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Nano-Coating Technique in Cementitious Composites

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Composites".

Deadline for manuscript submissions: closed (10 September 2023) | Viewed by 2117

Special Issue Editors


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Guest Editor
Department of Civil Engineering, Babol Noshirvani University of Technology (BNUT), Babol 47148-71167, Iran
Interests: concrete; cementitious composites; nanoconcrete; bond; sustainability; waste materials; durability
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Department of Civil Engineering, Babol Noshirvani University of Technology (BNUT), Babol 47148-71167, Iran
Interests: concrete; cementitious composites; nanoconcrete; bond; sustainability; waste materials; durability; fracture mechanic

E-Mail Website
Guest Editor
Department of Construction Engineering, École de Technologie Supérieure (ÉTS), Université du Québec, Montreal, QC H3C 1K3, Canada
Interests: cementitious composites; nanoconcrete; materials characterization; sustainability; life cycle assessment

Special Issue Information

Dear Colleagues,

Interfacial properties between components in fiber-reinforced cementitious composites (FRCC) are one of the main issues controlling composite behavior, especially when exposed to harsh environments. These interactions contain different regions, including the sand/matrix ITZ and the fiber/matrix interface. Recently, researchers experimentally conducted valuable studies to improve these areas by using novel techniques, such as surface treatments of fiber and sand. The newest method presented by researchers is the nanocoating approach using different nanomaterials. This surface treatment has various advantages in FRCC, including (1) using nanocoating on fiber surface can enhance mechanical characteristics of weak fibers so that the low content of fibers is necessary to obtain specific properties, which is so efficient in FRCC mixtures containing high volumes of fibers, such as ultra-high ductility concrete (UHDC) and 3D printing FRCC; (2) using surface treatments on surface of sand may improve the weak ITZ so that low-quality aggregates can be also used in the construction industries, such as recycled aggregates and ultra-lightweight aggregates; (3) nanocoating techniques can repair surface defects of natural, recycled, and weak fibers to be efficiently used in FRCC mixtures; and (4) using nanocoating method can help to produce a concrete surface with special applications, such as self-sealing, self-cleaning, and superhydrophobic cementitious composites.

Accordingly, this Special Issue (SI) of “Materials” intends to publish experimental, numerical, and review studies on normal or FRCC mixtures using different types of nanocoating techniques. The addressed areas of research include, but are not limited to:

  • Strengthening different types of fibers with nanocoating methods;
  • Nanocoated sand in cementitious composites;
  • Effect of nanocoating on fiber-matrix interfacial properties;
  • Thermal conductivity of nano-coated fiber composites;
  • Bond strength of nanocoated fibers in cementitious composites;
  • The effect of nanocoating techniques on the durability of cementitious composites;
  • The optimum dosage of nanomaterials in nanocoating techniques;
  • Design of cementitious composites with nanocoated fibers;
  • Design of cementitious composites with nanocoated sand;
  • Influence of nanocoating on improving the residual strength of thermally damaged concrete;
  • Superhydrophobic cementitious composites using nanocoating techniques;
  • Anticorrosion nanocoating in cementitious composites;
  • Effect of nanomaterial types on the nanocoating technique;
  • Self-sealing and self-cleaning nanocoating.

Dr. Seyed Sina Mousavi
Prof. Dr. Mehdi Dehestani
Prof. Dr. Claudiane M. Ouellet-Plamondon
Guest Editors

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Keywords

  • nanocoated concrete
  • nanocoated aggregates
  • anti-corrosion nanocoating
  • nanocoated fibres
  • interfacial transition zone

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Published Papers (1 paper)

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Research

14 pages, 6624 KiB  
Article
Preparation of Butyl Acrylate Copolymer Emulsion and Its Regulation Effect on Cement Hydration
by Sifan Li, Zhongyang Mao and Min Deng
Materials 2023, 16(7), 2887; https://doi.org/10.3390/ma16072887 - 5 Apr 2023
Cited by 3 | Viewed by 1758
Abstract
Due to its large volume and poor thermal conductivity, mass concrete is prone to temperature cracking caused by heat release during cement hydration after pouring. To address the issue of temperature cracking in mass concrete, this study utilized emulsion polymerization to prepare polybutyl [...] Read more.
Due to its large volume and poor thermal conductivity, mass concrete is prone to temperature cracking caused by heat release during cement hydration after pouring. To address the issue of temperature cracking in mass concrete, this study utilized emulsion polymerization to prepare polybutyl acrylate (PBA) emulsions. At an optimal dosage of 1.5%, the addition of a PBA emulsion reduced the temperature rise of cement paste by 12.4%. The inhibitory mechanism of a PBA emulsion on cement hydration was analyzed by characterization techniques such as isothermal calorimetry, X-ray diffraction Rietveld full-profile fitting method (XRD), thermogravimetric–differential scanning calorimetry (TG-DSC), and mercury intrusion porosimetry (MIP). The results showed that the C3S content in the cement specimens with 1%, 1.5%, and 2% PBA increased by 13.83%, 23.52%, and 34.65% compared to the blank group, respectively, while the C3A content increased by 92.59%, 79.63%, and 96.30%, respectively. The addition of a PBA emulsion can slow down the hydration rate of C3S and C3A, thereby reducing the temperature rise and fall rate of cement hydration, reducing the peak heat release of the hydration reaction, and ultimately achieving the inhibition of the cement hydration reaction. In addition, the mechanical properties of PBA-modified cement-based materials were also tested. The results show that the addition of PBA can affect the early strength development of cement samples, but has no effect on the strength after 60 days. Therefore, PBA can be used as a hydration temperature rise control material to reduce the risk of temperature cracking in mass concrete. Full article
(This article belongs to the Special Issue Nano-Coating Technique in Cementitious Composites)
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