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Electroanalysis of Biochemistry and Material Chemistry—2nd Edition

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Electrochemistry".

Deadline for manuscript submissions: 31 January 2025 | Viewed by 1309

Special Issue Editor


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Guest Editor
School of Materials Science and Hydrogen Energy, Foshan University, Foshan, China
Interests: electrocatalysis; computational electrochemical; nano electrochemical; electrochemical bio-sensors; low-temperature fuel cells; supercapacitors
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Special Issue Information

Dear Colleagues,

Electroanalysis is a useful tool for measuring the variation in the electrical parameters of electrode materials by controlling operating parameters. Based on compatibility and feasibility, electroanalysis plays a role as the bridge between empirical analytical chemistry and rationalistic physical chemistry. Due to its dynamic interaction with other disciplines (such as biochemistry and material chemistry), electroanalysis has been able to provide solutions for basic problems in biochemistry and material chemistry. Therefore, this Special Issue, titled “Electroanalysis of Biochemistry and Material Chemistry”, focuses on the most recent advances in the application of electroanalytical methods the field of biochemistry and material chemistry. Original research and reviews on advances in analytical voltammetry, potentiometry, conductometry and electrolytic methods, and electrochemical devices (such as electrochemical bio-sensors, fuel cells, batteries, and supercapacitors) are welcome.

Prof. Dr. Guangjin Wang
Guest Editor

Manuscript Submission Information

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Keywords

  • voltammetry
  • potentiometry
  • conductometry
  • electrolytic method
  • electrochemical bio-sensors
  • fuel cells
  • batteries
  • supercapacitors

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Published Papers (2 papers)

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Research

12 pages, 3451 KiB  
Article
Surface Microstructure Study on Corona Discharge-Treated Polyethylene Using Positron Annihilation Spectroscopy
by Jingjing Li, Zhiwei Shen, Liuyang Tie, Tianyuan Long, Qiyue Zhong, Xi Chen, Chongshan Yin, Liguo Liufu, Xianhao Huang, Bangyun Xiong, Xibo Li, Chongxiong Duan and Chunqing He
Molecules 2024, 29(17), 4147; https://doi.org/10.3390/molecules29174147 - 31 Aug 2024
Viewed by 682
Abstract
The microstructure and chemical properties of the corona discharge process could provide an effective method for predicting the performance of high-voltage cable insulation materials. In this work, the depth profile of the microstructure and chemical characteristics of corona discharge-treated PE were extensively investigated [...] Read more.
The microstructure and chemical properties of the corona discharge process could provide an effective method for predicting the performance of high-voltage cable insulation materials. In this work, the depth profile of the microstructure and chemical characteristics of corona discharge-treated PE were extensively investigated using Doppler broadening of position annihilation spectroscopy accompanied with positron annihilation lifetime spectroscopy, attenuated total reflectance Fourier transform infrared spectra, Raman spectra and contact angle measurement. By increasing corona discharge duration, the oxygen-containing polar groups, including hydroxyl, carbonyl and ester groups, strongly contribute to the deterioration of hydrophobicity and the enhancement of hydrophilicity. And the mean free volume size, with a broadening distribution, decreases slightly. The line shape S parameter decreases because of the decrease in free volume elements and the appearance of oxygen-containing groups. Also, the thickness of the degradation layer, determined from the S parameter with positron injection depth, increases and diffuses into the PE matrix. A linear S-W plot within the degradation layer of different corona treatment duration samples indicates the defect type does not change. The S parameter decreases and the W parameter increases with an increasing corona duration. Using a slow positron beam, the nondestructive probe can be used to profile the microstructure and chemical environment across the corona discharge damage depth, which is beneficial for investigating the surface and interfacial insulation materials. Full article
(This article belongs to the Special Issue Electroanalysis of Biochemistry and Material Chemistry—2nd Edition)
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18 pages, 9174 KiB  
Article
Influence of Bi3+ Doping on Electrochemical Properties of Ti/Sb-SnO2/PbO2 Electrode for Zinc Electrowinning
by Jia Wu, Xuanqi Kang, Shuangwen Xu, Zhen Wei, Shangyuan Xu, Kang Liu, Qing Feng, Bo Jia and Yunhai Wang
Molecules 2024, 29(17), 4062; https://doi.org/10.3390/molecules29174062 - 27 Aug 2024
Viewed by 473
Abstract
Bi3+ doped Ti/Sb-SnO2/PbO2 electrode materials were fabricated by electrodeposition to improve their electrochemical performance in zinc electrowinning. The surface morphology, chemical composition, and hydrophilicity of the as-prepared electrodes were characterized using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy [...] Read more.
Bi3+ doped Ti/Sb-SnO2/PbO2 electrode materials were fabricated by electrodeposition to improve their electrochemical performance in zinc electrowinning. The surface morphology, chemical composition, and hydrophilicity of the as-prepared electrodes were characterized using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and contact angle. An electrochemical measurement and an accelerated lifetime experiment were also conducted to investigate the electrocatalytic performance and stability of the electrodes. The results show that the Bi3+ modification electrode has an important effect on the coating morphology, the crystal structure, the surface hydrophilicity, the electrocatalytic activity, and the stability. The electrode prepared from the solution containing 2 mmol·L−1 Bi(NO3)3 (marked as the Ti/Sb-SnO2/2Bi-PbO2 electrode) exhibits the best hydrophilicity performance (θ = 21.6°) and the longest service life (1196 h). During the electrochemical characterization analysis, the Ti/Sb-SnO2/2Bi-PbO2 electrode showed the highest oxygen evolution activity, which can be attributed to it having the highest electroactive surface (qT* = 21.20 C·cm−2) and the best charge-transfer efficiency. The DFT calculation demonstrated that the doping of Bi3+ leads to a decrease in the OER reaction barrier and an increase in the DOS of the electrode, which further enhances the catalytic activity and the conductivity of the electrode. Moreover, the simulated zinc electrowinning experiment demonstrated that the Ti/Sb-SnO2/2Bi-PbO2 electrode consumes less energy than other electrodes. Therefore, it is expected that the Bi3+ modified electrode will become a very promising electrode material for zinc electrowinning in the future. Full article
(This article belongs to the Special Issue Electroanalysis of Biochemistry and Material Chemistry—2nd Edition)
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