Search Results (53)

There is a growing trend to promote circular economy practices and reduce petroleum-derived product consumption in the paving sector. In this context, a liquid lignin-rich industrial waste was incorporated at 0% (control), 5%, 10%, 15%, and 20% into a bitumen emulsion to manufacture a lignin-based biobinder for half-warm-mix asphalt (HWMA). The mix of the bitumen emulsion and the industrial waste was made using an Ultra-turrax device, with the final mixing temperature monitored using a thermographic camera. Microstructure analysis was conducted using scanning electron microscopy (SEM). The bitumen was extracted and characterized using needle penetration tests at several temperatures. Additionally, the ring-and-ball softening point, penetration index, and ductility were assessed. Incorporating up to 5% of lignin-rich industrial waste led to a lignin-based biobinder that could be used for a more sustainable and bitumen-efficient HWMA production. Full article

This research focuses on a mineral–cement mixture containing bitumen emulsion, designed for cold recycling procedures, the formulation of which includes 80% (m/m) of waste material. Deep cold recycling technology from the MCE mixture guarantees the implementation of a sustainable development policy in the field of road construction. The utilised waste materials include 50% (m/m) reclaimed asphalt pavement (RAP) from damaged asphalt layers and 30% (m/m) recycled aggregate (RA) sourced from the substructure. In order to assess the possibility of using a significant amount of waste materials in the composition of the mineral–cement–emulsion (MCE) mixture, it is necessary to optimise the MCE mix. Optimisation was carried out with respect to the quantity and type of binding agents, such as Portland cement (CEM), bitumen emulsion (EMU), and redispersible polymer powder (RPP). The examination of the impact of the binding agents on the physico-mechanical characteristics of the MCE blend was performed using a Box–Behnken trivalent fractional design. This method has not been used before to optimise MCE mixture composition. This is a novelty in predicting MCE mixture properties. Examinations of the physical properties, mechanical properties, resistance to the effects of climatic factors, and stiffness modulus were conducted on Marshall samples prepared in laboratory settings. Mathematical models determining the variability of the attributes under analysis in correlation with the quantity of the binding agents were determined for the properties under investigation. The MCE mixture composition was optimised through the acquired mathematical models describing the physico-mechanical characteristics, resistance to climatic factors, and rigidity modulus. The optimisation was carried out through the generalised utility function U^III. The optimisation resulted in indicating the proportional percentages of the binders, enabling the assurance of the required properties of the cold recycled mix while utilising the maximum quantity of waste materials. Full article

This review discusses recent research findings spanning the last two decades concerning ultrasonic technologies applicable to the oil, gas, and coal sectors. Various experiments conducted in laboratories have demonstrated the efficacy, cost-effectiveness, and environmental friendliness of ultrasound in recovering and processing oil, bitumen, coal, and oil shale. Ultrasound enhances formation permeability, coal gas permeability, and oil viscosity, particularly when delivered in short, powerful pulses at medium frequencies. Combining ultrasound with traditional recovery methods has shown promising results, boosting recovery efficiency by up to 100%. At the same time, ultrasonic treatment reduces the use of traditional reagents, thereby reducing environmental pollution. Moreover, ultrasound treatment shows potential in tasks such as separating oil–water emulsions, desulfurization, dewaxing oil, coal enrichment, and extracting valuable metals from metal-bearing shales through hydrometallurgical leaching. However, the widespread industrial implementation of ultrasonic technology necessitates further field and mathematical research. Full article

In spite of the demonstrated efficacy of basalt stone powder as a cost-effective and readily available additive in enhancing the mechanical properties and durability of ordinary-weight concrete, its application in Structural Lightweight Concrete (SLWC) remains unexplored. This study introduced a mixing design for SLWC incorporating Light Expanded Clay Aggregates (LECAs) and basalt stone powder with a subsequent evaluation of its strength and durability characteristics. The experimental procedure involved creating various samples, considering differing proportions of cement, water, basalt stone powder, sand, LECA, superplasticizer, and aerating agent. The compressive strength and density of the 28-day-cured concrete specimens were determined. An optimal SLWC with a compressive strength of 42 MPa and a density of 1715 kg/m³ was identified. The flexural and tensile strength of the optimal SLWC exceeded those of ordinary-weight concrete by 6% and 3%, respectively. Further evaluation revealed that the optimal SLWC exhibited 1.46% water absorption and an electrical resistivity of 139.8 Ohm.m. Notably, the high porosity of LECA contributed to the low durability of SLWC. To address this, cost-effective external coatings of emulsion and fiberglass were applied to enhance the durability of the SLWC. Four coating scenarios, including one-layer bitumen, two-layer bitumen, three-layer bitumen, and three-layer bitumen with fiberglass, were investigated. The measurements of electrical resistance and compressive strength revealed that the use of three layers of emulsion bitumen and fiberglass improved the durability of the concrete by over 90% when the SLWC was exposed to severe chloride attack. Consequently, the durability of the SLWC with an external coating surpassed that of ordinary-weight concrete. Full article

Double bituminous surface treatment (DBST) has been a widely utilized pavement maintenance material due to its capability to restore the surface roughness of existing pavement and provide a layer of protection against weathering, aging, and moisture. However, DBST is highly prone to aggregate loss at an early stage, which is a very common problem experienced by surface treatment. Therefore, to lessen the aggregate loss and prolong the service life of DBST, fiber additive can be incorporated to strengthen the adhesion between the asphalt emulsion and aggregates. This study investigated the performance of glass fiber-reinforced polymer-modified DBST against aggregate loss by conducting laboratory tests using typical DBST as the benchmark of the test results. Four laboratory tests were chosen to represent different loading applications on the surface of the pavement: the bitumen bond strength (BBS) test, the sweep test, the Hamburg wheel-track test (HWT test), and a one-third-scale model mobile load simulator (MMLS3) model. Furthermore, the curing time of the asphalt emulsion was considered in the BBS test and sweep test. Based on all results from the conducted laboratory tests, polymer-modified DBST with glass fiber reinforcement presented an increased resistance to aggregate loss compared with typical DBST. Moreover, it was found that a longer curing time of the asphalt emulsion, whether it was typical or modified, strengthened the surface treatment’s resistance to aggregate loss. Full article

Enhanced oil recovery (EOR) processes are technologies used in the oil and gas industry to maximize the extraction of residual oil from reservoirs after primary and secondary recovery methods have been carried out. The injection into the reservoir of surface-active substances capable of reducing the surface tension between oil and the rock surface should favor its extraction with significant economic repercussions. However, the most commonly used surfactants in EOR are derived from petroleum, and their use can have negative environmental impacts, such as toxicity and persistence in the environment. Biosurfactants on the other hand, are derived from renewable resources and are biodegradable, making them potentially more sustainable and environmentally friendly. The present review intends to offer an updated overview of the most significant results available in scientific literature on the potential application of biosurfactants in the context of EOR processes. Aspects such as production strategies, techniques for characterizing the mechanisms of action and the pros and cons of the application of biosurfactants as a principal method for EOR will be illustrated and discussed in detail. Optimized concepts such as the HLD in biosurfactant choice and design for EOR are also discussed. The scientific findings that are illustrated and reviewed in this paper show why general emphasis needs to be placed on the development and adoption of biosurfactants in EOR as a substantial contribution to a more sustainable and environmentally friendly oil and gas industry. Full article

To better reveal the performance development of bitumen emulsion-based cold in-place recycling (BE-CIR) mixture over curing, a semi-sealed laboratory curing method was proposed in this research to simulate the in situ moisture evaporation process and cracking resistance of the BE-CIR specimen at different depths during a curing time of 28 days, which was also investigated by the semi-circular bending (SCB) test. The influencing factors of cement content (1.5% to 2.5%), initial moisture content (3.5% to 4.5%), curing temperature (25 °C to 45 °C) and relative humidity were investigated, and the significance of different factors affecting the performance development was also analyzed. The results indicate significant variations in cracking performance parameters at different depths, with the top part exhibiting notably higher tensile strength and fracture energy compared to the bottom part, and a gradient index (GI) is proposed to describe the difference. Cement content affected early tensile strength and fracture energy, while the initial moisture content affected the development rate of the performance. The influence of curing temperature was extensive, and as the temperature increased beyond 40 °C, the strength of the effect decreased. High humidity during the early stage of curing inhibited the strength formation and development of fracture energy. The performance development of the BE-CIR mixture is more significantly influenced by the moisture migration process, which is governed by curing temperature and relative humidity, as opposed to the cement content and initial moisture content. Full article

The choice of a substance as a healing agent for asphalt concrete is determined by the scientific experience of researchers and the results of exploratory studies. There are no standard approaches for selecting healing agents or assessing their compatibility with the matrix components in asphalt concrete. However, such methods would make it possible to systematize research in the field of self-healing asphalt concrete and significantly expand the list of healing agents potentially suitable for encapsulation and ensuring the formation of a healing effect. An approach has been proposed for studying a substance and assessing the suitability of its use as a healing agent during encapsulation, using alginate technology in terms of solubility, homogeneity in a system with bitumen, and adhesive strength. This set of indicators can be used in the development and design of self-healing asphalt concrete, as well as for expanding the list of healing agents that can be used to implement self-healing technology. This article discusses sunflower oil and AR polymers as healing agents for self-healing asphalt concretes. The substances under consideration are capable of forming a homogeneous system ∆δ → 0 with bitumen, and the double systems “SfO-bitumen” and “ARP-bitumen” have a Gibbs energy value ∆G < 0, which confirms this. The studied healing agents are able to form an emulsion in alginate aqueous solutions, which was confirmed by the structuring effect and the extreme influence of their concentration on viscosity. The strength of the adhesive bonds under the influence of SfO was 14.2% of the initial value of the tensile strength during splitting. Under the influence of ARP, the strength of the adhesive bonds was 5.8% of the initial value of the tensile strength at splitting. The use of an activator in asphalt concrete makes it possible to increase the strength of the adhesive bonds to 25–45% of the initial splitting strength. Full article

Due to the decreasing availability of virgin materials coupled with an increased awareness of environmental sustainability issues, many researchers have focused their efforts on investigating innovative technological solutions in the civil engineering domain. This paper aims to evaluate the suitability of construction and demolition waste (C and DW) and reclaimed asphalt pavement (RAP) reused within asphalt mixtures (AMs) prepared for the binder layer of road pavements. Both hot and cold mixing methodologies were investigated. The technical assessment was based on the volumetric and mechanical suitability, according to saturated surface dry voids (SSDV) and indirect tensile strength (ITS) tests carried out at 10 °C, respectively. Laboratory findings showed that all the hot AMs matched the desired target SSDV at the design gyrations number at different optimum bitumen content levels, alternatively showing a non-significant variation or a significant increase in ITS compared to conventional hot mix asphalt. Conversely, the cold AMs with cement and emulsion bitumen showed a greater volume of voids and moisture sensitivity, and lower temperature susceptibility compared to hot AMs, reaching, on average, 11% lower ITS when using coarse C and DW aggregates and 43% lower ITS when using filler from C and DW. These volumetric and mechanical properties were modeled by means of support vector machines and categorical boosting (CatBoost) machine learning algorithms. The results proved to be satisfactory, with CatBoost determination coefficients R² referring to SSDV and ITS equal to 0.8678 and 0.9916, respectively. This allowed for the mechanical performance of these sustainable mixtures to be predicted with high accuracy and implemented within conventional mix design procedures. Full article

In recent years, cold recycling techniques have been widely used all over the world thanks to their huge environmental advantages. However, their performances are lower than the traditional hot-mix asphalt, both for the longer time to develop the final mechanical properties, which leads to delays in the reopening to road traffic, and for the lower fatigue resistance. The present paper deals with the characterization of cold recycled asphalt mixtures (CRAM), made with 100% reclaimed asphalt pavement, where synthetic fibers were included to improve the fatigue performance. The investigation involved the analysis of the curing time, volumetric properties, stiffness, strength, rheological behavior and resistance to cyclic loading. The results showed that the use of synthetic fiber, with the optimum dosage, determined a higher CRAM performance, especially in terms of fatigue resistance. Full article

Cold mix asphalt (CMA) is emerging as an environmentally friendly alternative to traditional hot mix asphalt (HMA). It offers advantages such as lower costs, reduced energy demands, decreased environmental impacts, and improved safety aspects. Among the various types of CMA, the cold bitumen emulsion mixture (CBEM) stands out. The CBEM involves diluting bitumen through emulsification, resulting in lower bitumen viscosity. However, this process has certain drawbacks, including extended setting (curing) times, lower early strength, increased porosity, and susceptibility to moisture. This study focuses on enhancing CBEM properties through the utilization of low-energy heat techniques, such as microwave technology, and the incorporation of a polymeric additive, specifically acrylic. These innovations led to the development of a novel paving technology known as a half-warm bitumen emulsion mixture (HWBEM). The research was conducted in two phases. First, the study assessed the impact of low-energy heating on the CBEM. Subsequently, it explored the combined effects of low-energy heating and the addition of an acrylic polymer. CBEM samples containing ordinary Portland cement (OPC) as an active filler were utilized in the sample manufacturing process. The effectiveness of these techniques in enhancing crack resistance was evaluated by analysing the results of the indirect tensile strength test. Notably, CBEM samples containing an amount of 2.5% of acrylic polymer and OPC exhibited the highest resistance to cracking. Furthermore, significant improvements were observed in their volumetric and mechanical properties, comparable to those of HMA. Full article

The strength growth of a bitumen emulsion-based cold in-place recycling asphalt mixture (BE-CIR) is time-dependent and time-consuming due to the addition of water. There is a great difference between the curing conditions of specification in the laboratory and the in situ conditions, which often leads to a great discrepancy between the results of lab specimens and the field cores. The main objective of this paper is to evaluate the curing effect on laboratory BE-CIR considering field-water evaporation and heat-transfer conditions. Four different curing methods were designed by using different combinations of waterproof layers, heat insulation layers, and variable temperature modes. The variations in temperature indexes, moisture content, air void, and indirect tensile strength (ITS) with curing time were tested, and the mutual influence of these indicators was analyzed. Furthermore, the results of the laboratory samples were compared with the field cores. Testing results show that the performance of the BE-CIR mixture is significantly different from that with no treatment, which is manifested as higher moisture content and lower air void and ITS under the same curing time. The internal temperature of the mixture is the main factor affecting the variation of moisture content, especially on the first curing day. The air void of the mixture has a strong linear relationship with the moisture content. Moisture content and ITS under different curing methods showed similar trends and could be divided into two stages. Taking the field cores as a benchmark, it can be concluded that the field-water evaporation condition should be considered in the setting of indoor curing methods, while the heat transfer could not. Full article

Construction and demolition waste (CDW) materials account for a considerable part of waste materials throughout the world. As these materials are not usually recycled, reusing them in construction projects is of major significance. In this study, recycled concrete, bricks, and glass were used as 100% aggregates of chip seal, which is a corrective or preventive pavement maintenance method. A cationic rapid setting (CRS-2) bitumen emulsion was also used to prepare the chip seal. Different tests, including the sand patch test, sweep test, British pendulum tester (BPT), interface bond, and Vialit test, were conducted. The results of these tests revealed that all these materials had sufficient aggregate embedment for vehicle speeds of more than 70 km/h, and the number of chips was less than 10%, indicating their good performance. All developed chip seals ranked as high skid resistance pavement at ambient temperature. The chip seals developed with concrete and glass showed the best adhesion with an asphalt pavement surface and an aggregate–bitumen adhesion at very cold and ambient temperatures due to the fact of their chemical compositions. Overall, using concrete aggregates to develop chip seals under different traffic loads is recommended. Finally, these findings can provide a novel approach for recycling CDW materials with low costs. Full article

Scientists have effectively demonstrated that the introduction of a waste product comprising cementitious chemical compositions can enhance the mechanical properties and durability of cold bitumen emulsion mixes (CBEMs). On the other hand, the high air void content of the CBEM mix remains a challenge that is considered unsatisfactory by paving engineers. As a result, this investigation highlights two major changes that were made. The first is the use of waste paper sludge ash (PSA) as a filler in CBEM instead of the conventional mineral filler (CMF). The second change was made to further improve the mixture by reducing the amount of CBEM air voids using microwave (MW) heating energy as a post-treatment method. When compared to typical hot mix asphalt (HMA), the new CBEMs showed great mechanical properties and durability. Moreover, the proposed method, using CBEMs, has lower environmental risks, is safer, and is more cost-effective than existing paving mix technologies. This study presents a method for controlling air voids within pavement specifications without affecting mechanical behaviour or generating additional environmental or economic considerations. When compared to typical mixtures, laboratory test results showed that MW-heating can enhance both the stiffness modulus and the air void content. Furthermore, these results revealed a minor reduction in creep stiffness and water sensitivity. Nevertheless, in terms of mechanical, volumetric, and economic properties, the suggested post-mix treatment was comparable to HMA. The findings point to the need to adopt CBEM post-heating approaches, particularly the MW treatment procedure. Full article

The planning of road infrastructure undergoes major changes, especially in terms of sustainable development. Recycling of pavement structures involves the reuse of materials from existing pavement structures due to its timesaving and environmental benefits, as well as cost reduction. According to the recycling temperature, recycling can be hot and cold. This paper deals with cold in-place recycling and the determination of the optimum fluid content for by-product materials in mixtures compared with one containing natural zeolite. The content of bitumen emulsion and cement—which are the most used materials so far in cold recycling along with foam bitumen—was replaced with fly ash, slag or natural zeolite, and bakelite, respectively, while recycled asphalt pavement from Serbia (Žabalj) was used. Six different mixtures were made. The mixture with the addition of fly ash had the highest optimum fluid content (7.6%) compared with all test mixtures. Mixtures with slag, natural zeolite, and bakelite were in the range of a mixture containing 2% cement. Furthermore, the mixture with 3% cement had the lowest optimum fluid content (5.7%) in comparison to all the mixtures that were tested. Full article