Mechanical and Mechanochemical Synthesis of Alloys

A special issue of Metals (ISSN 2075-4701).

Deadline for manuscript submissions: closed (30 September 2021) | Viewed by 7949

Special Issue Editor


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Guest Editor
Institut für Materialphysik, Universität Göttingen, 37077 Göttingen, Germany
Interests: metals and alloys; mechanical properties; microstructure-strength relationship; defect-solute interactions; thermodynamics; transmission electron microscopy

Special Issue Information

Dear Colleagues,

For modern-day industrial applications, metals and alloys should have mechanical properties such as high strength, high ductility, high fracture toughness, and high stiffness, preferably together with high temperature capability, high corrosion resistance, as well as low weight and low cost. Since such a metal currently does not exist, C. Suryanarayana called this metal utopium in his article “Mechanical Alloying: A Novel Technique to Synthesize Advanced Materials” in AAAS Research, Vol. 2019, Art. 4219812. One promising pathway towards developing materials with property combinations closer to utopium is mechanical/mechanochemical synthesis of alloys.

Mechanical/mechanochemical synthesis consists of non-equilibrium processing routes involving severe plastic deformation (SPD) that often leads to unexpected alloy properties, frequently nearer to utopium than the base metals. There has been a remarkable evolution of these methods since they were developed in the 1960s; however, it should be mentioned that mechanochemical methods have already been used as early as 300 BC. Mechanical alloying is one of these routes, high-pressure torsion, cold wire drawing, and accumulative roll bonding are three others. When applied to alloys, SPD often leads to mechanically driven phase transformations like forced mixing in immiscible alloy systems, decomposition of supersaturated solid solutions, dissolution of second phase particles, or even amorphization. These reactions justify the expression “mechanochemistry”.

This Special Issue will present the latest developments and findings in the area of mechanical and mechanochemical synthesis of alloys. The scope includes (but is not limited to) new alloys processed by these methods, their microstructural evolution, mechanical properties, failure/degradation analysis, fracture, fatigue, wear, and corrosion characteristics, in brief, the approach of these alloys to utopium. Theoretical and/or computational treatment of these phenomena, as well as application-related aspects, are also welcome.

Dr. Christine Borchers
Guest Editor

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Keywords

  • Mechanical/mechanochemical synthesis
  • Metastable alloys
  • Mechanical properties
  • Corrosion
  • Failure analysis
  • Simulation and modeling

Published Papers (2 papers)

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Research

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11 pages, 2632 KiB  
Article
Cooling under Applied Stress Rejuvenates Amorphous Alloys and Enhances Their Ductility
by Nikolai V. Priezjev
Metals 2021, 11(1), 67; https://doi.org/10.3390/met11010067 - 31 Dec 2020
Cited by 7 | Viewed by 2731
Abstract
The effect of tensile stress applied during cooling of binary glasses on the potential energy states and mechanical properties is investigated using molecular dynamics simulations. We study the three-dimensional binary mixture that was first annealed near the glass transition temperature and then rapidly [...] Read more.
The effect of tensile stress applied during cooling of binary glasses on the potential energy states and mechanical properties is investigated using molecular dynamics simulations. We study the three-dimensional binary mixture that was first annealed near the glass transition temperature and then rapidly cooled under tension into the glass phase. It is found that at larger values of applied stress, the liquid glass former freezes under higher strain and its potential energy is enhanced. For a fixed cooling rate, the maximum tensile stress that can be applied during cooling is reduced upon increasing initial temperature above the glass transition point. We also show that the amorphous structure of rejuvenated glasses is characterized by an increase in the number of contacts between smaller type atoms. Furthermore, the results of tensile tests demonstrate that the elastic modulus and the peak value of the stress overshoot are reduced in glasses prepared at larger applied stresses and higher initial temperatures, thus indicating enhanced ductility. These findings might be useful for the development of processing and fabrication methods to improve plasticity of bulk metallic glasses. Full article
(This article belongs to the Special Issue Mechanical and Mechanochemical Synthesis of Alloys)
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Review

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12 pages, 2919 KiB  
Review
High-Pressure Torsion for Synthesis of High-Entropy Alloys
by Kaveh Edalati, Hai-Wen Li, Askar Kilmametov, Ricardo Floriano and Christine Borchers
Metals 2021, 11(8), 1263; https://doi.org/10.3390/met11081263 - 11 Aug 2021
Cited by 22 | Viewed by 4624
Abstract
High-pressure torsion (HPT) is widely used not only as a severe plastic deformation (SPD) method to produce ultrafine-grained metals but also as a mechanical alloying technique to synthesize different alloys. In recent years, there have been several attempts to synthesize functional high-entropy alloys [...] Read more.
High-pressure torsion (HPT) is widely used not only as a severe plastic deformation (SPD) method to produce ultrafine-grained metals but also as a mechanical alloying technique to synthesize different alloys. In recent years, there have been several attempts to synthesize functional high-entropy alloys using the HPT method. In this paper, the application of HPT to synthesize high-entropy materials including metallic alloys, hydrides, oxides and oxynitrides for enhanced mechanical and hydrogen storage properties, photocatalytic hydrogen production and high light absorbance is reviewed. Full article
(This article belongs to the Special Issue Mechanical and Mechanochemical Synthesis of Alloys)
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