Novel Polymer Composites for Energy Storage Applications

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Physics and Theory".

Deadline for manuscript submissions: closed (10 February 2024) | Viewed by 6549

Special Issue Editors


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Guest Editor
School of Electrical and Computer Engineering, Pusan National University, Busandaehak-ro 63beon-gil, Geumjeong-gu, Busan 46241, Republic of Korea
Interests: energy storage; nanomaterials; renewables; supercapacitors; batteries
RAK Research and Innovation Centre, American University of Ras Al Khaimah (AURAK), Ras Al Khaimah P.O. Box 31208, United Arab Emirates
Interests: chemical engineering; 2D nanocomposites, MXenes; polymeric membrane distillation; polymer based solar reflective coatings

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Guest Editor
Department of Mechanical and Industrial Engineering, American University of Ras Al Khaimah, Ras Al Khaima, United Arab Emirates
Interests: industrial engineering; polymeric coatings; thermal spary process; nanomaterials; renewable energy

Special Issue Information

Dear Colleagues,

Novel Polymer Composites are identified as potential nanocomposites for the energy storage applications such as supercapacitors and batteries. The growing demand of high voltage, high capacity, and high efficiency capacitive electrical energy storage calls for polymer composites with high breakdown strength, high energy storage density, and high charge/discharge efficiency. Polymer composites can be deployed as predominant energy storage materials due to their diversified structural and morphological features. The advancements in novel polymer composites plays a crucial role in the next generation energy storage applications. The current special issue focus mainly on fabrication and synthesis of novel polymer composites for energy storage applications. Articles, communications, and reviews by the experts in this field are welcome.

Dr. Kummara Venkata Guru Raghavendra
Dr. Uday Kumar
Dr. Kadhim Alamara
Guest Editors

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Keywords

  • novel polymer composites
  • potential composites
  • energy storage applications
  • diversified structural and morphological features
  • fabrication and synthesis

Published Papers (3 papers)

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Research

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23 pages, 7433 KiB  
Article
Novel PEG6000–Silica-MWCNTs Shape-Stabilized Composite Phase-Change Materials (ssCPCMs) for Thermal-Energy Storage
by Cristina Lavinia Nistor, Ioana Catalina Gifu, Elena Maria Anghel, Raluca Ianchis, Cristiana-Diana Cirstea, Cristian Andi Nicolae, Augusta Raluca Gabor, Irina Atkinson and Cristian Petcu
Polymers 2023, 15(14), 3022; https://doi.org/10.3390/polym15143022 - 12 Jul 2023
Cited by 2 | Viewed by 1651
Abstract
This paper describes the preparation of new PEG6000–silica-MWCNTs composites as shape-stabilized phase change materials (ssPCMs) for application in latent heat storage. An innovative method was employed to obtain the new organic–inorganic hybrid materials, in which both a part of the PEG [...] Read more.
This paper describes the preparation of new PEG6000–silica-MWCNTs composites as shape-stabilized phase change materials (ssPCMs) for application in latent heat storage. An innovative method was employed to obtain the new organic–inorganic hybrid materials, in which both a part of the PEG chains, used as the phase change material, and a part of the hydroxyl functionalized multiwall carbon nanotubes (MWCNTs-OH), used as thermo-conductive fillers, were covalently connected by newly formed urethane bonds to the in-situ-generated silica matrix. The study’s main aim was to investigate the optimal amount of PEG6000 that can be added to the fixed sol–gel reaction mixture so that no leakage of PEG occurs after repeated heating–cooling cycles. The findings show that the optimum PEG6000/NCOTEOS molar ratio was 2/1 (~91.5% PEG6000), because both the connected and free PEG chains interacted strongly with the in-situ-generated silica matrix to form a shape-stabilized material while preserving high phase-transition enthalpies (~153 J/G). Morphological and structural findings obtained by SEM, X-ray and Raman techniques indicated a distribution of the silica component in the amorphous phase (~27% for the optimum composition) located among the crystalline lamellae built by the folded chains of the PEG component. This composite maintained good chemical stability after a 450-cycle thermal test and had a good storage efficiency (~84%). Full article
(This article belongs to the Special Issue Novel Polymer Composites for Energy Storage Applications)
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12 pages, 3417 KiB  
Article
Ion-Conducting Robust Cross-Linked Organic/Inorganic Polymer Composite as Effective Binder for Electrode of Electrochemical Capacitor
by Hui Gyeong Park, Jin Ju Jeong, Jae Hun Kim and Jung-Soo Lee
Polymers 2022, 14(23), 5174; https://doi.org/10.3390/polym14235174 - 28 Nov 2022
Viewed by 1372
Abstract
Poly(ionic liquid)s (PILs) are used in many electrochemical energy storage/conversion devices owing to their favorable physical properties. Therefore, PIL binders have been examined as polymeric binders for electrodes in energy storage systems (ESSs) and have shown superior performance. Several innovative technologies have been [...] Read more.
Poly(ionic liquid)s (PILs) are used in many electrochemical energy storage/conversion devices owing to their favorable physical properties. Therefore, PIL binders have been examined as polymeric binders for electrodes in energy storage systems (ESSs) and have shown superior performance. Several innovative technologies have been developed to improve the properties of polymers, with cross-linking being the most effective and easy strategy to achieve this. In this study, we designed a breakthrough complex cross-linking and composite technique that could successfully develop the physical properties of a polymer in a simple one-step process. Additionally, the technique could improve the thermal stability and mechanical properties of the polymer. The proposed polymeric binder showed better adhesion, higher capacitance, and good energy density with improved cyclic stability compared to that shown by conventional polyvinylidene fluoride (PVDF). This study revealed that cross-linked networks in polymeric binders are long-cycle-life features for electrochemical redox capacitors. Full article
(This article belongs to the Special Issue Novel Polymer Composites for Energy Storage Applications)
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Review

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21 pages, 2426 KiB  
Review
A Comprehensive Compilation of Graphene/Fullerene Polymer Nanocomposites for Electrochemical Energy Storage
by Judy Gopal, Manikandan Muthu and Iyyakkannu Sivanesan
Polymers 2023, 15(3), 701; https://doi.org/10.3390/polym15030701 - 30 Jan 2023
Cited by 17 | Viewed by 2825
Abstract
Electricity consumption is an integral part of life on earth. Energy generation has become a critical topic, addressing the need to fuel the energy demands of consumers. Energy storage is an offshoot of the mainstream process, which is now becoming a prime topic [...] Read more.
Electricity consumption is an integral part of life on earth. Energy generation has become a critical topic, addressing the need to fuel the energy demands of consumers. Energy storage is an offshoot of the mainstream process, which is now becoming a prime topic of research and development. Electrochemical energy storage is an attractive option, serving its purpose through fuel cells, batteries and supercapacitors manipulating the properties of various materials, nanomaterials and polymer substrates. The following review presents a comprehensive report on the use of carbon-based polymer nanocomposites, specifically graphene and fullerene-based polymer nanocomposites, towards electrochemical energy storage. The achievements in these areas, and the types of polymer nanocomposites used are listed. The areas that lack of clarity and have a dearth of information are highlighted. Directions for future research are presented and recommendations for fully utilizing the benefits of the graphene/fullerene polymer nanocomposite system are proposed. Full article
(This article belongs to the Special Issue Novel Polymer Composites for Energy Storage Applications)
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