Search Results (17)

This work focuses on modeling the performance of the natural gas-fired Allam cycle under off-design conditions. Key thermodynamic parameters, such as turbine inlet pressure (TIP), turbine inlet temperature (TIT), and turbine outlet temperature (TOT), were evaluated at part-load and varying environmental conditions. In the former case, different control strategies were implemented in the simulation code (Thermoflex^®) to reduce the power output. In the latter case, the impact of ambient temperature (T_amb) on the minimum cycle temperature (T_min) was evaluated. The ultimate goal is to predict the thermal efficiency (η_th) and its decrease due to partial load operation and warm climate, without thermal recovery from the air separation unit (ASU). With the most efficient partial load strategy, η_th decreased from 50.4% at full load to 40.3% at about 30% load, at nominal T_min. The penalty caused by the increase in T_min due to hot weather, up to T_amb = 30 °C, was significant at loads above 60%, but limited to 0.5 percentage points (pp). Full article

The growing demand for clean energy and sustainable industrial processes has driven interest in integrated energy systems that optimize resource utilization while minimizing environmental impacts. This study presents the simulation and environmental sustainability assessment of an integrated process combining liquefied natural gas (LNG), Allam–Fetvedt cycle, solid oxide electrolysis’ system, and methanol synthesis to produce clean energy. The proposed system enhances overall efficiency and sustainability by utilizing the Allam–Fetvedt cycle to generate power while capturing CO₂, which is then used in the manufacture of syngas and hydrogen by the electrolysis of water and CO₂. Syngas is subsequently transformed into methanol, a viable alternative fuel characterized by lowcarbon emissions. A comprehensive process simulation is conducted to evaluate energy efficiency, material flows, and system performance. The sustainability assessment focuses on environmental impact indicators, including carbon footprint reduction, energy efficiency improvements, and resource optimization. The results demonstrate that the integrated system significantly reduces CO₂ emissions while maximizing energy recovery, making it a promising approach for decarbonized energy production. In this study, the integrated process including the ASU, power cycle, electrolyzers, methanol production units, and LNG unit results in carbon emissions of 0.29 kg CO₂ per kg of LNG produced, which is very close to the literature-reported lower limit, even though it also has methanol production. On the other hand, when the identical process is assessed solely for methanol production (without the LNG unit), it attains net-zero carbon emissions. Despite the incorporation of high-energy electrolyzer systems, the overall energy demand of the proposed integrated process remains comparable to that of existing conventional technologies with high emission outputs. Full article

The increasing global demand for clean energy and sustainable industrial processes necessitates innovative approaches to energy production and chemical synthesis. This study proposed and simulated an innovative integrated system for the co-production of power, hydrogen, and dimethyl ether (DME), combining the high-efficiency Allam–Fetvedt cycle with co-electrolysis and indirect DME synthesis. The Allam–Fetvedt cycle generated electricity while capturing CO₂, which, along with water, was used in solid oxide electrolyzers (SOEs) to produce syngas via co-electrolysis. The resulting syngas was converted to methanol and subsequently to DME. Aspen HYSYS was used to model and simulate the process, and heat/mass integration strategies were implemented to reduce energy demand and optimize resource utilization. The proposed integrated process enabled an annual production of 980,021 metric tons of DME, 189,435 metric tons of hydrogen, and 7698.27 metric tons of methanol. The energy efficiency of the Allam–Fetvedt cycle reached 55%, and heat integration reduced the system’s net energy demand by 14.22%. Despite the high energy needs of the electrolyzer system (81.28% of net energy), the overall energy requirement remained competitive with conventional methods. Carbon emissions per kilogram of DME were reduced from 1.16 to 0.77 kg CO₂ through heat integration and can be further minimized to 0.0308 kg CO₂/kg DME (near zero) with renewable electrification. Results demonstrated that 96% of CO₂ was recycled within the Allam–Fetvedt cycle, and the rest (the 4% of CO₂) was captured and converted to syngas, achieving net-zero carbon emissions. This work presents a scalable and sustainable pathway for integrated clean energy and chemical production, advancing toward industrial net-zero targets. Full article

The self-diffusion coefficients of carbonaceous fuels in a supercritical CO₂ environment provide transport information that can help us understand the Allam Cycle mechanism at a high pressure of 300 atm. The diffusion coefficients of pure CO₂ and binary CO₂/CH₄ and CO₂/C₂H₆ at high temperatures (500 K~2000 K) and high pressures (100 atm~1000 atm) are determined by molecular dynamics simulations in this study. Increasing the temperature leads to an increase in the diffusion coefficient, and increasing the pressure leads to a decrease in the diffusion coefficients for both methane and ethane. The diffusion coefficient of methane at 300 atm is approximately 0.012 cm²/s at 1000 K and 0.032 cm²/s at 1500 K. The diffusion coefficient of ethane at 300 atm is approximately 0.016 cm²/s at 1000 K and 0.045 cm²/s at 1500 K. The understanding of diffusion coefficients potentially leads to the reduction in fuel consumption and minimization of greenhouse gas emissions in the Allam Cycle. Full article

The natural gas (NG)-powered compressors/engines used in liquified natural gas (LNG) plants are a major source of methane emission. The Allam–Fetvedt cycle (AFC), an oxyfuel, carbon-neutral, high-efficiency power plant, generates pipeline-grade CO₂. This work performed novel process modeling, economic analysis, and greenhouse gas emissions analysis for a heat-integrated, electrified LNG/AFC/air separation unit (ASU) complex (LAA), then compared it to standalone LNG and AFC/ASU plants (baseline) as well as an LNG plant electrified with AFC/ASU without heat integration. The low-grade heat generated from compressors of the LNG plant can enhance the AFC net power output by 7.1%. Utilizing the nitrogens cold energy reduces the compressor power requirement by 1.6%. In the integrated LAA complex, not only are GHG emissions avoided, but the energy efficiencies are also improved for both the LNG plant and the AFC power plant. A cash flow analysis of LAA was performed over a 20-year period with 5%, 7%, and 10% discount rates and three levels of LNG prices. The 45Q CO₂ credit of USD 85/T as stipulated by the recent Inflation Reduction Act (IRA) of 2022 has been incorporated. The results clearly indicate the economic and environmental benefits of the proposed electrification and heat/power integration. Full article

In recent years supercritical CO₂ power plants have seen a growing interest in a wide range of applications (e.g., nuclear, waste heat recovery, solar concentrating plants). The Allam Cycle, also known as the Allam-Fetvedt or NET Power cycle, seems to be one of the most interesting direct-fired sCO₂ cycles. It is a semi-closed loop, high-pressure, low-pressure ratio, recuperated, direct-fired with oxy-combustion, trans-critical Brayton cycle. Numerical simulations play a key role in the study of this novel cycle. For this reason, the aim of this review is to offer the reader a wide array of modeling solutions, emphasizing the ones most frequently employed and endeavoring to provide guidance on which choices seem to be deemed most appropriate. Furthermore, the review also focuses on the system’s performance and on the opportunities related to the integration of the Allam cycle with a series of processes, e.g., cold energy storage, LNG regasification, biomass or coal gasification, and ammonia production. Full article

In this study, thermodynamic modeling and simulations were used to optimize the design point performance of the Allam cycle. The topic fits perfectly with the strategies for power sector decarbonization toward net zero emission. In fact, it offers an environmentally friendlier alternative to natural gas combined cycle (NGCC) plants. The focus is on oxyfuel combustion that, combined with supercritical CO₂ (sCO₂) stream as working fluid, produces high-purity CO₂, electricity, and water by means of a highly recuperated Brayton cycle. The former is ready for sequestration, pipeline injection, or other applications, such as enhanced oil recovery or industrial processes. Being designed within the last decade, large-scale plants are poorly documented in the published literature and not yet ready for operation. Accordingly, a thermodynamic model was developed for a net power (P_n) output of 300 MW. After validation against the little data available from academic studies, simulation sets were conceived to assess the impact of main process parameters on cycle efficiency. To that end, operating conditions of the compressor, turbine, and air separation unit (ASU) were varied in a parametric analysis, preparatory to performance optimization. For the chosen layout, the maximum net electric efficiency (η_el,n) was found to be 50.4%, without thermal recovery from ASU. Full article

The accumulation of energy from non-programmable renewable sources is a crucial aspect for the energy transition. Using surplus electricity from renewable energy sources, power-to-gas plants allow to produce a substitute natural gas (SNG) that can be injected in the existing infrastructure for large-scale and long-term energy storage, contributing to gas grid decarbonisation. The plant layout, the method used for carbon dioxide capture and the possible cogeneration of electricity can increase the efficiency and convenience of SNG synthesis plants. In this work, a system for the simultaneous production of SNG and electricity starting from biomass and fluctuating electricity from renewables is proposed, using a plant based on the Allam thermodynamic cycle as the power unit. The Allam power cycle uses supercritical CO₂ as evolving fluid and is based on the oxycombustion of gaseous fuels, thus greatly simplifying CO₂ capture. In the proposed system, oxycombustion is performed using biomass syngas and electrolytic oxygen. The CO₂ generated by means of oxycombustion is captured, and it is subsequently used together with renewable hydrogen for the production of SNG through thermochemical methanation. The system is also coupled with a solid oxide electrolyser and a biomass gasifier. The whole plant was analysed from an energy-related point of view. The results show overall plant efficiency of 67.6% on an LHV basis (71.6% on an HHV basis) and the simultaneous production of significant amounts of electricity and of high-calorific-value SNG, whose composition could be compatible with the existing natural gas network. Full article

Today, with the increases in organic fuel prices and growing legislative restrictions aimed at increasing environmental safety and reducing our carbon footprint, the task of increasing thermal power plant efficiency is becoming more and more topical. Transforming combusting fuel thermal energy into electric power more efficiently will allow the reduction of the fuel cost fraction in the cost structure and decrease harmful emissions, especially greenhouse gases, as less fuel will be consumed. There are traditional ways of improving thermal power plant energy efficiency: increasing turbine inlet temperature and utilizing exhaust heat. An alternative way to improve energy efficiency is the use of supercritical CO₂ power cycles, which have a number of advantages over traditional ones due to carbon dioxide’s thermophysical properties. In particular, the use of carbon dioxide allows increasing efficiency by reducing compression and friction losses in the wheel spaces of the turbines; in addition, it is known that CO₂ turbomachinery has smaller dimensions compared to traditional steam and gas turbines of similar capacity. Furthermore, semi-closed oxy–fuel combustion power cycles can reduce greenhouse gases emissions by many times; at the same time, they have characteristics of efficiency and specific capital costs comparable with traditional cycles. Given the high volatility of fuel prices, as well as the rising prices of carbon dioxide emission allowances, changes in efficiency, capital costs and specific greenhouse gas emissions can lead to a change in the cost of electricity generation. In this paper, key closed and semi-closed supercritical CO₂ combustion power cycles and their promising modifications are considered from the point of view of energy, economic and environmental efficiency; the cycles that are optimal in terms of technical and economic characteristics are identified among those considered. Full article

To reduce carbon dioxide emissions into the environment, the energy sector develops oxygen-fuel energy cycles. One of the most promising cycles is the Allam cycle that features the highest efficiency of electricity generation among all others. One of the main elements of an oxy-fuel energy cycle is a high-temperature carbon dioxide turbine. The turbine’s working fluid and coolant consist predominantly of carbon dioxide at a supercritical pressure. Currently, there are no recommendations in the literature for the design of carbon dioxide turbines for an oxy-fuel energy system (OFES) operating according to the Allam cycle; therefore, there is a need to study the influence of parameters of the flow path of carbon dioxide turbines on its efficiency and overall performance. In this paper, we have presented the results of one-dimensional calculations of a flow path of the carbon dioxide turbine for the Allam cycle with a capacity of 300 MW, with an initial temperature and pressure of 1100 °C and 30 MPa, and an outlet pressure of 3 MPa. The study was carried out by varying the rotor speed, the reactivity level and the average diameter. Based on the results of one-dimensional calculations, we have found that the highest efficiency of the turbine flow path is achieved at a speed of 471 rad/s, a reactivity of 0.5, and an average diameter of 1.1 m for the first stage. Full article

This paper is devoted to improvement of environmental safety in hydrocarbon-firing TPPs. Despite the development of renewable power sources, the number of traditional power production facilities continues its growth. The toxic emission mitigation in traditional TPPs has been deeply investigated, but the problem of greenhouse gas atmospheric emissions is of topical interest. Oxy-fuel technology reduces CO₂ emissions and is highly efficient and environmentally safe. Also, it requires relatively low capital investments. Thermal efficiency analysis shows that the Allam cycle facilities have the best efficiency. Their thermodynamic parameters can be optimized with minimal primary costs and capital investments. This newly developed analysis was used to compare the investment efficiency of projects for the buildup of oxy-fuel and combined cycle facilities. Without emission quote payments, the NPV of combined cycle projects is 16% higher, as well as having a lower DPP. The electricity production primary costs in oxy-fuel and combined cycle facilities are similar, which reflects the technologies’ similarity and similar fuel costs. Implementation of carbon dioxide emission quote marketing makes oxy-fuel facilities more investment-attractive. Parametric studies show that when Russia implements CO₂ emission quotes compatible with the current EU level, an oxy-fuel facility erection project will be financially reasonable. Thus, it can be concluded that the construction of oxy-fuel power plants is one of the most promising and investment-attractive solutions to reduce CO2 emissions in the energy sector for large industrialized countries. The managerial consequences of their implementation will include the stabilization of greenhouse gas emissions while ensuring the financial stability of the energy industry. Full article

The world community is worried about the effects of global warming. A few agreements on the reduction of CO₂ emissions have been signed recently. A large part of these emissions is produced by the power production industry. Soon, the requirements for thermal power plant ecology and efficiency performance may become significantly higher. Thus, the contemporary problem is the development of highly efficient power production facilities with low toxic and greenhouse gas emission. An efficient way to reduce CO₂ emissions into the atmosphere, which implies maintaining economic growth, is the creation of closed thermodynamic cycles with oxy-fuel combustion. The Allam cycle is one of the most promising among oxy-fuel power plants. A 50 MW pilot Allam cycle plant was built in Texas. The design for a commercial system with an electrical output of 300 MW is under development. This work is devoted to the improvement of the efficiency and environmental safety of oxy-fuel combustion power cycles via the utilization of compressed working fluid heat. The results of computer simulation obtained using AspenONE software demonstrated that an additional circuit in the multi-flow regenerator might increase net efficiency by 3.5%. Besides this, the incorporation of a supercritical carbon dioxide (S–CO₂) Brayton cycle with recompression increased the efficiency by 0.2%. Therefore, the maximum net efficiency of the prospective power unit was 51.4%. Full article

The transition to oxy-fuel combustion power cycles is a prospective way to decrease carbon dioxide emissions into the atmosphere from the energy sector. To identify which technology has the highest efficiency and the lowest emission level, a thermodynamic analysis of the semiclosed oxy-fuel combustion combined cycle (SCOC-CC), the E-MATIANT cycle, and the Allam cycle was carried out. The modeling methodology has been described in detail, including the approaches to defining the working fluid properties, the mathematical models of the air separation unit, and the cooled gas turbine cycles’ calculation algorithms. The gas turbine inlet parameters were optimized using the developed modeling methodology for the three oxy-fuel combustion power cycles with CO₂ recirculation in the inlet temperature at a range of 1000 to 1700 °C. The effect of the coolant flow precooling was evaluated. It was found that a decrease in the coolant temperature could lead to an increase of the net efficiency up to 3.2% for the SCOC-CC cycle and up to 0.8% for the E-MATIANT cycle. The final comparison showed that the Allam cycle’s net efficiency is 5.6% higher compared to the SCOC-CC cycle, and 11.5% higher compared with the E-MATIANT cycle. Full article

Unless humanity achieves United Nations Sustainable Development Goals (SDGs) by 2030 and restores the relatively stable climate of pre-industrial CO₂ levels (as early as 2140), species extinctions, starvation, drought/floods, and violence will exacerbate mass migrations. This paper presents conceptual designs and techno-economic analyses to calculate sustainable limits for growing high-protein seafood and macroalgae-for-biofuel. We review the availability of wet solid waste and outline the mass balance of carbon and plant nutrients passing through a hydrothermal liquefaction process. The paper reviews the availability of dry solid waste and dry biomass for bioenergy with CO₂ capture and storage (BECCS) while generating Allam Cycle electricity. Sufficient wet-waste biomass supports quickly building hydrothermal liquefaction facilities. Macroalgae-for-biofuel technology can be developed and straightforwardly implemented on SDG-achieving high protein seafood infrastructure. The analyses indicate a potential for (1) 0.5 billion tonnes/yr of seafood; (2) 20 million barrels/day of biofuel from solid waste; (3) more biocrude oil from macroalgae than current fossil oil; and (4) sequestration of 28 to 38 billion tonnes/yr of bio-CO₂. Carbon dioxide removal (CDR) costs are between 25–33% of those for BECCS with pre-2019 technology or the projected cost of air-capture CDR. Full article

This paper provides an assessment of the expected Levelised Cost of Electricity enabled by Concentrated Solar Power plants based on Supercritical Carbon Dioxide (sCO ${}_2$ ) technology. A global approach is presented, relying on previous results by the authors in order to ascertain whether these innovative power cycles have the potential to achieve the very low costs of electricity reported in the literature. From a previous thermodynamic analysis of sCO ${}_2$ cycles, three layouts are shortlisted and their installation costs are compared prior to assessing the corresponding cost of electricity. Amongst them, the Transcritical layout is then discarded due to the virtually impossible implementation in locations with high ambient temperature. The remaining layouts, Allam and Partial Cooling are then modelled and their Levelised Cost of Electricity is calculated for a number of cases and two different locations in North America. Each case is characterised by a different dispatch control scheme and set of financial assumptions. A Concentrated Solar Power plant based on steam turbine technology is also added to the assessment for the sake of comparison. The analysis yields electricity costs varying in the range from 8 to over 11 ¢/kWh, which is near but definitely not below the 6 ¢/kWh target set forth by different administrations. Nevertheless, in spite of the results, a review of the conservative assumptions adopted in the analysis suggests that attaining costs substantially lower than this is very likely. In other words, the results presented in this paper can be taken as an upper limit of the economic performance attainable by Supercritical Carbon Dioxide in Concentrated Solar Power applications. Full article