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Editor’s Choice Articles

Editor’s Choice articles are based on recommendations by the scientific editors of MDPI journals from around the world. Editors select a small number of articles recently published in the journal that they believe will be particularly interesting to readers, or important in the respective research area. The aim is to provide a snapshot of some of the most exciting work published in the various research areas of the journal.

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14 pages, 1567 KB  
Article
Osteogenic Potential of Various Premixed Hydraulic Calcium Silicate-Based Sealers on Human Bone Marrow Stem Cells
by Na-Hyun You, Donghee Lee, Yemi Kim, Sieun Nam and Sin-Young Kim
Materials 2025, 18(23), 5326; https://doi.org/10.3390/ma18235326 - 26 Nov 2025
Cited by 1 | Viewed by 890
Abstract
This study aims to compare the osteogenic potential of premixed hydraulic calcium silicate-based sealers (HCSSs) with an epoxy resin-based sealer in human bone marrow-derived stem cells (hBMSCs). Three HCSSs (White Endoseal MTA, One-Fil, EndoSequence BC Sealer) were compared with AH Plus Jet, an [...] Read more.
This study aims to compare the osteogenic potential of premixed hydraulic calcium silicate-based sealers (HCSSs) with an epoxy resin-based sealer in human bone marrow-derived stem cells (hBMSCs). Three HCSSs (White Endoseal MTA, One-Fil, EndoSequence BC Sealer) were compared with AH Plus Jet, an epoxy resin-based sealer. Disk-shaped specimens were prepared using sterilized Teflon tubes and immersed in osteogenic medium to create eluates. hBMSCs were cultured in each eluate, and osteogenic potential was assessed by alkaline phosphatase (ALP) activity (n = 6), Alizarin Red-S (ARS) staining (n = 6), quantitative real-time polymerase chain reaction (qPCR) (n = 3), and Western blot analysis. Statistical analyses were conducted using SPSS (version 24.0), with significance set at p < 0.05. All experimental groups exhibited higher ALP activity than the control on day 4. ARS staining of HCSSs differed significantly from AH Plus Jet on day 14 (p < 0.05), while White Endoseal MTA exhibited the highest intensity. qPCR revealed that EndoSequence BC Sealer induced the highest SMAD1 expression on day 4, while One-Fil and EndoSequence BC Sealer significantly upregulated RUNX2 expression compared with AH Plus Jet (p < 0.05). Western blotting confirmed that EndoSequence BC Sealer induced the highest RUNX2 protein expression. Collectively, premixed HCSSs promoted superior mineralization and RUNX2 expression compared to conventional resin-based sealer in hBMSCs. Full article
(This article belongs to the Special Issue Development and Research of New Dental Materials)
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14 pages, 4599 KB  
Article
Improvement of a Switchable Wide-Incident-Angle Perfect Absorber Incorporating Sb2S3
by Yaolan Tian, Guoxu Zhang, Yan Li, Mei Shen, Yufeng Xiong, Ting Li, Yunzheng Wang, Xian Zhao and Changbao Ma
Materials 2025, 18(23), 5305; https://doi.org/10.3390/ma18235305 - 25 Nov 2025
Cited by 1 | Viewed by 863
Abstract
Active metasurfaces, whose optical properties can be tuned by an external stimulus such as electric or laser pulses, have attracted great research interest recently. The phase change material (PCM), antimony sulfide (Sb2S3), has been reported to modulate resonance wavelengths [...] Read more.
Active metasurfaces, whose optical properties can be tuned by an external stimulus such as electric or laser pulses, have attracted great research interest recently. The phase change material (PCM), antimony sulfide (Sb2S3), has been reported to modulate resonance wavelengths from the visible to the infrared. Here, we present a purely numerical study of an active and nonvolatile narrow-band perfect absorber in the infrared region based on a nanostructured metal–insulator–metal (MIM) metasurface incorporating Sb2S3. The proposed absorber exhibits a high quality factor and achieves near-unity absorption at resonance wavelengths. In addition, the absorption spectrum can be dynamically modulated by the phase transition of Sb2S3, with a modulation range approaching 1 μm. Moreover, the designed absorber shows insensitivity to the angle of incidence. This study offers a feasible strategy for developing Sb2S3-integrated metasurface perfect absorbers with potential applications in selective thermal emitters and bolometers. Full article
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17 pages, 1400 KB  
Article
GC-MS/MS and LC-MS/MS Identification of Opium and Tropane Alkaloids in Pottery from Funnel Beaker Culture Sites in South-Eastern Poland
by Marcin Osak, Grzegorz Buszewicz, Halina Taras, Anna Zakościelna, Grzegorz Teresiński, Robert Karpiński and Jacek Baj
Materials 2025, 18(23), 5316; https://doi.org/10.3390/ma18235316 - 25 Nov 2025
Cited by 2 | Viewed by 1431
Abstract
This study examines the occurrence of psychoactive opium and tropane alkaloids in ceramic vessels from the Funnel Beaker Culture (FBC) using optimized GC-MS/MS and LC-MS/MS analytical protocols. Twelve vessels and potsherds, including miniature forms and collared flasks, were subjected to standardized extraction, derivatization, [...] Read more.
This study examines the occurrence of psychoactive opium and tropane alkaloids in ceramic vessels from the Funnel Beaker Culture (FBC) using optimized GC-MS/MS and LC-MS/MS analytical protocols. Twelve vessels and potsherds, including miniature forms and collared flasks, were subjected to standardized extraction, derivatization, and chromatographic analysis. The GC-MS/MS method enabled highly sensitive detection of target compounds (LOD < 0.5 ng/g), while LC-MS/MS provided complementary confirmation of analytes. Papaverine was identified in three artifacts (N1, N2, G2) using GC-MS/MS, and its presence was independently confirmed in two of these vessels (N1, N2) by LC-MS/MS. In one miniature vessel (D1), trace amounts of tropane alkaloids—scopolamine and presumptive atropine—were detected following derivatization. Recovery values ranged from 55% to 61%, demonstrating effective alkaloid isolation despite extensive degradation processes and strong interactions between organic residues and the ceramic matrix. The analytical results indicate that psychoactive plant derivatives could have been intentionally used and stored in selected FBC vessels, supporting interpretations related to ritual or medicinal practices. The validated procedures developed in this work provide a robust framework for the detection of unstable biomolecular residues in prehistoric ceramics and can be applied to future archaeometric and materials-science research. Full article
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15 pages, 6796 KB  
Article
Surface Fluorination of Magnesium Powder: Enhancing High-Temperature Oxidation Resistance
by Yu Wang, Jae-Ho Kim and Susumu Yonezawa
Materials 2025, 18(23), 5307; https://doi.org/10.3390/ma18235307 - 25 Nov 2025
Cited by 1 | Viewed by 1017
Abstract
This study investigates the high-temperature oxidation mechanism of pure magnesium powder and the effect of surface fluorination on its oxidation resistance. The results showed that at high temperatures, pure Mg powder reacted with H2O and CO2 in air to form [...] Read more.
This study investigates the high-temperature oxidation mechanism of pure magnesium powder and the effect of surface fluorination on its oxidation resistance. The results showed that at high temperatures, pure Mg powder reacted with H2O and CO2 in air to form Mg(OH)2 and MgCO3, which decomposed at approximately 350 °C. Above 450 °C, the oxide film ruptured and catastrophic oxidation occurred. Surface fluorination with F2 gas generated a dense, uniform MgF2 protective film on the magnesium surface, significantly improving the ignition point and high-temperature oxidation resistance of Mg. Increasing the fluorination temperature increased the thickness and stability of the MgF2 layer, thereby further enhancing oxidation resistance. In particular, samples fluorinated at 200 °C showed oxidation growth limited to approximately 3%, even after heating at 500 °C for 8 h in air. Adjusting the surface fluorination conditions can create a protective MgF2 film to address high-temperature oxidation issues in magnesium powder metallurgy applications. Full article
(This article belongs to the Special Issue Surface Modification and Coating for Functional Materials)
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19 pages, 3695 KB  
Article
Comparative Study of Different Additive Manufacturing Methods for H13 Tool Steel
by Paweł Widomski, Marcin Kaszuba, Daniel Dobras, Dominik Terefinko and Michał Kołodziński
Materials 2025, 18(23), 5299; https://doi.org/10.3390/ma18235299 - 24 Nov 2025
Cited by 6 | Viewed by 2198
Abstract
Additive manufacturing (AM) of hot-work tool steels such as H13 offers unique opportunities for producing complex, conformally cooled tools with reduced production time and material waste. In this study, five metal AM technologies—Fused Deposition Modeling and Sintering (FDMS, Desktop Metal Studio System and [...] Read more.
Additive manufacturing (AM) of hot-work tool steels such as H13 offers unique opportunities for producing complex, conformally cooled tools with reduced production time and material waste. In this study, five metal AM technologies—Fused Deposition Modeling and Sintering (FDMS, Desktop Metal Studio System and Zetamix), Binder Jetting (BJ), Laser Powder Bed Fusion (LPBF), and Directed Energy Deposition (DED)—were compared in terms of microstructure, porosity, and post-processing heat treatment response. The as-printed microstructures revealed distinct differences among the technologies: FDMS and BJ exhibited high porosity (6–9%), whereas LPBF and DED achieved near-full densification (<0.1%). Samples with sufficiently low porosity (BJ, LPBF, DED) were subjected to tempering and quenching treatments to evaluate hardness evolution and microstructural transformations. The satisfactory post-treatment hardness was observed in both tempered and quenched and tempered BJ samples, associated with secondary carbide precipitation, while LPBF and DED samples retained stable martensitic structures with hardness around 600 HV0.5. Microstructural analyses confirmed the dependence of phase morphology and carbide distribution on the thermal history intrinsic to each AM process. The study demonstrates that while FDMS and BJ are more accessible and cost-effective for low-density prototypes, LPBF and DED offer superior density and mechanical integrity suitable for functional tooling applications. Full article
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19 pages, 1050 KB  
Article
Nature of the Dielectric Anomaly in Na0.5Bi0.5TiO3–Based Ferrolectrics
by Eriks Birks, Marija Dunce, Šarūnas Svirskas, Algimantas Kežionis, Juras Banys and Andrei Kholkin
Materials 2025, 18(23), 5289; https://doi.org/10.3390/ma18235289 - 24 Nov 2025
Cited by 1 | Viewed by 1146
Abstract
The temperature–frequency dependence of dielectric permittivity in Na0.5Bi0.5TiO3 (NBT) -based compositions displays a diffused, frequency-independent maximum along with a frequency-dependent shoulder below this maximum. This behavior deviates from that of both classical ferroelectrics and conventional relaxor ferroelectrics, and [...] Read more.
The temperature–frequency dependence of dielectric permittivity in Na0.5Bi0.5TiO3 (NBT) -based compositions displays a diffused, frequency-independent maximum along with a frequency-dependent shoulder below this maximum. This behavior deviates from that of both classical ferroelectrics and conventional relaxor ferroelectrics, and its interpretation is further complicated by challenges in linking it to known structural phase transitions. This study proposes a new interpretation of the dielectric behavior of NBT-based materials through a comparative analysis of temperature–frequency permittivity data in both unpoled and poled NBT samples and 0.95Na0.5Bi0.5TiO3–0.05CaTiO3 solid solution over a broad frequency range (10 Hz–100 MHz). Results reveal that the steep permittivity change between the maximum and shoulder—accompanied by pronounced thermal hysteresis—can be attributed to a phase transition between two non-ferroelectric phases. When this contribution is excluded, the dielectric response aligns with classical relaxor ferroelectric behavior. To reconcile this with other known properties of NBT, the “breathing” model is employed, offering a unified framework for understanding its relaxor-like characteristics. Full article
(This article belongs to the Special Issue Feature Papers in Materials Physics (2nd Edition))
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17 pages, 6823 KB  
Article
Analysis of a Two-Stage Magnetic Precession Gear Exploiting 3D Finite Element Method
by Lukasz Macyszyn, Cezary Jedryczka and Michal Mysinski
Materials 2025, 18(23), 5277; https://doi.org/10.3390/ma18235277 - 22 Nov 2025
Cited by 1 | Viewed by 756
Abstract
The paper presents the results of numerical simulations carried out to investigate the influence of selected geometric parameter–precession angle and dimensions of the magnetic circuit of a two-stage magnetic precession gear on the magnetic torques acting on its active components. The operating principle [...] Read more.
The paper presents the results of numerical simulations carried out to investigate the influence of selected geometric parameter–precession angle and dimensions of the magnetic circuit of a two-stage magnetic precession gear on the magnetic torques acting on its active components. The operating principle of the proposed gear and the developed numerical model based on the 3D finite element method (FEM) are discussed. The study focuses on the effects of air gap length, magnet dimensions, pole pitch coverage and precession angle. The results confirm a strong correlation between these parameters and the transmitted torque, providing valuable guidelines for the optimal design of high-torque, compact and efficient magnetic precession gears. Full article
(This article belongs to the Section Materials Simulation and Design)
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17 pages, 3872 KB  
Article
Computational Analysis of Thermal Performance of Heat Sinks with Foam Structures
by Welteji Iticha and Tomasz Stręk
Materials 2025, 18(23), 5280; https://doi.org/10.3390/ma18235280 - 22 Nov 2025
Cited by 4 | Viewed by 1436
Abstract
Ensuring efficient heat transfer to maintain optimal system performance is crucial in modern electronics owing to the rise of artificial intelligence. In the last few decades, scholars have explored various strategies for enhancing electronic device thermal management, focusing on the effects of fin [...] Read more.
Ensuring efficient heat transfer to maintain optimal system performance is crucial in modern electronics owing to the rise of artificial intelligence. In the last few decades, scholars have explored various strategies for enhancing electronic device thermal management, focusing on the effects of fin shape, dimension, and spacing on heat transfer efficiency. Recent advancements in additive manufacturing have enabled fabrication of complex geometries, such as triply periodic minimal surfaces (TPMSs), which represent promising alternatives to conventional designs. This study presents a comparative analysis of the thermal performance and fluid flow characteristics of two foam TPMS-based (gyroid and primitive) heat sinks with wavy fins made using aluminum foam. COMSOL Multiphysics version 5.1, employed along with the implemented finite element method, was used to simulate convective heat transfer, pressure drop, the Nusselt number, and thermal performance at different fluid velocities along the length of a channel. The foam structure was heated by a copper plate, and the Nusselt number was evaluated over porosity levels from 0.1 to 0.9. A porosity between 0.5 and 0.7 offers the best balance of cooling performance and pumping power. Foam TPMS heat sinks, particularly those with a gyroid structure, provide enhanced thermal dissipation owing to their high surface area-to-volume ratio and interconnected geometry. Our findings confirm that TPMS heat sinks have promising potential for use as alternatives to conventional wavy designs for advanced thermal management applications. Full article
(This article belongs to the Special Issue Modelling of Deformation Characteristics of Materials or Structures)
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24 pages, 4241 KB  
Article
Assessment of a Clothing Ensemble with an Active Heating Function Based on Thermal Manikin Tests
by Agnieszka Greszta, Magdalena Młynarczyk, Anna Dąbrowska, Sylwia Krzemińska, Monika Jangas, Łukasz Starzak, Paweł Marciniak and Bartosz Małachowski
Materials 2025, 18(23), 5258; https://doi.org/10.3390/ma18235258 - 21 Nov 2025
Cited by 1 | Viewed by 1282
Abstract
Heated clothing is an alternative to passive thermally insulating clothing used so far, made of thick, multi-layered fabric compounds. In this work, a personalized two-layer heated clothing ensemble for mountain rescuers was developed. It consisted of an electrically heated inner suit and an [...] Read more.
Heated clothing is an alternative to passive thermally insulating clothing used so far, made of thick, multi-layered fabric compounds. In this work, a personalized two-layer heated clothing ensemble for mountain rescuers was developed. It consisted of an electrically heated inner suit and an outer suit made of waterproof laminate. Total thermal insulation and local thermal insulations were determined using a thermal manikin. The heating system’s performance was assessed by comparing these results with those obtained with the heating turned off in the same ensemble, as well as with a down jacket added. It was confirmed that a thick thermally insulating layer (down jacket) can be eliminated through the application of electric heating. Heating improved the resultant effective thermal insulation of the clothing ensemble by 52% at a total power of 28.4 W. This exceeded the value obtained with the additional down jacket and no heating by 4%. Full article
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25 pages, 5741 KB  
Article
Stabilizing the Localized Surface Plasmon Resonance (LSPR) of Citrate-Synthesized Metal Nanoparticles in Organic Solvents
by Jacob P. Magdon, Matthew J. Jasienski, Madison R. Waltz, Gabrielle A. Grzymski, Calvin Chen, Arion M. Solomon, Minh Dang Nguyen, Jong Moon Lee, John C. Deàk, T. Randall Lee and Riddhiman Medhi
Materials 2025, 18(22), 5246; https://doi.org/10.3390/ma18225246 - 20 Nov 2025
Cited by 1 | Viewed by 1661
Abstract
Gold–silver nanoshells (GS-NSs) are hollow spherical nanoparticles with an alloyed Ag-Au shell. GS-NSs exhibit a tunable localized surface plasmon resonance (LSPR) in the visible to near-IR wavelengths as a function of composition and shell thickness and offer greater stability across pH ranges compared [...] Read more.
Gold–silver nanoshells (GS-NSs) are hollow spherical nanoparticles with an alloyed Ag-Au shell. GS-NSs exhibit a tunable localized surface plasmon resonance (LSPR) in the visible to near-IR wavelengths as a function of composition and shell thickness and offer greater stability across pH ranges compared to other metal nanoparticles. These properties make GS-NSs promising materials for diagnostics, photothermal therapy, and photocatalysis. However, current research has explored GS-NSs only in aqueous systems, since they immediately aggregate in other solvents, limiting their utility. This paper provides an in-depth study of the choice and effect of non-thiol ligands on the stability and phase-transfer of GS-NSs from aqueous to non-aqueous solvents, such as ethylene glycol, tetrahydrofuran, dichloromethane, and toluene. Ligand exchange for functionalization of GS-NSs was performed with Triton X-100 (TX100), sodium stearate (NaSt), polyvinylpyrrolidone (PVP), and hydroxypropyl cellulose (HPC), prior to phase-transfer. The nanoparticles were phase-transferred to the non-aqueous solvents, and the stability of the colloids in the various solvents before and after functionalization was recorded with UV–visible spectroscopy, dynamic light scattering (DLS), zeta potential (ζ), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The study was also extended to include silver nanoparticles (AgNPs) and gold nanoparticles (AuNPs) to evaluate broad-range applicability. Among the ligands studied, HPC functionalization demonstrated the widest range of phase-transfer stability across 21 days for all three particle systems studied. UV–vis spectroscopy demonstrated sustained LSPR integrity after HPC functionalization in EG, THF, and DCM. SEM, TEM, and hydrodynamic size measurements by DLS further confirmed no aggregation in EG, THF, and DCM but suggested possible twinning or clustering in the solution. Overall, this work successfully identified non-toxic alternatives to expand the LSPR stability of citrate-synthesized metal nanoparticles in organic solvents. Full article
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39 pages, 2270 KB  
Review
Laser Technologies of Welding, Surfacing and Regeneration of Metals with HCP Structure (Mg, Ti, Zr): State of the Art, Challenges and Prospects
by Adam Zwoliński, Sylwester Samborski and Jakub Rzeczkowski
Materials 2025, 18(22), 5237; https://doi.org/10.3390/ma18225237 - 19 Nov 2025
Cited by 3 | Viewed by 1629
Abstract
Metals with a hexagonal close-packed (HCP) structure such as magnesium, titanium and zirconium constitute key structural materials in the aerospace, automotive, biomedical and nuclear energy industries. Their welding and regeneration by conventional methods is hindered due to the limited number of slip systems, [...] Read more.
Metals with a hexagonal close-packed (HCP) structure such as magnesium, titanium and zirconium constitute key structural materials in the aerospace, automotive, biomedical and nuclear energy industries. Their welding and regeneration by conventional methods is hindered due to the limited number of slip systems, high reactivity and susceptibility to the formation of defects. Laser technologies offer precise energy control, minimization of the heat-affected zone and the possibility of producing joints and coatings of high quality. This article constitutes a comprehensive review of the state of knowledge concerning laser welding, cladding and regeneration of HCP metals. The physical mechanisms of laser beam interactions are discussed including the dynamics of the keyhole channel, Marangoni flows and the formation of gas defects. The characteristics of the microstructure of joints are presented including the formation of α′ martensite in titanium, phase segregation in magnesium and hydride formation in zirconium. Particular attention is devoted to residual stresses, techniques of cladding protective coatings for nuclear energy with Accident Tolerant Fuel (ATF) and advanced numerical modeling using artificial intelligence. The perspectives for the development of technology are indicated including the concept of the digital twin and intelligent real-time process control systems. Full article
(This article belongs to the Special Issue Microstructural and Mechanical Properties of Metal Alloys)
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16 pages, 3415 KB  
Article
Poly(glycerol)-Functionalized Gadolinium Tungstate Nanoflakes Loaded with Chlorin e6: Photodynamic Efficacy and Radiosensitization Potential for Multimodal Cancer Therapy
by Heon Gyu Kang and Lukas R. H. Gerken
Materials 2025, 18(22), 5198; https://doi.org/10.3390/ma18225198 - 16 Nov 2025
Cited by 1 | Viewed by 1016
Abstract
Gadolinium (Gd)-based nanomaterials have attracted a considerable amount of attention in cancer treatment research due to their applicability in radiotherapy. However, the clinical translation of Gd-based nanomaterials is limited by their high density and poor dispersibility in aqueous media, thereby necessitating surface functionalization [...] Read more.
Gadolinium (Gd)-based nanomaterials have attracted a considerable amount of attention in cancer treatment research due to their applicability in radiotherapy. However, the clinical translation of Gd-based nanomaterials is limited by their high density and poor dispersibility in aqueous media, thereby necessitating surface functionalization with biocompatible polymers. In this study, gadolinium tungstate (Gd2(WO4)3) nanoflakes (GW Nfs) were functionalized with poly(glycerol) (PG) to enhance their dispersibility and stability in aqueous media. Due to their high-Z elemental composition, the GW Nfs generated reactive oxygen species (ROS) under X-ray irradiation, with improved dispersibility induced by PG functionalization further enhancing ROS productivity compared to GW Nfs. Furthermore, PG-GW loaded with the photosensitizer chlorin e6 (Ce6) demonstrated strong photocytotoxicity at Ce6 concentrations as low as 0.2 μg mL−1 under light irradiation. Taken together, these results demonstrate that PG-GW/Ce6 is a promising nanomaterial for photodynamic therapy while also offering prospects for bimodal photon cancer therapy with X-rays. Full article
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21 pages, 2496 KB  
Article
Nuclear Magnetic Resonance Dynamics of LiTFSI–Pyrazole Eutectic Solvents
by Emilia Pelegano-Titmuss, Muhammad Zulqarnain Arif, Giselle de Araujo Lima e Souza, Phillip Stallworth, Yong Zhang, Adam Imel, Thomas Zawodzinski and Steven Greenbaum
Materials 2025, 18(22), 5184; https://doi.org/10.3390/ma18225184 - 14 Nov 2025
Cited by 5 | Viewed by 1565
Abstract
Deep Eutectic Solvents (DESs) have emerged as promising candidates to replace conventional organic solvents in various technological applications due to their low vapor pressure, non-flammability, and ease of preparation at low costs. In particular, Type IV DESs, which are composed of metal salts [...] Read more.
Deep Eutectic Solvents (DESs) have emerged as promising candidates to replace conventional organic solvents in various technological applications due to their low vapor pressure, non-flammability, and ease of preparation at low costs. In particular, Type IV DESs, which are composed of metal salts and hydrogen bond donors, are possible replacements for lithium-ion battery electrolytes. In this study, we investigate the molecular dynamics of solvents of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and pyrazole (PYR) at varying LiTFSI:PYR molar ratios (1:2, 1:3, 1:4, 1:5) using Nuclear Magnetic Resonance Dispersion (NMRD) and Pulsed Field Gradient (PFG) Nuclear Magnetic Resonance (NMR). PFG NMR reveals composition-dependent diffusion trends, while NMRD provides molecular-level insights into the longitudinal relaxation rate (R1 = 1/T1). Notably, the LiTFSI:PYR (1:2) sample shows distinct behavior across both techniques, exhibiting enhanced relaxation rates and lower self-diffusion for 1H compared to the other nuclei (19F and 7Li), suggestive of stronger and more efficient Li+–pyrazole interactions, as confirmed by the modeling of the relaxation profiles. Our study advances understanding of ion dynamics in azole-based eutectic solvents, supporting their potential use in safer battery electrolytes. Full article
(This article belongs to the Special Issue Ionic Liquid-Based Materials: Fundamentals and Applications)
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22 pages, 3634 KB  
Article
Spinning and Tactile Hand/Wear Comfort Characteristics of PET/Co-PET Hollow Fabrics Made of Inorganic Particles Embedded Sheath/3-Core Bicomponent Yarns
by Jiman Kang and Hyunah Kim
Materials 2025, 18(22), 5188; https://doi.org/10.3390/ma18225188 - 14 Nov 2025
Viewed by 1065
Abstract
This paper reports the spinning and wear comfort properties of polyethylene terephthalate (PET)/copolymer-PET (Co-PET) hollow yarns and their fabrics, as well as the effect of the wt.% of inorganic particles embedded in the core of the bicomponent yarns. The results are discussed in [...] Read more.
This paper reports the spinning and wear comfort properties of polyethylene terephthalate (PET)/copolymer-PET (Co-PET) hollow yarns and their fabrics, as well as the effect of the wt.% of inorganic particles embedded in the core of the bicomponent yarns. The results are discussed in terms of the types and amounts of inorganic particles (titanium dioxide (TiO2) and calcium carbonate (CaCO3)) embedded in the sheath of the bi-component yarns (Kolon semi-dull (KSD), Kolon full-dull (KFD), and Kolon calcium carbonate (KCC) PET/Co-PET yarns). The three sheath/3-core bicomponent yarns developed in this study exhibited good spinnability and weavability with relatively strong tenacity and breaking strain. Their optimal spinning conditions were determined. The KCC PET/Co-PET fabric showed the greatest hollowness ratio, followed by the KFD PET/Co-PET and KSD PET/Co-PET fabrics. This might be attributed to the higher wt.% (2.5 wt.%) of CaCO3 particles embedded in the sheath of the KCC PET/Co-PET yarns and to the larger particle size (0.8 μm) of CaCO3. Regarding the wear comfort, the moisture management system (MMT) test indicated that the KFD PET/Co-PET fabric is suitable for market applications because of its good moisture absorption and rapid drying. The KFD PET/Co-PET fabric is useful for winter clothing applications because of its relatively high heat retention rate and lack of durability issues with washing. An examination of the wearing performance for fitness with a tactile hand feel showed that KFD and KCC/Co-PET fabrics imparted a softer tactile hand feel than the KSD PET/Co-PET fabric. On the other hand, the KCC PET/Co-PET fabric was assumed to have some issues with wearing durability. Full article
(This article belongs to the Section Smart Materials)
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18 pages, 10871 KB  
Article
The Effect of In Situ Heat Treatment on the Microstructure and Mechanical Properties of H13 Tool Steel Specimens Produced by Laser-Engineered Net Shaping (LENS®)
by Michalina Rothen-Chaja, Izabela Kunce, Agata Radziwonko, Tomasz Płociński, Julita Dworecka-Wójcik and Marek Polański
Materials 2025, 18(22), 5164; https://doi.org/10.3390/ma18225164 - 13 Nov 2025
Cited by 3 | Viewed by 1497
Abstract
Samples of H13 tool steel were produced using the LENS® laser additive manufacturing technique. Three variants of samples were produced such that during and 2 h after deposition, both the substrate and sample temperatures were maintained at 80, 180, and 350 °C. [...] Read more.
Samples of H13 tool steel were produced using the LENS® laser additive manufacturing technique. Three variants of samples were produced such that during and 2 h after deposition, both the substrate and sample temperatures were maintained at 80, 180, and 350 °C. After the samples were produced, the effect of the substrate temperature on their metallurgical quality, microstructure, and mechanical properties was determined. No segregation of alloying elements was observed. The test results indicate that, depending on the temperature used, the structure of the H13 alloy is martensitic or martensitic-bainitic with a slight residual austenite content of up to 2.1%. Owing to structural changes, the obtained alloy is characterized by lower impact strength compared with conventionally produced alloys and high brittleness, particularly when using an annealing temperature of 350 °C. Isothermal annealing above the martensite start temperature results in extreme brittleness due to a partial structural transformation of martensite into bainite and probable carbide precipitation processes at the nanoscale. Full article
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13 pages, 2489 KB  
Article
UV-Engineered Oxygen Vacancies in MoOX Interlayers Enable 24.15% Efficiency for Crystalline Silicon Solar Cells
by Linfeng Yang, Wanyu Lu, Jingjie Li, Shaopeng Chen, Tinghao Liu, Dayong Yuan, Yin Wang, Ji Zhu, Hui Yan, Yongzhe Zhang and Qian Kang
Materials 2025, 18(22), 5167; https://doi.org/10.3390/ma18225167 - 13 Nov 2025
Cited by 2 | Viewed by 1139
Abstract
Molybdenum oxide (MoOX) has been widely utilized as a hole transport layer (HTL) in crystalline silicon (c-Si) solar cells, owing to characteristics such as a wide bandgap and high work function. However, the relatively low conductivity of MoOX [...] Read more.
Molybdenum oxide (MoOX) has been widely utilized as a hole transport layer (HTL) in crystalline silicon (c-Si) solar cells, owing to characteristics such as a wide bandgap and high work function. However, the relatively low conductivity of MoOX films and their poor contact performance at the MoOX-based hole-selective contact severely degrade device performance, particularly because they limit the fill factor (FF). Oxygen vacancies are of paramount importance in governing the conductivity of MoOX films. In this work, MoOX films were modified through ultraviolet irradiation (UV-MoOX), resulting in MoOX films with tunable oxygen vacancies. Compared to untreated MoOX films, UV-MoOX films contain a higher density of oxygen vacancies, leading to an enhancement in conductivity (2.124 × 10−3 S/m). In addition, the UV-MoOX rear contact exhibits excellent contact performance, with a contact resistance of 20.61 mΩ·cm2, which is significantly lower than that of the untreated device. Consequently, the application of UV-MoOX enables outstanding hole selectivity. The power conversion efficiency (PCE) of the solar cell with an n-Si/i-a-Si:H/UV-MoOX/Ag rear contact reaches 24.15%, with an excellent FF of 84.82%. Full article
(This article belongs to the Section Thin Films and Interfaces)
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25 pages, 5071 KB  
Article
Investigation of the Mechanical Properties of a Ceramic Material Fabricated Using Additive Manufacturing Technology
by Arkadiusz Popławski
Materials 2025, 18(22), 5165; https://doi.org/10.3390/ma18225165 - 13 Nov 2025
Cited by 2 | Viewed by 1391
Abstract
Additive manufacturing (AM) of ceramics has rapidly evolved over the past decade, enabling the production of complex, high-precision components with tailored porosity and geometry. Among AM techniques, stereolithography (SLA) and digital light processing (DLP) are particularly promising for fabricating dense and functional oxide [...] Read more.
Additive manufacturing (AM) of ceramics has rapidly evolved over the past decade, enabling the production of complex, high-precision components with tailored porosity and geometry. Among AM techniques, stereolithography (SLA) and digital light processing (DLP) are particularly promising for fabricating dense and functional oxide ceramics. However, the final properties of printed ceramics are strongly affected by sintering conditions, layer geometry, and microstructural uniformity. This study presents a two-stage experimental approach to evaluate the influence of sample geometry, layer thickness, and sintering schedule on the mechanical and microstructural performance of SLA-printed ceramic parts. In Stage I, the relationships between elastic modulus (Ec) and compressive strength (σc) were examined as a function of sample height, layer thickness (0.05 and 0.10 mm), and firing program. In Stage II, the effects of sintering temperature (1250, 1271, and 1300 °C) and holding time (2–20 min) were analyzed for the reference geometry. Microstructural characterization, including pore size distribution and quantitative porosity analysis, was conducted to establish correlations with the mechanical results (Stage III). The findings reveal that optimized sintering and geometry parameters can significantly enhance mechanical performance and reduce porosity variations. The study provides both scientific insights and engineering guidelines for improving the structural reliability of SLA-fabricated ceramic components. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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17 pages, 9586 KB  
Article
The Influence of the Upholstery Textiles Structure on Their Functional Properties
by Justyna Pinkos, Adam K. Puszkarz, Jacek Rutkowski and Martyna Borowińska
Materials 2025, 18(22), 5143; https://doi.org/10.3390/ma18225143 - 12 Nov 2025
Viewed by 1439
Abstract
This article evaluates selected performance parameters of commercial upholstery textiles that impact on user comfort and safety. The study included four commercial multilayer textiles: RIBCORD bright, RIBCORD dark, OREO, and ILIAS, each with varying morphology (thickness, number of layers, porosity, and raw material [...] Read more.
This article evaluates selected performance parameters of commercial upholstery textiles that impact on user comfort and safety. The study included four commercial multilayer textiles: RIBCORD bright, RIBCORD dark, OREO, and ILIAS, each with varying morphology (thickness, number of layers, porosity, and raw material composition). Statistical analysis of the textile microstructure was conducted using high-resolution micro-computed tomography (micro-CT). The performance parameters of the textiles were determined based on tests of air permeability, tensile strength, abrasion and pilling resistance, and flammability. The significantly different results obtained for all performance parameters of the tested textiles are justified by the results of the microstructure analysis. A clear correlation was observed between air permeability and the porosity of the inner layer of all tested textiles. Tensile strength tests revealed significant mechanical anisotropy in all textiles. Abrasion and pilling resistance tests demonstrated very good properties for RIBCORD bright, RIBCORD dark, and OREO. Flammability tests have shown that OREO is a flame-retardant textile material. Full article
(This article belongs to the Section Advanced Materials Characterization)
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21 pages, 5454 KB  
Article
An Electrochemical Study of the Corrosion Behaviour of the Polished Atomic Diffusion Additive Manufactured 17-4PH Stainless Steel Using Centrifugal Mass Finishing Method in Saltwater
by Juan Ignacio Ahuir-Torres, Xiaoxiao Liu, Jackson Chadwick and Tahsin Tecelli Öpöz
Materials 2025, 18(22), 5148; https://doi.org/10.3390/ma18225148 - 12 Nov 2025
Cited by 1 | Viewed by 970
Abstract
Additive manufacturing (AM) enables the fabrication of complex geometries and high-performance alloys such as 17-4PH stainless steel. However, the surface defects inherent to AM components compromise corrosion resistance. The post surface treatment can reduce and eliminate these defects. This study examines the effect [...] Read more.
Additive manufacturing (AM) enables the fabrication of complex geometries and high-performance alloys such as 17-4PH stainless steel. However, the surface defects inherent to AM components compromise corrosion resistance. The post surface treatment can reduce and eliminate these defects. This study examines the effect of centrifugal mass finishing on the corrosion behaviour of 17-4PH stainless steel produced by AM. Corrosion behaviour of the samples in a 0.6 M NaCl solution is assessed using electrochemical technique testing, including asymmetry electrochemical nose, potentiodynamic polarisation curves, electrochemical impedance spectroscopy, and Mott-Schottky. All electrochemical testing were conducted in concordance with the specifications of ASTM standards. The electrochemical impedance spectroscopy were performed over period ranging from 2 h to 96 h with intervals of approximately one day. Finished specimens exhibit significantly improved corrosion resistance compared with as-built counterparts. Notably, the polished surfaces demonstrate spontaneous oxidised layer recovery between −0.297 V and 0 V, indicative of the enhancement of the protection during early immersion stages. This behaviour is attributed to surface modifications induced by the finishing process, including reduced roughness in 78% and imperfections. These findings highlight the importance of optimising post-processing protocols to improve the durability of AM stainless steels in aggressive environments. Full article
(This article belongs to the Special Issue Research on Corrosion Behavior of Metallic Materials)
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14 pages, 9780 KB  
Article
Analysis of Microstructure and Pore Formation Mechanism in Magnetic Pulse-Assisted Semi-Solid Brazed Joints of Cu/Al Tubes
by Zhenglei Rui, Shangyu Huang and Huajun Wang
Materials 2025, 18(22), 5121; https://doi.org/10.3390/ma18225121 - 11 Nov 2025
Viewed by 722
Abstract
In this study, the joining of Cu/Al tubes was achieved using the magnetic pulse-assisted semi-solid brazing (MPASSB) technique. A coupled finite element method–smoothed particle hydrodynamics (FEM-SPH) model was established to analyze the influence mechanism of solid–liquid interface interaction on pore formation during the [...] Read more.
In this study, the joining of Cu/Al tubes was achieved using the magnetic pulse-assisted semi-solid brazing (MPASSB) technique. A coupled finite element method–smoothed particle hydrodynamics (FEM-SPH) model was established to analyze the influence mechanism of solid–liquid interface interaction on pore formation during the brazing forming process. The results indicate that the MPASSB technique can produce Cu/Al tube joints with excellent metallurgical bonding and performance at 390 °C, and no brittle Cu/Al intermetallic compounds (IMCs) are formed in the joints. Additionally, a stronger solid–liquid interface interaction and a higher surface roughness of the tubes lead to easier peeling of the copper matrix from the interface, thereby promoting pore formation. Mechanical property tests show that the shear strength of the joints prepared by this method can reach 63.3 MPa, and the fracture occurs in the brazing seam area adjacent to the copper–side interface. The MPASSB technique is expected to provide a feasible technical approach for the high-quality joining of dissimilar Cu/Al materials. Full article
(This article belongs to the Section Metals and Alloys)
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17 pages, 2551 KB  
Article
Structural Configuration Effects of Freestanding TiO2 Nanotube Arrays on Power Conversion Efficiency in Dye-Sensitized Solar Cells
by Gangasagar Sharma Gaudel, Seung-Ju Yu, Hwa-Young Yang, Ye-Chong Moon, Sang Hoon Kim, Sang-Ho Park, Bong-Hyun Jun, Young Jun Kim and Won-Yeop Rho
Materials 2025, 18(22), 5101; https://doi.org/10.3390/ma18225101 - 10 Nov 2025
Cited by 2 | Viewed by 812
Abstract
Dye-sensitized solar cells (DSSCs) are known for their excellent low-light performance, cost-effectiveness, and flexibility. The photoanode has a crucial role in enhancing the overall performance of DSSCs and can be modified with different nanostructures. This study explores the impact of photoanode structure on [...] Read more.
Dye-sensitized solar cells (DSSCs) are known for their excellent low-light performance, cost-effectiveness, and flexibility. The photoanode has a crucial role in enhancing the overall performance of DSSCs and can be modified with different nanostructures. This study explores the impact of photoanode structure on the power conversion efficiency (PCE) of DSSCs, where four configurations of freestanding TiO2 nanotube arrays (f-TNAs), closed-up, closed-down, open-up, and open-down, were employed as photoanodes. Performance was evaluated based on current density (Jsc), open-circuit voltage (Voc), fill factor (FF), and PCE concerning dye adsorption, electrolyte diffusion, electron transport, and barrier layer. DSSCs based on open configurations, open-up and open-down f-TNAs, demonstrated superior performance, achieving PCE of 7.73% and 7.71%, respectively. The primary distinction between the DSSCs based on open-up f-TNAs and those based on open-down f-TNAs lies in the dye adsorption time and electron diffusion characteristics. The PCE for DSSCs with closed-down f-TNAs was measured at 6.78%, while DSSCs with closed-up f-TNAs showed a lower PCE of 5.52%. The presence of a barrier layer under the bottom of f-TNAs impacted the PCE for DSSCs with closed-down f-TNAs, whereas for DSSCs with closed-up f-TNAs, insufficient dye loading, poor electrolyte diffusion and barrier layer reduced the performance. Full article
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14 pages, 1663 KB  
Article
Experimental Evaluation of Nonlinear Parameters in Fatigue Crack Growth Using Digital Image Correlation
by Giancarlo L. Gómez Gonzales and Francisco A. Díaz
Materials 2025, 18(22), 5110; https://doi.org/10.3390/ma18225110 - 10 Nov 2025
Cited by 1 | Viewed by 1138
Abstract
This study presents an experimental methodology for characterizing the crack-tip region using high-resolution Digital Image Correlation (DIC). The approach utilizes a stereoscopic microscope setup combined with 3D-DIC analysis to enable precise measurements within the small-scale region surrounding the crack tip. Two nonlinear parameters [...] Read more.
This study presents an experimental methodology for characterizing the crack-tip region using high-resolution Digital Image Correlation (DIC). The approach utilizes a stereoscopic microscope setup combined with 3D-DIC analysis to enable precise measurements within the small-scale region surrounding the crack tip. Two nonlinear parameters are evaluated: the plastic component of the crack-tip opening displacement (CTODp) and the cyclic plastic zone size. The investigation was conducted on disk-shaped compact tension specimens made of AISI 1020 steel under constant-ΔK fatigue testing. The results demonstrate a strong correlation between these nonlinear parameters and fatigue crack propagation, which was maintained stable, validating the proposed methodology. Furthermore, the relevance of crack-tip plasticity in fatigue crack propagation is verified under the tested conditions, highlighting its utility for fatigue life assessment under complex loading scenarios. Full article
(This article belongs to the Special Issue Fatigue Crack Growth in Metallic Materials (3rd Edition))
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16 pages, 4415 KB  
Article
Hydrogen–Dislocation Interactions at Cryogenic Temperatures: Serrated Yielding and Embrittlement Resistance in High-Strength Austenitic Alloys
by Nina Damm, Marina Lukas, Jan Platl, Andreas Drexler, Matthias Eichinger, Magdalena Eskinja, Gregor Mori, Zoltán Simon, Michael Scheerer, Stefan Marsoner and Vsevolod I. Razumovskiy
Materials 2025, 18(22), 5109; https://doi.org/10.3390/ma18225109 - 10 Nov 2025
Cited by 3 | Viewed by 1772
Abstract
Comprehensive studies of hydrogen embrittlement in high-strength austenitic alloys under cryogenic conditions are scarce, leaving the combined effect of hydrogen charging and extreme temperatures largely unexplored. Given the demands of cryogenic applications such as hydrogen storage and transport, understanding material behavior under these [...] Read more.
Comprehensive studies of hydrogen embrittlement in high-strength austenitic alloys under cryogenic conditions are scarce, leaving the combined effect of hydrogen charging and extreme temperatures largely unexplored. Given the demands of cryogenic applications such as hydrogen storage and transport, understanding material behavior under these conditions is crucial. Here, we present the first systematic study of hydrogen’s effect at liquid helium temperature (4.2 K) on the mechanical properties of precipitation hardened austenitic alloys, specifically the nickel-based Alloy 718 and austenitic stainless steel A286. Both materials were subjected to pressurized hydrogen charging at 473 K followed by slow strain rate tensile testing at room temperature and at 4.2 K. Hydrogen charging caused significant ductility loss at room temperature in both alloys. In contrast, testing at 4.2 K resulted in increased strength and no evidence of hydrogen embrittlement. Notably, materials pre-charged with hydrogen and tested at 4.2 K exhibited higher stress drop amplitudes and increased strain accumulation during serration events, suggesting persistent hydrogen–dislocation interactions and possible enhanced dislocation pinning by obstacles such as Lomer–Cottrell locks. These results indicate that while hydrogen influences plasticity mechanisms at cryogenic temperatures, embrittlement is suppressed, providing new insight into the safe development of austenitic alloys in cryogenic hydrogen environments. Full article
(This article belongs to the Special Issue Corrosion and Tribological Behaviour of Materials)
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18 pages, 2194 KB  
Article
Sustainable Fire-Resistant Materials: Thermal, Physical, Mechanical, and Environmental Behavior of Walls with Waste from the Aquaculture Industry
by Begoña Peceño, Bernabé Alonso-Fariñas, Giovanna Vega, Daniel Carrizo and Carlos Leiva
Materials 2025, 18(22), 5086; https://doi.org/10.3390/ma18225086 - 9 Nov 2025
Cited by 2 | Viewed by 1219
Abstract
The aquaculture industry generates large amounts of shell waste, with limited recycling options at the industrial scale. This study explores the feasibility of substituting 20% of gypsum with seashell waste to produce sustainable, fire-resistant panels for non-load-bearing walls on a semi-industrial scale (2.4 [...] Read more.
The aquaculture industry generates large amounts of shell waste, with limited recycling options at the industrial scale. This study explores the feasibility of substituting 20% of gypsum with seashell waste to produce sustainable, fire-resistant panels for non-load-bearing walls on a semi-industrial scale (2.4 × 2.2 × 0.1 m). The new composite exhibits high density (≈1500 kg/m3) and mechanical performance comparable to commercial gypsum. Thermal and fire tests confirmed its excellent insulation and stability: after 4 h of standard fire exposure, the non-exposed surface temperature remained below 80 °C, meeting European fire-resistance criteria. The incorporation of shell waste slightly reduced density and thermal conductivity (0.23 W/mK at 500 °C) without affecting strength or surface hardness. Environmental characterization revealed leaching and radionuclide levels well below regulatory limits, confirming its safety for building use. Overall, this work demonstrates, for the first time at a semi-industrial scale, the technical and environmental feasibility of reusing seashell waste as a gypsum substitute for fireproof materials. The proposed approach advances circular-economy strategies for aquaculture residues, providing an innovative pathway toward sustainable and low-impact construction products. Full article
(This article belongs to the Section Green Materials)
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40 pages, 29928 KB  
Article
Enhancing the Printability of Laser Powder Bed Fusion-Processed Aluminum 7xxx Series Alloys Using Grain Refinement and Eutectic Solidification Strategies
by Chukwudalu Uchenna Uba, Huan Ding, Yehong Chen, Shengmin Guo and Jonathan Richard Raush
Materials 2025, 18(22), 5089; https://doi.org/10.3390/ma18225089 - 9 Nov 2025
Cited by 4 | Viewed by 2371
Abstract
As the most commercially developed metal additive process, laser powder bed fusion (LPBF) is vital to advancing several industry sectors, enabling high-precision part production across aerospace, biomedical, and manufacturing industries. Al 7075 alloy offers low density and high-specific strength yet faces LPBF challenges [...] Read more.
As the most commercially developed metal additive process, laser powder bed fusion (LPBF) is vital to advancing several industry sectors, enabling high-precision part production across aerospace, biomedical, and manufacturing industries. Al 7075 alloy offers low density and high-specific strength yet faces LPBF challenges such as hot cracking and porosity due to rapid solidification, thermal gradients, and a wide freezing range. To address these challenges, this study proposes an integrated computational and experimental framework to enhance the LPBF processability of Al 7xxx alloys by compositional modification. Using the Calculation of Phase Diagram approach, printable Al 7xxx compositions were designed by adding grain refiners (V and/or Ti) and a eutectic solidification enhancer (Mg) to Al 7075 alloy to enable grain refinement and eutectic solidification. Subsequent LPBF experiments and characterization tests, such as metallography (scanning electron microscopy), energy-dispersive X-ray spectroscopy, X-ray diffraction, and X-ray micro-computed tomography, confirmed the production of refined microstructures with reduced defects. This study contributes to existing approaches for producing high-quality Al 7xxx alloy parts without significant compositional deviations using an integrated computational and experimental approach. Finally, aligning with the Materials Genome Initiative, this study contributes to the development and industrial adoption of advanced materials. Full article
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32 pages, 8299 KB  
Article
The Auto Sensor Test as an AE Signal Source in Concrete Specimens
by Magdalena Bacharz, Michał Teodorczyk and Jarosław Szulc
Materials 2025, 18(22), 5084; https://doi.org/10.3390/ma18225084 - 8 Nov 2025
Cited by 1 | Viewed by 952
Abstract
Numerous artificial sources of acoustic waves have been described in the literature, which are designed to replicate the process by which actual damage occurs in a given material. Knowledge of the velocity with which an acoustic wave propagates is important here, both in [...] Read more.
Numerous artificial sources of acoustic waves have been described in the literature, which are designed to replicate the process by which actual damage occurs in a given material. Knowledge of the velocity with which an acoustic wave propagates is important here, both in order to correctly locate the signal source and to determine the degree of material degradation or the location of damage that has already occurred in the medium. This work presents the results of laboratory tests comparing two sources of artificial waves in terms of determining their parameters: the Hsu–Nielsen source and a sensor with the Auto Sensor Test function. The AST function allows the sensors to send and receive an elastic wave and is used to calibrate the sensor before, during, or after the test. In this study, the impact of the positioning of the sensors on the element being tested, their spacing, and the distance of the wave source from the sensor on selected parameters of the recorded waves are analyzed: velocity, amplitude, energy, rise time, waveform shape, and wavelet maps. This work demonstrates that a sensor with the AST function can be an effective alternative for the Hsu–Nielsen source in diagnostic studies. Full article
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18 pages, 3412 KB  
Article
Comfort During Motion: Analyzing the Pressure Profile of Auxetic Bra Pads
by Yin-ching Keung, Kit-lun Yick, Joanne Yip and Annie Yu
Materials 2025, 18(22), 5071; https://doi.org/10.3390/ma18225071 - 7 Nov 2025
Cited by 3 | Viewed by 1734
Abstract
Auxetic structures, characterized by a negative Poisson’s ratio and unique form-fitting deformation, are adopted for designing a bra pad that would facilitate bras with a flexible and adaptive fit. This study compares the pressure distribution between auxetic and traditional molded bra pads, highlighting [...] Read more.
Auxetic structures, characterized by a negative Poisson’s ratio and unique form-fitting deformation, are adopted for designing a bra pad that would facilitate bras with a flexible and adaptive fit. This study compares the pressure distribution between auxetic and traditional molded bra pads, highlighting the advantages of auxetic materials in applying uniform pressure and addressing health concerns. Seven athletic female participants with a bra size of 75B comprise the study sample. Anthropometric data of naked breasts are collected by using three-dimensional (3D) scanning to obtain the underbust and full bust dimensions in the standing and leaning forward positions, while the pressure distribution is measured with the Novel Pliance® pressure measurement system in three poses: standing, static cycling, and dynamic cycling. The results show that the auxetic designs of bra pads consistently apply a more uniform pressure distribution compared to traditional foam pads, with mean pressures of 2.92 kPa for auxetic pads compared to 4.81 kPa for traditional foam pads during static cycling. Moreover, auxetic pads reduced maximum pressure by 25% compared to molded cups, and spatial variability was halved (SD 0.85 kPa vs. 1.70 kPa). Notably, at the bra neckline, auxetic pads exhibit increased pressure as the body leans forward, demonstrating their ability to adapt to changing breast shapes while maintaining adequate bra-breast contact. In contrast, in the lower breast area, the auxetic pads show a decrease in pressure, which indicates their capacity to accommodate variations in breast girth or volume without exerting excessive force. These findings highlight the superior adaptability and wear comfort provided by an auxetic structure, which shows its potential to address the dynamic support needs of active women. Overall, the auxetic designs of a bra pad in this study represent a significant advancement in sports bra technology and offer a promising alternative to traditional molded cups in activewear design. Full article
(This article belongs to the Special Issue Functional Textiles: Fabrication, Processing and Applications)
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16 pages, 2645 KB  
Article
Enhanced Superconductivity near the Pressure-Tuned Quantum Critical Point of Charge-Density-Wave Order in Cu1-δTe (δ = 0.016)
by Kwang-Tak Kim, Yeahan Sur, Ingyu Choi, Zifan Wang, Sangjin Kim, Dilip Bhoi, Duck Young Kim and Kee Hoon Kim
Materials 2025, 18(21), 5042; https://doi.org/10.3390/ma18215042 - 5 Nov 2025
Viewed by 1118
Abstract
We have investigated the evolution of CDW states and structural phases in a Cu-deficient Cu1-δTe (δ = 0.016) by employing high-pressure experiments and first-principles calculations. Raman scattering results reveal that the vulcanite structure at ambient pressure starts to change into the [...] Read more.
We have investigated the evolution of CDW states and structural phases in a Cu-deficient Cu1-δTe (δ = 0.016) by employing high-pressure experiments and first-principles calculations. Raman scattering results reveal that the vulcanite structure at ambient pressure starts to change into the Cu-deficient rickardite (r-CuTe) structure from 6.7 GPa, which then becomes fully stabilized above 8.3 GPa. Resistivity data show that TCDW1 (≈333 K) is systematically suppressed under high pressure, reaching zero at 5.9 GPa. In the pressure range of 5.2–8.2 GPa, a sharp resistivity drop due to superconductivity occurs at the onset temperature TC = ~2.0–3.2 K. The maximum TC = 3.2 K achieved at 5.6 GPa is clearly higher than that of CuTe (2.3 K), suggesting the importance of charge fluctuation in the vicinity of CDW suppression. At 7.5 GPa, another resistivity anomaly appears due to the emergence of a second CDW (CDW2) ordering at TCDW2 = ~176 K, which exhibits a gradual increase to ~203 K with pressure increase up to 11.3 GPa. First-principles calculations on the Cu-deficient Cu11Te12 with the r-CuTe structure show that including on-site Coulomb repulsion is essential for incurring an unstable phonon mode relevant for stabilizing the CDW2 order. These results point out the important role of charge fluctuation in optimizing the pressure-induced superconductivity and that of Coulomb interaction in creating the competing CDW order in the Cu-deficient CuTe system. Full article
(This article belongs to the Section Materials Physics)
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16 pages, 4760 KB  
Article
A Rapid Consolidation Route for Recycled NdFeB Powders and the Role of Particle Shape in Grain Growth
by Fabian Burkhardt, Alba Berja, Laura Grau, Matija Kreča, Lindrit Krasniqi, Benjamin Podmiljšak, Kristina Žužek, Carlo Burkhardt, Spomenka Kobe, Adrián Quesada and Tomaž Tomše
Materials 2025, 18(21), 5029; https://doi.org/10.3390/ma18215029 - 4 Nov 2025
Cited by 4 | Viewed by 1474
Abstract
The recycling of NdFeB magnets is essential to reduce reliance on critical rare earth elements and mitigate the environmental burden of virgin magnet production. Hydrogen Processing of Magnetic Scrap (HPMS) offers an efficient method to extract magnet powders from end-of-life (EOL) products, yet [...] Read more.
The recycling of NdFeB magnets is essential to reduce reliance on critical rare earth elements and mitigate the environmental burden of virgin magnet production. Hydrogen Processing of Magnetic Scrap (HPMS) offers an efficient method to extract magnet powders from end-of-life (EOL) products, yet oxidation and microstructural degradation during powder preparation limit the magnetic performance of recycled magnets. In this work, rapid Radiation-Assisted Sintering (RAS) was systematically evaluated for the first time as a consolidation route for HPMS-derived powders. Magnets prepared via RAS exhibited performance comparable to those obtained by conventional sintering. When oxygen uptake during milling was prevented, the addition of 1 wt.% NdH3 to the already oxygen-burdened recycled powder improved the intrinsic coercivity and squareness of the demagnetization curve. The best-performing samples achieved Br = 1.18 T, (BH)max = 263 kJ/m3, and Hci = 742 kA/m at 100 °C, surpassing the properties of the original EOL magnets. Furthermore, the study revealed that, when the HPMS powder fragments preferentially break along grain boundaries, the resulting near-equilibrium powder particles exhibit limited growth, thereby restraining grain coarsening. These findings highlight the strong potential of RAS for more energy-efficient magnet-to-magnet recycling and provide new insight into optimizing HPMS powder processing to achieve enhanced magnetic performance. Full article
(This article belongs to the Special Issue Advances in Magnetic Materials and Applications)
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23 pages, 6818 KB  
Article
Enhanced Osseointegration, Osteogenic Differentiation and Adherence Behaviour of Healthy Human Osteoblasts on a Roughened Titanium Surface by Vitamin K2 and Vitamin D3
by Katharina Tscheu, Ann Kathrin Bergmann, Christoph V. Suschek and Uwe Maus
Materials 2025, 18(21), 5012; https://doi.org/10.3390/ma18215012 - 3 Nov 2025
Cited by 1 | Viewed by 1219
Abstract
The number of endoprosthetic implants is constantly increasing. Successful osseointegration of the inserted material into the bone is essential for a prosthesis to remain in the bone as long as possible. In the clinical setting, a roughened titanium surface of implants is used [...] Read more.
The number of endoprosthetic implants is constantly increasing. Successful osseointegration of the inserted material into the bone is essential for a prosthesis to remain in the bone as long as possible. In the clinical setting, a roughened titanium surface of implants is used as standard to enable the best possible osseointegration. Vitamin K2 and vitamin D3 play a decisive role in dynamic bone metabolism and therefore also influence osseointegration. For the first time, we carried out in vitro investigations with clinically relevant cells, primary healthy human osteoblasts (hOBs). We qualitatively compared the adhesion behaviour of hOBs on a plastic surface, a smooth, regular titanium surface structure and a roughened, irregular titanium surface structure by scanning electron microscopy and fluorescence microscopy. The osteogenic behaviour and the osteogenic differentiation capacity were quantitatively investigated by analysing the activity of alkaline phosphatase and the alizarin red S assay under the influence of vitamin K2, vitamin D3 and the combination of both vitamins. It was shown that more adhesion points formed between the cells and the titanium on the rough surface structure. In addition, a solid cell network developed more quickly on this side, with cell runners forming in three-dimensional space, which means the interactions between the cells across different cell layers. On the other hand, a structured cell network also appeared on the regular smooth surface structure, which means that the network seems to be formed and built up along a defined structure. The addition of vitamins further increased the osteogenic differentiation capacity on the rough titanium surface structure. In particular, the isolated addition of vitamin K2 showed an improved osteogenic differentiation in the long-term observation, whereas the combined addition of both vitamins promoted the initial osteogenic differentiation. Vitamin K2, therefore, plays a greater role in osseointegration than previously assumed. This opens up new possibilities for the use of vitamin K2 during and after the surgical insertion of an implant. The use of vitamin K2 should be reconsidered for clinical applications in implant care and further investigated clinically. Full article
(This article belongs to the Section Biomaterials)
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15 pages, 1986 KB  
Article
Design and Optimization of a Hybrid Railcar Structure with Multilayer Composite Panels
by Alessio Cascino, Enrico Meli and Andrea Rindi
Materials 2025, 18(21), 5013; https://doi.org/10.3390/ma18215013 - 3 Nov 2025
Cited by 16 | Viewed by 1257
Abstract
Within contemporary railway engineering, manufacturers of rolling stock are increasingly focused on developing vehicles that combine reduced weight with enhanced reliability. This objective is largely motivated by the need to decrease energy demand and limit environmental impact, encouraging the integration of innovative materials [...] Read more.
Within contemporary railway engineering, manufacturers of rolling stock are increasingly focused on developing vehicles that combine reduced weight with enhanced reliability. This objective is largely motivated by the need to decrease energy demand and limit environmental impact, encouraging the integration of innovative materials and cut-ting-edge design strategies. The growing use of multilayer composite materials in the railway sector stems from their unique combination of high strength and low weight, making them particularly suitable for structural applications. This study investigates the structural performance and optimization of a hybrid car body system composed of an aluminum frame integrated with multilayer composite panels. A fully automated computational framework has been developed to generate and assess all possible stacking sequence permutations of the laminate plies, coupled with a high-fidelity finite element model of the car body. The methodology enables the evaluation of failure indices, including Maximum Stress, Tsai–Wu, and Interlaminar criteria, across a wide design space. A comprehensive assessment of both mechanical and dynamic performance has been carried out according to relevant railway standards, supporting the robustness and reliability of the proposed optimization framework. The results confirm the capability of the methodology to efficiently identify and compare multiple laminate configurations while maintaining compliance with structural and modal requirements. The optimized configurations demonstrated maximum Tsai–Wu values below 0.9, first-mode frequency variations below 0.5% and potential mass reductions of 25–45% on the selected components. This approach provides a powerful and versatile tool for the rapid optimization of lightweight hybrid structures in railway applications. Full article
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27 pages, 2616 KB  
Review
Recent Advances in Pulsed Laser Deposition of REBa2Cu3O7−δ High-Temperature Superconducting Coated Conductors and Artificial Flux Pinning
by Ziheng Guo, Liangkang Chen, Yuxiang Li, Xinyue Xia, Guangyao Lin, Penghong Hu, Dongliang Gong, Dongliang Wang and Yanwei Ma
Materials 2025, 18(21), 4988; https://doi.org/10.3390/ma18214988 - 31 Oct 2025
Cited by 3 | Viewed by 3293
Abstract
Rare-earth barium copper oxide (REBCO) high-temperature superconductors, owing to their ability to maintain high critical current density (Jc) under liquid-nitrogen-temperature and high-magnetic-field conditions, are widely regarded as one of the most promising material systems among all superconductors. This review systematically [...] Read more.
Rare-earth barium copper oxide (REBCO) high-temperature superconductors, owing to their ability to maintain high critical current density (Jc) under liquid-nitrogen-temperature and high-magnetic-field conditions, are widely regarded as one of the most promising material systems among all superconductors. This review systematically summarizes fabrication strategies for REBCO coated conductors, with a focus on pulsed laser deposition (PLD) for achieving high-quality epitaxial growth with precise composition control. To enhance in-field performance, strategies for introducing artificial pinning centers (APCs) are examined, including rare-earth element doping, substrate surface decoration, and nanoscale secondary phase incorporation. The mechanisms of vortex pinning from different dimensional defects and their synergistic effects are compared. Finally, we suggest potential future directions aimed at further enhancing the superconducting properties. Full article
(This article belongs to the Section Quantum Materials)
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12 pages, 2582 KB  
Article
Ytterbium-Modified Rapidly Solidified Mg-Zn-Ca Alloys: Improvements in Strength and Corrosion Resistance for Biodegradable Implant Applications
by Zuzana Molčanová, Beáta Ballóková, Karel Saksl, Miroslav Džupon, Dóra Zalka and Zoltán Dankházi
Materials 2025, 18(21), 4959; https://doi.org/10.3390/ma18214959 - 30 Oct 2025
Cited by 1 | Viewed by 932
Abstract
Biodegradable alloys are increasingly studied in medical research to find the best balance between mechanical performance and biocompatibility. Magnesium (Mg) alloys are particularly attractive because of their low density, good mechanical properties, and compatibility with the human body. However, rapid corrosion limits their [...] Read more.
Biodegradable alloys are increasingly studied in medical research to find the best balance between mechanical performance and biocompatibility. Magnesium (Mg) alloys are particularly attractive because of their low density, good mechanical properties, and compatibility with the human body. However, rapid corrosion limits their wider use. Recently, Mg alloys containing zinc (Zn) and calcium (Ca) have drawn interest due to more suitable degradation rates. In this study, Mg66Zn30Ca4 was chosen as the base alloy due to its high mechanical strength, excellent biocompatibility, and favorable corrosion behavior, making it an ideal starting point for biodegradable implants. We investigated how adding ytterbium (Yb) affects the mechanical and corrosion behavior of this base alloy. Mg66−xZn30Ca4Ybx (x = 2, 4, 6) rods were produced using rapid solidification, and their mechanical and electrochemical properties were systematically evaluated. The results show that adding Yb significantly improves corrosion resistance while maintaining high mechanical strength, making these materials promising for applications requiring both strength and controlled degradation. Corrosion tests indicated that the surface of the samples developed an oxygen-rich layer approximately 18 μm thick, as identified by EDS mapping. Overall, Yb modification enhances the suitability of Mg-Zn-Ca alloys for biodegradable orthopedic implants. Full article
(This article belongs to the Section Metals and Alloys)
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36 pages, 1016 KB  
Review
Fiber-Reinforced Polymer Laminates in Aviation and Structural Engineering: A Synthetic Comparison of Performance Requirements, Design Principles, and Defect Assessment Procedures
by Joana Janeikaitė, Ieva Misiūnaitė and Viktor Gribniak
Materials 2025, 18(21), 4938; https://doi.org/10.3390/ma18214938 - 29 Oct 2025
Cited by 14 | Viewed by 2216
Abstract
Fiber-reinforced polymer (FRP) laminates are widely used in both aviation and structural engineering, yet their implementation reflects fundamentally different paradigms. Aviation represents a fatigue-critical, certification-driven domain, while structural engineering emphasizes long-term durability and environmental resilience. These sectors were selected as conceptual extremes to [...] Read more.
Fiber-reinforced polymer (FRP) laminates are widely used in both aviation and structural engineering, yet their implementation reflects fundamentally different paradigms. Aviation represents a fatigue-critical, certification-driven domain, while structural engineering emphasizes long-term durability and environmental resilience. These sectors were selected as conceptual extremes to explore how contrasting design philosophies, degradation mechanisms, and inspection strategies shape the performance and reliability of laminated FRP composites. Their approaches offer complementary insights: aviation contributes high-fidelity modeling and embedded monitoring, while structural engineering provides scalable inspection strategies and exposure-based degradation logic. Both sectors employ classical laminate theory and finite element modeling, but diverge in modeling depth and regulatory integration. This review synthesizes these contrasts based on 168 literature references, including 141 published between 2020 and 2025, reflecting recent developments in composite design, modeling, and inspection. It contributes to materials engineering by proposing hybrid modeling and inspection frameworks that integrate progressive damage simulation with durability-based design logic. By bridging the modeling precision of aviation with the environmental realism of structural engineering, this review outlines a pathway toward unified, sustainable, and adaptive engineering practices for laminated FRP composites. Full article
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21 pages, 5722 KB  
Article
Calcium Phosphates for Bone Tissue Regeneration—Influence of Synthesis Method on Physicochemical and Biological Properties
by Julia Sadlik, Edyta Kosińska, Karina Niziołek, Mateusz M. Urbaniak, Agnieszka Sobczak-Kupiec and Dagmara Słota
Materials 2025, 18(21), 4945; https://doi.org/10.3390/ma18214945 - 29 Oct 2025
Cited by 3 | Viewed by 2013
Abstract
Calcium phosphates, including hydroxyapatite, are widely used biomaterials in bone tissue regeneration due to their bioactivity, osteoconductivity, and similarity to the mineral phase of bone. In this study, various apatite calcium phosphate powders were synthesized using three precipitation methods, with controlled pH conditions [...] Read more.
Calcium phosphates, including hydroxyapatite, are widely used biomaterials in bone tissue regeneration due to their bioactivity, osteoconductivity, and similarity to the mineral phase of bone. In this study, various apatite calcium phosphate powders were synthesized using three precipitation methods, with controlled pH conditions and reagent ratios, to assess the effect of the synthesis method on their physicochemical and biological properties. Elemental composition (Ca/P ratio), FT-IR spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled with EDS, and particle size measurements were used to determine the structure, morphology, and stoichiometry of the obtained powders. The results indicated that the synthesis method and pH significantly affect the phase composition of the material, particle size, and Ca/P ratio, which directly influence their solubility and bioactivity. Microbiological tests, NF-κB transcription factor activation, metabolic activity, and cell compatibility of mouse L929 fibroblasts and human hFOB 1.19 osteoblasts showed good biological tolerance of the obtained powders and no cytotoxic effects. The results confirm that a properly selected synthesis method allows for the control of material properties, which is crucial for applications in bone tissue engineering. The materials show potential for use as bioactive components in bone-related biomaterials. Full article
(This article belongs to the Section Biomaterials)
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16 pages, 7791 KB  
Article
Design and Comparative Numerical Analysis of AlSi10Mg PBF-LB/M Manufactured TPMS Lattice Structures for Improved Mechanical Performance
by Laura Luran Sun, Nikola Milenkovski, Kartikay Awasthi, Xuan Bach Nghiem, Nicola Mongelli, Eckhard Kirchner and Christian Mittelstedt
Materials 2025, 18(21), 4934; https://doi.org/10.3390/ma18214934 - 28 Oct 2025
Cited by 6 | Viewed by 1854
Abstract
Additive manufacturing enables the fabrication of lightweight structures with complex geometries, offering significant potential in aerospace and biomedical applications. Triply periodic minimal surface (TPMS) lattice structures are of particular interest due to their geometry. However, their intricate geometries pose challenges for both experimental [...] Read more.
Additive manufacturing enables the fabrication of lightweight structures with complex geometries, offering significant potential in aerospace and biomedical applications. Triply periodic minimal surface (TPMS) lattice structures are of particular interest due to their geometry. However, their intricate geometries pose challenges for both experimental characterization and numerical simulation. This study numerically investigates the effective mechanical properties and dynamic response of AlSi10Mg TPMS structures produced by laser powder bed fusion (PBF-LB/M). Using a micro–mesoscale approach with periodic boundary conditions, Young’s modulus, shear modulus, and Poisson’s ratio in the elastic region using the Johnson–Cook plasticity model are analyzed. Finite element simulations of the representative volume element (RVE) are employed to assess energy absorption and damage evolution under high strain rates, incorporating a ductile damage model. The performance of sheet-based TPMS lattices, namely, Schwarz–Primitive, Gyroid, Schwarz–Diamond, and IWP, is compared with strut-based lattices, namely, BCC and FCC, across volume fractions of 20–40%. Results demonstrate the superior stiffness and energy absorption of TPMS lattices, where Schwarz–Diamond and IWP outperformed the other structures, highlighting their advantages over conventional strut-based designs. This comprehensive numerical framework provides new insights into the high strain-rate behavior of TPMS structures and supports their design for demanding engineering applications. Full article
(This article belongs to the Section Materials Simulation and Design)
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15 pages, 2342 KB  
Article
Effect of Pre-Strain Induced Microstructure Evolution on Hydrogen Embrittlement Resistance of a CoCrNi Medium-Entropy Alloy
by Zening Wang, Sirui Jing and Yu Yan
Materials 2025, 18(21), 4915; https://doi.org/10.3390/ma18214915 - 27 Oct 2025
Cited by 4 | Viewed by 1217
Abstract
The effect of pre-strain-induced microstructural evolution on the hydrogen embrittlement (HE) resistance of an equiatomic CoCrNi medium-entropy alloy was systematically investigated by mechanical property testing, scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD) characterization. Three pre-strain levels (0%, 30%, and 50%) were [...] Read more.
The effect of pre-strain-induced microstructural evolution on the hydrogen embrittlement (HE) resistance of an equiatomic CoCrNi medium-entropy alloy was systematically investigated by mechanical property testing, scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD) characterization. Three pre-strain levels (0%, 30%, and 50%) were applied to produce distinct microstructures: dislocation-free and twin-free (P0), high dislocation density with few deformation twins (P30), and high densities of both dislocations and deformation twins (P50). Mechanical tests combined with hydrogen charging revealed that the P50 specimen exhibited the highest yield strength (1163.88 MPa) and the lowest HE-induced elongation loss (2.74%), indicating an improvement in HE resistance. By using SEM, detailed observations of the fracture morphology and crack propagation paths revealed that deformation twins can effectively reduce stress concentration, delay the nucleation and propagation rates of cracks, and suppress brittle intergranular fracture, thereby improving mechanical properties and resistance to hydrogen embrittlement. A detailed analysis was conducted of the HE resistance mechanism associated with the influence of deformation twins on hydrogen transport and distribution. Full article
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15 pages, 5984 KB  
Article
Phased Array Ultrasonic Testing of W/EUROFER Functionally Graded Coating
by Ashwini Kumar Mishra and Jarir Aktaa
Materials 2025, 18(21), 4896; https://doi.org/10.3390/ma18214896 - 26 Oct 2025
Cited by 1 | Viewed by 1298
Abstract
W/EUROFER functionally graded material (FGM) plasma-sprayed coatings are used as a protective layer in nuclear fusion applications. It is vital to develop a non-destructive test method to analyze interface characteristics and detect delamination in coatings. A phased array ultrasonic test method was developed [...] Read more.
W/EUROFER functionally graded material (FGM) plasma-sprayed coatings are used as a protective layer in nuclear fusion applications. It is vital to develop a non-destructive test method to analyze interface characteristics and detect delamination in coatings. A phased array ultrasonic test method was developed in this work to analyze the coating interface characteristics. Two types of coated samples were tested: first, a W/EUROFER FGM-coated flat small sample, and secondly, a large-scale L-shape 50% W and 50% EUROFER curve-coated sample. The phased array ultrasonic test method reliably detected two separate interfaces in W/EUROFER FGM coating, and no delamination was detected, which was verified by cross-sectional image analysis. Secondly, the phased array ultrasonic test precisely detected delamination created during deposition in a large-scale L-shape 50% W and 50% EUROFER curve coated sample. The accuracy in detecting delamination was verified by cross-sectional images of the interface. The phased array ultrasonic test was found to be a reliable method for detecting delamination in multilayer coatings from small-scale to large-scale curved components. Full article
(This article belongs to the Special Issue Advancements in Ultrasonic Testing for Metallurgical Materials)
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16 pages, 3262 KB  
Article
Experimental Study on the Role of Bond Elasticity and Wafer Toughness in Back Grinding of Single-Crystal Wafers
by Joong-Cheul Yun and Dae-Soon Lim
Materials 2025, 18(21), 4890; https://doi.org/10.3390/ma18214890 - 25 Oct 2025
Cited by 1 | Viewed by 1463
Abstract
Grinding semiconductor wafers with high hardness, such as SiC, remains a significant challenge due to the need to maximize material removal rates while minimizing subsurface damage. In the back-grinding process, two key parameters—the elastic modulus (Eb) of the grinding wheel bond and the [...] Read more.
Grinding semiconductor wafers with high hardness, such as SiC, remains a significant challenge due to the need to maximize material removal rates while minimizing subsurface damage. In the back-grinding process, two key parameters—the elastic modulus (Eb) of the grinding wheel bond and the fracture toughness (KIC) of the wafer—play a critical role in governing the behavior of diamond and the extent of wafer damage. This study systematically investigated the effect of Eb and KIC on diamond protrusion height (hp), surface roughness (Ra), grinding forces, and the morphology of generated debris. The study encompassed four wafer types—Si, GaP, sapphire, and ground SiC—using five Back-Grinding Wheels (BGWs), with Eb ranging from 95.24 to 131.38 GPa. A log–linear empirical relationship linking ℎₚ to Eb and KIC was derived and experimentally verified, demonstrating high predictive accuracy across all wafer–wheel combinations. Surface roughness (Ra) was measured in the range of 0.486 − 1.118𝜇m, debris size ranged from 1.41 to 14.74𝜇m, and the material removal rate, expressed as a thickness rate, varied from 555 to 1546𝜇m/h (equivalent to 75−209 mm³/min using an effective processed area of 81.07 cm²). For SiC, increasing the bond modulus from 95.24 to 131.38 GPa raised the average hp from 9.0 to 1.2 um; the removal rate peaked at 122.07 GPa, where subsurface damage (SSD) was minimized, defining a practical grindability window. These findings offer practical guidance for selecting grinding wheel bond compositions and configuring process parameters. In particular, applying a higher Eb is recommended for harder wafers to ensure sufficient diamond protrusion, while an appropriate dressing must be employed to prevent adverse effects from excessive stiffness. By balancing removal rate, surface quality, and subsurface damage constraints, the results support industrial process development. Furthermore, the protrusion model proposed in this study serves as a valuable framework for optimizing bond design and grinding conditions for both current and next-generation semiconductor wafers. Full article
(This article belongs to the Special Issue Advanced Materials Machining: Theory and Experiment)
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13 pages, 1934 KB  
Article
Ligand-Mediated, Temperature-Tuned Synthesis of CsPbBr3 Nanosheets for Ordered Superlattice Assembly
by Zahir Abdalla, Chengqi Liu, Shefiu Kareem, Xiaoqian Wang, Zisheng Tang and Yong Liu
Materials 2025, 18(21), 4885; https://doi.org/10.3390/ma18214885 - 24 Oct 2025
Cited by 3 | Viewed by 1510
Abstract
Two-dimensional (2D) colloidal CsPbBr3 nanosheets (NSs) possess size-dependent optoelectronic properties; however, conventional hot-injection methods often lack precise growth control and well-ordered superlattice self-assembly. Herein, we introduce a modified ligand-assisted hot-injection strategy that promotes direct precursor–ligand interactions prior to solvent mixing, thereby enabling [...] Read more.
Two-dimensional (2D) colloidal CsPbBr3 nanosheets (NSs) possess size-dependent optoelectronic properties; however, conventional hot-injection methods often lack precise growth control and well-ordered superlattice self-assembly. Herein, we introduce a modified ligand-assisted hot-injection strategy that promotes direct precursor–ligand interactions prior to solvent mixing, thereby enabling highly controlled nanosheet superlattice growth. By adjusting the reaction temperature from 130 to 150 °C, we obtained rectangular nanosheets with monodisperse, well-defined thicknesses of 3.35 ± 0.05 nm and 4.05 ± 0.09 nm at 130 and 140 °C, respectively, both below the 7 nm exciton Bohr diameter, consistent with strong quantum confinement. The resulting superlattices exhibited sharp, tunable photoluminescence peaks at 462, 464, and 513 nm, with time-resolved PL revealing a clear size–lifetime correlation, where smaller lateral superlattices at 130 °C showed a short decay time of 8.65 ns, intermediate growth at 140 °C yielded 15.42 ns, and larger lateral superlattices at 150 °C reached 35.49 ns. Importantly, the modified synthesis facilitated the formation of ordered superlattices that preserved their intrinsic emission properties, underscoring their structural stability and scalability. These findings establish a direct link between ligand-mediated synthesis, reaction temperature, nanosheet dimensions, and optical performance, offering a pathway to high-quality perovskite NS superlattices for advanced optoelectronic applications such as light-emitting diodes and sensors. Full article
(This article belongs to the Special Issue Advanced Materials in Photoelectrics and Photonics)
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20 pages, 5795 KB  
Article
Bone Formation and Anti-Inflammatory Properties of Iodine-Loaded Titanium Implants: An Animal Study
by Kazuto Yamada, Kazuya Inoue, Nanako Shimada, Tatsuya Kakutani, Yasuhisa Sawai, Naoko Imagawa-Fujimura, Kayoko Yamamoto, Nahoko Kato-Kogoe, Seiji Yamaguchi and Takaaki Ueno
Materials 2025, 18(21), 4836; https://doi.org/10.3390/ma18214836 - 22 Oct 2025
Viewed by 1349
Abstract
Titanium implants are subjected to various surface treatments to improve their in vivo function. In this study, we evaluated the usefulness of titanium implants treated with acid, NaOH, CaCl2, heat, and ICl3 (Ac-NaCaThIo) in terms of in vivo bone-bonding strength, [...] Read more.
Titanium implants are subjected to various surface treatments to improve their in vivo function. In this study, we evaluated the usefulness of titanium implants treated with acid, NaOH, CaCl2, heat, and ICl3 (Ac-NaCaThIo) in terms of in vivo bone-bonding strength, bone formation, and histological anti-inflammatory properties. Iodine-loaded experimental dental implants and commercial control dental implants were placed in rabbit femurs, and bone-bonding strength was evaluated by measuring the implant stability quotient (ISQ), bone formation using tissue specimens, and the effect of iodine using thyroid-stimulating hormone (TSH) levels. Iodine-loaded titanium plates and untreated titanium plates were placed on rat skulls and inoculated with Streptococcus mitis (S. mitis) solution to evaluate anti-inflammatory properties. Consequently, the experimental implants did not demonstrate non-inferiority in bone-bonding strength (ISQ) compared with the controls; however, histological specimens revealed dense bone contact and favorable bone formation. TSH levels showed no differences at 13 weeks, indicating no long-term adverse effects of iodine. The experimental tissue specimens of the soft tissue had fewer inflammatory cells than the control at 2 weeks after placement, demonstrating an anti-inflammatory effect. These results suggest that, although non-inferiority in ISQ was not demonstrated, Ac-NaCaThIo-treated implants showed favorable bone formation, dense bone contact, anti-inflammatory properties, and biosafety, indicating potential for future applications. Full article
(This article belongs to the Special Issue Materials for Drug Delivery and Medical Engineering)
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40 pages, 3997 KB  
Review
Advances in Polymer Nanocomposites for Drilling Fluids: A Review
by Shahbaz Wakeel, Ammara Aslam and Jianhua Zhang
Materials 2025, 18(20), 4809; https://doi.org/10.3390/ma18204809 - 21 Oct 2025
Cited by 11 | Viewed by 2160
Abstract
Hydrocarbon exploration and extraction increasingly rely on drilling fluids that guarantee operating safety and efficiency, particularly in ultra-deep, high-temperature, and unconventional reservoirs. Traditional drilling fluids, especially for water-based muds (WBMs), have several problems, including excessive fluid loss, severe swelling in shale and instability [...] Read more.
Hydrocarbon exploration and extraction increasingly rely on drilling fluids that guarantee operating safety and efficiency, particularly in ultra-deep, high-temperature, and unconventional reservoirs. Traditional drilling fluids, especially for water-based muds (WBMs), have several problems, including excessive fluid loss, severe swelling in shale and instability in high-pressure/high-temperature (HPHT) conditions. Polymer nanocomposites (PNCs) are new types of drilling fluid additives that combine the vast surface area and reactivity of nanoparticles (NPs) with the structural flexibility and stability of polymers. This combination enhances rheology, reduces filtrate loss, and, most importantly, creates hydrophobic and pore-blocking barriers that prevent shale from swelling. This review highlights important improvements in drilling fluids with PNCs regarding exceptional rheological properties, low fluid loss, and improved suppression of the shale swelling. The particular focus was placed on the specific mechanisms and role that PNCs play in enhancing shale stability, as well as their responsibilities in improving rheology, heat resistance, and salt tolerance. Current advancements, persistent hurdles, and prospective prospects are rigorously evaluated to emphasize the scientific and industrial trajectories for the development of next-generation, high-performance drilling fluids. Moreover, the current challenges and future opportunities of PNCs in drilling fluids are discussed to motivate future contributions and explore new possibilities. Full article
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9 pages, 3385 KB  
Article
Synthesis of Silver–Calcium Phosphate Visible Light Responsive Photocatalytic Materials and Their Antibacterial Properties
by Hiroaki Onoda and Chihiro Izaki
Materials 2025, 18(20), 4789; https://doi.org/10.3390/ma18204789 - 20 Oct 2025
Viewed by 921
Abstract
Photocatalytic materials use light energy to decompose harmful substances, antifouling, and deodorize. However, photocatalytic materials currently in practical use utilize ultraviolet light, and considering the ratio of ultraviolet light in sunlight and indoor specifications, there is a need for photocatalysts that can act [...] Read more.
Photocatalytic materials use light energy to decompose harmful substances, antifouling, and deodorize. However, photocatalytic materials currently in practical use utilize ultraviolet light, and considering the ratio of ultraviolet light in sunlight and indoor specifications, there is a need for photocatalysts that can act with visible light. Silver phosphate is a photocatalytic material that works with visible light, but the silver ions make it expensive and difficult to put to practical use. This material is also expected to have antibacterial properties derived from silver ions. In this study, we prepared silver–calcium phosphate with a reduced amount of silver. The composition, photocatalytic activity, and antibacterial properties of the obtained samples were evaluated to examine the potential of the novel material. Full article
(This article belongs to the Special Issue Advanced Nanomaterials for Photocatalytic Application)
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26 pages, 1624 KB  
Review
Silver-Exchanged Zeolites: Preparation and Applications—A Review
by Marin Senila, Eniko Kovacs and Lacrimioara Senila
Materials 2025, 18(20), 4779; https://doi.org/10.3390/ma18204779 - 19 Oct 2025
Cited by 16 | Viewed by 2838
Abstract
Zeolites are widely acknowledged as minerals with outstanding characteristics, primarily due to their complex porous structure and large specific surface area. The modification of natural and synthetic zeolites can improve their properties, making them suitable for a wider range of applications. In recent [...] Read more.
Zeolites are widely acknowledged as minerals with outstanding characteristics, primarily due to their complex porous structure and large specific surface area. The modification of natural and synthetic zeolites can improve their properties, making them suitable for a wider range of applications. In recent years, silver-exchanged natural zeolites have been increasingly studied because silver is known for its antimicrobial and electrical conductivity properties, which enhance their utility in various fields. This study aims to provide a comprehensive review specifically focused on the silver-zeolite composite system. It synthesizes advancements in silver modified zeolites, offering a targeted analysis that connects synthesis methodologies to enhanced properties and applications. The paper is structured to include an overview of the general characteristics of both natural and synthetic zeolites, and methods for their modification to serve as supports for Ag+ and silver nanoparticles (AgNPs). It subsequently covers the properties of silver-exchanged zeolites and their principal applications. The study also summarizes the advantages and limitations of these materials, along with an analysis of future trends regarding new production possibilities and potential applications. Full article
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15 pages, 8189 KB  
Article
Effect of High Ni Content in Gas-Atomized Cu-Ni-Si Powders for Laser Powder Bed Fusion
by Mirko Trovato, Nicolò Arcieri, Diego Manfredi, Federico Simone Gobber, Bhaskaranand Bhatt, Alessandra Martucci, Sara Biamino, Laura Montanaro, Mariangela Lombardi and Paolo Fino
Materials 2025, 18(20), 4772; https://doi.org/10.3390/ma18204772 - 18 Oct 2025
Cited by 1 | Viewed by 1135
Abstract
Cu-Ni-Si alloys are advanced materials for electronic applications combining high mechanical strength and electrical conductivity through precipitation of fine Ni silicides. Increasing the Ni content—and, thus, the Ni:Si ratio—enhances the volume fraction of strengthening precipitates. However, the conventional fabrication route is time-consuming and [...] Read more.
Cu-Ni-Si alloys are advanced materials for electronic applications combining high mechanical strength and electrical conductivity through precipitation of fine Ni silicides. Increasing the Ni content—and, thus, the Ni:Si ratio—enhances the volume fraction of strengthening precipitates. However, the conventional fabrication route is time-consuming and costly, as the slow cooling rates lead to a coarse microstructure and pronounced segregation, limiting Ni and Si content to 5 wt.%. Rapid solidification techniques offer a promising alternative, since the higher cooling rates refine the microstructure while suppressing the elemental segregation. This study presents a novel powder-based approach to overcome the compositional limitations of Cu-Ni-Si alloys, providing a pathway for faster alloy screening. Two gas-atomized powders with different Ni contents—CuNi3Si1.5 and CuNi10Si1.5 (wt.%)—were engineered as feedstock for laser powder bed fusion, produced, and characterized to assess the effect of the Ni level on the microstructure and properties. Gas-atomization yielded spherical powders with a fine dendritic structure and limited segregation. Increased Ni content enhanced strengthening mechanisms and hardness, as well as improved optical response, suggesting the potential of high-Ni Cu-Ni-Si compositions for use in laser powder bed fusion. Full article
(This article belongs to the Special Issue Microstructural and Mechanical Properties of Metal Alloys)
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26 pages, 12130 KB  
Article
Robocasting as an Additive Manufacturing Method for Oxide Ceramics: A Study of Mechanical Properties and Microstructure
by Szymon Przybyła, Maciej Kwiatkowski, Michał Kwiatkowski and Marek Hebda
Materials 2025, 18(20), 4775; https://doi.org/10.3390/ma18204775 - 18 Oct 2025
Cited by 2 | Viewed by 2072
Abstract
Additive manufacturing methods can constitute a valuable alternative to conventional production techniques for components used in the heavy industry, particularly in foundry applications. This innovative manufacturing approach enables an expanded product portfolio as well as higher precision and geometrical complexity of ceramic components. [...] Read more.
Additive manufacturing methods can constitute a valuable alternative to conventional production techniques for components used in the heavy industry, particularly in foundry applications. This innovative manufacturing approach enables an expanded product portfolio as well as higher precision and geometrical complexity of ceramic components. One additive technology applicable to ceramic processing is robocasting, classified within the direct ink writing (DIW) family. In this method, a semi-fluid ceramic paste is extruded to build the part layer by layer; the shaped green body is subsequently fired (sintered) to attain its final functional properties. This study presents the results of materials characterization of printed ceramic filters, encompassing phase composition analysis, density measurements, three-point bending strength testing, hardness, and microstructural examination. The investigations demonstrated that the oxide ceramic Al2O3 processed by the modern robocasting method exhibits mechanical performance at a comparably high level relative to classical manufacturing routes (slip casting, ceramic injection molding, dry pressing). Moreover, the porosity results indicate that 3D printing technology enables lower post-sintering porosity. Full article
(This article belongs to the Special Issue Advances in Materials Processing (4th Edition))
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14 pages, 19249 KB  
Article
Topological Phase Transition in Two-Dimensional Magnetic Material CrI3 Bilayer Intercalated with Mo
by Chen-En Yin, Angus Huang and Horng-Tay Jeng
Materials 2025, 18(20), 4751; https://doi.org/10.3390/ma18204751 - 16 Oct 2025
Viewed by 1374
Abstract
Motivated by the seminal discoveries in graphene, the exploration of novel physical phenomena in alternative two-dimensional (2D) materials has attracted tremendous attention. In this work, through theoretical investigation using first-principles calculations, we reveal that Mo-intercalated CrI3 bilayer exhibits ferromagnetic semiconductor behavior with [...] Read more.
Motivated by the seminal discoveries in graphene, the exploration of novel physical phenomena in alternative two-dimensional (2D) materials has attracted tremendous attention. In this work, through theoretical investigation using first-principles calculations, we reveal that Mo-intercalated CrI3 bilayer exhibits ferromagnetic semiconductor behavior with a small easy-plane magnetocrystalline anisotropy energy (MAE) of 0.618 meV/Cr(Mo) between (100) and (001) magnetizations. The spin–orbit coupling (SOC) opens a narrow band gap at the Fermi level for both magnetization orientations with nonzero Chern number for realizing the quantum anomalous Hall effect (QAHE) in the former and with trivial topology in the latter. The small MAE implies the efficient experimental manipulation of magnetization between distinct topologies through an external magnetic field. Our findings provide compelling evidence that the QAHE in this system originates from the quantum spin Hall effect (QSHE), driven by intrinsic magnetism under broken time-reversal symmetry. These unique properties position Mo-intercalated CrI3 as a promising candidate for tunable spintronic applications. Full article
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17 pages, 5132 KB  
Article
Melting Behavior of Direct Reduced Iron Pellets with Different Carbon Content in Molten Steel and Molten Slag
by Fabian Andres Calderon Hurtado, Joseph Govro, Arezoo Emdadi and Ronald J. O’Malley
Materials 2025, 18(20), 4749; https://doi.org/10.3390/ma18204749 - 16 Oct 2025
Cited by 1 | Viewed by 1220
Abstract
This study investigates the melting behavior of direct reduced iron (DRI) pellets in molten slag and steel baths, focusing on how the carbon content influences the melting rate through the stirring effects of gas evolution on heat transfer. A computational model using COMSOL [...] Read more.
This study investigates the melting behavior of direct reduced iron (DRI) pellets in molten slag and steel baths, focusing on how the carbon content influences the melting rate through the stirring effects of gas evolution on heat transfer. A computational model using COMSOL Multiphysics 6.1 is developed to simulate the temperature profile at the pellet’s core and the gas evolution resulting from the reaction between FeO and carbon within the pellet. The model is validated using experimental data from this study as well as literature on the DRI pellet–molten slag system. Results indicate that, despite the increased enthalpy demand associated with the gas-generating reactions, higher carbon content enhances heat transfer within the pellet, leading to an increased melting rate. The computational model accurately predicts gas generation and temperature profiles, aligning well with experimental observations. Overall, the findings demonstrate that increasing the carbon content in DRI pellets accelerates the melting process. Full article
(This article belongs to the Section Green Materials)
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15 pages, 4144 KB  
Article
Effect of Carbon-Based Modifications of Polydicyclopentadiene Resin on Tribological and Mechanical Properties
by Joanna Warycha, Janusz Kurowski, Jakub Smoleń and Krzysztof Stępień
Materials 2025, 18(20), 4754; https://doi.org/10.3390/ma18204754 - 16 Oct 2025
Viewed by 1006
Abstract
Self-lubricating polymer composites based on polydicyclopentadiene (PDCPD) were reinforced with carbon nanomaterials to evaluate the effect of filler type and loading on their mechanical and tribological performance. Four carbon forms were introduced: carbon nanotubes (0.3 and 0.5 wt.%), carbon fibers (5 and 10 [...] Read more.
Self-lubricating polymer composites based on polydicyclopentadiene (PDCPD) were reinforced with carbon nanomaterials to evaluate the effect of filler type and loading on their mechanical and tribological performance. Four carbon forms were introduced: carbon nanotubes (0.3 and 0.5 wt.%), carbon fibers (5 and 10 wt.%), flake graphite (5 and 10 wt.%) and dusty graphite (5 and 10 wt.%). Tensile tests showed that carbon fibers—and graphite-filled matrices reached ~50 MPa tensile strength, while the addition of carbon nanotubes resulted in a reduction in strength by half compared to the pure resin, indicating poor compatibility of carbon nanotubes with the matrix. The highest compressive strength, ~90 MPa, was obtained for PDCPD containing 5 wt.% carbon fibers. Tribological behavior was evaluated in a pin-on-disk configuration under dry sliding. All fillers lowered the coefficient of friction; the most pronounced, three-fold reduction was achieved with both graphite variants. The combined high load-bearing capacity and greatly reduced friction of the graphite and carbon fibers modified systems highlight their potential as self-lubricating bearing materials capable of replacing conventional metal or oil-lubricated components. Full article
(This article belongs to the Section Carbon Materials)
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23 pages, 2062 KB  
Review
Advances and Challenges in the Battery Thermal Management Systems of Electric Vehicles
by Tianze Wen, Zhequan Zhou, Yongyi Zhang and Xiaomei Xu
Materials 2025, 18(20), 4718; https://doi.org/10.3390/ma18204718 - 15 Oct 2025
Cited by 17 | Viewed by 6061
Abstract
Battery Thermal Management Systems (BTMS) are essential for ensuring the performance, safety, and longevity of lithium-ion batteries (Li-ion) in electric vehicles (EVs). First, this review examines the current state of BTMS technologies, focusing on three thermal management strategies: passive, active, and hybrid thermal [...] Read more.
Battery Thermal Management Systems (BTMS) are essential for ensuring the performance, safety, and longevity of lithium-ion batteries (Li-ion) in electric vehicles (EVs). First, this review examines the current state of BTMS technologies, focusing on three thermal management strategies: passive, active, and hybrid thermal management strategies. Passive thermal management strategies, such as using phase change materials (PCM) or heat-conductive materials, offer simplicity and low energy consumption but are limited in high-power applications. The active thermal management strategies, including forced air cooling and liquid cooling, provide superior heat dissipation but require complex design and higher energy input. The hybrid thermal management strategies combine the advantages of passive and active strategies, providing a more suitable solution for the thermal management of lithium-ion batteries under diverse operating conditions. Second, the review also highlights challenges posed by high-energy density batteries, fast charging, and emerging battery technologies like solid-state and lithium–sulfur batteries. Finally, the technical summary draws from the research status of BTMS and future development directions are proposed. Full article
(This article belongs to the Special Issue Systems and Materials for Recycling Spent Lithium-Ion Batteries)
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