Advances in Halide Perovskites

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Materials for Energy Applications".

Deadline for manuscript submissions: 20 June 2024 | Viewed by 1290

Special Issue Editors


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Guest Editor
Department of Physics and Materials Science, University of Luxembourg, L-1511 Luxembourg, Luxembourg
Interests: perovskite; material characterization; thin films and nanotechnology; surface characterization; nanomaterials; thin-film deposition

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Guest Editor
Wuhan National Laboratory for Optoelectronics (WNLO), Huazhong University of Science and Technology (HUST), Wuhan, China
Interests: perovskite solar cells; perovskite optoelectronic devices

Special Issue Information

Dear Colleagues,

Organic–inorganic halide perovskite materials have experienced tremendous interest from the research community due to their easy fabrication process and high-power conversion efficiency (PCE). Compared to silicon technology, perovskites have the potential to be employed on flexible substrates and semi-transparent windows, areas where silicon is absent. In less than 15 years, the best perovskite solar cell devices have passed the benchmark of 25.8% PCE, making this emerging technology competitive with conventional silicon cells. Efficiency is not the main challenge anymore in perovskite materials; the research community is now slowly shifting toward a more fundamental and crucial question, which is: “How to build perovskite cells with long-term stability”? In order to facilitate the commercialization of perovskite solar cells, their stability needs to be improved to compete with other technology on the market. In this Special Issue of Crystals, we would like to collect some pioneering works in the field that investigate innovative approaches to increase the stability of perovskite absorbers, such as material composition, halide and cation mixing, surface passivation, interface layers, 2D perovskites, crystal structure and orientation, and more.

Dr. Jérémy Hieulle
Dr. Zonghao Liu
Guest Editors

Manuscript Submission Information

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Keywords

  • perovskite
  • long-term stability
  • surface passivation
  • 2D perovskite
  • halide mixing and cation mixing
  • crystal orientation

Published Papers (1 paper)

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Research

13 pages, 15465 KiB  
Article
Lead-Free Organic Manganese (II) Bromide Hybrid with Highly Efficient and Stable Green Emission for UV Photodetection
by Ye Tian, Qilin Wei, Lian Duan and Chengyu Peng
Crystals 2023, 13(12), 1678; https://doi.org/10.3390/cryst13121678 - 12 Dec 2023
Viewed by 1068
Abstract
Lead halide perovskites have been widely used in optoelectronic devices due to their excellent properties; however, the toxicity of lead and the poor stability of these perovskites hinder their further application. Herein, we report a zero-dimensional (0D) lead-free organic manganese (II) bromide hybrid [...] Read more.
Lead halide perovskites have been widely used in optoelectronic devices due to their excellent properties; however, the toxicity of lead and the poor stability of these perovskites hinder their further application. Herein, we report a zero-dimensional (0D) lead-free organic manganese (II) bromide hybrid compound of (TBA)2MnBr4 (TBA+ = tetrabutylammonium cation) single crystals (SCs) with great environmental stability. The (TBA)2MnBr4 SCs show a strong green emission peak at 518 nm with a high photoluminescence quantum yield (PLQY) of 84.98% at room temperature, which is attributed to the d-d transition of single Mn2+ ions, as also confirmed through density functional calculation. A green light-emitting diode was produced based on (TBA)2MnBr4 SCs, which exhibited CIE coordinates (0.17, 0.69) close to those of standard green. A photodetector fabricated by the (TBA)2MnBr4 SCs shows an obvious photo response with a rapid millisecond rise/decay response time (at 365 nm). Our findings promote the research of Mn(II)-based organic–inorganic hybrid materials and pave the way by using these materials for future high-performance optoelectronic devices. Full article
(This article belongs to the Special Issue Advances in Halide Perovskites)
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