One-Pot Green Catalytic Preparation of 3-Aminobenzoic Acid in the Presence of Carbonaceous Bio-Based Materials in Subcritical Water †
Abstract
:1. Introduction
2. Experimental
2.1. Reagents
2.2. Synthesis of 3-Aminobenzoic Acid in the Presence of NORIT GAC 12-40 in Subcritical Water
2.3. Gas Chromatography Analysis
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Entry | Material | Material [g] | Yield [%] |
---|---|---|---|
1 | NORIT GAC 12-40 | 3 | 30 |
2 | NORIT GAC 12-40 | 6 | 33 |
3 | NORIT GAC 12-40 | 8 | 15 |
4 | NORIT GAC 12-40 | 10 | 20 |
5 | DACARB PC 1000 | 6 | 1 |
6 | NORIT A supra | 6 | 23 |
7 | NORIT SA2 | 6 | 20 |
Entry | 3-Nitrobenzaldehyde [mmol] | Water [mL] | Temperature [°C] | Time [min] | Yield [%] |
---|---|---|---|---|---|
1 | 10 | 35 | 310 | 6 | 15 |
2 | 10 | 45 | 310 | 6 | 16 |
3 | 10 | 55 | 310 | 6 | 33 |
4 | 10 | 65 | 310 | 6 | 26 |
5 | 10 | 55 | 250 | 6 | 12 |
6 | 10 | 55 | 270 | 6 | 36 |
7 | 10 | 55 | 300 | 6 | 59 |
8 | 10 | 55 | 320 | 6 | 21 |
9 | 5 | 55 | 300 | 6 | 20 |
10 | 20 | 55 | 300 | 6 | 22 |
11 | 30 | 55 | 300 | 6 | 30 |
12 | 30 | 55 | 300 | 2 | 30 |
13 | 30 | 55 | 300 | 4 | 30 |
14 | 30 | 55 | 300 | 8 | 25 |
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Tadrent, S.; Len, C. One-Pot Green Catalytic Preparation of 3-Aminobenzoic Acid in the Presence of Carbonaceous Bio-Based Materials in Subcritical Water. Chem. Proc. 2020, 2, 16. https://doi.org/10.3390/ECCS2020-07541
Tadrent S, Len C. One-Pot Green Catalytic Preparation of 3-Aminobenzoic Acid in the Presence of Carbonaceous Bio-Based Materials in Subcritical Water. Chemistry Proceedings. 2020; 2(1):16. https://doi.org/10.3390/ECCS2020-07541
Chicago/Turabian StyleTadrent, Sarra, and Christophe Len. 2020. "One-Pot Green Catalytic Preparation of 3-Aminobenzoic Acid in the Presence of Carbonaceous Bio-Based Materials in Subcritical Water" Chemistry Proceedings 2, no. 1: 16. https://doi.org/10.3390/ECCS2020-07541
APA StyleTadrent, S., & Len, C. (2020). One-Pot Green Catalytic Preparation of 3-Aminobenzoic Acid in the Presence of Carbonaceous Bio-Based Materials in Subcritical Water. Chemistry Proceedings, 2(1), 16. https://doi.org/10.3390/ECCS2020-07541