Polycyclic Aromatic Hydrocarbons (PAHs): Sources, Detection and Health Effects

A special issue of Atmosphere (ISSN 2073-4433). This special issue belongs to the section "Air Quality and Human Health".

Deadline for manuscript submissions: closed (20 May 2022) | Viewed by 4874

Special Issue Editors


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Guest Editor
The Main School of Fire Service, Faculty of Civil Safety Engineering, 52/54 Slowackiego St., 01-629 Warsaw, Poland
Interests: air pollution; polycyclic aromatic hydrocarbons; aerosol particles; toxicology; exposure; organic compounds; legislation
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Hong Kong
Interests: environmental analytical chemistry; heavy metal contamination; indoor air quality; ambient air analysis; particulate matter pollution; polycyclic aromatic hydrocarbons (PAHs) and oxygenated polycyclic aromatic hydrocarbons (OPAHs) analysis; oxidative stress and bioreactivity analysis; low temperature chemistry

E-Mail Website
Guest Editor
The Main School of Fire Service, Faculty of Civil Safety Engineering, 52/54 Slowackiego St., 01-629 Warsaw, Poland
Interests: environmental impact assessment; environmental analysis; environment; soil; environmental science; environmental analytical chemistry; minerals; environmental management; soil analysis; water quality

Special Issue Information

Dear Colleagues,

Polycyclic aromatic hydrocarbons (PAHs) constitute a diverse class of compounds that consist of two or more fused aromatic rings made up of carbon and hydrogen atoms. PAHs are semi-volatile to volatile compounds and can therefore be found both in the gaseous phase and bound to particles in ambient air. They are hydrophobic molecules with high toxicity and environmental persistence. Harmful potency varies among individual PAHs, and many of them are known carcinogens, mutagenic agents, respiratory irritants and bioaccumulative toxicants.

PAHs are formed mainly during the carbonization and incomplete combustion of organic materials, both fossil fuels and biomass. The major sources of ambient PAH concentrations are power production, gasoline and diesel engine vehicles, waste incineration, iron and steel production, aluminum production, cement manufacturing, dye or rubber tire manufacturing, asphalt industries, as well as fungicide and insecticide production. Due to their potentially carcinogenic, teratogenic, and mutagenic nature, their concentration and distribution in environmental components are extensively investigated worldwide for assessing the total human exposure to PAH.

The atmosphere is a major pathway for the transport and deposition of PAHs. The removal rate of semi-volatile organic compounds by wet and dry deposition is controlled in part by their distribution between particle and gas phases. The meteorological conditions influence the distribution of PAHs in the gaseous and particulate phases and their transfer to water, soil, plants, and other organisms.

In this context, this Special Issue is initiated to be a forum for information exchange on the presence and variability of PAH concentrations in different parts of the world, and aims to cover the following research aspects:

  • Partitioning model of PAHs between gaseous and particulate phases;
  • Distribution and emission sources of PAHs in ambient air;
  • Atmospheric PAHs and meteorological conditions;
  • The polycyclic aromatic hydrocarbons pollution index prediction of urban air;
  • Inhalation exposure to PAHs;
  • PAHs in the atmosphere: health risk assessment.

Prof. Dr. Joanna Rakowska
Dr. Ka Hei LUI
Prof. Dr. Marzena Rachwał
Guest Editors

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Published Papers (2 papers)

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Research

13 pages, 810 KiB  
Article
Health Exposure Assessment of Firefighters Caused by PAHs in PM4 and TSP after Firefighting Operations
by Joanna Rakowska, Marzena Rachwał and Agata Walczak
Atmosphere 2022, 13(8), 1263; https://doi.org/10.3390/atmos13081263 - 10 Aug 2022
Cited by 6 | Viewed by 2127
Abstract
Among the many different chemicals in the air, polycyclic aromatic hydrocarbons (PAHs) pose a serious threat to human health. Firefighters are exposed to them both during fire suppression and in fire vehicles and fire stations due to inhalation of the fumes from contaminated [...] Read more.
Among the many different chemicals in the air, polycyclic aromatic hydrocarbons (PAHs) pose a serious threat to human health. Firefighters are exposed to them both during fire suppression and in fire vehicles and fire stations due to inhalation of the fumes from contaminated clothing and personal protective equipment. This study aimed to estimate the exposure and cancer risk caused by suspended particulate matter and PAHs present in these particles. Air samples were collected for 4 months in a garage of the fire station in a small town, located in an urban–rural area. PAH concentrations were measured using the gas chromatography method with mass spectrometry (GC/MS). The concentration of PM4 (particulate matter with a diameter below 4µm) and TSP (total suspended particulate) in the fire station garage was 7 and 9 times higher than outside, respectively. The calculated values of health hazard risks associated with the exposure to PAHs in PM4 and TSP are: a toxic equivalent (TEQ) up to 10.36 and 23.3, incremental lifetime cancer risk (ILCR) up to 3.45 and 4.65 and hazard quotient (HQ) up to 0.42 and 0.57, respectively. A significantly increased risk of cancers in the professional group of firefighters was found. Full article
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14 pages, 2207 KiB  
Article
Optimization of the Efficient Extraction of Organic Components in Atmospheric Particulate Matter by Accelerated Solvent Extraction Technique and Its Application
by Hao Zhang, Yanqin Ren, Jie Wei, Yuanyuan Ji, Xurong Bai, Yanqiu Shao, Hong Li, Rui Gao, Zhenhai Wu, Zhijian Peng and Feng Xue
Atmosphere 2022, 13(5), 818; https://doi.org/10.3390/atmos13050818 - 17 May 2022
Cited by 3 | Viewed by 2169
Abstract
Organic components in atmospheric fine particulate matter have attracted much attention and several scientific studies have been performed, although most of the sample extraction methods are time consuming and laborious. Accelerated solvent extraction (ASE) is a new sample extraction method offering number of [...] Read more.
Organic components in atmospheric fine particulate matter have attracted much attention and several scientific studies have been performed, although most of the sample extraction methods are time consuming and laborious. Accelerated solvent extraction (ASE) is a new sample extraction method offering number of advantages, such as low extraction cost, reduced solvent and time consumption, and simplified extraction protocols. In order to optimize ASE methods to determine the concentrations of organic compounds in atmospheric fine particulate matter, different parameters were set out for the experiment, and the optimal method was selected according to the recoveries of the standard (i.e., n−alkanes and polycyclic aromatic hydrocarbons (PAHs)). This study also involves a comparison of the optimal method with the traditional method of ultrasonic extraction (USE). In addition, the optimized method was applied to measure the mass concentrations of organic compounds (n−alkanes and PAHs) in fine particulate matter samples collected in Beijing. The findings showed that the average recovery of target compounds using ASE was 96%, with the majority of compounds falling within the confidence levels, and the ASE recoveries and precision were consistent with the USE method tested. Furthermore, ASE combines the advantages of high extraction efficiency, automation, and reduced solvent use. In conclusion, the optimal ASE methods can be used to extract organic components in atmospheric particulate matter and serve as a point of reference for the development of analytical methodologies for assessing organic compounds in atmospheric particulate matter in China. Full article
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