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Locally Ordered Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Materials Characterization".

Deadline for manuscript submissions: closed (20 June 2023) | Viewed by 1634

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Guest Editor
Institute of Materials Sciences, University of Silesia, Katowice, Poland
Interests: relaxor ferroelectrics; domain structure of ferroelectrics; low-frequency dielectric relaxation; non-linear dielectric response; mesoscopic disorder in ferroics
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Special Issue Information

Dear Colleagues,

Ferromagnetics, ferroelectrics, ferroelastics, and ferrotoroidics (generally referred to as four ferroic orders) represent a family of materials with collective features reaching spontaneous, stable long-range ordered ground states of matter. In addition to that, ferroic orientation states (domains) may be reversed under the action of an appropriate external field. Very often, such a switching process manifests in a respective hysteresis loop. Here one deals with the engineering of charge, spin, and lattice, respectively.

On the other hand, imperfections in the form of locally or short-range ordered states of matter incorporated into the well-ordered crystalline lattice have recently attracted a great deal of attention. The point is that such local ordering phenomena break the long-range, average symmetry at the nanometre scale and thus radically modify behaviors stemming from the simplified model. Among others, these materials comprise mesoscopic ferroic glasses such as relaxor ferroelectrics or magnetic cluster glasses. In such systems, quenched statistical fluctuations of short-ranged interactions generate the ferroic clusters, while long-ranged dipolar electric/magnetic or quadrupolar stress field interactions may stabilize their glassy disorder on mesoscopic length scales. Another possible scenario may originate from geometrical frustration, where the interacting elementary units tend to stick to anomalous positions. Furthermore, the chemical heterogeneity of the cationic site occupation may also be considered a possible reason for intrinsic disorder. As a consequence, one obtains very complex systems that demand intense research activity. These materials may also offer unique potential for developing new electronic devices.

This Special Issue, “Locally Ordered Materials”, will cover a broad range of their physical properties, technological aspects, and potential applications with new advances in this attractive field of research. We cordially invite you to contribute your research paper, communication, or review for this Special Issue.

Prof. Dr. Jan Dec
Guest Editor

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Keywords

  • ferroelectrics
  • ferromagnetics
  • ferroelastics
  • ferroics
  • relaxors
  • dipolar glasses
  • spin glasses
  • mesoscopic glasses
  • frustrated materials
  • domains
  • local order
  • quenched random fields
  • nano-domains
  • polar nanoregions
  • clusters

Published Papers (1 paper)

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Research

14 pages, 2395 KiB  
Article
Structure, Antiferroelectricity and Energy-Storage Performance of Lead Hafnate in a Wide Temperature Range
by Vidhi Chauhan, Bi-Xia Wang and Zuo-Guang Ye
Materials 2023, 16(11), 4144; https://doi.org/10.3390/ma16114144 - 2 Jun 2023
Cited by 5 | Viewed by 1316
Abstract
Lead hafnate (PbHfO3) has attracted a lot of renewed interest due to its potential as antiferroelectric (AFE) material for energy storage. However, its room temperature (RT) energy-storage performance has not been well established and no reports on the energy-storage feature of [...] Read more.
Lead hafnate (PbHfO3) has attracted a lot of renewed interest due to its potential as antiferroelectric (AFE) material for energy storage. However, its room temperature (RT) energy-storage performance has not been well established and no reports on the energy-storage feature of its high-temperature intermediate phase (IM) are available. In this work, high-quality PbHfO3 ceramics were prepared via the solid-state synthesis route. Based on high-temperature X-ray diffraction data, the IM of PbHfO3 was found to be orthorhombic, Imma space group, with antiparallel alignment of Pb2+ ions along the [001]cubic directions. The polarization–electric field (P–E) relation of PbHfO3 is displayed at RT as well as in the temperature range of the IM. A typical AFE loop revealed an optimal recoverable energy-storage density (Wrec) of 2.7 J/cm3, which is 286% higher than the reported data with an efficiency (η) of 65% at 235 kV/cm at RT. A relatively high Wrec value of 0.7 J/cm3 was found at 190 °C with an η of 89% at 65 kV/cm. These results demonstrate that PbHfO3 is a prototypical AFE from RT up to 200 °C, making it a suitable material for energy-storage applications in a wide temperature range. Full article
(This article belongs to the Special Issue Locally Ordered Materials)
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