3.4.1. Group I: Sensors for the Measurement of Individual Parameters
This group comprised patents disclosing sensors for the detection or measurement of (a) fruit safety parameters, (b) fruit firmness, (c) fruit composition, (d) fruit damage, (e) fruit size and shape and (f) gaseous phase surrounding or produced by the fruit.
(a) Fruit safety: hazardous compounds from the environment, including heavy metals and residues from inputs for agricultural production such as pesticides increase public concern related to health risks, with agricultural production positioned as a source and the most critical stage for transmitting food safety problems along the supply chain [
23]. Mitigating the risks of chemical hazards such as pesticides, heavy metals and microbial pathogens requires rapid screening methods [
24].
In the observed portfolio, a significant number of patents focused on pesticide and heavy metal detection (
Table 3). Patents related to pesticide detection employed various sensors, including aptamer sensors, molecularly imprinted electrochemical sensors, fluorescent array sensors, ratio fluorescence sensors, photonic crystal sensors and sensors based on nanomaterials. The methods of detection included electrochemical, fluorescence, photonic crystal and adhesive tape methods.
In contrast to traditional food safety approaches, some inventions in the portfolio were designed to be handheld. Additionally, some patents described the sensor production process, with their intended use for various devices.
(b) Fruit firmness: one of the properties characterizing changes in fruit is the loss of firmness [
25]. Nondestructive methods of measuring fruit firmness have gained popularity in recent years, as they allow fruit quality to be assessed without causing damage [
26]. Nondestructive fruit firmness sensors have the potential to determine ripeness and quality objectively and efficiently [
27].
Patented inventions related to fruit firmness testing are numerous, and include both destructive and nondestructive methods (
Table 4). Some patents revealed innovations in firmness testing through traditional destructive approaches, while the majority explored nondestructive methods. Nondestructive methods involve various sensors, including acoustic vibration sensors, piezoelectric beam sensors and multisensor solutions. Two patented inventions incorporated flexible finger sensors. Some patents in this domain described components of firmness testing devices without specifying the type of sensor, enabling the devices to be upgraded with any firmness sensor solution. These patents addressed firmness measurement for specific fruits such as apples, pears, kiwis, watermelons and spherical fruits and vegetables in general.
(c) Fruit composition: timely and accurate information on fruit composition is relevant in several aspects. Fruit composition determines its maturity and related storability [
28,
29], nutritive profile [
30], acceptability for consumers [
31] and its value as raw material for processing [
32]. Information regarding changes in the composition of metabolites during fruit processes provides valuable input for fresh fruit supply chain optimization [
33].
Patents in the domain of fruit composition testing primarily utilized near-infrared spectroscopy (NIRS) and multispectral imaging for nondestructive measurement of the sugar content in various fruits, including oranges, apples and others (
Table 5). Inventions aimed at detecting sugar in fruits encompassed those designed for measuring its content in oranges as well as fruit in general. The analyzed patent portfolio also encompassed inventions for determining several compounds that were important for fruit production, management or processing. Examples included waxberry fruit acidity testing, electrochemical sensors for detecting indoleacetic acid and salicylic acid in tomatoes, ascorbic acid estimation in fruits, immunosensors for detecting capsaicin in peppers and molecularly imprinted electrochemically modified electrodes for measuring gibberellin and detecting nitrate and moisture content in fruits.
(d) Fruit defects: mechanical injuries occur during production, harvesting, handling and postharvest stages in fruit supply chains, and internal physical or pest-related damage highly influences the market value and storability of fruit [
34]. The development of nondestructive measurement techniques for assessing fruit damage can help in quality evaluation and in preventing economic losses [
35].
Inventions related to fruit damage testing utilized a variety of sensors, including acoustic, time-resolved fluorescence spectroscopy, machine vision, microwave and thermal sensors (
Table 6). These patented innovations included devices for detecting frostbite in apples, defects in fruit appearance, defects in fruits and vegetables and decay. Notably, all damage assessment inventions employed nondestructive methods, allowing for multiple measurements on a single fruit and enabling the monitoring of damage development. The use of acoustic and machine vision sensors was demonstrated in apple-related applications, while microwave and thermal sensors were designed for more general fruit and vegetable testing.
(e) Fruit size and shape: the ability to assess and detect fruit size and shape in real-time for bulk quantities of fruit is crucial to maximize market value [
36] and is indispensable for efficient fruit grading and packaging [
37].
All patented inventions for fruit assessment were nondestructive (
Table 7). A laser sensor-based solution involved the measurement of distances and the creation of 3D models. A color sensor-based solution assessed fruit appearance using advanced color analysis. A weight sensor-based solution indirectly estimated size based on weight. A spectrometer-based solution analyzed the reflected light spectrum for size and quality evaluation, while a camera-based solution captured images for automated size and shape analysis. Displacement sensor-based solutions measured position variations to evaluate fruit size and shape. The relevance of these sensors varied based on the specific type of fruit. For example, a weight sensor was commonly used for pomelos, as their size and weight are closely related. A color sensor was well-suited for tangerines, for which color is a critical indicator of quality. Grapes, on the other hand, benefited from camera technology due to their small size and the need for bulk assessment. Laser sensors and displacement sensors were applied to various fruits to capture detailed shape variations. All disclosed sensing technologies facilitated quality control and ensured consistent standards across fruit types.
(f) Analysis of composition of gases: an analysis of the gas composition in the environment where fruit is stored or the gases produced by fruit can provide comprehensive insight into fruit processes including ripening [
38], respiration [
39] and quality deterioration [
40,
41], and enable precise implementation of various postharvest measures [
42] and treatments [
43]. A range of specialized devices and methods for the detection of ethylene and other gases have been patented.
Ethylene sensors were featured in several patents, including one that introduced a method and device for measuring ethylene concentration in fruit samples, another that described a portable ethylene-detecting instrument for enhanced convenience in ethylene level monitoring, one that presented an ethylene gas sensor and a method for efficient detection, one focusing on selective detection with a gas sensor that can identify acetylene and ethylene, and one that utilized a nano-sized composite film for ethylene detection (
Table 8). Conversely, there were patents that focused on methods for detecting multiple gases with broader applications. One patent described a semiconductor gas sensor and a gas sensing method that can detect various gases, such as hydrogen, carbon monoxide and nitrogen dioxide. Another introduced a gas sensor designed to detect a range of gases including methane, propane and butane, while another presented a comprehensive gas sensor system that can detect various gases including carbon dioxide, methane and propane.
3.4.2. Group II. Sensor Based Determination of Complex Properties
This group comprised patents disclosing sensor-based solutions that enable the assessment of complex fruit properties such as (a) changes in fruit quality, (b) ripeness and maturation processes and (c) freshness and deterioration.
(a) Fruit quality is a multifaceted attribute that is unique to each fruit, and even each cultivar, which requires the evaluation of various parameters to determine overall desirability [
44]. Quality is a critical attribute influencing consumer acceptance. Fruit quality is assessed based on parameters such as size and shape, uniformity [
36], firmness [
25], absence of visible or hidden defects [
35], skin and flesh color [
45], taste, flavor and aroma [
41], soluble solid content, acidity, pH and other aspects to do with nutritive value, storability and processing properties. Assessing fruit properties along the supply chain enables suppliers to deliver high-quality, safe produce to consumers [
46].
Patents targeting the complex assessment of fruit quality rely on two approaches. The first approach involves the use of sensing techniques that provide signals based on which aspects of fruit quality are being assessed (
Table 9). Most of the disclosed inventions were based on optical methods. Patents included methods for measuring the near-infrared spectral area, visible light area or a combination of both. Patents in this group included the use of laser light sources, electroluminescent diodes or other light sources. Data obtained at different wavelengths were further processed to obtain values related to internal fruit quality, in some cases expressed as a combination of common quality parameters such as firmness or brix, and in other cases, in the form of indices such as a maturity index or fruit grading criteria for example, good/bad or ripe/not ripe. In addition to spectroscopic methods, approaches using color, acoustic or vibration sensors for quality assessment were also disclosed, but the number of patents describing such solutions was much lower.
The second group of sensor-based solutions for complex quality assessment were solutions that integrated multiple sensors for measuring different fruit properties that operated on different sensing principles. The combinations of sensors in the disclosed inventions were quite diverse and included, for example, (i) spectrograph, light source, photoelectric sensor and camera; (ii) CCD camera and position sensor; (iii) weighing sensors, three-dimensional camera, laser projector and color sensor; (iv) gas sensor array and visual sensor; (v) camera and multiple sensors; (vi) gas sensor array and Raman spectrometer; (vii) hardness, sugar and spectrophotometric detection modules; and (viii) color and pesticide residue detection units. Integrating different cameras, such as a three-dimensional camera and CCD camera, enabled the determination of diverse quality parameters through further processing of obtained images. Solutions that integrated gas sensors or nondestructive sensor-based measurement of firmness related to quality were disclosed in a number of patents.
Patents intended for the detection of quality as a complex set of fruit properties disclosed solutions with different purposes, including a multisensor solution integrated into conveying or grading devices, or devices used to determine fruit quality in the field or at harvest, and multisensor-based stand-alone devices for fruit quality testing; some patents disclosed evidence regarding the possibility of determining fruit quality using multiple sensors. Some patents in this group disclosed portable or hand-held devices with integrated optical sensors, while others disclosed devices intended to be integrated into conveyer lines and fruit classification/grading equipment. Some indicated the possibility of attaching devices to vehicles such as drones, tractors, crawlers and other vehicles or integrating sensors into wearable gloves and other ways to facilitate operation. Some inventions were related to improvements regarding temperature correction of measurement performance.
(b) Fruit ripening and maturation involves various physical and chemical changes that affect the quality and shelf life of fruit. Physical changes include changes in color, texture and composition. In the case of ripening, similar to quality, there have been attempts to generalize ripeness or maturity based on the response of sensor-based measurements. Most disclosed inventions were intended for detecting fruit ripeness based on diverse sensor-based measurements and transforming the obtained results into information regarding ripeness through various mathematical modeling approaches. Sensors used for measuring signals used to predict ripeness include electronic noses, ultrasonic sensors, sound sensors, resonance frequency sensors, photoelectric sensors for ethylene respiration gases and volatiles and sensors for color and shape (
Table 10). The majority of disclosed inventions were intended for general application to determine fruit ripeness, but there were also inventions developed for specific fruits, such as the sound-based determination of ripeness of melons and watermelons, color expression-based determination of apple ripeness by shape and color, a stereoscopic vision system for determining the ripeness of bananas at harvest and temperature and gas composition based determination of the ripeness of bagged bananas.
Some inventions were related to monitoring fruit maturation in orchards and determining optimal harvest times. Disclosed solutions included combinations of sensors measuring different ripening-related parameters such as relative humidity and temperature, combined with an electronic nose device or a bioelectric sensor to measure sugar, polyphenol and chlorophyl. Other solutions were based on measuring ethylene release and use ultrasonic sensors.
There were also solutions for monitoring the maturation process of fruit in the supply chain. Sensing solutions used for data measuring included color sensing using RGB sensors and different combinations of gas composition measuring sensors. Data processing methods included simple utilization of preprogrammed thresholds, mixed signal analytical models or machine learning algorithms.
The most sophisticated solutions included gas or image analysis for the purpose of management of fruit processes such as the ethylene quantity needed for maturation or the reduction of electricity consumption.
(c) Fruit freshness is a holistic attribute that integrates a complex assessment of how recently the fruit was harvested and how well its properties have been preserved. Loss of freshness is perceived as spoilage, rotting, loss of turgor, development of an unpleasant odor, loss of firmness etc. Preserving the freshness of fruits and vegetables depends on several factors, including temperature, humidity and ethylene concentration [
47]. Loss of freshness can be quantified by parameters including visual properties, intensity of respiration or the synthesis of volatile compounds characterizing postharvest processes [
41].
The first group of inventions intended for characterizing freshness comprised different constructions and integrations of multiple sensors that acquired data on the environmental conditions in which fruit was stored and used formulas or mathematical models to transform the measured data into information that can be used to assess fruit freshness or predict remaining shelf life (
Table 11). Patents in this group often included the specific postharvest purpose for such inventions, such as integrating them into fruit grading equipment in order to separate fruit that has lost freshness from the rest or providing information about lots in which rotten fruits were present and their location.
The second group of inventions included sensors for detecting the composition of volatiles such as ethanol, color-sensitive odor components, conjugated hydrocarbons and esters. The relationships between detected odor compounds and freshness indicators such as rotting were determined through experimental investigations of these parameters with different volatile compound concentrations or measurements at different points. Some patents specified the purpose of postharvest measurement, such as alerting users to rotten fruits and vegetables.
3.4.3. Group III. Sensor Coupled with Artificial Intelligence
Artificial intelligence involves the use of computers to simulate behaviors characterizing human intelligence such as learning and decision-making [
48]. A prerequisite for developing AI solutions is the existence of big datasets. The introduction and wide application of sensor-based fruit measurement has led to the creation of multidimensional databases, paving the way for the development of artificial intelligence solutions for fruit handling and management.
An analysis of patents related to the use of sensors for measuring fruit properties revealed that the artificial intelligence related solutions included those based on (a) computer vision, (b) machine learning and (c) deep learning.
(a) Computer vision applications refers to the processing of images obtained from cameras to derive conclusions in order to identify the properties of observed objects, similar to the processing of inputs through human eyes by the brain. In addition, the development of multispectral, hyperspectral, three-dimensional and other types of cameras enable even more sophisticated inputs to be obtained which are processed via computer vision techniques into information about the observed object [
49].
In some patents in the identified portfolio, computer vision techniques were used to pre-process images obtained from RGB visual sensors, lasers, color infrared sensors, cameras, multispectral devices or even photographs taken with hand-held mobile equipment (
Table 12). Machine learning and deep learning techniques were commonly used to further process the data obtained via computer vision techniques. However, the inputs for machine learning and deep learning applications were not limited to data from preprocessed images; data obtained from multiple sensor devices and networks were also used as inputs for artificial intelligence-based models.
(b) Machine learning involves probability theory, statistics, approximation theory, convex analysis, algorithm complexity theory and other disciplines to optimize the performance of computers when simulating human learning behaviors to acquire new knowledge and reorganize existing knowledge structures, with the aim of continuously improving the performance by establishing a learning system for specific tasks [
50].
Within the observed patent portfolio, machine learning was used, for example, to derive information on fruit odor from data obtained via micro-electromechanical gas sensors, cuticle permeability from data obtained via image processing, and spongy tissue from data obtained via electrochemical and laser-based sensors (
Table 12). Machine learning was also used for predicting fruit ripening patterns. As an input for machine learning-based prediction of ripening based on gas composition, diverse data obtained from multisensor networks and image processing were used. Machine learning was also used to develop applications for the nondestructive prediction of sugar content in fruit based on data from sensors that recorded fruit and environmental properties.
(c) Deep learning is an advanced approach that can be used for solving the problem of processing multilayered big datasets. Deep learning uses artificial neural networks to achieve multilayer perceptrons within multiple hidden layers in datasets to discover the characteristics of data distribution by forming higher-level attributes through combinations of low-level features [
51]. Deep learning was used in the studied patent portfolio to predict fruit ripeness from color-based and ethanol release measurements and to distinguish between naturally and artificially ripened fruits (
Table 12).
The disclosed inventions were developed with the intention of substituting human decision-making at relevant points in order to manage fresh produce supply chains, such as determining optimal harvest time, classifying fruits optimally, performing fruit phenotyping, predicting fruit quality, supporting fruit traceability, identifying individual fruits with deteriorated quality and assessing how fruit can be stored and transported.
Applying artificial intelligence-based models to the management of fresh produce supplies also implies solutions for data acquisition and processing through cloud computing or by integrating the whole system with the user’s mobile phone.