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Surfaces, Volume 7, Issue 4

December 2024 - 22 articles

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Cover Story: Charged microdroplets generated in the electrospray source (ESI) of a mass spectrometer represent a unique medium where redox reactions can be strongly accelerated with respect to the bulk processes. The synthesis of gold nanoparticles (AuNPs) by charged microdroplet deposition of HAuCl4 solution without a reducing agent was exploited to modify the surface of graphite screen-printed electrodes. The deposited AuNPs were subsequently functionalized with 6-ferrocenyl-hexanethiol (6Fc-ht). The ESI technique provided specific interaction between 6Fc-ht and AuNPs, minimizing non-specific adsorption. The modified electrodes demonstrated improved redox properties, highlighting the technique's potential for the easy and fast production of nanostructured-based electrodes. View this paper

Articles (22)

  • Feature Paper
  • Article
  • Open Access
1,019 Views
16 Pages

Surface Characteristics and Performance Optimization of W-Doped Vanadium Dioxide Thin Films

  • Chuen-Lin Tien,
  • Chun-Yu Chiang,
  • Jia-Kai Tien,
  • Ching-Chiun Wang and
  • Shih-Chin Lin

20 December 2024

This study explores the surface characteristics evaluation and performance optimization of tungsten (W)-doped vanadium dioxide (VO2) thin films. W-doped vanadium dioxide films were deposited on B270 glass substrates using an electron beam evaporation...

  • Article
  • Open Access
1 Citations
1,227 Views
13 Pages

High-Pressure and High-Temperature Dissolution of Titanium from Titanium and Aluminum Residues: A Comparative Study

  • Srecko Stopic,
  • Duško Kostić,
  • Elif Emil-Kaya,
  • Emircan Uysal,
  • Sebahattin Gürmen,
  • Aleksandar Mitrašinović,
  • Mitar Perušić and
  • Bernd Friedrich

20 December 2024

This study presents a comparative analysis of titanium leaching from tionite (a byproduct of the titanium dioxide production process) and carbothermally reduced red mud (derived from aluminum residues). Tionites from the sulfate process and red mud r...

  • Article
  • Open Access
3 Citations
2,752 Views
17 Pages

Improving Cotton Fabric Dyeability by Oxygen Plasma Surface Activation

  • Víctor M. Serrano-Martínez,
  • Carlos Ruzafa-Silvestre,
  • Carlota Hernández-Fernández,
  • Elena Bañón-Gil,
  • Francisca Arán-Ais and
  • Elena Orgilés-Calpena

20 December 2024

This paper focuses on investigating the use of low-pressure oxygen plasma as a surface treatment aimed at enhancing the wettability and dyeability of cotton fabrics for use in textiles and footwear materials. Plasma activation modified the cotton fab...

  • Article
  • Open Access
1 Citations
1,060 Views
19 Pages

19 December 2024

The acidity of anatase titania before and after KOH doping was probed by pyridine adsorption in a pulse microreactor and modeled by DFT optimization of the geometry of CO and pyridine adsorption on a periodic slab of (101) and (100) surfaces using a...

  • Article
  • Open Access
1,066 Views
8 Pages

19 December 2024

The mechanism of carbon nanotube unzipping on a Cu(111) surface was investigated using density functional theory calculations. Optimized structures of armchair and zigzag carbon nanotubes of various sizes were considered, and their energies were comp...

  • Article
  • Open Access
1 Citations
1,215 Views
23 Pages

1 December 2024

A variety of NiP-TiC-SiC nanocomposite coatings were deposited to acrylonitrile–butadiene–styrene (ABS) substrates at varying plating periods and bath temperatures using electroless plating. A field emission scanning electron microscope (...

  • Article
  • Open Access
1 Citations
1,214 Views
21 Pages

Improvement in Biological Performance of Poly(Lactic Acid)-Based Materials via Single-Point Surface Modification with Glycopolymer

  • Viktor Korzhikov-Vlakh,
  • Ekaterina Sinitsyna,
  • Kirill Arkhipov,
  • Mariia Levit,
  • Evgenia Korzhikova-Vlakh and
  • Tatiana Tennikova

1 December 2024

As a promising polymer for the production of biomaterials and drug delivery systems, poly(lactic acid) (PLA) is characterized by its relative hydrophobicity, as well as its chemical and biological inertness. Here, we aimed to improve the biological p...

  • Feature Paper
  • Article
  • Open Access
997 Views
5 Pages

28 November 2024

Many interesting materials in a broad range of applications have in their composition the coexistence of zinc and iron. Their characterization by XPS should identify and quantify both elements. The most intense regions for these elements Zn 2p and Fe...

  • Article
  • Open Access
1 Citations
1,426 Views
13 Pages

Highly Reproducible Automated Tip Coater for In Situ and Operando EC-STM Measurements

  • Robert Kurczak,
  • Paulina Wira,
  • Anna Futyma,
  • Radosław Wasielewski and
  • Tomasz Kosmala

18 November 2024

High-quality, reproducible tip coatings are essential for minimizing faradaic currents in electrochemical scanning tunneling microscopy (EC-STM), especially during in situ and operando measurements. The variability inherent in manual coating methods,...

  • Article
  • Open Access
1,330 Views
11 Pages

Modeling the Terminal Velocity of Rising Electrocharged Microbubbles

  • Roberto Pérez-Garibay,
  • Arturo Bueno-Tokunaga,
  • Francisco Andrés Acosta-González and
  • Ramón Arellano-Piña

8 November 2024

The generation of electrocharged microbubbles is very important for several separation processes (e.g., water treatment, paper industry, and mineral processing). However, their rising terminal velocities are not fully understood. This work presents a...

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