Surfaces, Volume 7, Issue 4
December 2024 - 22 articles
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Cover Story: Charged microdroplets generated in the electrospray source (ESI) of a mass spectrometer represent a unique medium where redox reactions can be strongly accelerated with respect to the bulk processes. The synthesis of gold nanoparticles (AuNPs) by charged microdroplet deposition of HAuCl4 solution without a reducing agent was exploited to modify the surface of graphite screen-printed electrodes. The deposited AuNPs were subsequently functionalized with 6-ferrocenyl-hexanethiol (6Fc-ht). The ESI technique provided specific interaction between 6Fc-ht and AuNPs, minimizing non-specific adsorption. The modified electrodes demonstrated improved redox properties, highlighting the technique's potential for the easy and fast production of nanostructured-based electrodes. View this paper