Fuels

Since the hydrogen-production process is not yet fully efficient, this paper proposes a poly-generation system that is driven by a geothermal energy source and utilizes a combined Kalina/organic Rankine cycle coupled with an electrolyzer unit to produce, simultaneously, power and green hydrogen in an efficient way. A comprehensive thermodynamic analysis and an exergetic evaluation are carried out to assess the effect of key system parameters (geothermal temperature, high pressure, ammonia–water concentration ratio, and terminal thermal difference) on the performance of concurrent production of power and green hydrogen. Thereby, two configurations are investigated with/without the separation of turbines. The optimal ammonia mass fraction of the basic solution in KC is identified, which leads to an overall optimal system performance in terms of exergy efficiency and green hydrogen production rate. In both configurations, the optimal evaluation is made possible by conducting a genetic algorithm optimization. The simulation results without/with the separation of turbines demonstrate the potential of the suggested cycle combination and emphasize its effectiveness and efficiency. Exemplary, for the case without the separation of turbines, it turns out that the combination of ammonia–water and MD2M provides the best performance with net power of 1470 kW, energy efficiency of 0.1184, and exergy efficiency of 0.1258 while producing a significant green hydrogen amount of 620.17 kg/day. Finally, an economic study allows to determine the total investment and payback time of $3,342,000 and 5.37 years, respectively. The levelized cost of hydrogen (LCOH) for the proposed system is estimated at 3.007 USD/kg H₂, aligning well with values reported in the literature. Full article

This study conducts a life cycle assessment (LCA) of a microalgae-based biorefinery producing biofuels, using a well-to-tank approach. Microalgae were cultivated using greenhouse wastewater, while the extracted lipids were converted to biofuels via catalytic hydrotreatment. Experimental data supported an Aspen Plus model to generate inventory data for the LCA. The assessment incorporated multiple environmental metrics, including global warming potential (GWP), net energy ratio (NER) etc., under variant energy sources scenarios. Results show a low GWP (0.86 kg CO₂-eq/MJ) and a NER (3.7), indicating favorable environmental performance, while the downstream processes were identified as the most energy-intensive. Sensitivity analysis highlighted the critical role of energy sources, with renewable energy improving the sustainability compared to fossil-based inputs. Overall, the results support the viability of wastewater-grown microalgae for sustainable biofuel production, particularly when integrated with low-impact energy sources. Full article

Fuel cells have become a fundamental technology in the development of clean energy systems, playing a vital role in the global shift toward a low-carbon future. With the growing need for sustainable hydrogen production, perfluoro sulfonic acid (PFSA) ionomer membranes play a critical role in optimizing green hydrogen technologies and fuel cells. This study aims to investigate the effects of different environmental and solvent treatments on the chemical and physical properties of Nafion N−115 membranes to evaluate their suitability for both hydrogen production in proton exchange membrane (PEM) electrolyzers and hydrogen utilization in fuel cells, supporting integrated applications in the local and global green hydrogen economy. To achieve this, Nafion N−115 membranes were partially dissolved in various solvent mixtures, including ethanol/isopropanol (EI), isopropanol/water (IW), dimethylformamide/N-methyl-2-pyrrolidone (DN), and ethanol/methanol/isopropanol (EMI), evaluated under water immersion and thermal stress, and characterized for chemical stability, mechanical strength, water uptake, and proton conductivity using advanced electrochemical and spectroscopic techniques. The results demonstrated that the EMI-treated membrane showed the highest proton conductivity and maintained its structural integrity, making it the most promising for hydrogen electrolysis applications. Conversely, the DN-treated membrane exhibited reduced stability and lower conductivity due to solvent-induced degradation. This study highlights the potential of EMI as an optimal solvent mixture for enhancing PFSA membranes performance in green hydrogen production, contributing to the advancement of sustainable energy solutions. Full article

Samples of refined petroleum fuels from the three major oil-marketing companies (GOIL Company Limited, Total Energies Ghana Limited and Shell Vivo Ghana Limited) in Ghana have been analysed for elemental concentrations using an X-ray fluorescence facility at the National Nuclear Research Institute, Ghana Atomic Energy Commission. The samples were acquired from seven different fuel service stations where customers directly purchase refined petroleum fuels such as diesel, petrol and kerosene. The X-ray fluorescence method was considered for the study because sample preparation does not require the addition of reagents, and the fluorescence measurements involve a direct electron transition effect. The fluorescence study was carried out to estimate the concentrations of sulphur and other contaminants in the major refined petroleum fuel products patronised in Ghana. The average sulphur concentration in the samples of diesel products were 17.543, 25.805 and 26.813 ppm in DFS, DE and DXP samples compared to 22.258, 22.623 and 15.748 ppm in petrol samples of PE, PXP and VP. Also, the sulphur concentration of sample KE, kerosene products, is 33.250 ppm. Among the diesel samples, DE and DXP recorded the highest but most comparable average concentration of elemental contaminants, and DFS the least, while PXP recorded the least among the petrol samples. The study estimated the concentrations of four heavy metal elements that are toxic to biological life (Hg, Pb, Cr and Mn) to be less than 10.0 ppm, except Cr. The study concluded that most of the elemental contaminants of heavy metals in the samples were relatively less than ultra-low levels. Therefore, exhaust emissions may have little impact on the environment. Also, the content of the ash-producing metal elements in each sample of the seven refined fuel products is between 10.0 and 50.0 ppm. Since the concentration of sulphur and a few other elemental contaminants could not meet the internationally accepted standard (<10.0 ppm), the imported refined fuel products used in Ghana may be considered relatively good but not environmentally safe. Full article

Plugs of lignite coal from multiple formations were subjected to a series of tests to determine the amount of rare-earth elements (REEs) to be extracted from coal in an in situ mining operation. These tests were used to determine if extraction of REEs and other critical minerals in an in situ environment would be possible for future attempts as an alternative to extraction mining. The tests involved subjecting whole lignite coal plugs from the Twin Butte coal seams in North Dakota to flow-through tests of water, and concentrations of 1.0 M ammonium nitrate, 1.0 M and 1.5 M sulfuric acid, and 1.0 M and 1.5 M hydrochloric acid (HCl) solvents at different concentrations and combinations. The flow-through testing was conducted by alternating the solvent and water flow-through to simulate an in situ mining scenario. The samples were analyzed for their concentrations of REEs (lanthanum [La], cerium [Ce], praseodymium [Pr], neodymium [Nd], samarium [Sm], europium [Eu], gadolinium [Gd], terbium [Tb], dysprosium [Dy], holmium [Ho], erbium [Er], thulium [Tm], ytterbium [Yb], lutetium [Lu], yttrium [Y], and scandium [Sc], as well as germanium [Ge] and cobalt [Co], manganese [Mn], nickel [Ni], and barium [Ba]). Results from the testing showed that REEs were extracted in concentrations that were on average higher using sulfuric acid (8.9%) than with HCl (5.8%), which had a higher recovery than ammonium nitrate. Tests were performed over a standard time interval for comparison between solvents, while a second set of testing was done to determine recovery rates of REEs and critical minerals under certain static and constant flow-through times to determine extraction in relation to time. Critical minerals had a higher recovery rate than the REEs across all tests, with a slightly higher recovery of light REEs over heavy REEs. Full article

This work focuses on the fabrication, characterization, and performance of a structured iron catalyst to produce hydrocarbons by the Fischer–Tropsch synthesis (FTS). The structured catalyst enhances the heat and mass transfer and provides a larger surface area and lower pressure drop. Iron-based structured catalysts indicate more activity in lower H₂/CO ratios and improve carbon conversion as compared to other metals. These catalysts were manufactured using the sponge replication method (powder metallurgy). The performance of the structured iron catalyst was assessed in a fixed-bed reactor under industrially relevant conditions (250 °C and 20 bar). The feed gas was a synthetic syngas with a H₂/CO ratio of 1.2, simulating a bio-syngas derived from lignocellulosic biomass gasification. Notably, the best result was reached under these conditions, obtaining a CO conversion of 84.8% and a CH₄ selectivity of 10.4%, where the catalyst exhibited a superior catalytic activity and selectivity toward desired hydrocarbon products, including light olefins and long-chain paraffins. The resulting structured catalyst reached a one-pass CO conversion of 84.8% with a 10.4% selectivity to CH₄ compared to a traditionally produced catalyst, for which the conversion was 18% and the selectivity was 19%, respectively. The results indicate that the developed structured iron catalyst holds considerable potential for efficient and sustainable hydrocarbon production, mainly C10–C20 (diesel-range hydrocarbons), via Fischer–Tropsch synthesis. The catalyst’s excellent performance and improved stability and selectivity offer promising prospects for its application in commercial-scale hydrocarbon synthesis processes. Full article

The utilization of ammonia as a fuel for gas turbines involves practical challenges due to its low reactivity, narrow flammability limits, and slow laminar flame propagation. One of the potential solutions to enhance the combustion reactivity of ammonia is co-firing with syngas. This paper presents an experimental and numerical investigation of the laminar burning velocity (LBV) of ammonia/syngas/air mixtures under elevated pressures (up to 10 bar) and temperatures (up to 473 K). Experiments were conducted in a constant-volume combustion chamber with a total volume of 11 L equipped with a dual-electrode capacitive discharge ignition system. A systematic sensitivity analysis was conducted to experimentally evaluate the system performance under various syngas compositions and equivalence ratios from 0.7 to 1.6 and ultimately identify the factors with the most impact on the system. As a complement to the experiments, a detailed numerical simulation was carried out integrating available kinetic mechanisms—chemical reaction sets and their rates—to support advancements in the understanding and optimization of ammonia/syngas co-firing dynamics. The sensitivity analysis results reveal that LBV is significantly enhanced by increasing the hydrogen content (>50%). Furthermore, the LBV of the gas mixture is found to increase with the use of a rich flame, higher mole fractions of syngas, and higher initial temperatures. The results indicate that higher pressure reduces LBV by 40% but at the same time enhances the adiabatic flame temperature (by 100 K) due to an equilibrium shift. The analysis was also extended to quantify the impact of syngas mole fractions and elevated initial temperatures. The kinetics of the reactions are analyzed through the reaction pathways, and the results reveal how the preferred pathways vary under lean and rich flame conditions. These findings provide valid quantitative design data for optimizing the combustion kinetics of ammonia/syngas blends, offering valuable design data for ammonia-based combustion systems in industrial gas turbines and power generation applications, reducing NOₓ emissions by up to 30%, and guiding future research directions toward kinetic models and emission control strategies. Full article

Experimental research was conducted to characterize the ignition delay time and combustion performance of non-toxic reactants as a possible replacement for highly toxic fuels, such as hydrazine. The liquid fuel and oxidizer were N,N,N′,N′-tetramethylethylenediamine (TMEDA) and white fuming nitric acid (WFNA), respectively. The hypergolic ignition delay of the reactants was determined using 100% TMEDA with either >90% or >99.5% WFNA that was distilled, titrated, and droplet-tested in a laboratory setting while controlling the parameters that affect the quality of the yielded product. It was observed that >90% WFNA had three times longer average ignition delay than >99.5% WFNA with both mixtures producing ignition delay times less than 20 ms. Based upon the demonstrated hypergolic droplet test results, a fluid delivery feed system and hypergolic heavyweight bipropellant rocket engine were designed and fabricated to characterize the combustion efficiency of these non-toxic reactants. The rocket injector and characteristic length differed while operating under similar flow conditions to evaluate combustion efficiency. Results demonstrated similar engine performance between both cases of WFNA with improvements of over 30% in combustion efficiency with increased characteristic length. Tests using 100% TMEDA/>90% WFNA achieved a combustion efficiency of 88%. Full article

Vegetable oils are an important alternative to the massive use of fuels and lubricants from non-renewable energy sources. In this study, the physicochemical properties of coconut oil and waste cooking oil are investigated for biofuels and biolubricant applications. A transesterification of both oils was reached, and the transesterified oils were characterized by infrared analysis and gas chromatography. The lubricant performances of these oils have been evaluated using a ball-on-plane tribometer under an ambient atmosphere. Different formulations were developed using graphite particles as solid additive. Each initial and modified oil has been investigated as a base oil and as a liquid additive lubricant. The best friction reduction findings have been obtained for both initial oils as liquid additives, highlighting the key role of triglycerides in influencing tribological performances. Full article

Vibration-stimulated waterflooding (VS-WF) is a promising enhanced oil recovery (EOR) method, especially for reservoirs with high-viscosity or emulsified oil. This study explores the effect of low-frequency vibration (2 Hz and 5 Hz) on oil mobilization under constant pressure and flow rate, using both crude and emulsified oil samples. Vibration significantly improves recovery by inducing stick-slip flow, lowering the threshold pressure, and enhancing oil phase permeability while suppressing the water phase flow. Crude oil recovery increased by up to 24% under optimal vibration conditions, while emulsified oil showed smaller gains due to higher viscosity. Intermittent vibration achieved similar recovery rates to continuous vibration, but with reduced energy use. Statistical analysis revealed a strong correlation between pressure fluctuations and oil production in vibration-assisted tests, but no such relationship in non-vibration cases. These results provide insight into the mechanisms behind vibration-enhanced recovery, supported by analysis of pressure and flow rate responses during waterflooding. Full article

Biobutanol is becoming more relevant as a promising alternative biofuel, primarily due to its advantageous characteristics. These include a higher energy content and density compared to traditional biofuels, as well as its ability to mix effectively with gasoline, further enhancing its viability as a potential replacement. A viable strategy for attaining carbon neutrality, reducing reliance on fossil fuels, and utilizing sustainable and renewable resources is the use of biomass to produce biobutanol. Lignocellulosic materials have gained widespread recognition as highly suitable feedstocks for the synthesis of butanol, together with various value-added byproducts. The successful generation of biobutanol hinges on three crucial factors: effective feedstock pretreatment, the choice of fermentation techniques, and the subsequent enhancement of the produced butanol. While biobutanol holds promise as an alternative biofuel, it is important to acknowledge certain drawbacks associated with its production and utilization. One significant limitation is the relatively high cost of production compared to other biofuels; additionally, the current reliance on lignocellulosic feedstocks necessitates significant advancements in pretreatment and bioconversion technologies to enhance overall process efficiency. Furthermore, the limited availability of biobutanol-compatible infrastructure, such as distribution and storage systems, poses a barrier to its widespread adoption. Addressing these drawbacks is crucial for maximizing the potential benefits of biobutanol as a sustainable fuel source. This document presents an extensive review encompassing the historical development of biobutanol production and explores emerging trends in the field. Full article

This study investigates the energy performance of paraffin-based hybrid fuels enhanced with potassium nitrate (KNO₃), ammonium nitrate (NH₄NO₃), aluminum (Al), titanium (Ti), and stearic acid additives. The fuels were evaluated using thermochemical calculations via ProPEP3 Version 1.0.3.0 software, revealing significant improvements in specific impulse (I_sp) and combustion temperature. While formulations with nitrates and aluminum exhibited noticeable increases in combustion efficiency and thermal output, titanium-containing mixtures provided moderate improvements. Stearic acid improved fuel processability and provided a stable burning profile without significant energy penalties. These findings demonstrate that suitable combinations of additives can substantially improve the energy output of paraffin-based hybrid fuels, making them more viable for aerospace propulsion applications. Full article

Alternative energies have become relevant in global strategies to address climate change, and third-generation biodiesel derived from the generation of lipids from microalgae represents a viable option. This process can also be coupled with wastewater treatment to remove organic matter. To determine the effects of two catalyst levels (1 and 1.5% KOH) and two molar ratios of alcohol (methanol) with oil (1:6 and 1:9) on the conversion of lipids into FAMEs and the quality of the biodiesel produced, this work suggests a method for the ultrasonication-based extraction of lipids from C. vulgaris. It also employs an experimental 2² design and three replicates. It was found that with a molar ratio of 1:9 and a 1% catalyst, the highest yield of 98.48 ± 1.13% was achieved. The FAME profile was similar to the profiles obtained in cultures with bold basal medium or INETI. The quality of the biodiesel met ASTM standards, achieving refractive indices of 1.435–1.478. The flash point (FP) was 165 ± 18 °C, and the acid number was 0.31 ± 0.17 mg KOH/g. The viscosity ranged from 4.33 to 4.87 mm²/s. However, the rheological behavior was correlated with the Ostwald–de Waele model with pseudoplastic behavior. Full article

The global energy sector is aiming to substantially reduce CO₂ emissions to meet the UN climate goals. Among the proposed strategies, underground storage solutions such as radioactive disposal, CO₂, NH₃, and underground H₂ storage (UHS) have emerged as promising options for mitigating anthropogenic emissions. These approaches require rigorous research and development (R&D), often involving laboratory-scale experiments to establish their feasibility before being scaled up to pilot plant operations. Microorganisms, which are ubiquitous in laboratory environments, can significantly influence geochemical reactions under variable experimental conditions of porous media and a salt cavern. We have selected a consortium composed of Bacillus sp., Enterobacter sp., and Cronobacter sp. bacteria, which are typically present in the laboratory environment. These microorganisms can contaminate the rock sample and develop experimental artifacts in UHS experiments. Hence, it is pivotal to sterilize the rock prior to conduct experimental research related to effects of microorganisms in the porous media and the salt cavern for the investigation of UHS. This study investigated the efficacy of various disinfection and sterilization methods, including ultraviolet irradiation, autoclaving, oven heating, ethanol treatments, and gamma irradiation, in removing the microorganisms from silica sand. Additionally, the consideration of their effects on mineral properties are reviewed. A total of 567 vials, each filled with 9 mL of acid-producing bacteria (APB) media were used to test killing efficacy of the cleaning methods. We conducted serial dilutions up to 10⁻⁸ and repeated them three times to determine whether any deviation occurred. Our findings revealed that gamma irradiation and autoclaving were the most effective techniques for eradicating microbial contaminants, achieving sterilization without significantly altering the mineral characteristics. These findings underscore the necessity of robust cleaning protocols in hydrogeochemical research to ensure reliable, reproducible data, particularly in future studies where microbial contamination could induce artifacts in laboratory research. Full article

This study presents a comprehensive characterization of oak biochar produced via downdraft gasification at 850 °C. The research employs a wide range of advanced analytical techniques to examine the biochar’s physical, chemical, and structural properties. Scanning electron microscopy (SEM) revealed a mesoporous structure, while Brunauer–Emmett–Teller (BET) analysis showed a surface area of 88.97 m²/g. Thermogravimetric analysis (TGA) demonstrated high thermal stability and carbon content (78.7%). X-ray photoelectron spectroscopy (XPS) and ultimate analysis confirmed the high degree of carbonization, with low O/C (0.178) and H/C (0.368) ratios indicating high aromaticity. Fourier transform infrared spectroscopy (FTIR) identified functional groups suggesting potential for CO₂ adsorption. The biochar exhibited a negative zeta potential (−31.5 mV), indicating colloidal stability and potential for soil amendment applications. X-ray diffraction (XRD) and Raman spectroscopy provided insights into the biochar’s crystalline structure and graphitization degree. These findings highlight the oak biochar’s suitability for diverse applications, including soil improvement, carbon sequestration, and environmental remediation. By filling knowledge gaps in oak-specific biochar research, this study underscores the benefits of optimized downdraft gasification and sets a foundation for future advancements in sustainable biochar applications. Full article

In bulk liquid or on solid surfaces, nanobubbles (NBs) are gaseous domains at the nanoscale. They stand out due to their extended (meta)stability and great potential for use in practical settings. However, due to the high energy cost of bubble generation, maintenance issues, membrane bio-fouling, and the small actual population of NBs, significant advancements in nanobubble engineering through traditional mechanical generation approaches have been impeded thus far. With the introduction of the electric field approach to NB creation, which is based on electrostrictive NB generation from an incoming population of “electro-fragmented” meso-to micro bubbles (i.e., with bubble size broken down by the applied electric field), when properly engineered with a convective-flow turbulence profile, there have been noticeable improvements in solid-state operation and energy efficiency, even allowing for solar-powered deployment. Here, these innovative methods were applied to a selection of upstream and downstream activities in the oil–water–fuels nexus: advancing core flood tests, oil–water separation, boosting the performance of produced-water treatment, and improving the thermodynamic cycle efficiency and carbon footprint of internal combustion engines. It was found that the application of electric field NBs results in a superior performance in these disparate operations from a variety of perspectives; for instance, ~20 and 7% drops in surface tension for CO₂- and air-NBs, respectively, a ~45% increase in core-flood yield for CO₂-NBs and 55% for oil–water separation efficiency for air-NBs, a rough doubling of magnesium- and calcium-carbonate formation in produced-water treatment via CO₂-NB addition, and air-NBs boosting diesel combustion efficiency by ~16%. This augurs well for NBs being a potent agent for sustainability in the oil and fuels sector (whether up-, mid-, or downstream), not least in terms of energy efficiency and environmental sustainability. Full article

This research work seeks to introduce eco-friendly, low-carbon, and high-octane biofuel gasoline production using a synergistic approach. Four types of high-octane gasoline, including SynergyFuel-92, SynergyFuel-95, SynergyFuel-98, and SynergyFuel-100, were generated, emphasizing the deliberate combination of petroleum-derived gasoline fractions using reformate, isomerate, and delayed coking (DC) naphtha with octane-boosting compounds—bio-methanol and bio-ethanol. A set of tests have been performed to examine the effects of antiknock properties, density, oxidation stability, distillation range characteristics, hydrocarbon composition, vapor pressure, and the volatility index on gasoline blends. The experimental results indicated that the gasoline blends made from biofuel (SynergyFuel-92, -95, -98, and 100) showed adherence to important fuel quality criteria in the USA, Europe, and China. These blends had good characteristics, such as low quantities of benzene and sulfur, regulated levels of olefins and aromatics, and good distillation qualities. By fulfilling these strict regulations, Synergy Fuel is positioned as a competitive and eco-friendly substitute for traditional gasoline. The results reported that SynergyFuel-100 demonstrated the strongest hot-fuel-handling qualities and resistance to vapor lock among all the mentioned Synergy Fuels. Finally, the emergence of eco-friendly, low-carbon, and high-octane biofuel gasoline production with synergistic benefits is a big step in the direction of sustainable transportation. Full article

To investigate the combustion characteristics of moxa under a nitrogen atmosphere, this study employed an integrated approach combining experimental and theoretical analysis. Twelve moxa floss samples with different leaf-to-floss ratios, geographical origins, and storage durations were selected for thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FTIR) of their carbonized products in nitrogen environment. Through TG-DTG analysis, the thermal degradation patterns of the twelve moxa floss samples under nitrogen atmosphere were systematically examined to elucidate their pyrolysis behaviors, with particular emphasis on the influence of pyrolysis temperature and leaf-to-floss ratio on combustion characteristics. The pyrolysis process occurred in three distinct stages, with the most significant mass loss (120–430 °C) observed in the second stage. Higher leaf–fiber ratios and longer storage years were found to promote more complete pyrolysis. Kinetic analysis was performed to fit thermogravimetric data, establishing a reaction kinetic model for moxa pyrolysis. Results indicated that samples with higher leaf–fiber ratios required greater activation energy, while storage duration showed negligible impact. Notably, Nanyang moxa demanded higher pyrolysis energy than Qichun moxa. FTIR analysis identified the primary components of carbonized products as water, ester compounds, flavonoids, and cellulose. These findings suggest that moxa carbonization products retain chemical reactivity, demonstrating potential applications in adsorption and catalysis processes. Full article

This paper presents the results of a study of the catalytic hydrogenation of phenanthrene using catalysts based on chrysotile modified with nickel and titanium (chrysotile/NiTi), as well as coal shale. Complex characterization of catalysts in terms of acid, texture and morphological properties was carried out. Pre-reduction in the catalysts has been found to increase the yield of partially and fully hydrogenated products, including tetrahydronaphthalene, trans-decalin and dihydrophenanthrene. Particular attention is paid to the role of coal shale as a donor source of hydrogen in thermolysis conditions. The results of hydrogenation revealed complex mechanisms of phenanthrene transformations, including partial saturation of aromatic rings, desulfurization and the formation of alkyl-substituted compounds. The obtained data emphasize the prospects of using the studied catalysts in the processes of processing heavy and solid hydrocarbon raw materials, which opens up opportunities for creating new technologies for the production of liquid fuel. Full article