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Synthesis and Optical Properties of ZnO Nanostructured Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Advanced Nanomaterials and Nanotechnology".

Deadline for manuscript submissions: closed (10 October 2023) | Viewed by 4540

Special Issue Editor


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Guest Editor
Institute of Physics of the Czech Academy of Sciences, Prague, Czech Republic
Interests: nanomaterials; nanorods; nanopillars; TCO; ZnO; nanoparticle synthesis; hydrothermal growth; perovskites; solar cells

Special Issue Information

Dear Colleagues,

Due to its fascinating multi-functional properties, zinc oxide (ZnO) has attracted significant attention in both the academic and industrial spheres. ZnO nanostructures, in particular, have been a focus of research for various applications because these nanostructures can be easy prepared in a variety of precisely tuned morphologies and sizes, and they also offer a wide direct band gap (3.37 eV), high thermal conductivity, a high refractive index (2.0041) and a rather large excitation binding energy (60 meV). Heretofore, a wide range of chemical and physical technologies were implemented for the preparation of ZnO nanostructures, such as chemical vapor deposition, sputtering, a microwave and ultrasonic combined technique, hydrothermal synthesis, etc. The optical properties of ZnO nanostructures can be modified through annealing, plasma and/or doping processes.

Therefore, combining different synthesis and post-modification approaches can lead to highly tunable opto-electrical ZnO nanostructures with well-defined physico-chemical properties. The main objective of this Special Issue, “Synthesis and Optical Properties of ZnO Nanostructured Materials”, is to highlight new approaches in regarding the synthesis of ZnO nanostructures, with bare or doped structures, and their opto-electrical and physico-chemical properties. Original research papers, short communications and state-of-the-art reviews are welcome for this Special Issue.

Kind regards,

Dr. Neda Neykova
Guest Editor

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Keywords

  • ZnO nanostructures
  • optical properties
  • doping
  • modification
  • crystal structure
  • defects

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Published Papers (2 papers)

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Research

20 pages, 3518 KiB  
Article
Improved Visible Emission from ZnO Nanoparticles Synthesized via the Co-Precipitation Method
by Alexandra Apostoluk, Yao Zhu, Pierrick Gautier, Audrey Valette, Jean-Marie Bluet, Thibaut Cornier, Bruno Masenelli and Stephane Daniele
Materials 2023, 16(15), 5400; https://doi.org/10.3390/ma16155400 - 1 Aug 2023
Cited by 6 | Viewed by 1270
Abstract
Since ZnO nanoparticles (NPs) possess a variety of intrinsic defects, they can provide a wide spectrum of visible emission, without adding any impurity or any doping atoms. They are attracting more and more interest as a material for light sources and energy downshifting [...] Read more.
Since ZnO nanoparticles (NPs) possess a variety of intrinsic defects, they can provide a wide spectrum of visible emission, without adding any impurity or any doping atoms. They are attracting more and more interest as a material for light sources and energy downshifting systems. However, defect emission with a high luminescence quantum efficiency (PL QY) is difficult to obtain. Here, we present the co-precipitation synthesis parameters permitting to attain ZnO NPs with highly visible PL QYs. We found that the nature of zinc precursors and alkaline hydroxide (KOH or LiOH) used in this method affects the emission spectra and the PL QY of the as-grown ZnO NPs. LiOH is found to have an advantageous effect on the visible emission efficiency when added during the synthesis of the ZnO NPs. More precisely, LiOH permits to increase the emission efficiency in the visible up to 13%. We discuss the effects of the nanoparticle size, the morphology and the surface stabilization on the enhancement of the luminescent emission efficiency. Various spectral contributions to the luminescent emission were also examined, in order to achieve a control of the defect emission to increase its efficiency. Full article
(This article belongs to the Special Issue Synthesis and Optical Properties of ZnO Nanostructured Materials)
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12 pages, 3676 KiB  
Article
Hydrothermal Synthesis of Zinc Oxide Nanoparticles Using Different Chemical Reaction Stimulation Methods and Their Influence on Process Kinetics
by Tomasz Strachowski, Magdalena Baran, Marcin Małek, Robert Kosturek, Ewa Grzanka, Jan Mizeracki, Agata Romanowska and Stefan Marynowicz
Materials 2022, 15(21), 7661; https://doi.org/10.3390/ma15217661 - 31 Oct 2022
Cited by 9 | Viewed by 2845
Abstract
The aim of this work was to study the effect of the applied chemical reaction stimulation method on the morphology and structural properties of zinc oxide nanoparticles (ZnONPs). Various methods of chemical reaction induction were applied, including microwave, high potential, conventional resistance heater [...] Read more.
The aim of this work was to study the effect of the applied chemical reaction stimulation method on the morphology and structural properties of zinc oxide nanoparticles (ZnONPs). Various methods of chemical reaction induction were applied, including microwave, high potential, conventional resistance heater and autoclave-based methods. A novel, high potential-based ZnONPs synthesis method is herein proposed. Structural properties–phase purity, grain size–were examined with XRD methods, the specific surface area was determined using BET techniques and the morphology was examined using SEM. Based on the results, the microwave and autoclave syntheses allowed us to obtain the desired phase within a short period of time. The impulse-induced method is a promising alternative since it offers a non-equilibrium course of the synthesis process in an highly energy-efficient manner. Full article
(This article belongs to the Special Issue Synthesis and Optical Properties of ZnO Nanostructured Materials)
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