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Sustainable Chemistry, Volume 6, Issue 4

2025 December - 19 articles

Cover Story: In this work, deep eutectic solvents (DES) were selected for the extraction of anthocyanins from red grape skins (winery by-products) as efficient and environmentally friendly alternatives to traditional solvent mixtures. In silico studies were employed as screening tools to identify the most suitable options, and a total of 30,132 DES combinations were assessed. The selected DESs comprised polyalcohols (ethyleneglycol, glycerol, 1,2-propanediol, and 1,6-hexanediol) and carboxylic acids (citric, oxalic, malic, and lactic acids) as hydrogen bond donors, and choline chloride, betaine, or salts (potassium carbonate, sodium acetate, and propionate) as hydrogen bond acceptors. Furthermore, time, temperature, and water content were optimized in ultrasound- and microwave-assisted extraction using a design of experiments based on the response surface methodology. View this paper
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Articles (19)

  • Article
  • Open Access
610 Views
11 Pages

The old spectral displacement method can be suitably revitalized for a didactic experimental approach to fundamental concepts of supramolecular chemistry and to the study of complex equilibria in general. In particular, the case of the β-cyclode...

  • Article
  • Open Access
1,509 Views
23 Pages

Mercury Removal and Antibacterial Performance of A TiO2–APTES Kaolin Composite

  • Awal Adava Abdulsalam,
  • Sabina Khabdullina,
  • Zhamilya Sairan,
  • Yersain Sarbassov,
  • Madina Pirman,
  • Dilnaz Amrasheva,
  • George Z. Kyzas,
  • Tri Thanh Pham,
  • Elizabeth Arkhangelsky and
  • Stavros G. Poulopoulos

Mercury (Hg2+) contamination in water systems poses a severe environmental and health hazard due to its high toxicity and bioaccumulation potential. In this study, a novel adsorbent was developed by sequentially modifying kaolin via acid–base t...

  • Article
  • Open Access
1,156 Views
17 Pages

New Approaches for the Extraction of Anthocyanins from Grape Skins Using Deep Eutectic Solvents

  • Marta Jiménez-Salcedo,
  • Filipe H. B. Sosa,
  • João A. P. Coutinho and
  • María Teresa Tena

Deep eutectic solvents (DES) were selected for the extraction of anthocyanins from red grape skins as an efficient and environmentally friendly solvent alternative to traditional mixtures based on methanol. In silico studies (COSMO-RS) were employed...

  • Article
  • Open Access
758 Views
23 Pages

Valorization of Aronia melanocarpa Pomace: A Sustainable Source of Bioactive Compounds for Developing Colored Healthcare Textiles, Biomedical Hydrogels, and Green Corrosion Inhibitor

  • Vukašin Ugrinović,
  • Anđela Simović,
  • Marija Ćorović,
  • Katarina Mihajlovski,
  • Jelena Lađarević,
  • Jelena Bajat and
  • Aleksandra Ivanovska

This interdisciplinary study explores the potential of bioactive compounds from Aronia melanocarpa pomace, a juice industry by-product. The ethanol extract of the pomace was analyzed using HPLC, revealing key polyphenolic acids and anthocyanins. The...

  • Article
  • Open Access
1 Citations
858 Views
24 Pages

Design and Development of Sustainable Geopolymers Based on Fly Ash, Slag, and Diatomaceous Earth: A Chemometric Approach

  • Dušan V. Trajković,
  • Natalija D. Milojković,
  • Nevenka N. Mijatović,
  • Aleksandra S. Popović,
  • Đorđe N. Veljović,
  • Aleksandra A. Perić Grujić and
  • Dragana Z. Živojinović

The burning of coal in thermal power plants throughout Serbia produces significant amounts of industrial waste, primarily in the form of fly ash, boiler ash, and slag. Given their annual production, availability, and fine grain structure, it is neces...

  • Article
  • Open Access
698 Views
22 Pages

Catalytic Upgrading of Ethanol to 1-Butanol Biofuel Additive Using Pd/MgO-Al2O3 and Bimetallic Pd-Cu/MgO-Al2O3 Mixed Oxide Catalysts

  • Amosi Makoye,
  • Ferenc Lónyi,
  • Hanna E. Solt,
  • Catia Cannilla,
  • Giuseppe Bonura,
  • Gyula Novodárszki,
  • Róbert Barthos,
  • József Valyon,
  • Tibor Nagy and
  • Anna Vikár

Catalytic upgrading of bioethanol via a C–C coupling reaction is a sustainable method of producing 1-butanol, a high-performance biofuel. This reaction was studied using a flow-through microreactor system with Pd/MgO-Al2O3 and bimetallic Pd-Cu/...

  • Article
  • Open Access
1,170 Views
20 Pages

Use of a 3D Workpiece to Inductively Heat an Ammonia Cracking Reactor

  • Debora de Figueiredo Luiz,
  • Martien Koppes,
  • Marija Sarić and
  • Jurriaan Boon

Ammonia, widely regarded as the “hydrogen carrier of the future,” offers high hydrogen content, ease of production, and a well-established infrastructure for handling and transportation globally. Meanwhile, ammonia cracking requires a hea...

  • Review
  • Open Access
1 Citations
2,663 Views
22 Pages

Comprehensive Review of SBA-15 Mesoporous Silica: Functionalization Strategies, Diffusion Mechanisms, and Emerging Applications

  • Morayma Muñoz,
  • Diego Flores,
  • Grace Morillo,
  • Ricardo Narváez,
  • Antonio Marcilla and
  • Marco Rosero

Mesoporous materials have attracted increasing attention due to their ordered pore systems; tunable surface chemistry; and versatile applications in catalysis, adsorption, and environmental technologies. Among them, SBA-15 stands out for its large su...

  • Article
  • Open Access
1,025 Views
31 Pages

Mechanochemical Solvent-Free Synthesis and Biological Profiling of Novel 2-Hydrazone-Bridged Benzothiazoles as Potent Anticancer Agents

  • Ivana Sokol,
  • Hanja Mlinar,
  • Dajana Kučić Grgić,
  • Leentje Persoons,
  • Dirk Daelemans,
  • Moris Mihovilović and
  • Tatjana Gazivoda Kraljević

This study reports the solvent-free mechanochemical synthesis of a novel series of 2-hydrazone-bridged benzothiazole derivatives 1952 via the reaction of 2-hydrazinylbenzothiazole derivatives 46 with O-alkylated benzaldehydes 718...

  • Article
  • Open Access
940 Views
16 Pages

Removal of Myclobutanil and Detoxification in Modified Biomixtures: Fungal Bioaugmentation and Biochar Amendment

  • Paraskevas Parlakidis,
  • Víctor Castro-Gutiérrez,
  • Mario Masís-Mora,
  • Zisis Vryzas and
  • Carlos E. Rodríguez-Rodríguez

Biopurification systems are designed for the treatment of pesticide-containing agricultural wastewater; their biologically active matrix, the biomixture, can be modified to enhance the pesticide removal capacity. Two approaches, fungal bioaugmentatio...

  • Article
  • Open Access
928 Views
18 Pages

Rapid Synthesis of a CHA Membrane Using a Small Tubular Reactor

  • Rizqan Jamal,
  • Manabu Miyamoto,
  • Yasuhisa Hasegawa,
  • Yasunori Oumi and
  • Shigeyuki Uemiya

Known for its excellent adsorption and molecular sieving properties, CHA-type zeolite is highly effective in separation technologies, including alcohol dehydration and gas separation. Despite their advantages, especially in terms of energy savings, t...

  • Review
  • Open Access
2,766 Views
43 Pages

The composite material lignocellulose makes up the majority of biomass on earth and is characterized by a high biological and chemical resistance, which is essentially caused by the phenylpropanoid polymer lignin. Thus, the removal and depolymerizati...

  • Article
  • Open Access
878 Views
16 Pages

Enhanced Stability of Water-Processed Sb2Te3: PEO Thermoelectric Hybrids via Thiol-Based Surface Functionalization

  • Oskars Bitmets,
  • Bejan Hamawandi,
  • Raitis Grzibovskis,
  • Jose Francisco Serrano Claumarchirant,
  • Muhammet S. Toprak and
  • Kaspars Pudzs

This study explores the development of a water-based hybrid thermoelectric (TE) material composed of Sb2Te3 nanoparticles (NPs) and polyethylene oxide (PEO). Sb2Te3 NPs were synthesized via the microwave-assisted colloidal route, where X-ray diffract...

  • Article
  • Open Access
1,052 Views
18 Pages

Antimony and Bismuth Recovery from an Acidic Chloride Eluate of a Copper Electrolyte Purification Plant with an Arsenic Sequestration

  • Mateusz Ciszewski,
  • Szymon Orda,
  • Michał Drzazga,
  • Katarzyna Leszczyńska-Sejda,
  • Andrzej Chmielarz and
  • Patricia Córdoba

Antimony (Sb), bismuth (Bi), and arsenic (As) are common contaminants of copper (Cu) electrolyte and anodes, necessitating strict control of their concentrations. The purification of Cu electrolytes is required and demands the application of appropri...

  • Article
  • Open Access
1 Citations
695 Views
16 Pages

Supercritical CO2 Extraction from Bacupari (Garcinia brasiliensis) and Leiteira (Tabernaemontana catharinensis) Seeds

  • Guilherme de Souza Lopes,
  • Matheus Almeida Conceição,
  • Carlos Toshiyuki Hiranobe,
  • Camila da Silva,
  • Erivaldo Antônio da Silva,
  • Renivaldo José dos Santos and
  • Leandro Ferreira-Pinto

This study evaluated the extraction of oils from the seeds of bacupari (Garcinia brasiliensis Mart.) and leiteira (Tabernaemontana catharinensis), using carbon dioxide (CO2) in the supercritical state. The effects of temperature (40, 50, and 60 °...

  • Article
  • Open Access
1,852 Views
20 Pages

The substitution of hazardous, environmentally persistent solvents (NMP and DMAc) with more sustainable alternatives (ETAc and GBL) in fabricating flat sheet polyactic acid (PLA) membranes via nonsolvent-induced phase separation for air filtration ap...

  • Article
  • Open Access
1 Citations
1,754 Views
17 Pages

Rare earth elements (REEs) make up integral components in personal electronics, healthcare instrumentation, and modern energy technologies. REE leaching with organic acids is an environmentally friendly alternative to traditional extraction methods....

  • Article
  • Open Access
984 Views
14 Pages

Reduction in Chemical Oxygen Demand of Effluents from the Confectionery Sector of Agroindustry Using the Fenton Process

  • Maiara A. P. Frigulio,
  • Angélica G. Morales,
  • Felipe A. Santos and
  • Juliane C. Forti

25 September 2025

The confectionery industry produces effluents with diverse and complex compositions and high organic loads, which are typically not treated by conventional treatment plants. In this context, the Fenton process presents itself as an advanced chemical...

  • Article
  • Open Access
2 Citations
1,272 Views
18 Pages

Designing a Photocatalyst: Relationship Between Surface Species and Specific Production of Desired ROS

  • Fabrizio E. Viale,
  • Verónica R. Elías,
  • Tamara B. Benzaquén,
  • Gerardo F. Goya,
  • Griselda A. Eimer and
  • Gabriel O. Ferrero

23 September 2025

Bimetallic mesoporous photocatalysts were synthesized via a wet impregnation method using SBA-15 as a support, and characterized by UV–visible diffuse reflectance spectroscopy, low-angle X-ray diffraction and N2 physisorption. Among the tested...

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Sustain. Chem. - ISSN 2673-4079