1. Introduction
The global steel industry stands as a cornerstone of modern civilization, serving as the backbone of infrastructure, manufacturing, and technological advancement. The rising demand for high-quality steel products with precise characteristics has prompted ongoing innovations and advancements in steelmaking industry. Secondary steelmaking processes, a vital stage following primary steel production, have emerged as a critical avenue for refining and enhancing steel properties [
1]. In particular, the intrinsic part of gas stirring has garnered significant attention in recent years. It entails injecting an inert gas into the molten metal to achieve uniform mixing to facilitate the homogenization of the chemical composition of different alloy elements and the removal of inclusions from the molten steel [
2]. The implementation of stirring aids elevates the caliber and purity of the steel, enhancing its mechanical attributes and minimizing defects in the final product. Turbulence, driven by the injection of inert gas, stirs the molten metal vigorously, facilitating efficient mass transfer and promoting uniform distribution of alloying elements. This dynamic mixing action intensifies the interaction between the molten steel and the slag, a process can further amplified by the distinctive depression of the slag eye. This intensified interaction zone becomes a hotspot for chemical reactions, promoting the removal of undesired impurities and inclusions from the steel, which are buoyed to the surface and subsequently removed through slag formation [
1,
3]. Therefore, the flow turbulence can aids in achieving the desired steel characteristics though the formation of the slag eye, enhances its purity, consistency of mechanical attributes, and overall quality in the final product. Over the past few decades, researchers have extensively studied the slag eye formation under laboratory conditions. And dynamically- scaled water model apparatus have been applied, which involves using water at room temperature instead of molten steel. Water at room temperature has the similar kinetic viscosity to molten steel [
4], and thus the properly scaled water ladle apparatus is a suitable physical model to be studied for understanding the related flow process inside steel ladles.
Szekely et al. [
5] first proposed a simplified water model to study the flow characteristics of a ladle by injecting gas from the bottom, assuming a constant bubble size, and using Spalding’s k-ω model to solve the Navier-Stokes equations for velocity and turbulence predictions. The model was developed to simulate the thermal and flow behavior of molten steel during the pouring process using a water ladle, offering a simple and effective way to predict the behavior of molten steel during pouring process. Debroy et al. [
6] improved Szekely’s model by refining the bubble model and accounting for the effects of turbulence and bubble coalescence. These added terms helped to predict the behavior of bubbles more accurately in the liquid metal and their impact on the mixing and refining of the steel. Johansen et al. [
7] furthered the research by discovering that bubbles can create turbulence and affect flow velocity in the bubble plume region thus a bottom injection water model was adapted. Peranandhantan et al. [
8] conducted an experiment to study the behavior of the slag eye in a ladle during steelmaking process by injecting air into a ladle filled with water and various fluids to simulate the injection of gas into molten steel. The size and shape of the slag eye were then measured using a high-speed photography and image analysis techniques. Based on their observation from tested multiple variables, including gas flow rate, slag thickness and liquid depth, an empirical expression was derived to formulate the slag eye size in terms of gas flow rate, the ladle dimension, gravity, surface tension, and the momentum of the gas bubbles. Mazumdar et al. [
9] reviewed several studies related to the physical modeling and empirical correlation of gas-stirred ladle, highlighting the impact of various variables involved in the gas-stirring process, specifically the plug positions.
Several researchers experimented with changing the plug positions in their water ladle model to achieve a better mixing and wall shear stress distribution [
9,
10,
11]. It is argued that plug design can change the bubble size distribution close to the plug, but not the average size and distribution in the whole ladle [
8,
12,
13,
14]. The study conducted by Gajjar et al. [
15] delve into the influence of injector design on turbulence within ladle metallurgy processes, investigating how different injector designs affect the level and characteristics of turbulence in the flow. In 2019, Owusu et al. [
16] used Particle Image Velocimetry (PIV) to investigate the behavior of bubbles and their effect on turbulence kinetic energy (TKE) on the cross-sectional plane of the water ladle. So far, many researchers have used PIV to study the flow field in water ladle models, but only the flow field on two-dimension planes were resolved.
Therefore, in this study, to further investigate the three-dimensional internal flow field in a water ladle model of a cylindrical container, a Particle Tracking Velocimetry system with refractive index matching is implemented to quantify the unsteady/three-dimensional flow field while eliminating the particle imaging distortion. Such study cannot only improve our understanding of the complex flow behavior in gas-stirred ladles but also can be used to validate the CFD simulation models.
2. Materials and Methods
Based on an industrial steel refining ladle, a cylindrical water ladle model is designed and built. The dimensions and parameters of the industrial prototype and the downscaled water ladle are summarized in
Table 1. Four typical flow rates of gas injection on the industrial ladle is also presented. To maintain a dynamic similarity on the Froude number, the flow rates of gas injection on water ladle model are calculated and determined, ranging from 0.1 L per minute to 0.4 L per minute. Although, we were able to keep a very similar Froude number between the industrial prototype and water ladle model, the Reynolds number are different remaining a considerable challenge of achieving a complete dynamic similarity. Equation (1) is utilized for estimating the Froude number, where
Up is the velocity of the plume and
H is the height of the molten steel/solution. Plume velocity
Up is calculated with the Equation (2), where
Q is the volumetric flow rate of the gas injection,
R is the radius of the ladle/model [
17].
Consequently, in this experiment, eight conditions of gas stirring/injection with a volumetric flow rate ranging from 0.1 L per minute (LPM) to 0.4 LPM were adopted. An overview of the experimental conditions is presented in the
Table 2. Since two plugs are geometrically identical and symmetric to each other, therefore for single gas injection the same plug (plug 2) was used to inject the gas for the cases 5–8.
2.1. Cylindrical Water Ladle Model and Refractive Index Matching
In this experiment, a cylindrical container with an inner diameter of 70 mm is implemented to simulate and replicate the characteristics of a cylindrical ladle (To avoid NaI solution spill onto the high-speed cameras and Laser a tall cylindrical wall of 178 mm is implemented). However, due to the curved surface of the cylindrical container that would introduce significant particle image distortion from refraction, the conventional flow field measurement methods, such as Particle Image Velocimetry and Particle Tracking Velocimetry, cannot be directly implemented to measure the flow field. Therefore, this study adopted the refractive index matching method to counteract the effects of image distortion due to refraction. Additionally, to capture and film the particle images from four different perspectives, a four-camera particle tracking velocimetry system was strategically configured on a larger hexagon tank with six flat walls meticulously designed to accommodate the angle of imagining. This larger hexagon tank was designed to allow the cameras to film the flow inside the cylindrical tank, which was positioned at the center of the larger hexagon tank, with the cameras filming perpendicular to the flat walls. Both tanks were fabricated from plexi-glass. To ensure optimal refractive index matching and thereby minimize image distortion, a Sodium Iodide solution was prepared and used to fill the tanks to a height of 84 mm. Importantly, the refractive index of the Sodium Iodide solution closely aligns with that of plexi-glass, ensuring minimum light refraction as the scatted light from the seeding particles traverses the curved plexiglass walls and the solution, eliminating particle image distortion when the Particle Tracking Velocimetry is employed. During the experiment, the compressed gas is introduced to the cylindrical tank through two 4.7 mm circular plugs at the bottom of the tank. The plugs sat on the centerline of tank with a distance of 40 mm. Two mechanical flow meters with an accuracy of 0.02 L per minute (Brooke Instrument, Hatfield, UK) were utilized to measure and monitor the flow rate of the compressed gas during the experiments.
2.2. Particle Tracking Velocimetry System
The state-of-the-art: Shake-the-Box system (Lavision, Gottingen) was implemented on the cylindrical water ladle model, which inject compressed air to stir the flow. To accurately track the intricate gas-stirred water flow within the water ladle model, hollow glass spheres with a diameter range of 8 to 12 μm were used as seeding particles. To capture the seeding particles in the flow field and film the particle images, a high repetition rate laser (Nd: YLF single cavity, Photonics DM-30-527) and four high-speed cameras (Phantom VEO 640), were strategically positioned on two sides of the experimental setup (See
Figure 1a,b). Lenses (Tokina Macro) with a focal length of 100 mms and aperture size of f/4.5 and f/11 were incorporated into the imaging system to facilitate capturing particle images within the flow field. To ensure optimal illumination and imaging, cylindrical optical lenses were added to the laser head, generating a 20 mm thick laser light that penetrated the walls and illuminated the inner cylindrical tank from the side. The sampling frequency of the images/laser was set at 100 Hz, with an image resolution of 1024 × 1024 pixels maintained across all four high-speed cameras, enabling a flow measurement volume of 57 mm × 62 mm × 19 mm that locates between the plugs and 18 mm above the bottom of the tank (See
Figure 1c). For each testing condition (see
Table 1), on each high-speed camera, the maximum number of 2000 image/data samples were collected over a time duration of 20 s. During the experiment, the gas injection was started at least 2 min before the data collection (image collection with laser illumination) with a 5 min break between each case of data collection.
The software Davis 10 (LaVision, Gottingen, Germany) was employed for calibration, data collection, and velocity field constructions. To achieve accurate calibration, a 55 × 55 mm calibrate target was positioned within the Sodium Iodide solution, allowing for the acquisition of calibration images. Calibration was performed in the Davis 10 using four images of the target. On each data set of collected particle images, for enhanced accuracy in sub-pixel measurements and to facilitate volumetric flow field measurement, volume self-calibration was incorporated during the final calibration. The Shake-the-Box algorithm (LaVision, Gottingen, Germany) was then used to carry out the particle reconstruction/tracking on each data set by shaking the particle position by 1 voxel during the iterations. The culmination of these process involves the reconstruction of the instantaneous volumetric velocity field through post-processing within Davis 10. This resulted in three 13 × 14 × 5 matrices, each representing volumetric velocities along the three dimensions with a spatial resolution of 4.7 mm/velocity vector. For a more in-depth understanding of Shake-the-Box algorithm and its principle, please refer to Schanz et al. [
20].
4. Summary and Discussion
Through the analysis of the velocity field within the volumetric flow of the water ladle model using mean velocity magnitude (as discussed in
Section 3.1), streamlines (as outlined in
Section 3.2), and turbulent kinetic energy (as outlined in
Section 3.3), a consistent trend has emerged and can be confirmed across multiple figures. In the context of double gas injection, a clear flow trend emerges as the gas injection rate increases. This flow trend is characterized by the extension of high velocity concentration from the top to the bottom in the vertical direction and higher fluid velocity magnitudes throughout the entire volumetric region. Particularly, in considering the vertical velocity and velocity magnitude, this trend is more prominent, suggesting the uneven fluid motion at the top under the stirring of gas injections. This has exceptional importance as critical processes, such as desulfurization, takes place at the interface between the molten steel and slag. Furthermore, when the flow rate is increased from 0.1 to 0.2 L per minute, the flow field shifts from an organized and structured mean velocity field pattern to a disorganized one. This transition is clearly illustrated in the volumetric distribution of vertical velocity plot in the
Figure 2. As the flow rate continues to rise, the disorderly flow pattern persists, accompanied by a notable elevation in velocity magnitude across flow region. This progression of irregular and asymmetrical flow patterns with increasing gas flow rates is further underscored by a particularly vivid visual representation of
Figure 4 of the mean 3D streamline plots.
With the gas injection flow rate elevated from 0.1 to 0.2 L per minute, the previously symmetrical, organized, and predominantly vertical streamlines evolve into irregular and predominantly horizontal flow pattern. While the effect is less pronounced, another transition occurs as the flow rate is further increased to 0.3 L per minute. This shift is evident in the changing orientations of the streamlines, which regain a more vertical alignment. Upon examination of the mean velocity streamlines at various planes, additional confirmation of the observed trends is confirmed in
Figure 5 and
Figure 6.
Figure 5 solidifies the depiction of a highly organized and structured flow pattern at the low double gas injection rate of 0.1 L per minute. Intriguingly, it becomes apparent that despite gas injection aiming to introduce upward momentum, downward flow dominates the measured flow field at the low gas injection rate of 0.1 L per minute. A focused analysis of the streamlines and mean velocity across stream-slices reveals the concentration of low velocity around the focal point on frontal plane (
Figure 5c). The presence of this low velocity spot in the mean velocity field is unwanted, as it leads to fluid accumulation, hindering the efficient fluid mixing process. Raising the gas flow rate to 0.3 L per minute, the dominant flow momentum alters from downward to upward while exhibiting reduced outward curvature (
Figure 6). Furthermore, high velocity concentrations become more prevalent across all planes. These trends suggest that higher gas flow rates could be advantageous in attaining the desired flow uniformity and mitigating the accumulation of stagnant fluid.
For single gas injection in
Figure 3, however, increasing the gas flow rate does not introduce changes in location of contour concentration. Instead, it augments overall magnitude of velocity while maintaining a consistent contour pattern. As flow rate increases, the contour patterns of high velocity regions become sharper and more pronounced, suggesting the mean velocity field becomes more concentrated. Additionally, in
Figure 4, streamlines under single gas injection consistently lack orderly structure across all flow rates. They display a disorganized and irregular flow pattern marked by random flow directions and clusters of streamline concentration. This observation is further verified through the examination of the 2D mean velocity streamlines plots in
Figure 7 and
Figure 8.
Figure 7 confirms the presence of a disorganized flow pattern, lacking a dominant flow momentum direction. This complexity could be attributed to the existence of multiple nodal, focal, and saddle points. Moreover, the flow field is primarily characterized by low velocity concentration, indicating the potential for stationary fluid within the volume under single gas injection with low flow rate. With the gas flow rate increased to 0.4 L per minute, as demonstrated in
Figure 8, the flow maintains its disrupted nature without a prevailing momentum direction. However, the concentration of high velocity becomes more intense and extended, encompassing the outer boundaries and enhancing fluid bulk motion. By contrasting the effects of double and single gas injections, distinct flow differences become evident.
Figure 4 illuminates the evolution of the streamlines for double and single gas injections.
As the flow rate increases, double gas injections tend to align the streamlines more within the vertical orientation, whereas single gas injections continue to exhibit fluid motion in multiple directions. Additionally, single gas injections manifest more concentrated streamline groups, while double gas injections maintain a more uniform distribution throughout the region. The volumetric contour plots of turbulent kinetic energy further support our observation from the mean velocity field plots. At condition 1, with double gas injection at a low flow rate of 0.1 L per minute, the turbulent kinetic energy distribution is significantly low at the range of 0~0.003 m2/s2 while the turbulent kinetic energy plot for other conditions rise to much higher value in the range of 0~0.3 m2/s2 with higher TKE value distribution in other double gas injection cases and lower TKE value distribution in single gas injection cases, implying a fundamental flow behavior difference between the condition 1 and other conditions which can be correlated to the laminar and turbulent flow. With double gas injections at low flow rate, the fluid inside the cylindrical container is stirred but still able to maintain at laminar flow regime. However, at higher flow rate or single gas injection, the fluid inside the container is turned into turbulent when more momentum and asymmetry are added to the flow.
Therefore, to achieve the homogenization of the molten steel inside a real gas stirred steel refining ladle, a high flow rate and single (asymmetrical) gas injection should be implemented to introduce desired turbulent flow inside the ladle. In gas stirred refining ladles, the process of injected argon bubbles rising stirs the molten steel, promoting uniform composition and temperature, reducing segregation, and facilitating the removal of inclusions. In essence, ladle argon blowing serves to clean the molten steel, decrease hydrogen, oxygen, and nitrogen levels, enhance temperature and composition uniformity. In this study, the implementation of advanced Particle-Tracking-Velocimetry systems, particularly the Shake-the-Box method, on a cylindrical water ladle model, provided great insights into the three-dimensional flow field, illuminating the nuances of gas stirring, crucial for achieving desired steel quality.