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Surfaces, Volume 7, Issue 4

2024 December - 22 articles

Cover Story: Charged microdroplets generated in the electrospray source (ESI) of a mass spectrometer represent a unique medium where redox reactions can be strongly accelerated with respect to the bulk processes. The synthesis of gold nanoparticles (AuNPs) by charged microdroplet deposition of HAuCl4 solution without a reducing agent was exploited to modify the surface of graphite screen-printed electrodes. The deposited AuNPs were subsequently functionalized with 6-ferrocenyl-hexanethiol (6Fc-ht). The ESI technique provided specific interaction between 6Fc-ht and AuNPs, minimizing non-specific adsorption. The modified electrodes demonstrated improved redox properties, highlighting the technique's potential for the easy and fast production of nanostructured-based electrodes. View this paper
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Articles (22)

  • Feature Paper
  • Article
  • Open Access
1,615 Views
16 Pages

Surface Characteristics and Performance Optimization of W-Doped Vanadium Dioxide Thin Films

  • Chuen-Lin Tien,
  • Chun-Yu Chiang,
  • Jia-Kai Tien,
  • Ching-Chiun Wang and
  • Shih-Chin Lin

20 December 2024

This study explores the surface characteristics evaluation and performance optimization of tungsten (W)-doped vanadium dioxide (VO2) thin films. W-doped vanadium dioxide films were deposited on B270 glass substrates using an electron beam evaporation...

  • Article
  • Open Access
2 Citations
2,283 Views
13 Pages

High-Pressure and High-Temperature Dissolution of Titanium from Titanium and Aluminum Residues: A Comparative Study

  • Srecko Stopic,
  • Duško Kostić,
  • Elif Emil-Kaya,
  • Emircan Uysal,
  • Sebahattin Gürmen,
  • Aleksandar Mitrašinović,
  • Mitar Perušić and
  • Bernd Friedrich

20 December 2024

This study presents a comparative analysis of titanium leaching from tionite (a byproduct of the titanium dioxide production process) and carbothermally reduced red mud (derived from aluminum residues). Tionites from the sulfate process and red mud r...

  • Article
  • Open Access
5 Citations
4,593 Views
17 Pages

Improving Cotton Fabric Dyeability by Oxygen Plasma Surface Activation

  • Víctor M. Serrano-Martínez,
  • Carlos Ruzafa-Silvestre,
  • Carlota Hernández-Fernández,
  • Elena Bañón-Gil,
  • Francisca Arán-Ais and
  • Elena Orgilés-Calpena

20 December 2024

This paper focuses on investigating the use of low-pressure oxygen plasma as a surface treatment aimed at enhancing the wettability and dyeability of cotton fabrics for use in textiles and footwear materials. Plasma activation modified the cotton fab...

  • Article
  • Open Access
3 Citations
1,777 Views
19 Pages

19 December 2024

The acidity of anatase titania before and after KOH doping was probed by pyridine adsorption in a pulse microreactor and modeled by DFT optimization of the geometry of CO and pyridine adsorption on a periodic slab of (101) and (100) surfaces using a...

  • Article
  • Open Access
1,723 Views
8 Pages

19 December 2024

The mechanism of carbon nanotube unzipping on a Cu(111) surface was investigated using density functional theory calculations. Optimized structures of armchair and zigzag carbon nanotubes of various sizes were considered, and their energies were comp...

  • Article
  • Open Access
2 Citations
1,623 Views
23 Pages

1 December 2024

A variety of NiP-TiC-SiC nanocomposite coatings were deposited to acrylonitrile–butadiene–styrene (ABS) substrates at varying plating periods and bath temperatures using electroless plating. A field emission scanning electron microscope (...

  • Article
  • Open Access
2 Citations
1,907 Views
21 Pages

Improvement in Biological Performance of Poly(Lactic Acid)-Based Materials via Single-Point Surface Modification with Glycopolymer

  • Viktor Korzhikov-Vlakh,
  • Ekaterina Sinitsyna,
  • Kirill Arkhipov,
  • Mariia Levit,
  • Evgenia Korzhikova-Vlakh and
  • Tatiana Tennikova

1 December 2024

As a promising polymer for the production of biomaterials and drug delivery systems, poly(lactic acid) (PLA) is characterized by its relative hydrophobicity, as well as its chemical and biological inertness. Here, we aimed to improve the biological p...

  • Feature Paper
  • Article
  • Open Access
1 Citations
1,393 Views
5 Pages

28 November 2024

Many interesting materials in a broad range of applications have in their composition the coexistence of zinc and iron. Their characterization by XPS should identify and quantify both elements. The most intense regions for these elements Zn 2p and Fe...

  • Article
  • Open Access
1 Citations
2,238 Views
13 Pages

Highly Reproducible Automated Tip Coater for In Situ and Operando EC-STM Measurements

  • Robert Kurczak,
  • Paulina Wira,
  • Anna Futyma,
  • Radosław Wasielewski and
  • Tomasz Kosmala

18 November 2024

High-quality, reproducible tip coatings are essential for minimizing faradaic currents in electrochemical scanning tunneling microscopy (EC-STM), especially during in situ and operando measurements. The variability inherent in manual coating methods,...

  • Article
  • Open Access
2,217 Views
11 Pages

Modeling the Terminal Velocity of Rising Electrocharged Microbubbles

  • Roberto Pérez-Garibay,
  • Arturo Bueno-Tokunaga,
  • Francisco Andrés Acosta-González and
  • Ramón Arellano-Piña

8 November 2024

The generation of electrocharged microbubbles is very important for several separation processes (e.g., water treatment, paper industry, and mineral processing). However, their rising terminal velocities are not fully understood. This work presents a...

  • Article
  • Open Access
3 Citations
1,932 Views
10 Pages

8 November 2024

This paper reports on the successful preparation of a low absorption–emission thermal control coating on the surface of LAZ933 magnesium–lithium alloy using the micro-arc oxidation method. This study analyzed the microstructure, phase com...

  • Article
  • Open Access
1 Citations
2,191 Views
18 Pages

A Comprehensive Approach to Optimization of Silicon-Based Solar Cells

  • Nikolay Chuchvaga,
  • Nazira Aubakirova,
  • Nurlan Tokmoldin,
  • Vasiliy Klimenov and
  • Danil W. Boukhvalov

5 November 2024

In this work, we report a detailed scheme of computational optimization of solar cell structures and parameters using PC1D and AFORS-HET codes. Each parameter’s influence on the properties of the components of heterojunction silicon-based solar...

  • Article
  • Open Access
2 Citations
2,777 Views
13 Pages

Studying the Photoactivity of Ag-Decorated TiO2 Nanotubes with Combined AFM and Raman Spectroscopy

  • Manjunath Veeranna Shinnur,
  • Marco Menegazzo,
  • Gianlorenzo Bussetti,
  • Lamberto Duò,
  • MariaPia Pedeferri and
  • Maria Vittoria Diamanti

2 November 2024

The drive for the development of systems that can simultaneously investigate chemical and morphological information comes from the requisite to fully understand the structure and chemical reactivity relationships of materials. This is particularly re...

  • Article
  • Open Access
1,667 Views
18 Pages

A Study of the Features of Coating Deposition on a Carbide Substrate Using Preliminary Etching with Glow-Discharge Plasma

  • Sergey Grigoriev,
  • Marina Volosova,
  • Yuri Bublikov,
  • Catherine Sotova,
  • Filipp Milovich,
  • Anton Seleznev,
  • Ilya Shmakov and
  • Alexey Vereschaka

2 November 2024

The properties of coatings obtained using two surface preparation methods were compared: heating and etching by ion bombardment with plasma generation by arc evaporators and heating and etching by a glow discharge. A Ti-TiN-(Ti,Cr,Al)N coating was de...

  • Article
  • Open Access
5 Citations
3,065 Views
22 Pages

Photoelectrochemical and Structural Insights of Electrodeposited CeO2 Photoanodes

  • Alberto E. Molina-Lozano,
  • Marcos R. V. Lanza,
  • Pablo Ortiz and
  • María T. Cortés

19 October 2024

Cerium dioxide (CeO2) is a promising material for photoelectrochemical applications, requiring a thorough understanding of the interplay between its properties and structure for optimal performance. This study investigated the photoelectrochemical pe...

  • Article
  • Open Access
3 Citations
2,119 Views
19 Pages

Development of Natural Fungicidal Agricultural Defensives Using Microbial Glycolipid and Vegetable Oil Blends

  • Anderson O. de Medeiros,
  • Maria da Gloria C. da Silva,
  • Attilio Converti,
  • Fabiola Carolina G. de Almeida and
  • Leonie A. Sarubbo

16 October 2024

The use of pesticides causes significant environmental problems, which drives the search for natural and non-toxic alternatives. In this study, a glycolipid biosurfactant (BS), produced by the yeast Starmerella bombicola ATCC 22214, was utilized as a...

  • Article
  • Open Access
4 Citations
1,855 Views
15 Pages

Synthesis of BiOCl Colloidal Particles by Laser Ablation of Solids in Liquids

  • Abril Vázquez Francisco,
  • Armando Pérez-Centeno,
  • Laura P. Rivera and
  • José G. Quiñones-Galván

15 October 2024

Colloidal bismuth nanoparticles (NPs) were synthesized in sodium chloride (NaCl) solutions at different concentrations using the laser ablation of solids in liquids technique. The obtained materials were characterized using various techniques. The mo...

  • Review
  • Open Access
1 Citations
2,237 Views
18 Pages

15 October 2024

As society moves away from heavy industry, large metallic structures will be abandoned. As an alternative to dismantling, these structures could be repurposed. Beyond being a practical solution, the conservation of these structures would serve as an...

  • Communication
  • Open Access
1,588 Views
8 Pages

Synthesis and Properties of Novel Acrylic Fluorinated Surfactants

  • Chao Lin,
  • Jinhua Li,
  • Yejun Qin,
  • Ping Xing and
  • Biao Jiang

14 October 2024

Branched fluorinated surfactants with creatively introduced acrylate in the hydrophilic group were designed and prepared by adopting perfluoro-2-methyl-2-pentene as the raw substrate. These new compounds showed excellent surface properties, and the s...

  • Article
  • Open Access
3 Citations
2,005 Views
14 Pages

Increasing the Wear and Corrosion Resistance of a CP-Ti Surface by Plasma Electrolytic Borocarburizing and Polishing

  • Marina A. Volosova,
  • Sergei A. Kusmanov,
  • Ivan V. Tambovskiy,
  • Tatiana L. Mukhacheva,
  • Artem P. Mitrofanov,
  • Igor V. Suminov and
  • Sergey N. Grigoriev

7 October 2024

The paper examines the possibility of increasing the wear and corrosion resistance of a CP-Ti surface by duplex plasma electrolytic treatment (borocarburizing and polishing). The structure and composition of diffusion layers, their microhardness, sur...

  • Article
  • Open Access
5 Citations
3,234 Views
12 Pages

PVD Coatings for Lightweight Bipolar Plates

  • Parnia Navabpour,
  • Liam Cooper,
  • Shicai Yang,
  • Jinlong Yin,
  • Kun Zhang,
  • Ahmad El-Kharouf and
  • Hailin Sun

2 October 2024

Bipolar plates are one of the main components of proton exchange membrane fuel cells (PEMFCs). Their functions include distributing reactants, supporting the cell, and conducting heat and electricity. They account for a significant proportion of the...

  • Article
  • Open Access
1 Citations
1,862 Views
11 Pages

Charged Microdroplets Deposition for Nanostructured-Based Electrode Surface Modification

  • Rosaceleste Zumpano,
  • Marco Agostini,
  • Franco Mazzei,
  • Anna Troiani,
  • Chiara Salvitti,
  • Marta Managò,
  • Alessia Di Noi,
  • Andreina Ricci and
  • Federico Pepi

1 October 2024

Accelerated synthesis of gold nanoparticles (AuNPs) in charged microdroplets produced by electrospray ionization (ESI) was exploited to modify the surface of graphite screen-printed electrodes (GSPEs). The deposited AuNPs were then functionalized by...

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Surfaces - ISSN 2571-9637