High-Entropy Alloys for Extreme Environments

A special issue of Metals (ISSN 2075-4701).

Deadline for manuscript submissions: closed (31 August 2021) | Viewed by 6067

Special Issue Editors


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Guest Editor
Department of Microstructure Physics and Alloy design, Max Planck Institute for Iron Research GmbH, Düsseldorf 40237, Germany
Interests: : alloy design; mechanical behavior; thermomechanical processing; microstructure; high-entropy alloys

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Guest Editor
Center for High Entropy Alloys, Pohang University of Science and Technology, Pohang 37673, South Korea
Interests: mechanical properties of materials; high-entropy alloys; materials design; heterogeneous materials; low-temperature mechanical behavior of materials

Special Issue Information

Dear Colleagues,

High-entropy alloys (HEAs), consisting of multi-principal elements, have been attracting extensive attention as promising candidates for structural applications beyond those of conventional metallic materials. The concept of HEAs enables a paradigmatic shift from the conventional alloying strategies consisting of one or two principal elements to unique alloy design with multi-principal elements by opening vast compositional space and providing vast compositional degrees of freedom. Moreover, new physical phenomena and excellent properties for HEAs under various environments have been reported. Examples include severe lattice distortion; the exceptional combination of strength, ductility, and fracture toughness at cryogenic temperatures; the high-temperature strength of refractory HEAs; resistance to grain growth; and thermal stability that is relevant for structural applications and extreme environments.

For this Special Issue, reviews and research articles in the field of high-entropy alloys for extreme environments are welcomed. This includes research related to high-entropy alloys in temperatures ranging from deep cryogenic temperatures to ambient and high temperatures on physical metallurgy, mechanical properties, microstructures, corrosion resistance, alloy design, severe plastic deformation, and industrial applications. We welcome either experimental or theoretical approaches on the above subjects. Hopefully, new discoveries and perspectives for high-entropy alloys and their industrialization will be shared and discussed through this Special Issue.

Dr. Jae Wung Bae
Dr. Jongun Moon
Guest Editors

Manuscript Submission Information

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Keywords

  • high-entropy alloys;
  • physical metallurgy;
  • mechanical properties;
  • microstructures;
  • materials design;
  • corrosion resistance;
  • oxidation resistance;
  • deformation mechanisms;
  • strengthening mechanisms;
  • industrial applications.

Published Papers (2 papers)

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Research

11 pages, 2160 KiB  
Article
Influence of Ti Addition on the Strengthening and Toughening Effect in CoCrFeNiTix Multi Principal Element Alloys
by Dukhyun Chung, Heounjun Kwon, Chika Eze, Woochul Kim and Youngsang Na
Metals 2021, 11(10), 1511; https://doi.org/10.3390/met11101511 - 24 Sep 2021
Cited by 3 | Viewed by 2254
Abstract
Multi principal element alloys have attracted interests as a promising way to balance the bottleneck of the “inverse relationship” between high hardness and high fracture toughness. In the present study, the authors demonstrate the effects of Ti addition on the microstructures and mechanical [...] Read more.
Multi principal element alloys have attracted interests as a promising way to balance the bottleneck of the “inverse relationship” between high hardness and high fracture toughness. In the present study, the authors demonstrate the effects of Ti addition on the microstructures and mechanical properties of the CoCrFeNiTix alloys (x values in molar ratio, x = 0.7, 1.0, and 1.2), which exhibits a multi-phase structure containing face-centered cubic phase and various secondary phases, such as sigma, Laves, and (Cr,Fe)-rich phase. Throughout the combined experimental examination and modeling, we show that superb hardness (~9.3 GPa) and excellent compressive strength (~2.4 GPa) in our alloy system are attributed to solid-solution strengthening of the matrix and the formation of hard secondary phases. In addition, high indentation fracture toughness is also derived from the toughening mechanism interplay within the multiple-phase microstructure. At the fundamental level, the results suggest that multi-principal element alloys containing dual or multi-phase structures may provide a solution for developing structural alloys with enhanced strength-toughness synergy. Full article
(This article belongs to the Special Issue High-Entropy Alloys for Extreme Environments)
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14 pages, 4880 KiB  
Article
Hydrogen Effects in Equiatomic CrFeNiMn Alloy Fabricated by Laser Powder Bed Fusion
by Xuan Yang, Yuriy Yagodzinskyy, Yanling Ge, Eryang Lu, Joonas Lehtonen, Lauri Kollo and Simo-Pekka Hannula
Metals 2021, 11(6), 872; https://doi.org/10.3390/met11060872 - 27 May 2021
Cited by 8 | Viewed by 2595
Abstract
This study investigates the effects of laser powder bed fusion (LPBF) on the hydrogen uptake of the face-centered cubic (FCC) equiatomic CrFeNiMn multicomponent alloy after cathodic hydrogen charging (HC). Hydrogen desorption was evaluated using thermal desorption spectroscopy (TDS), and microstructural changes after the [...] Read more.
This study investigates the effects of laser powder bed fusion (LPBF) on the hydrogen uptake of the face-centered cubic (FCC) equiatomic CrFeNiMn multicomponent alloy after cathodic hydrogen charging (HC). Hydrogen desorption was evaluated using thermal desorption spectroscopy (TDS), and microstructural changes after the TDS test were examined. Results reveal that the amount of hydrogen absorbed by LPBF CrFeNiMn alloy was significantly higher than that in pulsed electric current sintered (PECS) CrFeNiMn alloy or in conventional 316L austenitic stainless steel. The observations are ascribed to the differences in the amount of hydrogen absorbed by the multicomponent lattice, dislocation densities, width of segregation range at cell walls created by the rapid cooling in LBPF, and vacancies remaining after cooling to room temperature. A hydrogen-charged LBPF transmission electron microscope (TEM) specimen was also characterized. Stacking faults and cracks along the (111)-planes of austenite were observed. Scanning electron microscopy (SEM) of the surface of the TDS-tested samples also indicated hydrogen-induced cracks and hydrogen-induced submicron pits at the grain boundary inclusions. Full article
(This article belongs to the Special Issue High-Entropy Alloys for Extreme Environments)
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