New Catalysts in Green Chemistry: from Conversion of Renewable Biomass to Elimination of Organic Pollutants

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Environmental Catalysis".

Deadline for manuscript submissions: closed (31 December 2020) | Viewed by 3716

Special Issue Editors


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Guest Editor
Department of Agricultural Sciences, Università degli Studi di Napoli “Federico II”, 80055 Naples, Italy
Interests: heterogenous catalysis; agrochemicals chemistry; remediation processes; biocatalyst; reuse of agricultural waste

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Guest Editor
Department of Chemical, Materials and Production Engineering, Università degli Studi di Napoli “Federico II”, Naples, Italy
Interests: enzymatic and fermentative bioreactors; advanced catalysts
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Special Issue Information

Dear Colleagues,

The search for new catalysts plays a key role in the development of risk-free chemical processes, and more generally in green chemistry. Catalytically active nanomaterials with improved activity and stability for biomass conversion have become, in recent years, an important topic in view of the transition towards a bio-based economy. In particular, it is important to study new solid acid catalysts with tailored properties in terms of both type and density of acid sites and water tolerance, as in bio-refinery reactions are carried out in the presence of water as vapor or even in liquid state.

It is recognized that the conversion of lignocellulosic materials into fuels can become an economically feasible process only if coupled with the production of valuable chemicals.

Hexoses and pentoses are the carbohydrates that represent the largest component of biomass and are widely found in almost all the biomass species. Acid-catalyzed dehydration of hexoses and pentoses is a demanding reaction due to the huge market potential of the resulting 5-hydroxymethylfurfural (HMF) and furfural products, being these products’ key intermediates in future biorefineries.

Innovative systems for organic pollutants abatement in advanced sustainable oxidative processes are a great challenge, as well. Clean water is one of the biggest concerns of future society, as the concentrations of several types of contaminants (pharmaceuticals, pesticides, and metabolites) are increasing. The main techniques applied to perform the purification of wastewater, such as adsorption by the use of activated carbon, biological treatment, and filtration, do not eliminate these contaminants completely. Therefore, novel water purification methods need to be developed. In this view, advanced oxidation processes involving the generation of reactive oxygen species (ROS), in particular, the  heterogeneous photocatalysis, offer promising technology to remove most of organic contaminants.

Prof. Dr. Filomena Sannino
Prof. Dr. Domenico Pirozzi
Guest Editors

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Keywords

  • Biorefinery
  • Heterogenous catalysis
  • Green chemistry
  • Renewable biomass
  • Advanced oxidation
  • Water treatment
  • Organic pollutants

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Published Papers (1 paper)

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Research

20 pages, 2185 KiB  
Article
Long-Term Storage and Use of Artificially Immobilized Anaerobic Sludge as a Powerful Biocatalyst for Conversion of Various Wastes Including Those Containing Xenobiotics to Biogas
by Olga Senko, Marina Gladchenko, Olga Maslova and Elena Efremenko
Catalysts 2019, 9(4), 326; https://doi.org/10.3390/catal9040326 - 2 Apr 2019
Cited by 27 | Viewed by 3418
Abstract
The aim of this paper is to demonstrate the possibilities of anaerobic sludge cells immobilized into poly(vinyl alcohol) cryogel for the methanogenic conversion of various lignocellulosic waste and other media containing antibiotics (ampicillin, kanamycin, benzylpenicillin) or pesticides (chlorpyrifos or methiocarb and its derivatives). [...] Read more.
The aim of this paper is to demonstrate the possibilities of anaerobic sludge cells immobilized into poly(vinyl alcohol) cryogel for the methanogenic conversion of various lignocellulosic waste and other media containing antibiotics (ampicillin, kanamycin, benzylpenicillin) or pesticides (chlorpyrifos or methiocarb and its derivatives). It was established that the immobilized cells of the anaerobic consortium can be stored frozen for at least three years while preserving a high level of metabolic activity. The cells after the long-term storage in an immobilized and frozen state were applied for the methanogenesis of a wide number of wastes, and an increase in both methane yield and methane portion in the produced biogas as compared to the conventionally used suspended anaerobic sludge cells, was ensured. It was shown that the “additional” introduction of bacterial Clostridium acetobutylicum, Pseudomonas sp., Enterococcus faecalis cells (also immobilized using same support) improves characteristics of methanogenesis catalyzed by immobilized anaerobic sludge. Full article
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