Search Results (79,118)

Seasonal dynamics of dissolved organic matter (DOM) in agricultural ditches significantly impact carbon cycling and water quality in connected rivers. This study aimed to characterize seasonal variations in DOM composition and dynamics within hierarchical agricultural ditch systems in Tianjin, northern China. Surface water samples were collected from river channels, main ditches, branch ditches, lateral ditches, and field ditches during wet (June 2021) and dry (December 2021) seasons. DOM characteristics were analyzed using dissolved organic carbon (DOC) quantification, ultraviolet-visible (UV-Vis) absorption spectroscopy, and three-dimensional excitation–emission matrix spectroscopy (3D-EEMs) coupled with parallel factor analysis (PARAFAC). The concentration of DOC in ditch surface water exhibited significant seasonal variations, with significantly higher levels observed during the wet season (Huangzhuang: 6.72 ± 0.7 mg/L; Weixing: 13.15 ± 3.1 mg/L) compared to the dry season (Huangzhuang: 5.93 ± 0.3 mg/L; Weixing: 9.35 ± 2.6 mg/L). Both UV-Vis spectral and EEM-PARAFAC analysis revealed that DOM in ditch systems was predominantly composed of fulvic-like and tryptophan-like components, representing the portion of organic matter in water bodies that is highly biologically active, highly mobile, relatively “fresh”, or “not fully humified”. PARAFAC identified microbial humic-like (C1: wet season 40.36%, dry season 34.42%) and protein-like (C3: wet season 40.3%, dry season 49.87%) components as dominant. DOM sources were influenced by dual inputs from terrestrial and autochthonous origins during the wet season, while primarily deriving from autochthonous sources in the dry season. This study elucidates the advances of spectroscopic techniques in deciphering the composition, sources, and influencing factors of DOM in aquatic systems. The findings support implementing riparian buffer strips and optimized fertilizer management to mitigate seasonal peaks of bioavailable DOM in agricultural ditch systems. Full article

Increasing gender equality, United Nations Sustainable Development Goal Five (UN SDG 5), is one of many wicked problems that are difficult to solve in sport. Innovative policies may create a backdrop for improving women’s career outcomes in sport and beyond. This research aims to theorize and empirically demonstrate some of these contextual relationships. Using FIFA Women’s World Cup standings as outcomes, international analyses show that sustainability has real consequences for women and their countries’ success. Guided by wicked problems Literature explicitly recognizing complexities, this research considers the interconnectedness of the UN SDGs with a focus on sports. International empirical analyses demonstrate that leading countries’ more holistic sustainability policies help to address UN SDG 5. This study also compares sustainable development indicators in regression analyses to clarify how these composite measures relate to improved outcomes for women. Overall, future research should incorporate gender differences and thereby consider a broad set of sustainability factors. Full article

A novel approach was developed in this work in which composite nanofiltration (NF) membranes were directly and efficiently fabricated with control of the membrane pore structure and surface morphology. The fabrication of mesoporous silicon-modified polysulfone blend membranes is achieved via a phase inversion method. The structural morphology, surface functional group analysis, elemental analysis, hydrophilicity, chargeability, and nitrogen pollutant (ammonia nitrogen, nitrate nitrogen, total nitrogen) rejection properties of the modified membranes were found to be dependent on the amount of mesoporous silicon incorporated. The combination of the mesoporous silicon framework layer can not only effectively improve the surface structure of the modified membrane with a narrow pore size distribution but also increase the rejection of nitrogen pollutants compared with pure NF membranes. The mesoporous material interlayer can absorb and store the aqueous amino solution to facilitate the subsequent interfacial polymerization as well as induce changes in the pore radius and surface structure. Compared with pure NF composite membranes, the modified blend membranes exhibit increased water permeation flux as high as 29.09 L m⁻² h⁻¹ at 0.2 MPa. The results show that the optimum doping amount of mesoporous silicon is in the range of 0.5–1.0%. Characterization studies demonstrated that the addition of mesoporous silicon leads to a decreased membrane pore size. Then the retention of nitrogen pollutants was enhanced because of a combination of hydrophilicity enhancement from the carboxylic and hydroxyl functional groups present in their surfaces leading to electrostatic repulsion between functional groups present in the membranes and the nitrogen pollutant molecules. Full article

Cyanobacteria are a natural source of bioactive compounds increasingly recognized for their anti-inflammatory properties. In the Euganean Thermal District (Italy), thermal muds, used to cure arthro-rheumatic diseases, are prepared using natural clay and thermal water, resulting in a mature mud characterized by a complex microbial biofilm dominated by Cyanobacteria. Among these, Phormidium sp. ETS-05 has been shown to contribute to the therapeutic properties of the mud, mainly through the production of bioactive compounds such as exopolysaccharides (EPS) and glycoglycerolipids (GLs). In contrast, the role of biomolecules from Thermospirulina andreolii ETS-09 and Kovacikia euganea ETS-13, also abundant in mature muds but at higher maturation temperatures, has not been investigated. This study focuses on the lipid profiles of these cyanobacteria, cultivated under temperature conditions that mimic their natural environment and that are different for the three species. Lipid extracts were analyzed for GLs classes and fatty acid composition, and their anti-inflammatory potential was assessed in vivo using a zebrafish inflammation model. All extracts showed anti-inflammatory activity with Phormidium sp. ETS-05 displaying the highest lipid content and the most rapid and potent beneficial effect, likely due to the specific composition of its GLs, presenting the greatest abundance of polyunsaturated fatty acids. These findings provide new insights into the biological basis of the therapeutic effects of Euganean muds and emphasize the importance of maturation conditions for cyanobacterial growth and bioactive lipid production. Full article

Background/Objectives: This study investigates the antimicrobial properties of pomegranate peel extract (PoPEx) and its major polyphenolic constituents against Gram-positive and Gram-negative bacteria, employing six clinical isolates of Staphylococcus aureus and five isolates of Escherichia coli. The study further aims to elucidate mechanisms of action through molecular docking and transport studies. Methods: Chemical composition was analyzed using liquid chromatography–mass spectrometry (LC–MS). Antimicrobial activity was determined by the broth microdilution method. Molecular docking was performed with the AutoDock Vina algorithm, and transport studies through porin channels were carried out using Caver software. Results: PoPEx showed stronger activity against Gram-positive (MICs 15.62–500.00 μg/mL) than Gram-negative bacteria (MICs 125.00–500.00 μg/mL). Punicalagin was most active against S. aureus, while gallic acid was most effective against E. coli. Docking revealed high affinities of punicalagin and punicalin, whereas transport studies highlighted the advantage of smaller phenolics like gallic acid in crossing porins. Conclusions: Larger tannins exhibited strong target binding but limited porin permeability, reducing efficacy in Gram-negative bacteria. These findings provide insights into structure–activity relationships of pomegranate polyphenols and support their potential as natural antimicrobial agents. Full article

This study aimed to investigate the influence of different organic fertilizers and their concentrations on the growth of ‘Orah’ (Citrus reticulata Blanco) seedlings, as well as on the mineral nutrient contents, chemical and biological properties, and microbial community of the soil. Five types of organic fertilizers and three concentrations were studied. The seedling growth indexes, leaf mineral elements, soil mineral elements, soil enzyme activity, and soil microorganisms were measured. The results showed that organic fertilization significantly increased the contents of eight mineral elements in leaves, depending on the types and concentrations used. Specifically, rapeseed cake fertilizer was found to significantly increase the content of iron (Fe), manganese (Mn), and zinc (Zn) in the leaves. Furthermore, compared with applying only chemical fertilizers or no fertilizers at all, the application of organic fertilizer significantly increased the content of soil organic matter (SOM) and several mineral elements in the soil. The bacterial species composition of soil treated with common organic fertilizer and bio-organic fertilizer, and sheep manure were similar; however, the bacterial composition was significantly different in the soil which been treated with rapeseed cake compared to these other three fertilizers. Additionally, PICRUSt function predicting indicates that the core microbial community in the rapeseed cake group could promote synthesis and the transport of sugar, iron and other substances. Organic fertilizer can change soil chemical and biological properties by affecting the core microbial community structure, and further promote accumulation of mineral elements in the leaves of citrus seedlings. Full article

Urban green hearts provide essential ecosystem services, including carbon sequestration, water purification, and hydrological regulation. The Green Heart Area of the Chang-Zhu-Tan Urban Agglomeration in Hunan Province, China, is the largest globally, and plays a critical role in regional water management. These functions are increasingly threatened by intensive land-use, while soil, as the foundational ecosystem component, mediates water retention, nutrient cycling, and erosion resistance. This study examined the effects of four land-use types—cropland, plantation, arbor woodland, and other woodland—on soil particle composition and key nutrients (organic carbon, total nitrogen, and total phosphorus). Statistical comparisons among land-use types were performed. Results indicated that silt was the dominant soil fraction across all land-uses (64–72%). Arbor woodland exhibited significantly higher sand content (29%) compared to cropland (19%; p < 0.05), suggesting improved water permeability and erosion resistance. Cropland showed elevated nutrient levels, with TN (1450.32 mg·kg⁻¹) and TP (718.86 mg·kg⁻¹) exceeding both national averages and those in arbor woodland. Coupled with acidic soil conditions (pH 5.23) and lower stoichiometric ratios (C/N: 10.82; C/P: 35.67; N/P: 3.29), these traits indicate an increased risk of nutrient leaching in croplands. In contrast, arbor woodland displayed more balanced C:N:P ratios (C/N: 12.21; C/P: 48.05; N/P: 3.84), supporting greater nutrient retention and aggregate stability. These findings underscore the significant influence of land-use type on soil ecological functions, including water infiltration, runoff reduction, and climate adaptability. The study highlights the importance of adopting conservation-oriented practices such as reduced tillage and targeted phosphorus management in croplands, alongside reforestation with native species, to improve soil structure and promote long-term ecological sustainability. Full article

The consumption of edible flowers is gaining global popularity due to their culinary appeal, vibrant colors, and health-promoting compounds. Traditional production methods—including wild collection, open-field cultivation, and greenhouse systems—offer limited control over environmental factors, often resulting in inconsistent yield, quality, and safety. To address these limitations, plant factories with artificial lighting (PFALs) have emerged as a promising technology for producing high-quality edible flowers year-round in controlled environments. This review explores the evolution of edible flower cultivation, from conventional methods to PFALs, and highlights key environmental factors—light, temperature, and nutrient management—that influence growth, flowering, and phytochemical profiles. Special attention is given to how light intensity, spectrum, and photoperiod affect morphogenesis and metabolite accumulation, and how nutrient solution composition, particularly nitrogen form and EC levels, modulates flowering and plant health. While recent studies have demonstrated the potential of PFALs in cultivating species such as calendula, nasturtium, and marigold, research remains limited for many commercially relevant species. The review identifies current challenges, such as high operational costs and knowledge gaps in species-specific protocols, and outlines future research directions aimed at improving efficiency, optimizing quality, and expanding market viability. PFALs offer a transformative opportunity for the edible flower industry by integrating precision agriculture with consumer demand for safe, functional, and visually appealing food products. Full article

This study addresses the limitations of buoyancy factor and compensation capacity in pressure hulls for full-ocean-depth underwater gliders operating in extreme deep-sea conditions. A novel lightweight multifunctional composite structure pressure hull (CSPH) is proposed, utilizing a carbon fiber cylindrical shell as the primary load-bearing structure and silicone oil as the buoyancy compensation medium. A mechanical model of the carbon fiber cylindrical shell under hydrostatic pressure was developed based on three-dimensional elastic mechanics theory. Furthermore, a comprehensive performance evaluation model for the CSPH was created, incorporating both the buoyancy factor (B_f) and buoyancy fluctuation coefficient (f_B). The NSGA-II optimization algorithm was employed to simultaneously minimize B_f and f_B by co-optimizing the carbon fiber ply parameters and the silicone oil volume (V_C). This optimization resulted in a Pareto optimal solution balancing buoyancy and compensation performance. The accuracy of the mechanical model and optimization results was validated through finite element analysis and pressure testing. The results show that, compared to traditional metallic pressure hull designs, the CSPH reduces the buoyancy factor by 48% and enhances buoyancy compensation performance by 2.5 times. The developed CSPH has been successfully deployed on the “Sea-Wing 11000” full-ocean-depth underwater glider, significantly improving its endurance and motion stability for long-term deep-sea observation missions. Full article

Biomass ashes are considered to be sustainable alternatives for fly ashes from hard coal combustion for the use as supplementary cementitious material (SCM). However, their diverse composition and properties are impeding their standardized use. This study aims to gain a better understanding of how composition affects performance. It investigates three wood ashes (one bottom ash, two fly ashes), one spelt husk ash and a mineral residue from sewage sludge ash after wet-chemical phosphorus recovery for their suitability as SCM. After characterization of the materials including the determination of environmentally relevant parameters, the reactivity was tested using the R³ test and mortar compressive strength with different substitution levels. The effect on hydration was studied in blends with Portland cement using isothermal calorimetry and X-ray diffractometry (XRD). The composition of the ashes differed significantly, also between the wood ashes. The wood ashes showed no significant reactivity (cumulative R³ heat lower than 125 J/g SCM after 7 days), while the spelt husk ash and the sewage sludge ash residue showed distinct reactivity with a cumulative R³ heat of 249 and 181 J/g SCM after 7 days, respectively. Following an initial period of unaffected hydration, the wood fly ashes were found to impede clinker reactivity. In contrast, the other materials exhibited no significant influence on the hydration process, aside from the consumption of portlandite by the reactive ones. The wood fly ashes also impaired strength development in blended mortar formulations (e.g., relative compressive strengths with a cement substitution level of 20 wt% after 28 days were <0.6), whereas the reactive spelt husk ash and the mineral residue were associated with a measurable contribution to strength gain (e.g., relative compressive strengths with a cement substitution level of 20 wt% after 28 days were >0.85). The wood bottom ash was the only material investigated which perfectly sustained mortar workability and rather acts like a nearly inert addition. The results show both the potential and the limitations of using different types of ash, which cannot be generalized due to the wide variation in raw materials and combustion conditions. Full article

The crystal structure of caysichite-(Y) from the Ploskaya Mt (Kola Peninsula, Russia) has been refined to R₁ = 0.051 for 4472 unique observed reflections. The mineral is orthorhombic, Ccm2₁, a = 13.2693(3), b = 13.9455(4), c = 9.7384(2) Å, V = 1802.06(8) ų, Z = 4. There are two M sites predominantly occupied by Y, but also including Ca and other rare earth elements (REEs). Both M sites are coordinated by eight O atoms to form distorted bicapped trigonal prisms. The crystal structure is based upon a three-dimensional framework formed by columns of MO₈ polyhedra and (CO₃) groups and double-crankshaft chains of SiO₄ tetrahedra running parallel to the c-axis. The topology of linkage of MO₈ polyhedra understood in terms of the M–M links shorter than 5 Å corresponds to the M network with the paracelsian (pcl) topology. The channels in the network are occupied by double-crankshaft Si chains and H₂O groups. The new general chemical formula of a caysichite-(Y)-type mineral can be written as [Y_2+2x−y′Ca_{2−3x−y″}☐_x+y′+y″][Si₄O₁₀](HCO₃)_3y′+2y″(CO₃)_{3−3y′−2y″}·(4−z)H₂O, where z ~ 0.2; x ≤ 2/3; y′ ≤ 2/3; y″ ≤ 1; 3y′+2y″ ≤ 2. This general formula allows for several end-member formulas according to different x, y′ and y″ values: (Y₂Ca₂)[Si₄O₁₀](CO₃)₃·4H₂O (x = y′ = y″ = z = 0), (Y₂Ca☐)[Si₄O₁₀](HCO₃)₂(CO₃)·4H₂O (x = y′ = z = 0; y″ = 1), (Y_10/3☐_2/3)[Si₄O₁₀](CO₃)₃·4H₂O (y′ = y″ = z = 0; x = 2/3), Ca₂Y_4/3☐_2/3)[Si₄O₁₀](HCO₃)₂(CO₃)·4H₂O (x = y″ = z = 0; y′ = 2/3). The samples studied in this work have the compositions (REE_2.05Ca_1.87☐_0.18)[Si₄O₁₀](HCO₃)_0.11(CO₃)_2.89·3.8H₂O (x = 0.025, y′ = 0, y″ = 0.055) and (REE_2.25Ca_1.52☐_0.23)[Si₄O₁₀](HCO₃)_0.21(CO₃)_2.79·3.8H₂O (x = 0.125, y′ = 0, y″ = 0.115). The end-member formula most close to these compositions is (Y₂Ca₂)[Si₄O₁₀](CO₃)₃·4H₂O, which is different from the formula (Ca,Yb,Er)₄Y₄(Si₈O₂₀)(CO₃)₆(OH)·7H₂O currently adopted by the International Mineralogical Association but is generally identical to the formula (Y,Ca)₄Si₄O₁₀(CO₃)₃·4H₂O proposed in the original study of the mineral. In order to resolve the problem of the caysichite-(Y) formula, additional studies of materials from different localities (and, especially, one from the holotype locality) are needed. Full article

Osteoarthritis (OA) is a major cause of equine lameness, with few effective disease-modifying treatments. This systematic review, conducted following the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines, evaluated the efficacy of platelet-rich plasma (PRP) for equine OA by analyzing 11 studies (6 clinical, 5 experimental) identified through Web of Science, Scopus, and PubMed (2000–2024). The screening process identified 252 records, of which 136 were duplicates and 105 were excluded based on predefined criteria. The analysis showed that intra-articular PRP injections are generally safe, with transient synovial inflammation occurring mainly when PRP was activated with bovine thrombin. Both leukocyte-rich (L-PRP) and leukocyte-poor (P-PRP) formulations exhibited comparable efficacy, though optimal platelet concentrations (423–658 × 10³/μL) and dosing regimens remain undefined. A PRISMA-based quality assessment highlighted substantial variability in study design, with clinical trials constrained by small sample sizes and high risk of bias. Experimental studies confirmed PRP’s biological activity but showed inconsistencies in preparation methods. The findings indicate that PRP activation is unnecessary and may even be pro-inflammatory, that multiple injections could improve outcomes, and that reporting of cellular composition is inconsistent across studies. The PRISMA framework identified critical evidence gaps, particularly regarding long-term efficacy and protocol standardization. These results emphasize the need for PRISMA-compliant randomized controlled trials featuring standardized PRP protocols, validated outcome measures, and extended follow-up periods to establish evidence-based guidelines for managing equine OA. Full article

Background/Objectives: Current guidelines do not specifically address the use of P2Y12 inhibitor (P2Y12i) pretreatment in patients with non-ST-segment elevation acute coronary syndrome (NSTE-ACS) who are expected to undergo a late invasive strategy. Nevertheless, such pretreatment may be considered in patients without a high bleeding risk (Class of Recommendation, IIb; Level of Evidence, C). Despite this ambiguity, P2Y12i pretreatment remains a common clinical practice. The present study aimed to evaluate the in-hospital prognostic impact of P2Y12i treatment prior to coronary angiography (CAG) in NSTE-ACS patients undergoing a late invasive strategy (CAG > 24 h after hospital admission). Methods: A retrospective analysis was conducted on NSTE-ACS patients undergoing a late invasive strategy included in the Portuguese Registry on Acute Coronary Syndromes between 2010 and 2023. The primary endpoint was a composite of in-hospital events, including all-cause mortality, non-fatal re-infarction, non-fatal stroke, and heart failure (HF). Secondary endpoints included the individual components of the primary endpoint and major bleeding (BARC types 3 and 4). Results: A total of 3776 patients were included (mean age, 66 ± 12 yrs; 29% female), of whom 1530 (41%) received P2Y12i pretreatment (group 1). Group 1 had a lower prevalence of prior myocardial infarction (16% vs. 21%) and prior percutaneous coronary intervention (12% vs. 15%) (both p ≤ 0.001). Although obstructive coronary artery disease was more frequent in group 1 (84% vs. 77%, p < 0.001), the presence of multivessel disease did not differ (52% vs. 52%, p = 0.667). Considering in-hospital antithrombotic therapy, group 1 had higher prescriptions of clopidogrel (68% vs. 56%), aspirin (99% vs. 81%), unfractionated heparin (21% vs. 8%), and enoxaparin (80% vs. 56%) (all p < 0.001). There was no significant difference in the primary composite endpoint between groups (9% vs. 9%, p = 0.906). Similarly, the secondary endpoints of all-cause mortality (0.6% vs. 0.7%), re-infarction (1.3% vs. 0.7%), stroke (0.7% vs. 0.4%), and HF (7% vs. 8%) did not differ significantly between groups (all p > 0.05). Nevertheless, group 1 exhibited higher rates of major bleeding (0.8 vs. 0.2%, OR 3.48, CI 95% 1.22–9.89, p = 0.013). Conclusions: Pretreatment with a P2Y12i in NSTE-ACS patients undergoing a late invasive strategy was not associated with reduction in the primary endpoint, although it was associated with higher rates of major bleeding. Full article

Turfgrass provides significant functional, environmental, recreational and aesthetic benefits; however, its high management inputs raise sustainability concerns due to intensive irrigation, fertilization and mowing. The aim of this study is to evaluate whether adopting a new mowing technology can support or enhance current low-input strategies in turfgrass management, such as reducing synthetic fertilization and deficit irrigation. This study was conducted from September 2023 to October 2024 at the Centre for Research on Turfgrass for Environment and Sports (CeRTES) in Pisa, Italy. Two turf compositions, pure tall fescue and tall fescue–microclover mixture, were managed using an autonomous mower operating daily at three mowing heights, 20, 40 and 60 mm. Turf quality, color, the NDVI, weed cover, leaf morphology, and clover presence were assessed throughout the growing season, including a drought and recovery period. The experimental design consisted of a two-factor split-plot randomized complete block design with four replications, and the statistical approach used was two-way and one-way ANOVAs with Fisher’s LSD at p = 0.05. The results of the study indicated that, under conditions where an autonomous mower was set to operate on a daily basis, the selected mowing height had minimal influence on drought response or recovery when water availability was a limiting factor. Furthermore, when subjected to the lowest mowing heights, the legume species included in the turfgrass mix demonstrated strong resilience, maintaining its presence and performance. In addition, when mowing with a high mowing frequency and at low mowing heights, the overall quality of the turfgrass appeared enhanced. These results serve as an important starting point for considering autonomous mowing technology as an innovative strategy in advancing toward turf management systems that prioritize sustainability and efficient use of resources. Full article

Background and Objectives: Nutritional status is essential for outcomes in hemodialysis (HD) patients. Incremental HD (iHD) may help preserve residual renal function, but its effect on nutrition and body composition is unclear. Nutritional ultrasound (NUS) offers a non-invasive way to assess muscle and fat, complementing methods like BIA. This study compared nutritional status using morphofunctional assessment in patients on iHD versus conventional HD (cHD). Material and Methods: This single-center observational cross-sectional study included 74 stable adult HD patients (>3 months). Patients were stratified into iHD (n = 13; 1–2 sessions/week) and cHD (n = 61; 3 sessions/week). Evaluations included clinical and biochemical parameters, BIA, handgrip strength, nutritional scores and NUS assessed mass muscle of anterior quadriceps rectus femoris (QRF), supramuscular fat (SMF), subcutaneous adipose tissue (SAT), and preperitoneal visceral fat (PPVF). Results: Patients on iHD exhibited a more favorable nutritional and inflammatory profile, with a lower risk of malnutrition and a reduced prevalence of protein-energy wasting (PEW) syndrome. Although BIA failed to clearly differentiate between groups, NUS identified better preservation of SMF in iHD patients (8.3 ± 2.5 vs. 6.6 ± 2 mm; p = 0.009), as well as higher preperitoneal visceral fat thickness (1.9 ± 4.9 vs. 0.6 ± 0.3 cm; p = 0.04). There was also a trend toward greater muscle thickness in the iHD group, such as the Y-axis (9.5 ± 2 vs. 8.5 ± 2.3 mm; p = 0.17) and cross-sectional area muscle of rectus femoris (CS-MARF in cm²) (2.9 ± 0.6 vs. 2.6 ± 0.8 mm; p = 0.1) of anterior QRF, although without reaching statistical significance. Conclusions: These results highlight the value of NUS as a sensitive method for assessing nutritional status in HD patients, particularly within individualized strategies such as iHD, where it may provide key complementary information not captured by conventional methods. Full article