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Proton-Exchange Membranes: Advances and Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (30 November 2021) | Viewed by 7656

Special Issue Editor


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Guest Editor
Energy, Mining & Environment Research Centre, National Research Council Canada, 4250 Wesbrook Mall, Vancouver, BC V6T 1W5, Canada
Interests: hydrogen fuel cell; proton-exchange membrane; perfluorinated sulfonic acid membrane; ion-exchange membrane; membranes for vanadium flow batteries; membranes for CO2 electrolyzers

Special Issue Information

Dear Colleagues,

Proton-exchange membrane (PEM), playing roles as both a proton conductor and an anode–cathode separator, is a crucial component determining the performance and durability of MEA for PEM fuel cells and other energy conversion technologies. Because of their superior chemical/electrochemical stability and excellent proton conductivity, perfluorinated sulfonic acid (PFSA) membranes have become the benchmark of fuel cell membrane materials. Currently, the e-PTFE reinforced PFSA membranes containing free-radical scavenger additives can serve basic needs for the rapidly developing fuel cell vehicle markets.

Recent research has focused on facilitating advances in PEMs resulting in outstanding performance in a variety of energy conversion devices. For example, PEMs with improved proton conductivity at high temperature and low humidity are under development, with novel approaches such as aligned ionic cluster channels with proton pathways or incorporated nanoparticle/-sheet additives. Due to the drawbacks associated with PFSA production cost and environmental concerns of fluoropolymers, the study of hydrocarbon membranes has been a continual effort toward seeking alternative membranes. In addition, an in-depth understanding of the structure–property relationship is essential for the design of next-generation membranes.

In addition to fuel cell applications, PEM, in recent years, has extended its clean energy applications to other electrochemical devices, such as PEM water electrolyzers for hydrogen production, vanadium redox flow batteries for energy storage, and CO2 electrolyzers for the reduction of GHG emissions.

This Special Issue is focused on novel approaches for designing and developing advanced PEM materials for a wide range of renewable energy applications as well as a better understanding of the structure–property relationship of current PEM materials. It is my pleasure to invite you to submit a manuscript. Full papers, communications, and reviews covering these subjects are all welcome.

Dr. Zhiqing (Ken) Shi
Guest Editor

Manuscript Submission Information

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Keywords

  • proton-exchange membrane
  • perfluorinated sulfonic acid membrane
  • organic–inorganic hybrid membrane
  • proton conductivity
  • structure–property relationship
  • PEM fuel cell
  • vanadium redox flow battery

Published Papers (2 papers)

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Research

16 pages, 4835 KiB  
Article
Superior Proton Exchange Membrane Fuel Cell (PEMFC) Performance Using Short-Side-Chain Perfluorosulfonic Acid (PFSA) Membrane and Ionomer
by Nana Zhao, Zhiqing Shi and Francois Girard
Materials 2022, 15(1), 78; https://doi.org/10.3390/ma15010078 - 23 Dec 2021
Cited by 9 | Viewed by 4440
Abstract
Optimization of the ionomer materials in catalyst layers (CLs) which sometimes is overlooked has been equally crucial as selection of the membranes in membrane electrode assembly (MEA) for achieving a superior performance in proton exchange membrane fuel cells (PEMFCs). Four combinations of the [...] Read more.
Optimization of the ionomer materials in catalyst layers (CLs) which sometimes is overlooked has been equally crucial as selection of the membranes in membrane electrode assembly (MEA) for achieving a superior performance in proton exchange membrane fuel cells (PEMFCs). Four combinations of the MEAs composed of short-side-chain (SSC) and long-side-chain (LSC) perfluorosulfonic acid (PFSA) polymers as membrane and ionomer materials have been prepared and tested under various temperatures and humidity conditions, aiming to investigate the effects of different side chain polymer in membranes and CLs on fuel cell performance. It is discovered that SSC PFSA polymer used as membrane and ionomer in CL yields better fuel cell performance than LSC PFSA polymer, especially at high temperature and low RH conditions. The MEA with the SSC PFSA employed both as a membrane and as an ionomer in cathode CL demonstrates the best cell performance amongst the investigated MEAs. Furthermore, various electrochemical diagnoses have been applied to fundamentally understand the contributions of the different resistances to the overall cell performance. It is illustrated that the charge transfer resistance (Rct) made the greatest contribution to the overall cell resistance and then membrane resistance (Rm), implying that the use of the advanced ionomer in CL could lead to more noticeable improvement in cell performance than only the substitution as the membrane. Full article
(This article belongs to the Special Issue Proton-Exchange Membranes: Advances and Applications)
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17 pages, 4519 KiB  
Article
Improved Thermo-Mechanical Properties and Reduced Hydrogen Permeation of Short Side-Chain Perfluorosulfonic Acid Membranes Doped with Ti3C2Tx
by Panpan Guan, Jianlong Lei, Yecheng Zou and Yongming Zhang
Materials 2021, 14(24), 7875; https://doi.org/10.3390/ma14247875 - 19 Dec 2021
Cited by 9 | Viewed by 2756
Abstract
Benefiting from its large specific surface with functional -OH/-F groups, Ti3C2Tx, a typical two-dimensional (2D) material in the recently developed MXene family, was synthesized and used as a filler to improve the properties of the short side-chain [...] Read more.
Benefiting from its large specific surface with functional -OH/-F groups, Ti3C2Tx, a typical two-dimensional (2D) material in the recently developed MXene family, was synthesized and used as a filler to improve the properties of the short side-chain (SSC) perfluorosulfonic acid (PFSA) proton exchange membrane. It is found that the proton conductivity is enhanced by 15% while the hydrogen permeation is reduced by 45% after the addition of 1.5 wt% Ti3C2Tx filler into the SSC PFSA membrane. The improved proton conductivity of the composite membrane could be associated with the improved proton transport environment in the presence of the hydrophilic functional groups (such as -OH) of the Ti3C2Tx filler. The significantly reduced hydrogen permeation could be attributed to the incorporation of the impermeable Ti3C2Tx 2D fillers and the decreased hydrophilic ionic domain spacing examined by the small angle X-ray scattering (SAXS) for the composite membrane. Furthermore, improved thermo-mechanical properties of the SSC/Ti3C2Tx composite membrane were measured by dynamic mechanical analyzer (DMA) and tensile strength testing. The demonstrated higher proton conductivity, lower hydrogen permeation, and improved thermo-mechanical stability indicate that the SSC/Ti3C2Tx composite membranes could be a potential membrane material for PEM fuel cells operating above the water boiling temperature. Full article
(This article belongs to the Special Issue Proton-Exchange Membranes: Advances and Applications)
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