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Challenges and Opportunities of Superconducting Materials for Future Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Physics".

Deadline for manuscript submissions: closed (31 October 2021) | Viewed by 19996

Special Issue Editors


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Guest Editor
CNR-SPIN Salerno, via Giovanni Paolo II n. 132, 84084 Fisciano, Italy
Interests: superconducting materials; vortex physics; electrical and magnetic measurements; coated conductor technology; superconductor-based devices

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Guest Editor
CNR-SPIN, c/o University of Salerno, I-84084 Fisciano, Italy
Interests: materials electrical and thermal properties’ characterization; superconductivity; vortex matter in superconductors; superconducting materials applications

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Guest Editor
Department of Physics “E.R. Caianiello”, University of Salerno, Via Giovanni Paolo II, 132, I-84084 Fisciano, Salerno, Italy
Interests: superconductivity; iron-based superconductors; magnetic properties of low- and high-temperature superconductors; vortex dynamics; flux pinning properties; magnetism; magnetic measurements; magnetic materials; nanomaterials; magnetic nanoparticles
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Special Issue Information

Dear Colleagues,

Many present and future applications rely on superconducting technology. Indeed, high field magnets used in particle accelerators, high resolution MRIs, energy storage systems such as SMESs, TOKAMAK fusion reactors, as well as energy efficient electronics and high sensitivity photon sensors all use at the moment or will use in the future superconducting materials.

In order to be a good candidate for application, a superconducting material must have high values of critical temperature, of the irreversibility field, as well as of the upper critical field and should also be characterized by a fairy high critical current density, which should be isotropic and robust with respect to a high applied magnetic field. However, the reliability and the scalability of the fabrication process also plays an important role.

To achieve these goals, a wide empirical knowledge and a solid theoretical framework are necessary. Thus, this Special Issue will present the latest results on the improvement of superconductors in their different forms (i.e., thin films, single crystals, and bulks), as well as recent findings which help to understand the physics of superconducting materials in order to improve their performance in view of applications. We encourage the community active in both experimental and theoretical research on superconductors to share this knowledge.

This Special Issue will be focused on all different kinds of superconductors (low temperature, high temperature, iron-based, etc.) which are suitable for applications and will include, but not be limited to, the following topics:

  • Electrical transport properties’ improvement;
  • Thermal transport and quench;
  • Novel materials fabrication and structural characterization;
  • Magnetic and superconducting heterostructures;
  • Nanostructured superconductors;
  • Wires’ and tapes’ technology development;
  • Superconducting films for sensors, electronic devices, and spintronics;
  • Non-equilibrium vortex dynamics: models and findings;
  • Imaging of vortex matter and material defects;
  • Material properties for practical superconductors.

Dr. Gaia Grimaldi
Dr. Antonio Leo
Dr. Armando Galluzzi
Guest Editors

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

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Keywords

  • superconducting materials characterization
  • superconducting wires and tapes
  • materials synthesis progress
  • vortex matter

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Published Papers (8 papers)

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Research

16 pages, 2447 KiB  
Article
Dimensionality of the Superconductivity in the Transition Metal Pnictide WP
by Angela Nigro, Giuseppe Cuono, Pasquale Marra, Antonio Leo, Gaia Grimaldi, Ziyi Liu, Zhenyu Mi, Wei Wu, Guangtong Liu, Carmine Autieri, Jianlin Luo and Canio Noce
Materials 2022, 15(3), 1027; https://doi.org/10.3390/ma15031027 - 28 Jan 2022
Cited by 5 | Viewed by 2956
Abstract
We report theoretical and experimental results on the transition metal pnictide WP. The theoretical outcomes based on tight-binding calculations and density functional theory indicate that WP is a three-dimensional superconductor with an anisotropic electronic structure and nonsymmorphic symmetries. On the other hand, magnetoresistance [...] Read more.
We report theoretical and experimental results on the transition metal pnictide WP. The theoretical outcomes based on tight-binding calculations and density functional theory indicate that WP is a three-dimensional superconductor with an anisotropic electronic structure and nonsymmorphic symmetries. On the other hand, magnetoresistance experimental data and the analysis of superconducting fluctuations of the conductivity in external magnetic field indicate a weakly anisotropic three-dimensional superconducting phase. Full article
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15 pages, 6304 KiB  
Article
Modelling and Performance Analysis of MgB2 and Hybrid Magnetic Shields
by Michela Fracasso, Fedor Gömöry, Mykola Solovyov, Roberto Gerbaldo, Gianluca Ghigo, Francesco Laviano, Andrea Napolitano, Daniele Torsello and Laura Gozzelino
Materials 2022, 15(2), 667; https://doi.org/10.3390/ma15020667 - 17 Jan 2022
Cited by 8 | Viewed by 2372
Abstract
Superconductors are strategic materials for the fabrication of magnetic shields, and within this class, MgB2 has been proven to be a very promising option. However, a successful approach to produce devices with high shielding ability also requires the availability of suitable simulation [...] Read more.
Superconductors are strategic materials for the fabrication of magnetic shields, and within this class, MgB2 has been proven to be a very promising option. However, a successful approach to produce devices with high shielding ability also requires the availability of suitable simulation tools guiding the optimization process. In this paper, we report on a 3D numerical model based on a vector potential (A)-formulation, exploited to investigate the properties of superconducting (SC) shielding structures with cylindrical symmetry and an aspect ratio of height to diameter approaching one. To this aim, we first explored the viability of this model by solving a benchmark problem and comparing the computation outputs with those obtained with the most used approach based on the H-formulation. This comparison evidenced the full agreement of the computation outcomes as well as the much better performance of the model based on the A-formulation in terms of computation time. Relying on this result, the latter model was exploited to predict the shielding properties of open and single capped MgB2 tubes with and without the superimposition of a ferromagnetic (FM) shield. This investigation highlighted that the addition of the FM shell is very efficient in increasing the shielding factors of the SC screen when the applied magnetic field is tilted with respect to the shield axis. This effect is already significant at low tilt angles and allows compensating the strong decrease in the shielding ability that affects the short tubular SC screens when the external field is applied out of their axis. Full article
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8 pages, 13519 KiB  
Article
Drag Voltages in a Superconductor/Insulator/Ferromagnet Trilayer
by Paola Romano, Albino Polcari, Carla Cirillo and Carmine Attanasio
Materials 2021, 14(24), 7575; https://doi.org/10.3390/ma14247575 - 9 Dec 2021
Cited by 1 | Viewed by 2027
Abstract
The interaction between two spatially separated systems is of strong interest in order to study a wide class of unconventional effects at cryogenic temperatures. Here we report on drag transverse voltage effects in multilayered systems containing superconducting and ferromagnetic materials. The sample under [...] Read more.
The interaction between two spatially separated systems is of strong interest in order to study a wide class of unconventional effects at cryogenic temperatures. Here we report on drag transverse voltage effects in multilayered systems containing superconducting and ferromagnetic materials. The sample under test is a conventional superconductor/insulator/ferromagnet (S/I/F) trilayer in a cross configuration. S/F as well as S/N (here N stands for normal metal) bilayers in the same geometry are also analyzed for comparison. Current–voltage (I–V) characteristics measured at T = 4.2 K in the presence of a perpendicular magnetic field show strong peculiarities related to the interaction between the layers. The results are interpreted in terms of interaction effects between the layers. Full article
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18 pages, 1714 KiB  
Article
Superconducting Properties and Electron Scattering Mechanisms in a Nb Film with a Single Weak-Link Excavated by Focused Ion Beam
by Marlon Ivan Valerio-Cuadros, Davi Araujo Dalbuquerque Chaves, Fabiano Colauto, Ana Augusta Mendonça de Oliveira, Antônio Marcos Helgueira de Andrade, Tom Henning Johansen, Wilson Aires Ortiz and Maycon Motta
Materials 2021, 14(23), 7274; https://doi.org/10.3390/ma14237274 - 28 Nov 2021
Cited by 3 | Viewed by 2664
Abstract
Granularity is one of the main features restricting the maximum current which a superconductor can carry without losses, persisting as an important research topic when applications are concerned. To directly observe its effects on a typical thin superconducting specimen, we have modeled the [...] Read more.
Granularity is one of the main features restricting the maximum current which a superconductor can carry without losses, persisting as an important research topic when applications are concerned. To directly observe its effects on a typical thin superconducting specimen, we have modeled the simplest possible granular system by fabricating a single artificial weak-link in the center of a high-quality Nb film using the focused ion beam technique. Then, its microstructural, magnetic, and electric properties in both normal and superconducting states were studied. AC susceptibility, DC magnetization, and magneto-transport measurements reveal well-known granularity signatures and how they negatively affect superconductivity. Moreover, we also investigate the normal state electron scattering mechanisms in the Boltzmann theory framework. The results clearly demonstrate the effect of the milling technique, giving rise to an additional quadratic-in-temperature contribution to the usual cubic-in-temperature sd band scattering for the Nb film. Finally, by analyzing samples with varying density of incorporated defects, the emergence of the additional contribution is correlated to a decrease in their critical temperature, in agreement with recent theoretical results. Full article
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9 pages, 2093 KiB  
Article
Critical Current and Pinning Features of a CaKFe4As4 Polycrystalline Sample
by Armando Galluzzi, Antonio Leo, Andrea Masi, Francesca Varsano, Angela Nigro, Gaia Grimaldi and Massimiliano Polichetti
Materials 2021, 14(21), 6611; https://doi.org/10.3390/ma14216611 - 3 Nov 2021
Cited by 2 | Viewed by 2144
Abstract
We analyze the magnetic behavior of a CaKFe4As4 polycrystalline sample fabricated by a mechanochemically assisted synthesis route. By means of DC magnetization (M) measurements as a function of the temperature (T) and DC magnetic field (H) we study its critical parameters and pinning [...] Read more.
We analyze the magnetic behavior of a CaKFe4As4 polycrystalline sample fabricated by a mechanochemically assisted synthesis route. By means of DC magnetization (M) measurements as a function of the temperature (T) and DC magnetic field (H) we study its critical parameters and pinning features. The critical temperature Tc has been evaluated by M(T) curves performed in Zero Field Cooling-Field Cooling conditions. These curves show the presence of a little magnetic background for temperatures above Tc, as also confirmed by the hysteresis loops M(H). Starting from the M(H) curves, the critical current density Jc of the sample has been calculated as a function of the field at different temperatures in the framework of the Bean critical state model. The Jc(H) values are in line with the ones reported in the literature for this typology of samples. By analyzing the temperature dependence of the critical current density Jc(T) at different magnetic fields, it has been found that the sample is characterized by a strong type pinning regime. This sample peculiarity can open perspectives for future improvement in the fabrication of this material. Full article
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22 pages, 4518 KiB  
Article
Effect of Heat Treatments under High Isostatic Pressure on the Transport Critical Current Density at 4.2 K and 20 K in Doped and Undoped MgB2 Wires
by Daniel Gajda, Andrzej J. Zaleski, Andrzej J. Morawski, Malgorzata Małecka, Konstantin Nenkov, Matt Rindfleisch, Md Shahriar A. Hossain and Tomasz Czujko
Materials 2021, 14(18), 5152; https://doi.org/10.3390/ma14185152 - 8 Sep 2021
Cited by 1 | Viewed by 1747
Abstract
Annealing undoped MgB2 wires under high isostatic pressure (HIP) increases transport critical current density (Jtc) by 10% at 4.2 K in range magnetic fields from 4 T to 12 T and significantly increases Jtc by 25% in range [...] Read more.
Annealing undoped MgB2 wires under high isostatic pressure (HIP) increases transport critical current density (Jtc) by 10% at 4.2 K in range magnetic fields from 4 T to 12 T and significantly increases Jtc by 25% in range magnetic fields from 2 T to 4 T and does not increase Jtc above 4 T at 20 K. Further research shows that a large amount of 10% SiC admixture and thermal treatment under a high isostatic pressure of 1 GPa significantly increases the Jtc by 40% at 4.2 K in magnetic fields above 6 T and reduces Jtc by one order at 20 K in MgB2 wires. Additionally, our research showed that heat treatment under high isostatic pressure is more evident in wires with smaller diameters, as it greatly increases the density of MgB2 material and the number of connections between grains compared to MgB2 wires with larger diameters, but only during the Mg solid-state reaction. In addition, our study indicates that smaller wire diameters and high isostatic pressure do not lead to a higher density of MgB2 material and more connections between grains during the liquid-state Mg reaction. Full article
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18 pages, 7271 KiB  
Article
Experimental and Numerical Analysis of High-Temperature Superconducting Tapes Modified by Composite Thermal Stabilization Subjected to Thermomechanical Loading
by Eva Cuninková, Marcela Pekarčíková, Michal Skarba, Jozef Krajčovič and Matej Pašák
Materials 2021, 14(13), 3579; https://doi.org/10.3390/ma14133579 - 26 Jun 2021
Cited by 4 | Viewed by 1872
Abstract
The strain behavior of SiC/Stycast 2850 FT composites under thermomechanical loading using a finite element analysis (FEA) was studied. These composites can serve as thermal stabilizers of high-temperature superconducting (HTS) tapes during limitation event in resistive superconducting fault current limiter (R-SCFCL) applications. For [...] Read more.
The strain behavior of SiC/Stycast 2850 FT composites under thermomechanical loading using a finite element analysis (FEA) was studied. These composites can serve as thermal stabilizers of high-temperature superconducting (HTS) tapes during limitation event in resistive superconducting fault current limiter (R-SCFCL) applications. For this purpose, the thermomechanical properties of four composite systems with different filler content were studied experimentally. The FEA was calculated using an ANSYS software and it delivered useful information about the strain distribution in the composite coating, as well as in particular layers of the modified HTS tapes. The tapes were subjected to bending over a 25 cm core, cooled in a liquid nitrogen (LN2) bath, and finally, quenched from this temperature to various temperatures up to 150 °C for a very short time, simulating real limitation conditions. The outputs from simulations were also correlated with the experiments. The most promising of all investigated systems was SB11-SiC20 composite in form of 100 µm thick coating, withstanding a temperature change from LN2 up to 120 °C. Full article
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8 pages, 3852 KiB  
Article
Measurement of Electrical Properties of Superconducting YBCO Thin Films in the VHF Range
by Yakir Dahan, Eldad Holdengreber, Elichai Glassner, Oz Sorkin, Shmuel E. Schacham and Eliyahu Farber
Materials 2021, 14(12), 3360; https://doi.org/10.3390/ma14123360 - 17 Jun 2021
Cited by 6 | Viewed by 2405
Abstract
A new measurement technique of electrical parameters of superconducting thin films at the Very High Frequency (VHF) range is described, based on resonators with microstrip (MS) structures. The design of an optimal resonator was achieved, based on a thorough theoretical analysis, which is [...] Read more.
A new measurement technique of electrical parameters of superconducting thin films at the Very High Frequency (VHF) range is described, based on resonators with microstrip (MS) structures. The design of an optimal resonator was achieved, based on a thorough theoretical analysis, which is required for derivation of the exact configuration of the MS. A theoretical model is presented, from which an expression for the attenuation of a MS line can be derived. Accordingly, simulations were performed, and an optimal resonator for the VHF range was designed and implemented. Production constraints of YBa2Cu3O7 (YBCO) limited the diameter of the sapphire substrate to 3″. Therefore, a meander configuration was formed to fit the long λ/4 MS line on the wafer. By measuring the complex input reflection coefficients of a λ/4 resonator, we extracted the quality factor, which is mainly affected by the dielectric and conductor attenuations. The experimental results are well fitted by the theoretical model. The dielectric attenuation was calculated using the quasi-static analysis of the MS line. An identical copper resonator was produced and measured to compare the properties of the YBCO resonator in reference to the copper one. A quality factor of ~6·105 was calculated for the YBCO resonator, three orders of magnitude larger than that of the copper resonator. The attenuation per unit length of the YBCO layer was smaller by more than five orders of magnitude than that of the copper. Full article
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