-friendly biosorbent for the removal of the cationic dye Toluidine Blue (TB) from aqueous solutions. The physicochemical properties of the material...

  • Article
  • Open Access
1,989 Views
18 Pages

23 September 2025

The present study develops and optimizes a targeted chromatographic method coupled with mass spectrometry, employing design of experiments, for the determination of several emerging contaminants in environmental waters. Their widespread presence pose...

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Separations - ISSN 2297-8739