materials-logo

Journal Browser

Journal Browser

Advanced Catalysts towards Lignocellulosic Biomass Conversion and Water Splitting

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (20 April 2023) | Viewed by 1138

Special Issue Editors

State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
Interests: biomass conversion; electrocatalysis; carbon materials; 3D printing; X-ray absorption fine structure
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
Interests: graphene; carbon materials; electrocatalysis; lithium-ion batteries; lithium-metal batteries; supercapacitor

Special Issue Information

Dear Colleagues,

Development of new energy is currently a significant supplement of traditional fossil resources. Lignocellulosic biomass conversion and water splitting are two of the most important styles of energy conversion and utilization, since the former is a carbon neutral process and the latter only produces hydrogen and oxygen without carbon dioxide. However, it is challenging to develop high-performance catalysts for the two processes. Current applied catalysts are mainly precious and non-noble metal catalysts coupled with acid and/or base sites for one-pot conversion of lignocellulosic biomass to sugars and sugar alcohols, as well as some platform molecules such as levulinic acid, glycols, and furanic compounds. Various transition-metal hydroxides, nitrides, chalcogenides, and phosphides have been investigated as efficient bifunctional electrocatalysts for water splitting.

Advanced catalysts for lignocellulosic biomass conversion and water splitting should be highly active, selective, and stable. This requires metallic and composite sites anchored on a specific supporting matrix (especially for carbonaceous and metallic supports) that could satisfy multiple functions during operation conditions. Structural functions include nanostructures of nanofiber, nanorod, core–shell, yolk–shell, and mechanical properties such as strength, damage resistance, fracture toughness, etc. Nonstructural functions include electrical and thermal conductivities, porosity, particle size, morphology, etc.

The aim of this Special Issue is to understand the basic principles of catalyst preparation and catalytic performance, as well as the structure–property relationship for lignocellulosic biomass conversion and water splitting. Today, it is widely recognized that a rational design is necessary to the render superior properties needed and, thus, enable excellent catalytic performance of catalysts during reactions.

Dr. Ying Yang
Dr. Junying Wang
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • cellulose
  • glucose
  • acid
  • base
  • levulinic acid
  • carbon
  • hydrogen evolution
  • non-noble metal catalysts
  • nickel foam
  • mechanism

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

14 pages, 2881 KiB  
Article
Ru Single Atoms on One-Dimensional CF@g-C3N4 Hierarchy as Highly Stable Catalysts for Aqueous Levulinic Acid Hydrogenation
by Ying Yang, Suoying Zhang, Lin Gu and Shijie Hao
Materials 2022, 15(21), 7464; https://doi.org/10.3390/ma15217464 - 25 Oct 2022
Cited by 4 | Viewed by 1579
Abstract
Herein, we report a stable catalyst with Ru single atoms anchored on a one-dimensional carbon fiber@graphitic carbon nitride hierarchy, by assembling wet wipes composed of fiber-derived carbon fiber (CF), melamine-derived graphitic carbon nitride (g-C3N4) and RuCl3 before NaBH4 reduction. The atomically dispersed Ru [...] Read more.
Herein, we report a stable catalyst with Ru single atoms anchored on a one-dimensional carbon fiber@graphitic carbon nitride hierarchy, by assembling wet wipes composed of fiber-derived carbon fiber (CF), melamine-derived graphitic carbon nitride (g-C3N4) and RuCl3 before NaBH4 reduction. The atomically dispersed Ru species (3.0 wt%) are tightly attached via N-coordination provided by exterior g-C3N4 nanosheets, and further stabilized by the interior mesoporous CF. The obtained CF@g-C3N4–Ru SAs catalyst can be cycled six times without notable leaching of Ru or loss of GVL yield in the acidic media. This catalyst is more stable than Ru nanoparticles supported on CF@g-C3N4, as well as Ru single atoms anchored on CF and g-C3N4, and proves to be one of the most efficient metal catalysts for aqueous LA hydrogenation to γ-valerolactone (GVL). The isolated Ru atoms by strong N-coordination, and their enhanced electron/mass transfer afforded by the one-dimensional hierarchy, can be responsible for the excellent durability of CF@g-C3N4–Ru SAs under harsh reaction conditions. Full article
Show Figures

Figure 1

Back to TopTop