Electrochemical Corrosion and Protection of Alloys and Steels

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Corrosion and Protection".

Deadline for manuscript submissions: closed (30 September 2023) | Viewed by 1766

Special Issue Editor


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Guest Editor
1. Corrosion Research Centre St. Antony’s College of Arts and Sciences for Women, Thamaraipadi, Dindigul-624 005, India
2. Centre for Nanoscience and Technology, Pondicherry University, Puducherry 605 014, India
Interests: corrosion inhibitors; green inhibitors; simulated concrete pore solution; artificial sweat; simulated oil-well water

Special Issue Information

Dear Colleagues,

Corrosion theory entails that the process involves an anodic reaction. This type of reaction is produced through dissolving metal, which generates electrons. This is further consumed by another process called the cathodic reaction. These two processes balance the charges produced during corrosion.

The electrochemical corrosion of metals occurs when electrons from atoms at the surface of the metal are transferred to a suitable electron acceptor or depolarizer. Water must be present to serve as a medium for the transport of ions. The most common depolarizers are oxygen, acids, and the cations of less-active metals.

Alloy steel is most commonly used to manufacture pipes, especially pipes for energy-related applications. It is also used in the manufacturing of heating elements in appliances like toasters, silverware, pots and pans, and corrosion-resistant containers.

Smaller items such as screws, nails and bolts made of alloy steels are used in the building and construction industry. Bridges use special alloy steels known as weathering steels. These provide enhanced protection from corrosion because of the presence of nickel, copper and chromium as alloying elements.

Because of its high tensile strength and low cost, steel is used in buildings, infrastructure, tools, ships, trains, cars, machines, electrical appliances, weapons, and rockets.

Alloys have different properties to the pure metal components. For any particular use, an alloy is matched that has the most suitable range of properties.

Aluminum and copper are useful metals. This table shows examples of common alloys that contain these metals:

Alloy

Composition

Uses

Duralumin

Aluminum and copper

Aircraft parts

Magnalium

Aluminum and magnesium

Aircraft parts

Bronze

Copper and tin

Propellers for ships, bells

Brass

Copper and zinc

Coins, musical instruments

Jewelry gold

Gold and copper

Jewelry

Solder

Tin and copper

Joining copper pipes and electrical components

Alloys and steel undergo corrosion in various environments. This corrosion can be controlled by various methods, such as the use of corrosion inhibitors , painting, cathodic protection etc.

Articles are invited on topics including (but not limited to) the following:

  • Basic aspects of corrosion;
  • Theories of corrosion;
  • Corrosion control in concrete technology;
  • Corrosion inhibitors for cooling water systems;
  • Corrosion resistance of mild steel in simulated concrete pore solution;
  • Corrosion resistance of mild steel in simulated oil-well water;
  • Corrosion resistance of gold 18 K in the presence of artificial sweat;
  • Corrosion resistance of gold 22 K in the presence of artificial sweat;
  • Corrosion resistance of gold 18 K in the presence of artificial saliva;
  • Corrosion resistance of gold 20 K in the presence of artificial saliva;
  • Corrosion resistance of 316 L alloy in the presence of artificial saliva;
  • Corrosion resistance of 18/8 alloy in the presence of artificial saliva;
  • Corrosion resistance of mild steel in the presence of green inhibitors;
  • Corrosion problems in aircraft parts;
  • Titanic corrosion;
  • Silver bridge corrosion.

Prof. Dr. Susai Rajendran
Guest Editor

Manuscript Submission Information

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Keywords

  • electrochemical corrosion
  • protection of alloys
  • protection of steels
  • corrosion resistance
  • artificial sweat
  • artificial saliva
  • green inhibitors
  • simulated concrete pore solution

Published Papers (1 paper)

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Research

22 pages, 11014 KiB  
Article
Corrosion Current Density of API 5L X65 Carbon Steel in Contact with Natural Callovian-Oxfordian Clay Pore Water, Assessed by Various Electrochemical Methods over 180 Days
by Yendoube Charles Sano Moyeme, Stephanie Betelu, Johan Bertrand, Karine Groenen Serrano and Ioannis Ignatiadis
Metals 2023, 13(5), 966; https://doi.org/10.3390/met13050966 - 17 May 2023
Viewed by 1385
Abstract
Near-neutral pH and a low redox potential are considered favorable conditions for immobilizing radionuclides in deep repository systems within clay formations. Cigeo is the future French Industrial Center for Geological Disposal for high- and intermediate-level long-lived radioactive waste, to be built at a [...] Read more.
Near-neutral pH and a low redox potential are considered favorable conditions for immobilizing radionuclides in deep repository systems within clay formations. Cigeo is the future French Industrial Center for Geological Disposal for high- and intermediate-level long-lived radioactive waste, to be built at a depth of 500 m within the Callovian–Oxfordian clay. In-depth knowledge of the mechanisms and kinetics of corrosion occurring on the surface of API 5L X65 (X65) carbon steel tubing is essential for the reversible nuclear waste management of the Cigeo site. By using all-solid and robust handmade electrodes in addition to electrochemical and gravimetric techniques, we determined the corrosion phenomenology and kinetics of X65 in contact with natural Cox pore water in equilibrium with its rock gases, flowing continuously through a multi-parameter probe device and placed at a depth of 500 m at the Bure Underground Research Laboratory, for over 180 days. Two iron oxidants were encountered, namely, depleted dioxygen (O2) and proton H(I), accompanied by hydrogen sulfide. Corrosion mechanisms and kinetics were well established for the two X65 electrodes, whether electrochemically perturbed or not. The corrosion thickness loss rates, determined by both electrochemical and gravimetric techniques, were between 0.016 and 0.032 mm/year. This study demonstrates, on site, the reliability of a developed methodology for continuous monitoring of the corrosion kinetics of the API 5L X65 carbon steel at the same time as the temporal variation of the key geochemical parameters of the fluid was assessed. Full article
(This article belongs to the Special Issue Electrochemical Corrosion and Protection of Alloys and Steels)
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