Next Article in Journal
Graphene-Oxide and Hydrogel Coated FBG-Based pH Sensor for Biomedical Applications
Previous Article in Journal
A Sensor System for the Monitoring of Production Processes of Low FODMAP Food
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Proceeding Paper

V2O5 Thin Films as Nitrogen Dioxide Sensors †

by
Krystyna Schneider
* and
Wojciech Maziarz
AGH University of Science and Technology, Faculty of Computer Science, Electronics and Telecommunications, Department of Electronics, 30-059 Krakow, Poland
*
Author to whom correspondence should be addressed.
Presented at the Eurosensors 2018 Conference, Graz, Austria, 9–12 September 2018.
Proceedings 2018, 2(13), 759; https://doi.org/10.3390/proceedings2130759
Published: 3 December 2018
(This article belongs to the Proceedings of EUROSENSORS 2018)

Abstract

:
V2O5 thin films were deposited onto insulating support (either fused silica or alumina) by means of rf reactive sputtering from a metallic vanadium target. Argon-oxygen gas mixtures of different compositions controlled by the flow rates were used for sputtering. X-ray diffraction at glancing incidence (GIXD) and Scanning Electronic Microscopy (SEM) were used for structural and phase characterization. Optical transmittance and reflectance spectra were recorded with a Lambda 19 Perkin-Elmer double spectrophotometer. Thickness of the films was determined from the profilometry. It has been confirmed by GIXD that the deposited films are composed of V2O5 phase. The estimated optical band gap was ca. 2.5 eV. The gas sensing properties of V2O5 thin films were investigated at RT-690 K towards NO2 gas of 0–20 ppm. The results indicated that material exhibited good response and reversibility towards nitrogen dioxide.

1. Introduction

Nitrogen dioxide, NO2 is an extremely toxic gas. It is produced by all combustion in air and by industrial processes. NO2 can cause various problems such as smog and acid rain. Therefore there is an urgent need to develop some devices that allow fast, portable, low-cost monitoring of the NO2 responsible for air pollution and danger to human health. Successful development of NO2 gas sensors for commercialization requires achieving three “S”: sensitivity, selectivity and stability. Several metal oxides such as SnO2, ZnO, In2O3 and WO3 were studied extensively for construction semiconductor gas sensors [1,2,3,4]. Recently, vanadium oxides have attracted considerable interest due to their multi-valence, good chemical stability and excellent catalytic properties [5]. V2O5, the most stable compound among above 15 known vanadium oxides, is one of good promising NO2 sensor material [6]. It demonstrated high sensitivity and selectivity for ethanol [7], ammonia [8], hydrogen and hydrocarbons [9].
In this paper the effect of gas concentration and operating temperature of V2O5 thin films as NO2 gas sensor was determined.

2. Materials and Methods

2.1. Thin Film Preparation

VOx thin films were deposited onto insulating support (either fused silica or alumina) for sample characterization or conductometric sensor substrate type CC1.W, for electrical measurements, by means of rf sputtering in a reactive atmosphere 4.75 Pa (24% O2–76% Ar) from a metallic V target. Conductometric supports presented in Figure 1 were provided by BVT Technologies. Details of the film deposition are given elsewhere [9].

2.2. Morphology and Structural Characterization

Scanning electron microscopy (SEM) studies were carried out for as-sputtered thin films using NOVA NANOSEM 200 (FEI Company, Hillsboro, OR, USA) microscope. Phase composition of as-sputtered thin films were studied by X-ray diffraction at glancing incidence, GIXD.

2.3. Sensing Characterization

The responses of films to the target gases, defined as changes in electrical resistance, were measured at different concentrations of flowing gases. The atmosphere of the sample chamber was a mixture of synthetic air and argon containing target gas. The flow rates of gases were independently controlled by MKS Type 1179A mass-flow controller. The total flow rate was maintained at the same level of 190 sccm. The film response to reactions on the hydrogen was measured. The concentration of target gases was up to 3000 ppm in a measurement chamber atmosphere. The sensor measurements were performed within the temperature range extending from RT to 523 K. An equipment applied for measurements of the sensor characteristics was described in detail elsewhere [10]. Sensor response (sensitivity) S was defined as: S = R N O 2 R a i r .

3. Results and Discussion

Structural and Microstructural Characteristics
Figure 2 presents the typical XRD patterns of the sample annealed at several temperatures in argon atmosphere. X-ray diffraction analysis of the samples revealed the presence of the V2O5orthorhombic phase. The determined lattice parameters (a = 1.149 ± 0.002 nm; b = 0.436 ± 0.003 nm; c = 0.436 ± 0.003 nm) well agree with that literature reports [11]. Presented XRD patterns were used for determination of the crystallite size. Crystallite size, dXRD, was calculated according to Scherrer’smethod: dXRD = (20 ± 1.8) nm. No effect of sintered temperature on obtained XRD results is observed.
As can be seen, the as sputtered thin films (Figure 3a) are poly-dispersed, and the grains are mostly columnar in shape (565 ± 100 nm) of the length and (220 ± 40 nm) of the diameter. On the other hand, after sintering (Figure 3b) they are rather spherical (mean diameter = 500 ± 75 nm). Chemical analysis performed by EDS technique revealed presence of high picks coming from the silicon support and much smaller picks corresponding to oxygen and vanadium elements.
V2O5 sensor responses to 20 ppm NO2 are shown in Figure 4a,b. As it results from Figure 4, the electrical conductivity of the V2O5 thin films increases upon exposure of NO2.
It can be explained by the direct adsorption of NO2 molecules according to the reaction:
N O 2 ( g a s ) + e   N O 2 ( a d s )
Response and recovery times at 483 K, determined from the Figure 4b are: (698 ± 2) s and (1233 ± 185) s, respectively.
Figure 5a illustrates sensor response, S, versus temperature. The abrupt increase of the sensor response is observed at 545–547 K. This behaviour may be explained by occurrence of the metal-insulator transition, MIT. According to Kang et al. [12] at temperature ca. 530 K the MIT takes place in the thin films of V2O5.

4. Conclusions

In the present work, we fabricated V2O5 thin films by rf reactive sputtering. The film structure and morphology were studied by X-ray diffraction at glancing incidence (GIXD) and Scanning Electronic Microscopy (SEM). Gas sensing studies showed that the V2O5 thin films were sensitive to NO2 at a relatively low operating temperatures. The considerable increase of the sensor sensitivity was observed above 545 K, which is related with postulated metal-insulator transition.

Acknowledgments

This work was financially supported by the National Science Centre of the Republic of Poland, under Grant No. 2016/23/B/ST8/00163.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Comini, E.; Faglia, G.; Sberveglien, G.; Pan, Z.; Wang, Z.L. Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts. Appl. Phys. Lett. 2002, 81, 1869–1871. [Google Scholar] [CrossRef]
  2. Kim, B.-M.; Kim, J.-S. Sensor array based on metal oxide semiconductors for detecting gas mixtures and its sensing properties. In Proceedings of the 5th International Conference on Sensors Networks, SENSORNETS 2016, Gdansk, Poland, 11–14 September 2016; pp. 169–174. [Google Scholar]
  3. GFine, F.; Cavanagh, L.M.; Afonja, A.; Binions, R. Metal oxide semi-conductor gas sensors in environmental monitoring. Sensors 2010, 10, 5469–5502. [Google Scholar] [CrossRef]
  4. Peterson, P.J.D.; Aulja, A.; Grant, K.H.; Brundle, A.G.; Thomson, M.R.; Hey, J.V.; Leigh, R.J. Practical Use of Metal Oxide Semiconductor Gas Sensors for Measuring Nitrogen Dioxide and Ozone in Urban Environments. Sensors 2017, 17, 1653. [Google Scholar] [CrossRef]
  5. Beke, S. A review of the growth of V2O5 films from 1885 to 2010. Thin Solid Films 2011, 519, 1761–1771. [Google Scholar] [CrossRef]
  6. Han, S.D.; Moon, H.G.; Noh, M.S.; Pyeon, J.J.; Shim, Y.S.; Nahm, S.; Kim, J.-S.; Yoo, K.S.; Kang, C.-Y. Self-doped nanocolumnar vanadium oxides thin films for highly selective NO2 gas sensing at low temperatures. Sens. Actuators B 2017, 241, 40–47. [Google Scholar] [CrossRef]
  7. Liu, J.; Wang, X.; Peng, Q.; Li, Y. Vanadium pentoxide nanobelts: Highly selective and stable ethanol sensor material. Adv. Mater. 2005, 17, 764–767. [Google Scholar] [CrossRef]
  8. Huotari, J.; Björklund, R.; Lappalainen, J.; Lloyd Spetz, A. Nanostructured mixed phase vanadium oxide thin films as highly sensitive ammonia sensormaterial. Procedia Eng. 2014, 87, 1035–1038. [Google Scholar] [CrossRef]
  9. Schneider, M. Lubecka, A. Czapla, V2O5 thin films for gas sensor applications. Sens. Actuators B 2016, 236, 970–977. [Google Scholar] [CrossRef]
  10. Radecka, M.; Łyson, B.; Lubecka, M.; Czapla, A.; Zakrzewska, K. Photocatalytical decomposition of contaminants on thin film gas sensors. Acta Phys. Pol. 2010, 117, 415–419. [Google Scholar] [CrossRef]
  11. Chakrabarti, A.; Hermann, K.; Druzinic, R.; Witko, M.; Wagner, F.; Petersen, M. Geometric and electronic structure of vanadium pentoxide: A density functional bulk and surface study. Phys. Rev. B 1999, 59, 10583–10590. [Google Scholar] [CrossRef]
  12. Kang, P.; Kim, I.; Kim, S.; Park, H.Y. Metal-insulator transition without structural phase transition in V2O5 film. Appl. Phys. Lett. 2011, 98, 131907–131916. [Google Scholar] [CrossRef]
Figure 1. Conductometric support BVT.
Figure 1. Conductometric support BVT.
Proceedings 02 00759 g001
Figure 2. X-ray diffraction patterns for V2O5 thin film.
Figure 2. X-ray diffraction patterns for V2O5 thin film.
Proceedings 02 00759 g002
Figure 3. Scanning electron micrographs of: (a) as sputtered thin film; (b) after annealing at 673 K.
Figure 3. Scanning electron micrographs of: (a) as sputtered thin film; (b) after annealing at 673 K.
Proceedings 02 00759 g003
Figure 4. Dynamic changes in the electrical resistance of V2O5 thin film upon interaction with 20 ppm NO2, (a) at several temperatures; (b) at 486 K.
Figure 4. Dynamic changes in the electrical resistance of V2O5 thin film upon interaction with 20 ppm NO2, (a) at several temperatures; (b) at 486 K.
Proceedings 02 00759 g004
Figure 5. Temperature dependence of: (a) NO2 sensor response, S and (b) response vs. NO2 concentration.
Figure 5. Temperature dependence of: (a) NO2 sensor response, S and (b) response vs. NO2 concentration.
Proceedings 02 00759 g005
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Share and Cite

MDPI and ACS Style

Schneider, K.; Maziarz, W. V2O5 Thin Films as Nitrogen Dioxide Sensors. Proceedings 2018, 2, 759. https://doi.org/10.3390/proceedings2130759

AMA Style

Schneider K, Maziarz W. V2O5 Thin Films as Nitrogen Dioxide Sensors. Proceedings. 2018; 2(13):759. https://doi.org/10.3390/proceedings2130759

Chicago/Turabian Style

Schneider, Krystyna, and Wojciech Maziarz. 2018. "V2O5 Thin Films as Nitrogen Dioxide Sensors" Proceedings 2, no. 13: 759. https://doi.org/10.3390/proceedings2130759

Article Metrics

Back to TopTop