Polymer Based Composites for Electromagnetic Interference Shielding

A special issue of Polymers (ISSN 2073-4360).

Deadline for manuscript submissions: closed (15 July 2019) | Viewed by 7992

Special Issue Editor


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Guest Editor
Wireless Access Engineering Department, TIM S.p.A., 61-00148 Rome, Italy
Interests: electromagnetic propagation in lossy media, mobile telecommunication, 2G, 3G, 4G, 5G wireless access engineering, nanocomposites, electromagnetic shielding structures, radar absorbing structures, dielectric characterization of materials, electromagnetic measurement in reverberation chamber, electromagnetic measurement with transmission line method

Special Issue Information

Dear Colleagues,

The topic of electromagnetic interference shielding is becoming a very important issue in the modern world. In fact, the wireless world of mobile and satellite telecommunication and radar observation and the electronic war systems have nowadays to coexist and operate simultaneously. In such a scenario, the paradigm is reducing electromagnetic interference (EMI) and intentional electromagnetic interference (IEMI) as much as possible. Electromagnetic compatibility (EMC) is the ability of different electronic devices and components to work correctly even in the presence of other devices that emit electromagnetic waves.

For example, in modern automobiles, the growing number of onboard electronics and microprocessor-controlled systems requires that the electronic sub-assemblies (ESA) in the vehicle meet EMC requirements. If airbag, cruise control, anti-lock braking, or other electronically controlled assemblies are adversely affected by EMI, the vehicle’s operation or its critical safety systems could be compromised. As mandated by safety and reliability requirements, the automotive onboard ESAs must not emit EMI signals and must be immune to external EMI signals.

One of the approaches to reduce the effect of electromagnetic interference consists in designing and developing materials and structures able to effectively shield electromagnetic interference.

As a function of the frequency of the electromagnetic field and depending on the system to shield, different approaches can be applied. This Special Issue is devoted to carbon-based composites for electromagnetic interference shielding.

Metal, in the form of thin sheets or sheathing, is an effective EMI shielding material, common, for example, in automotive applications. However, metal is expensive, heavy, and prone to corrosion, which adds to the complexity and cost of the manufacturing processes. Moreover, because of their high electrical conductivity, metals play a role in scattering the electromagnetic interference on other parts. Conductive polymer composites offer a potentially cost-effective and process-friendly alternative to metal. The embedded thin metal foils of aluminum, copper, or silver in the polymer matrix are in vogue with suitable provision for grounding. Conventional conductive fillers such as metal flakes, stainless steel fibers, or carbon-based fillers can be dispersed in a polymer matrix creating an electrically conductive network that improves electromagnetic absorption and shielding as a function of the frequency of EMI.

Recently, conductive polymer nano-composites have attracted a great deal of academic and industrial interest due to their potential applications in many areas, including EMI shielding.

Plastic housings are natural insulators and do not reflect or absorb EMI. Most of the energy waves are not obstructed by thermoplastics and enter or leave the housings readily, which causes interference problems. A prompt solution is, therefore, to increase their electrical conductivity by incorporating electro-conducting fillers.

To shield EMI, technical approaches have been extensively considered, aimed at modifying the electrical conductivity of the plastics:

  1. Conductive Coating on Plastics
  2. Compounding with Conductive Fillers
  3. Intrinsically Conductive Polymers (ICP)

For what concerns compounding with conductive fillers, nano-composite fillers, in contrast with larger conventional composite fillers, have at least one dimension in the nanometer range and include materials such as carbon nanotubes (CNT), graphite nanoplatelets (GNP), and metal oxides. These high-aspect-ratio nano-scale fillers form conductive networks much more readily than the conventional conductive fillers. Because of their larger filler–matrix interface, their mechanical and thermal properties may also be enhanced or improved. Furthermore, conductive polymeric nano-composites are lighter and more easily processed.

Some studies reported how composites of very high specific strength and stiffness were produced by incorporating continuous aligned filaments of glass and carbon into matrices of thermosetting plastics like epoxy or polyester.

By incorporating different types of particles into polymeric matrices, improved performance of different types of composites can be achieved.

Currently, many researches are focused on optimizing the dispersion of conductive nano-fillers in the matrix of polymers of different types, such as polypropylene (PP), ABS, conductive rubber composites based on Ethylene–Propylene–Diene Rubber (EPDM), Acrylonitrile butadiene rubber (NBR), polyphenylene oxide polystyrene blend, nylon, polyphenylene sulfide (PPS), PET, and PPO.

Because of the strong tendency of nanoparticles to agglomerate, uniform dispersion of conductive nano-fillers in the polymer matrix is a considerable challenge. Yet, this is essential to the formation of an effective conductive network at low filler loading. Advancements have been made in this area through the use of a proprietary compounding technique.

We look forward to your submission

Dr. Davide Micheli
Guest Editor

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Keywords

  • Electromagnetic Interference
  • Electromagnetic Shielding
  • Electromagnetic Absorption
  • Electric Conductive Polymers
  • Conductive Nano-Fillers
  • Conductive Fillers

Published Papers (2 papers)

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14 pages, 2483 KiB  
Article
Accurate Measurement of the True Plane-Wave Shielding Effectiveness of Thick Polymer Composite Materials via Rectangular Waveguides
by Robert Moučka, Stanislav Goňa and Michal Sedlačík
Polymers 2019, 11(10), 1603; https://doi.org/10.3390/polym11101603 - 1 Oct 2019
Cited by 11 | Viewed by 2787
Abstract
This paper presents a methodology for accurately gauging the true plane wave shielding effectiveness of composite polymer materials via rectangular waveguides. Since the wave propagation of the waveguides is not in the form of plane wave patterns, it is necessary to post-process the [...] Read more.
This paper presents a methodology for accurately gauging the true plane wave shielding effectiveness of composite polymer materials via rectangular waveguides. Since the wave propagation of the waveguides is not in the form of plane wave patterns, it is necessary to post-process the S-parameters for the measured data of the waveguide lines to obtain such patterns and ascertain the effectiveness of true plane wave shielding. The authors propose two different methods to achieve this. The first applies simple renormalization of S-parameters, where reference impedance is changed from the value for the waveguide to that for free space, which ensures good accuracy of shielding effectiveness with a small degree of discontinuity across the range of frequencies. The other relies on rigorous extraction of the composite materials’ effective permittivity and permeability ascertained from rectangular waveguides; afterward, plane wave shielding effectiveness is calculated analytically and gives very high accuracy. Both procedures assume the given samples are isotropic in character. We validated the accuracy of the methodologies by conducting tests on a set of synthetic samples of 2 mm thickness with unit permittivity and variable conductivity and on a dielectric material of known permittivity (FR4 laminate). The applicability of both methods was further proven by analyzing the isotropic composite materials, a process involving the use of iron particles embedded in a dielectric matrix. The synthetic samples and an FR4 material were tested to check the accuracy of the methods. Based on numerical studies and measurements, we concluded that materials with a shielding effectiveness of up to 25 dB could be measured at a maximum amplitude error of 1 dB to 3dB to a frequency of 18 GHz, depending on the relative permittivity of the material; hence, the first method was suitable for approximation purposes. For maximal accuracy, the second method typically demonstrated an amplitude error of below 0.5 dB to the same frequency across the entire range. Full article
(This article belongs to the Special Issue Polymer Based Composites for Electromagnetic Interference Shielding)
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13 pages, 5302 KiB  
Article
Comparison of Experimental and Modeled EMI Shielding Properties of Periodic Porous xGNP/PLA Composites
by Avi Bregman, Eric Michielssen and Alan Taub
Polymers 2019, 11(8), 1233; https://doi.org/10.3390/polym11081233 - 25 Jul 2019
Cited by 25 | Viewed by 3802
Abstract
Microwave absorbing materials, particularly ones that can achieve high electromagnetic interference (EMI) absorption while minimizing weight and thickness are in high demand for many applications. Herein we present an approach that relies on the introduction of periodically placed air-filled pores into polymer composites [...] Read more.
Microwave absorbing materials, particularly ones that can achieve high electromagnetic interference (EMI) absorption while minimizing weight and thickness are in high demand for many applications. Herein we present an approach that relies on the introduction of periodically placed air-filled pores into polymer composites in order to reduce material requirements and maximize microwave absorption. In this study, graphene nano platelet (xGNP)/poly-lactic acid (PLA) composites with different aspect ratio fillers were characterized and their complex electromagnetic properties were extracted. Using these materials, we fabricated non-perfect electrical conductor (PEC) backed, porous composites and explored the effect of filler aspect ratio and pore geometry on EMI shielding properties. Furthermore, we developed and experimentally verified a computational model that allows for rigorous, high-throughput optimization of absorbers with periodic porous geometries. Finally, we extend the modeling approach to explore the effect of pore addition on PEC-backed composites. Our composite structures demonstrated decreased fractions of reflected power and increased fractions of absorbed power over the majority of the X Band due to the addition of periodically arranged cylindrical pores. Furthermore, we showed that for xGNP/PLA composite material, reflection loss can be increased by as much as 13 dB through the addition of spherical pores. The ability to adjust shielding properties through the fabrication of polymer composites with periodically arranged pores opens new strategies for the modeling and development of new microwave absorption materials. Full article
(This article belongs to the Special Issue Polymer Based Composites for Electromagnetic Interference Shielding)
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