Search Results (17)

The timing of uranium mineralization in the Xiangshan ore field has long been controversial. Although various geochronometers have been applied by previous researchers, including pyrite Rb-Sr, mica Ar-Ar, and fluorite Sm-Nd, the results remain inconsistent and inconclusive. In recent years, the discovery of abundant Pb-Zn veins in the deeper parts of the Xiangshan ore field has further complicated the interpretation of its metallogenic history. In this study, abundant vein-type hydrothermal apatites closely associated with U-Pb-Zn polymetallic mineralization were identified in both uranium and Pb-Zn ore veins. Combined major-element Electron Probe Microprobe Analysis (EPMA), Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) U-Pb dating, and trace-element analysis were conducted on these apatite grains. The results suggest a mineralization age of 130.9 ± 1.1 Ma for the Shannan uranium deposit, which is consistent with the previously reported apatite U-Pb age of 131.3 ± 7.2 Ma from the Zoujiashan uranium deposit and coincides with the main pulse of volcanic-intrusive activity in the Xiangshan ore field (133–137 Ma). The deep Niutoushan Pb-Zn deposit suggests a younger mineralization age of 124.5 ± 1.3 Ma, which is consistent with a thermal event age of 125.6 Ma determined by zircon fission-track dating and the zircon LA-ICP-MS U-Pb age of late-stage granite porphyry (125.4 ± 1.0 Ma). These ages may constrain the timing of U-Pb-Zn polymetallic mineralization in the Xiangshan ore field. Both magmatic and hydrothermal apatites are classified as fluorapatite and exhibit similar chondrite-normalized rare earth element (REE) patterns. Compared with magmatic apatites, hydrothermal apatites are characterized by elevated Th, U, Ca, and Sr contents, depletion in light rare earth elements (LREEs), Mn, and Na, and distinctly lower Th/U ratios. On major-element variation diagrams, magmatic and hydrothermal apatites define coherent trends but display clear compositional differences related to their formation stages. Apatites from uranium ore veins show strongly negative Eu anomalies and weakly positive Ce anomalies, similar to magmatic apatites. In contrast, apatites from Pb-Zn ore veins display positive Eu anomalies and weakly negative Ce anomalies, with lower Mn and Ga contents and higher SO₃ contents relative to both magmatic apatites and hydrothermal apatites from uranium ore veins. These features indicate that the ore-forming fluids during Pb-Zn mineralization were characterized by significantly higher oxygen fugacity than those during uranium mineralization and magmatism. Combined with published Sr isotopic data for the Xiangshan ore field, we propose that both uranium and Pb-Zn mineralization were genetically linked to the prolonged magmatic evolution of the deep volcanic-intrusive complex. The subsequent incursion of meteoric water modified the physicochemical conditions of the ore-forming system, particularly during the formation of the Pb-Zn mineralization. Full article

Interpretation of ⁴⁰Ar/³⁹Ar dates of alkali feldspar and U-Pb dates of apatite depends on the dominant mechanism of isotopic transport in these minerals, which can be either diffusion or fluid-assisted dissolution-reprecipitation. To clarify the contributions of these processes, we have conducted a holistic study of alkali feldspar, apatite and other minerals from the Mt. Isa Inlier in NE Australia. Mineral characterisation by electron microscopy, optical cathodoluminescence imaging and element mapping reveal a complex interplay of textures resulting from magmatic crystallisation, deuteric recrystallisation, local deformation with subsequent higher-temperature alteration, and finally ubiquitous low-temperature alteration. U-Pb and Pb isotopic data for zircon, apatite, fluorite and alkali feldspar suggest that the latter event occurred at ~300 Ma and was associated with fluid-assisted exchange of Pb isotopes between minerals in the same rock, causing some apatite grains to have ²⁰⁷Pb-corrected U-Pb dates that exceed their crystallisation age. However, this event had no unequivocal effect on the ⁴⁰Ar/³⁹Ar or Rb-Sr systematics of the alkali feldspar, which were disturbed by higher-temperature alteration at ~1450 Ma. The age of the latter event is derived from Rb-Sr data. ⁴⁰Ar/³⁹Ar dates are very scattered and suggest that ⁴⁰Ar redistribution proceeded by diffusion in the presence of traps in some places and by dissolution-reprecipitation with variable amounts of recycling in other places. Our results demonstrate the complex effects that interaction with limited amounts of fluids can have on ⁴⁰Ar/³⁹Ar dates of alkali feldspar and U-Pb dates of apatite and thereby reinforce previous critique of their suitability for thermochronological reconstructions. We further identify and discuss potential implications for noble gas geochronology of groundwaters and fission track dating of apatite. Full article

Recently, a large-scale gas reservoir was discovered in granitic buried hills of the Songnan Low Uplift in the Qiongdongnan Basin. However, the strong heterogeneity of granite reservoirs limits further exploration and evaluation. Based on observations of sixty core samples and sixty thin sections, mineral composition, zircon dating, apatite fission tracks, physical properties, image logs, outcrop surveys and seismic interpretations, the characteristics of granite weathering crust of the Songnan Low Uplift are analyzed, and its controlling factors and evolution process are evaluated. The results show that weathered granite in the study area can be divided into several zones, from top to bottom: eluvium–slope zone, sandy zone, weathered fracture zone and horizontal undercurrent vuggy zone. The reservoirs in the eluvium–slope zone are dominated by microfissures and intergranular dissolution pores and have an average porosity of 4.68% and permeability of 2.34 md; the reservoirs in the sandy zone are composed of intergranular and intragranular dissolution pores and have an average porosity of 11.46% and permeability of 4.99 md; the reservoirs in the weathered fracture zone consist of various fractures and have an average porosity of 3.91% and permeability of 2.5 md; the reservoirs in the horizontal undercurrent vuggy zone are subhorizontal fractures and vugs and have an average porosity of 2.7% and permeability of 0.23 md. The development of granite reservoirs is jointly influenced by petrology and minerals, long-term exposure in a warm humid paleoclimate, faults, diverse topographies and shallow buried depth. Based on the above, our study establishes a development model of weathering crust and suggests that only the gentle slope and platform remain strongly weathered zones. After undergoing a complex evolution process of formation–destruction/denudation–regeneration–preservation, the current weathering crust of the Songnan Low Uplift is finally established. The results of this study have important theoretical and application value for the hydrocarbon exploration of buried hills in the Qiongdongnan Basin and provide a reference example for other granite reservoirs worldwide. Full article

The Ordos Basin is rich in oil and gas resources in the Paleozoic strata. The southern part of the basin boasts a thick Paleozoic sedimentary sequence, enriched organic matter, favorable sedimentary facies, and hydrocarbon source rocks with an over-mature thermal evolution stage. However, the lack of in-depth study of the tectono-thermal evolution in the southern basin limits regional oil and gas exploration. In this study, drill core and outcrop samples were collected from the Shanbei Slope and the Weibei Uplift, respectively. These samples were subjected to apatite fission track (AFT) and (U-Th)/He dating (AHe). The results were used to reconstruct the thermal history of the southern basin, calculate exhumation rates, and analyze the tectonic evolution of the basin. The seven annealed AFT data values from the Shanbei Slope range from 21.4 to 52.8 Ma, with mean track lengths of 13.24 μm, and the twelve unannealed AFT data values from the Weibei Uplift range from 111.9 to 204.6 Ma. The seven AHe data values from the Shanbei Slope range from 17.0 to 31.8 Ma, and the eight AHe data values from the Weibei Uplift range from 31.7 to 47.5 Ma. The thermal history is characterized by a prolonged phase of burial and heating from the Triassic to the Late Early Cretaceous, followed by a phase of uplift and cooling that continued into the Cenozoic. This cooling phase exhibits three distinct stages with varying rates of uplift and cooling. According to the dating results, the cooling timing of the southern basin was earlier than that of the central part, and the southern basin experienced higher uplift rates during the Paleogene than in other periods of the Cenozoic. This may be attributed to the far-field effects of the collision between the Indian Plate and the Eurasian Plate during the Paleogene. Full article

Patterns of Phanerozoic burial and erosion across the cratonic interior of North America can help constrain the continental hypsometric history and the potential influence of dynamic topography on continental evolution. Large areas of the Canadian Shield currently lack Phanerozoic sedimentary cover, but thermochronology data can help reconstruct the previous extent, thickness, and erosion of Phanerozoic strata that once covered the craton. Here, we report apatite (U-Th)/He (AHe) data for 15 samples of Precambrian basement rocks and 1 sample of Triassic kimberlite from a 1400 km–long east–west transect across the southern Canadian Shield. Single-grain basement AHe dates range from >500 Ma in the west to <250 Ma in the east. AHe dates for the kimberlite in the middle of the transect overlap with the pipe’s Triassic eruption age. These data, combined with previous apatite fission-track data, geologic constraints, and thermal history modeling, are used to constrain the first-order regional thermal history that we interpret in the context of continental burial and erosion. Our burial and erosion model is characterized by Paleozoic burial that was greater to the east, unroofing that migrated eastward through Jurassic time, and little to no post-Triassic burial. This pattern suggests dynamic and tectonic forces related to Appalachian convergence, subduction cessation, and later rifting as drivers. The AHe data contribute to efforts to collect thermochronology data across the Canadian Shield to map out continental-scale burial and erosion patterns. The outcomes can be used to refine mantle dynamic models and test how dynamic topography, far-field tectonics, and other effects influence the surface histories of continental interiors. Full article

The Qinling Shan is located between the North China Craton and the South China Block. Not only is investigating the exhumation process of the Qinling Shan beneficial for comprehending the tectonic collision history of mainland China but also for enhancing our understanding of the development of the Yellow and Yangtze Rivers. Previous studies have predominantly focused on bedrock analysis in the Qinling Shan. However, modern fluvial detrital samples offer a more extensive range of thermal history information. Therefore, we gathered modern fluvial debris samples from the Hanjiang River, which is the largest river in the South Qinling Shan. Subsequently, we conducted apatite fission-track analysis using the laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) method. A total of 214 valid track ages were obtained, with an age distribution ranging from 9.5 to 334.0 Ma. The Density Plotter software was employed to decompose the data and generate four prominent age peaks: 185, 103, 69, 35, and 12 Ma. The exhumation events of the Early Jurassic (185 Ma) and Cretaceous (103–69 Ma) in the Southern Qinling Shan were strongly influenced by the collision between the South China Block and the North China Craton, as well as the subduction of the West Pacific Plate, respectively. The far-field effect of the collision between the Indian Plate and the southern Asian continent influenced the exhumation of the South Qinling Shan during the Late Eocene (35 Ma) and Middle Miocene (12 Ma), respectively. In conjunction with the reported findings, we comprehensively analyzed the geological implications of the Mesozoic and Cenozoic exhumations of the Qinling Shan. The Qinling Shan emerged as a watershed between the Ordos and Sichuan Basins in the early Mesozoic and Cenozoic, respectively. However, the exhumation and expansion of the Tibetan Plateau has forced the Yangtze River to flow eastward, resulting in its encounter with the South Qinling Shan in the late Cenozoic. The exhumation of the Qinling Shan has resulted in fault depression in the southern Ordos Basin. This geological process has also contributed to the widespread arid climatic conditions in the basin. During the Miocene, the Yellow River experienced limited connectivity due to a combination of structural and climatic factors. As a result, the Qinling Shan served as an obstacle, dividing the connected southern Yangtze River from the northern segment of the Yellow River during the late Cenozoic era. Full article

The closure timing of the Paleo-Asian Ocean and the terminal stage of the Central Asian Orogenic Belt have been widely debated in the geological community. It’s known that the gradual scissor-like closure of the Paleo-Asian Ocean occurred from west to east during the Paleozoic period. However, it was not until the Triassic period that the complete closure of the ocean occurred at the northeastern margin of the North China Craton. Nevertheless, there is still much uncertainty regarding the Late Triassic tectonic setting in Northeast China. In this study, we focused on the Upper Triassic Dajianggang Formation, located in the Shuangyang area of central Jilin Province, which is situated on the northeastern margin of the North China Plate. Our aim was to determine the formation age of the Dajianggang Formation by analyzing the detrital particle composition, petrogeochemistry, detrital zircon U-Pb isotope dating, and apatite fission track thermochronology. Our results indicated that the primary sandstone provenance area of the Dajianggang Formation in the Shuangyang area is the island arc orogenic belt. The tectonic background of the sandstone provenance area is mainly a continental island arc environment. The provenance area is mostly composed of felsic rocks with sedimentary tendencies, and some of its material may have originated from the northern margin of the North China Craton or the eroded recycle orogenic belt. LA-ICP-MS U-Pb dating of detrital zircons shows that the Dajianggang Formation formed after 226.8 ± 5 Ma. Moreover, analysis of the thermal evolution history modelling shows that the Dajianggang Formation in the Shuangyang area continued to be deposited and heated in the early stage, and then experienced rapid exhumation around 30 Ma. This suggests that the study area underwent an orogenic process during the early stage of formation, but then transitioned into a post-orogenic extension period, which constrained the final closure of the Paleo-Asian Ocean prior to the Late Triassic period. In addition, our study indicates that the remote effect of the Pacific subduction did not reach the study area until 30 Ma. The central age of the detrital apatite fission track of sample 19DJ-1 is 94.2 ± 8.3 Ma, which is younger than its corresponding stratigraphic age. The two peak ages of the fission track analysis are 62.9 ± 5.4 Ma and 126 ± 11 Ma. These findings provide new evidence for the tectonic evolution of Northeast China and shed light on the Late Triassic tectonic setting, as well as the influence time of subsequent tectonic domains in the southern part of Northeast China. Full article

Thermal history modeling based on low-temperature thermochronological data is widely used in the study of geology. Despite its common applications, several problems remain easy to ignore yet should not be overlooked in the execution of such models. This paper describes four key problems of thermal history modeling, namely, (1) is the best-fit thermal history the best? (2) Is the date constraint box a suitable constraint? (3) Does the bimodal distribution of the apatite fission track confined track length absolutely correspond to the cooling reheating model? (4) Is the whole thermal history path credible? Counterexamples are then provided to stress the importance of accounting for these problems in the application of thermal history modeling. Acknowledging the uncertainty and considering the geological constraints are recommended to improve the accuracy of thermal history models. Moreover, thermal historical intervals with high credibility and strong constraint ability are recommended to interpret the selected geological phenomenon. Full article

The emergence of the Tibetan Plateau is one of the most significant geological events in East Asia. The Central Qilian Shan connects North and South Qilian Shan in the northeastern part of the Tibetan Plateau. However, the exhumation history of the Central Qilian Block from the Mesozoic to Cenozoic remains unclear. Determining the cooling ages of detrital zircon and apatite in modern river sediments is an ideal method for tracing the evolutionary processes of orogenic belts. In this study, we present the first single-grain detrital apatite (153) and zircon fission-track (108) data for the Huangshui River sediments from the Central Qilian Shan. The decomposition of the dataset revealed major Mesozoic and Cenozoic age peaks at ca. 145–93, and 11 Ma. The Central Qilian Shan entered the intracontinental orogeny stage dating back to the Cretaceous (ca. 145–93 Ma) and Late Cenozoic (ca. 11 Ma) caused by the subduction of the Neo-Tethys and Indian–Asian collision. Therefore, we propose that the geomorphic framework of the northeastern margin of the Tibetan Plateau was initially established during the Mesozoic and further consolidated in the Late Miocene. Full article

The timing of fault activity is a concern for geologists. This study used zircon U-Pb and apatite fission-track dating of fault breccia to determine the upper and lower limits for the time of faulting. The Guangsan fault in South China was taken as an example, and zircon U-Pb and apatite fission-track thermochronology were applied to the surrounding rock and fault breccia. The surrounding rock and fault breccia demonstrated 74.9–91.8 Ma and 73.9–93.5 Ma zircon U-Pb dates, respectively, indicating that the breccia formed after 73.9 Ma. They also demonstrated 71.6 ± 7.3 Ma and 85.9 ± 8.2–65.5 ± 6.5 Ma fission-track dates, implying that the fault breccia samples likely formed before ~70 Ma. Their thermal histories were highly consistent: both showed rapid cooling during 70–65 Ma and slow cooling during 65–0 Ma, implying that the fault was likely still active during 70–65 Ma, resulting in the rapid exhumation. Full article

Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) is classically used in U-Pb dating to measure U and Pb isotopic concentrations. Recently, it has become frequently used in fission-track (FT) chronometry too. As an advantage, the U-Pb and FT double dating will enable efficiently determining the crystallization ages and the thermo-tectonic history concurrently as samples volume, analytical time, efforts, and cost will be greatly reduced. To demonstrate the validity of this approach, a Younger granite (Ediacaran age) sample from North Eastern Desert (NED), Egypt was analyzed for U-Pb and FT double dating. The integration of multiple geochronologic data yielded a zircon U-Pb crystallization age of 599 ± 30 Ma, after emplacement, the rock cooled /uplifted rapidly to depths of 9–14 km as response to the post-Pan African Orogeny erosional event as indicated by apatite U-Pb age of 474 ± 9 Ma. Afterwards, the area experienced a slow cooling/exhumation for a short period, most-likely as response to denudation effect. During the Devonian, the area was rapidly exhumed to reach depths of 1.5–3 km as response to the Hercynian tectonic event, as indicated by a zircon FT age of 347 ± 16 Ma. Then the studied sample has experienced a relatively long period of thermal stability between the Carboniferous and the Eocene. During the Oligocene-Miocene, the Gulf of Suez opening event affected the area by crustal uplift to its current elevation. This integration of Orogenic and thermo-tectonic information reveals the validity, efficiency, and importance of double dating of U-Pb and FT techniques using LA-ICP-MS methodology. Full article

The West Siberian Basin (WSB) is one of the largest intracratonic Meso-Cenozoic basins in the world. Its evolution has been studied over the recent decades; however, some fundamental questions regarding the tectonic evolution of the WSB remain unresolved or unconfirmed by analytical data. A complete understanding of the evolution of the WSB during the Mesozoic and Cenozoic eras requires insights into the cooling history of the basement rocks as determined by low-temperature thermochronometry. We presented an apatite fission track (AFT) thermochronology study on the exposed parts of the WSB basement in order to distinguish tectonic activation episodes in an absolute timeframe. AFT dating of thirteen basement samples mainly yielded Cretaceous cooling ages and mean track lengths varied between 12.8 and 14.5 μm. Thermal history modeling based on the AFT data demonstrates several Mesozoic and Cenozoic intracontinental tectonic reactivation episodes affected the WSB basement. We interpreted the episodes of tectonic activity accompanied by the WSB basement exhumation as a far-field effect from tectonic processes acting on the southern and eastern boundaries of Eurasia during the Mesozoic–Cenozoic eras. Full article

The Intra-Sudetic Basin, a Late-Paleozoic intramontane trough located on the NE flank of the Bohemian Massif, is comprised of numerous outcrops of continental (extension-related) Early-Permian volcanogenic rocks that are commonly altered to spilites. In this contribution, we provide insights into the formation of spilitized (albite- and chlorite-rich) trachyandesites from the Głuszyca quarry (Lower Silesia, Poland), based on mineralogical and micro-textural investigations supported by apatite fission-track dating (AFT). Our results indicate that the trachyandesites, emplaced as a shallow-level laccolith-type body, have been strongly affected by chloritization of both aegirine and augite, combined with an occasional celadonitization of volcanic glass. Furthermore, chlortitization of sodic pyroxenes must have released notable amounts of Na⁺, which could be involved during later pervasive albitzation of primary andesine-labradorite. According to various chemical and semi-empirical thermometers, the replacive chlorites formed in the range of 124–170 °C. Trachyandesites from Głuszyca contain abundant fluorapatites, marked by the occurrence of swallow-type terminations, which are indicative of rapid-cooling formation conditions. Central AFT ages of the samples vary between 161–182 Ma and correspond to the Middle-Jurassic period. Meanwhile, these ages are significantly younger than the emplacement of igneous rocks during the Middle-Rotliegendes period (~299–271 Ma). The discrepancy between the stratigraphic age of the rocks and the AFT results cannot be, however, explained by, for example, slow cooling rates of magmatic body, compositional variations of apatite, or burial under Late-Mesozoic sediments. Hence, it may be assumed that the obtained AFT ages (161–182 Ma) reflect the timing of spilitization and associated partial reheating of volcanic rocks from the Intra-Sudetic Basin above the apatite partial annealing zone (70–110 °C). Full article

This work presents new apatite fission track LA–ICP–MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) data from Mid–Late Paleozoic rocks, which form the substratum of the Swiss Jura mountains (the Tabular Jura and the Jura fold-and-thrust belt) and the northern margin of the Swiss Molasse Basin. Samples were collected from cores of deep boreholes drilled in North Switzerland in the 1980s, which reached the crystalline basement. Our thermochronological data show that the region experienced a multi-cycle history of heating and cooling that we ascribe to burial and exhumation, respectively. Sedimentation in the Swiss Jura Mountains occurred continuously from Early Triassic to Early Cretaceous, leading to the deposition of maximum 2 km of sediments. Subsequently, less than 1 km of Lower Cretaceous and Upper Jurassic sediments were slowly eroded during the Late Cretaceous, plausibly as a consequence of the northward migration of the forebulge of the neo-forming North Alpine Foreland Basin. Following this event, the whole region remained relatively stable throughout the Paleogene. Our data show that the Tabular Jura region resumed exhumation at low rates in early–middle Miocene times (≈20–15 Ma), whereas exhumation in the Jura fold-and-thrust belt probably re-started later, in the late Miocene (≈10–5 Ma). Erosional exhumation likely continues to the present day. Despite sampling limitations, our thermochronological data record discrete periods of slow cooling (rates of about 1°C/My), which might preclude models of elevated cooling (due to intense erosion) in the Jura Mountains during the Miocene. The denudation (≈1 km) of the Tabular Jura region and the Jura fold-and-thrust belt (≈500 m) has provided sediments to the Swiss Molasse Basin since at least 20 Ma. The southward migration of deformation in the Jura mountains suggests that the molasse basin started to uplift and exhume only after 5 Ma, as suggested also by previous authors. The data presented here show that the deformation of the whole region is occurring in an out-of-sequence trend, which is more likely associated with the reactivation of thrust faults beneath the foreland basin. This deformation trend suggests that tectonics is the most determinant factor controlling denudation and exhumation of the region, whereas the recently proposed “climate-induced exhumation” mechanism might play a secondary role. Full article