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25 pages, 4286 KB  
Article
How Do Vertical Alliances Form in Agricultural Supply Chains?—An Evolutionary Game Analysis Based on Chinese Experience
by Ranran Hu, Hongwei Fang and Weizhong Liu
Sustainability 2025, 17(17), 7975; https://doi.org/10.3390/su17177975 - 4 Sep 2025
Abstract
Vertical alliances within agricultural supply chains serve as critical institutional vehicles for deepening triple-sector integration (primary–secondary–tertiary) in rural economies, driving agricultural modernization, and advancing rural revitalization. However, sustaining alliance stability constitutes a complex dynamic process wherein inadequate stakeholder engagement and collaborative failures frequently [...] Read more.
Vertical alliances within agricultural supply chains serve as critical institutional vehicles for deepening triple-sector integration (primary–secondary–tertiary) in rural economies, driving agricultural modernization, and advancing rural revitalization. However, sustaining alliance stability constitutes a complex dynamic process wherein inadequate stakeholder engagement and collaborative failures frequently precipitate alliance instability or even dissolution. Existing scholarship exhibits limited systematic examination of the micro-mechanisms and regulatory pathways through which multi-agent strategic interactions affect alliance stability from a dynamic evolutionary perspective. To address this gap, this research focuses on China’s core agricultural innovation vehicle—the Agricultural Industrialization Consortium—and examines the tripartite structure of “Leading Enterprise–Family Farm–Integrated Agricultural Service Providers.” We construct a tripartite evolutionary game model to systematically analyze (1) the influence mechanisms governing cooperative strategy selection, and (2) the regulatory effects of key parameters on consortium stability through strategic stability analysis and multi-scenario simulations. Our key findings are as follows: Four strategic equilibrium scenarios emerge under specific conditions, with synergistic parameter optimization constituting the fundamental driver of alliance stability. Specific mechanisms are as follows: (i) compensation mechanisms effectively mobilize leading enterprises under widespread defection, though excessive penalties erode reciprocity principles; (ii) strategic reductions in benefit sharing ratios coupled with moderate factor value-added coefficients are critical for reversing leading enterprises’ defection; (iii) dual adjustment of cost sharing and benefit sharing coefficients is necessary to resolve bilateral defection dilemmas; and (iv) synchronized optimization of compensation, cost sharing, benefit sharing, and value-added parameters represents the sole pathway to achieving stable (1,1,1) full-cooperation equilibrium. Critical barriers include threshold effects in benefit sharing ratios (defection triggers when shared benefits > cooperative benefits) and the inherent trade-off between penalty intensity and alliance resilience. Consequently, policy interventions must balance immediate constraints with long-term cooperative sustainability. This study extends the application of evolutionary game theory in agricultural organization research by revealing the micro-level mechanisms underlying alliance stability and providing a novel analytical framework for addressing the ‘strategy–equilibrium’ paradox in multi-agent cooperation. Our work not only offers new theoretical perspectives and methodological support for understanding the dynamic stability mechanisms of agricultural vertical alliances but also establishes a substantive theoretical foundation for optimizing consortium governance and promoting long-term alliance stability. Full article
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9 pages, 2158 KB  
Communication
Ultrafast Laser Writing of In-Line Filters Based on MZI
by Longwang Xiu, Yanfei Liu, Xinyu Hu, Yuxi Pang and Xiangdong Cao
Photonics 2025, 12(9), 889; https://doi.org/10.3390/photonics12090889 - 4 Sep 2025
Abstract
In mode-locked fiber lasers and optical sensors, in-line filters are essential components. Fiber-core Mach–Zehnder interferometer (MZI) technology has garnered a lot of research interest for the several manufacturing techniques for in-line MZI filters. Although multi-line inscription is frequently needed in existing methods to [...] Read more.
In mode-locked fiber lasers and optical sensors, in-line filters are essential components. Fiber-core Mach–Zehnder interferometer (MZI) technology has garnered a lot of research interest for the several manufacturing techniques for in-line MZI filters. Although multi-line inscription is frequently needed in existing methods to attain enough waveguide width, this approach adds complexity to production and may result in compromised waveguide quality. In this work, we present an improved single-line direct-writing method that attains similar MZI filtering results to multi-line scan. Additionally, the MZI filter created with the modified single-line direct-writing technique has a smaller insertion loss and requires less direct-writing energy than the previous single-line direct-writing technique. A 516 μm long MZI-based in-line filter was successfully constructed. The results of the characterization showed a central loss dip at 1089.82 nm, a free-spectral range (FSR) of 141.36 nm, an extinction ratio of 19.69 dB, and an insertion loss of 1.122 dB. This method decreased the insertion loss by a factor of 2.7 for an identical extinction ratio and improved the direct-writing efficiency by a factor of 9 for an equivalent FSR with multi-line scan. There was consistency between the experimental and simulation results. We also took measurements of the MZI’s temperature sensitivity. This work shows notable improvements in waveguide quality and ease of manufacture. This accomplishment lays the groundwork for further advancements in integrated mode-locked fiber laser technology. Full article
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18 pages, 2260 KB  
Article
Distribution and Ecological Risks of Organic Carbon, Nitrogen, and Phosphorus in Dongzhai Harbor Mangrove Sediments, China
by Gucheng Zhang, Jiaming Wang, Bo Ma, Xin Li, Changping Mao, Di Lin and Dongming Zhang
Water 2025, 17(17), 2613; https://doi.org/10.3390/w17172613 - 3 Sep 2025
Abstract
This study characterized the spatial distribution and assessed the ecological risks of carbon, nitrogen, and phosphorus in sediments of the Dongzhai Harbor mangrove wetland, Hainan, China. Analysis of key environmental indicators (grain size, pH, TOC, TN, TP) across twenty-seven sediment cores (0–100 cm [...] Read more.
This study characterized the spatial distribution and assessed the ecological risks of carbon, nitrogen, and phosphorus in sediments of the Dongzhai Harbor mangrove wetland, Hainan, China. Analysis of key environmental indicators (grain size, pH, TOC, TN, TP) across twenty-seven sediment cores (0–100 cm depth) revealed distinct decreasing land–sea gradients and vertical stratification of nutrient concentrations. Mangrove plant debris was identified as the primary source of sedimentary organic matter. Elemental ratio analysis indicated terrestrial inputs as the dominant phosphorus source. Significant positive correlations between TOC, TN, and TP in surface sediments suggested coupled nutrient dynamics. Vertical distribution of C/N to C/P ratios increased with depth, which may be related to increased nitrogen and phosphorus inputs due to regional human activities. Pollution assessment showed significantly higher ecological risks in surface sediments (0–50 cm), particularly near inland areas and dense mangroves, indicating co-regulation by vegetation processes and human impacts. These findings highlight significant spatial heterogeneity in ecological risks, underscoring the need for enhanced monitoring and targeted management strategies in critical land–sea transition zones. Full article
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20 pages, 9688 KB  
Article
Hypolipidemic Effects of Alpinia japonica Extracts: Modulation of PPAR Signaling, Gut Microbiota, and Intestinal Barrier Function in Hyperlipidemic Rats
by Liqing Zhou, Cong Fang, Hongwei Li, Yifan Lin, Huiqing Que, Hongxu Liu, Lihong Ma and Wenjin Lin
Pharmaceuticals 2025, 18(9), 1320; https://doi.org/10.3390/ph18091320 - 3 Sep 2025
Abstract
Objectives: Alpinia japonica (A. japonica) is traditionally used for digestive disorders, but its hypolipidemic mechanisms remain unclear. This study investigated the lipid-lowering effects of its fruit (SJGS), rhizome (SJGJ), and leaf (SJY) extracts, exploring their bioactive constituents and organ-specific mechanisms. [...] Read more.
Objectives: Alpinia japonica (A. japonica) is traditionally used for digestive disorders, but its hypolipidemic mechanisms remain unclear. This study investigated the lipid-lowering effects of its fruit (SJGS), rhizome (SJGJ), and leaf (SJY) extracts, exploring their bioactive constituents and organ-specific mechanisms. Methods: Sprague Dawley rats (n = 8/group) fed a high-fat diet received SJGS, SJGJ, or SJY (200 mg/kg/day) for 4 weeks. Serum lipids (TC, TG), liver enzymes (AST, ALT), and intestinal barrier markers (DAO) were measured. Gut microbiota (16S rDNA sequencing), hepatic histopathology, and ileal tight junction proteins were analyzed. Transcriptomics and qPCR assessed ileal gene expression. LC-MS identified chemical constituents, while network pharmacology predicted compound-target interactions. Results: All extracts significantly reduced serum TC (↓ 27–33%), TG (↓ 29–38%), AST/ALT (↓ 22–30%), and DAO (↓ 35–42%) versus controls (p < 0.05). They improved hepatic steatosis, enhanced intestinal barrier function, and modulated gut microbiota (↑ α-diversity, ↓ Firmicutes/Bacteroidetes ratio). Transcriptomics revealed PPAR signaling as the core pathway: SJGS/SJGJ downregulated fatty acid oxidation genes (ACSL1, ACOX1, ACADM), while SJY upregulated APOA1 (2.3-fold). LC-MS identified 33–48 compounds/part, with seven shared constituents. Network analysis prioritized three flavonoids (pinocembrin, luteolin, galangin) targeting TNF, AKT1, and PPAR pathways. Conclusions: The findings suggest A. japonica extracts ameliorate hyperlipidemia through distinct mechanisms—SJGS/SJGJ may inhibit fatty acid oxidation, while SJY potentially enhances APOA1-mediated clearance. Shared flavonoids likely contribute to these effects via PPAR signaling, supporting its traditional use. This study provides a scientific basis for the sustainable utilization of A. japonica resources. Full article
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17 pages, 4501 KB  
Article
Highly Sensitive SNS Structure Fiber Liquid-Sealed Temperature Sensor with PVA-Based Cladding for Large Range
by Si Cheng, Chuan Tian, Xiaolei Bai and Zhiyu Zhang
Photonics 2025, 12(9), 887; https://doi.org/10.3390/photonics12090887 - 3 Sep 2025
Abstract
A liquid-sealed single-mode–no-core–single-mode (SNS) structure fiber temperature sensor based on polyvinyl alcohol (PVA) partial replacement coating is proposed. Using a liquid-sealed glass capillary structure, the PVA solution is introduced into the SNS structure and avoids its influence by environmental humidity. Temperature can be [...] Read more.
A liquid-sealed single-mode–no-core–single-mode (SNS) structure fiber temperature sensor based on polyvinyl alcohol (PVA) partial replacement coating is proposed. Using a liquid-sealed glass capillary structure, the PVA solution is introduced into the SNS structure and avoids its influence by environmental humidity. Temperature can be obtained by measuring the shift of the multimode interference spectrum, which is affected by the thermal optical effect of the PVA solution. Through theoretical simulation of the sensor, the optimal NCF fiber length and coating stripped length are obtained by comprehensively considering the transmitted loss and output spectrum signal-to-noise ratio (SNR). The optimal PVA solution concentration is selected by measuring the thermo-optic coefficient (TOC) and refractive index (RI). Based on the theoretical optimization results, a PVA solution-coated SNS fiber optic temperature sensor is experimentally fabricated, and temperature-sensing characteristics are measured within −3.6 to 73.2 °C. The experimental results show that the sensor has a high sensitivity (nm/°C, maximum is 21.713 nm/°C) and has a resolution of 10−3 °C. λdip has a stable negative linear relationship with temperature, and the correlation coefficient of the fitting curve exceeds 95%. The temperature cycling experiment and long-term stability test show that the temperature sensor has good repeatability and stability. The experimental results also show the nonlinear relationship between the temperature measurement range and sensitivity, clarify the important factors affecting the response performance of fiber temperature sensors, and provide important reference values for optical fiber temperature sensors. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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17 pages, 3877 KB  
Article
Numerical Elucidation on the Dynamic Behaviour of Non-Premixed Flame in Meso-Scale Combustors
by Muhammad Lutfi Abd Latif, Mohd Al-Hafiz Mohd Nawi, Mohammad Azrul Rizal Alias, Chu Yee Khor, Mohd Fathurrahman Kamarudin, Azri Hariz Roslan and Hazrin Jahidi Jaafar
Modelling 2025, 6(3), 94; https://doi.org/10.3390/modelling6030094 - 1 Sep 2025
Viewed by 131
Abstract
Meso-scale combustors face persistent challenges in sustaining stable combustion and efficient heat transfer due to high surface-to-volume ratios and attendant heat losses. In contrast, larger outlet diameters exhibit weaker recirculation and more diffused temperature zones, resulting in reduced combustion efficiency and thermal confinement. [...] Read more.
Meso-scale combustors face persistent challenges in sustaining stable combustion and efficient heat transfer due to high surface-to-volume ratios and attendant heat losses. In contrast, larger outlet diameters exhibit weaker recirculation and more diffused temperature zones, resulting in reduced combustion efficiency and thermal confinement. The behavior of non-premixed flames in meso-scale combustor has been investigated through a comprehensive numerical study, utilizing computational fluid dynamics (CFD) under stoichiometric natural gas (methane)–air conditions; three outlet configurations (6 mm, 8 mm, and 10 mm) were analysed to evaluate their impact on temperature behaviour, vortex flow, swirl intensity, and central recirculation zone (CRZ) formation. Among the tested geometries, the 6 mm outlet produced the most robust central recirculation, intensifying reactant entrainment and mixing and yielding a sharply localised high-temperature core approaching 1880 K. The study highlights the critical role of geometric parameters in governing heat release distribution, with the 6 mm configuration achieving the highest exhaust temperature (920 K) and peak wall temperature (1020 K), making it particularly suitable for thermoelectric generator (TEG) integration. These findings underscore the interplay between combustor geometry, flow dynamics, and heat transfer mechanisms in meso-scale systems, providing valuable insights for optimizing portable power generation devices. Full article
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20 pages, 12575 KB  
Article
Seismic Fragility of Large-Span Elevated U-Shaped Aqueduct Based on Incremental Dynamic Analysis
by Jing Wei and Xinjun Yan
Appl. Sci. 2025, 15(17), 9623; https://doi.org/10.3390/app15179623 - 1 Sep 2025
Viewed by 150
Abstract
This study uses a U-shaped aqueduct structure in a specific irrigation area as the research object to examine the damage patterns of large-span elevated U-shaped aqueduct structures under seismic action. A single-span aqueduct model that integrates fluid–structure interaction is created with the finite [...] Read more.
This study uses a U-shaped aqueduct structure in a specific irrigation area as the research object to examine the damage patterns of large-span elevated U-shaped aqueduct structures under seismic action. A single-span aqueduct model that integrates fluid–structure interaction is created with the finite element program ANSYS. The incremental dynamic analysis approach is utilized to perform nonlinear dynamic time–history assessments for three types of bearings—plate rubber bearings, pot rubber bearings and lead-core rubber bearings—under conditions of an empty condition, a half-full condition and a design water level. Seismic fragility curves for the bearings and piers subjected to transverse seismic stress are developed using capacity–demand ratio models and specified damage limit states. The findings demonstrate that the likelihood of aqueduct components being damaged increases substantially as seismic intensity increases, with bearings failing before piers. Under the conditions of empty, half-full and design water levels, the structural mass increases as a result of higher water levels. This alters the dynamic response characteristics and increases the likelihood of failure in a variety of damage states. The probability of plate rubber bearings experiencing minor damage exceedance increases from 11.75% to 61.6% as the water level rises from vacant to design conditions. Lead-core rubber bearings provide better seismic isolation than plate rubber bearings and pot rubber bearings. This greatly lowers the aqueduct structure’s displacement response and damage likelihood. Under design water level circumstances, the chance of mild damage to lead rubber bearings is 8.64%, at a peak ground acceleration of 0.4 g. The damage probabilities for the pot rubber bearings and the plate rubber bearings are 80.68% and 97.45%, respectively. The research findings establish a theoretical foundation for the seismic design and damage evaluation of aqueduct structures in places with high seismic activity, ensuring the stable operation of water transfer projects and sustainable water resource utilization, presenting considerable technical applicability. Full article
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24 pages, 11780 KB  
Article
Additive Manufacturing of Carbon Fiber Cores for Sandwich Structures: Optimization of Infill Patterns and Fiber Orientation for Improved Impact Resistance
by Claudio Tosto, Lorena Saitta, Ignazio Blanco, Gabriele Fichera, Mattia Evangelista, Jerin Jose, Alessia Pantaleoni and Irene Bavasso
J. Manuf. Mater. Process. 2025, 9(9), 299; https://doi.org/10.3390/jmmp9090299 - 1 Sep 2025
Viewed by 250
Abstract
Carbon fiber-reinforced composites (CFRCs) are widely used in aerospace, automotive, and defense applications due to their high strength-to-weight ratio and excellent mechanical performance. In this study, cores and sandwich panels were fabricated via fused filament fabrication (FFF) using co-polyester filaments reinforced with 20 [...] Read more.
Carbon fiber-reinforced composites (CFRCs) are widely used in aerospace, automotive, and defense applications due to their high strength-to-weight ratio and excellent mechanical performance. In this study, cores and sandwich panels were fabricated via fused filament fabrication (FFF) using co-polyester filaments reinforced with 20 wt.% short carbon fibers. The mechanical response of the structures was evaluated under low-velocity impact (LVI) conditions using instrumented drop weight testing at energy levels ranging from 2 to 20 J. A three-factor, three-level full factorial experimental design was employed, considering build orientation (flat vs. upright), infill pattern (trihexagonal vs. triangular), and impact energy as factors. The maximum contact force was selected as the primary response variable. The results revealed that upright-printed specimens exhibited significantly improved impact resistance compared to flat-printed ones, with increases in peak force of up to 28% for cores and over 68% for sandwich structures. Among the tested infill geometries, the triangular pattern outperformed the trihexagonal one across all configurations and energy levels. The combination of upright orientation and triangular infill proved to be the most effective, providing enhanced energy absorption and reduced rear-side damage, especially under higher impact energies. These findings offer valuable insights into the design of lightweight, impact-resistant structures produced by additive manufacturing, with direct implications for structural components in demanding engineering environments. Full article
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28 pages, 7342 KB  
Article
Numerical Analysis of Flow-Induced Resonance in Pilot-Operated Molten Salt Control Valves
by Shuxun Li, Yu Zhao, Jianzheng Zhang, Linxia Yang and Xinhao Liu
Energies 2025, 18(17), 4631; https://doi.org/10.3390/en18174631 - 31 Aug 2025
Viewed by 214
Abstract
To address the problem of flow-induced resonance in the valve core assembly of a pilot-operated molten salt regulating valve in a concentrated solar thermal power generation molten salt energy storage system under high pressure differential and high flow rate conditions, the flow-induced vibration [...] Read more.
To address the problem of flow-induced resonance in the valve core assembly of a pilot-operated molten salt regulating valve in a concentrated solar thermal power generation molten salt energy storage system under high pressure differential and high flow rate conditions, the flow-induced vibration characteristics of the pilot-operated molten salt regulating valve were analyzed using computational fluid dynamics (CFD) and fluid–structure interaction modal analysis. The vibration characteristics of the valve core assembly under the excitation force of the molten salt medium were analyzed using the harmonic response method, and the influence of different parameters on the valve core assembly’s vibration characteristics was studied. The results show that under typical operating openings, the first six modal frequencies of the valve core motion assembly are not close to the fluid excitation frequency, indicating that flow-induced resonance does not occur. The maximum vibration stress and displacement of the valve core assembly decrease with increasing damping ratio. With increasing pressure differential, the maximum stress and maximum amplitude of the valve core assembly increase. By changing the valve stem constraint conditions, the vibration stress of the valve core assembly can be reduced. This study provides a reference for the design of flow-induced vibration suppression for pilot-operated molten salt regulating valves and provides guidance for the safe operation of concentrated solar thermal power generation molten salt regulating valves under high pressure differential and high flow rate conditions. Full article
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15 pages, 4977 KB  
Article
A Study on the Formation Water Retention State and Production Mechanism of Tight High-Water Saturation Reservoirs Based on Micro-Nanofluidic Experiments
by Zhanyang Zhang, Tiantian Dong, Jianbiao Wu, Hui Guo, Jianxin Lu, Junjie Zhong, Liang Zhou and Hai Sun
Energies 2025, 18(17), 4605; https://doi.org/10.3390/en18174605 - 30 Aug 2025
Viewed by 258
Abstract
Tight sandstone gas is currently one of the largest unconventional oil and gas resources being developed. In actual reservoir development, the complex pore structure affects the distribution of residual gas and water during the displacement process. However, there is still a lack of [...] Read more.
Tight sandstone gas is currently one of the largest unconventional oil and gas resources being developed. In actual reservoir development, the complex pore structure affects the distribution of residual gas and water during the displacement process. However, there is still a lack of experimental research on the multi-scale visualization of pore structures in high-water-content tight gas reservoirs. Therefore, based on the porosity and permeability properties of reservoir cores and the micropore throat structural characteristics, this study designs and prepares three micro-physical models with different permeability ranges. Through micro-experiments and visualization techniques, the microscopic flow phenomena and gas–water distribution in the pore medium are observed. When the water–gas ratio exceeds 5, the produced water type is free water; when the water–gas ratio is between 2 and 5, the produced water type is weak capillary water; and when the water–gas ratio is less than 2, the produced water type is strong capillary water. The latter two types are collectively referred to as capillary water. In the Jin 30 well area, the main types of produced water are first free water, followed by capillary water, accounting for 58.5%. The experimental results of the micro-physical models with different permeability levels show that the production pattern of formation water varies due to differences in pore connectivity. In the low-permeability model, the high proportion of nano-pores and small pore throats requires a large pressure difference to mobilize capillary water, resulting in a higher proportion of residual water. Although the pores in the medium-permeability model are larger, the poor connectivity of nano-pores leads to local water phase retention. In the high-permeability model, micro-fractures and micropores are highly developed with good connectivity, allowing for rapid mobilization of multi-scale water phases under low pressure. The connectivity of nano-pores directly impacts the mobilization of formation water in micron-scale fractures, and poor pore connectivity significantly increases the difficulty of capillary water mobilization, thus changing the production mechanism of formation water at different scales. Full article
(This article belongs to the Topic Oil, Gas and Water Separation Research)
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19 pages, 23351 KB  
Article
Integrated Geomechanical Modeling of Multiscale Fracture Networks in the Longmaxi Shale Reservoir, Northern Luzhou Region, Sichuan Basin
by Guoyou Fu, Qun Zhao, Guiwen Wang, Caineng Zou and Qiqiang Ren
Appl. Sci. 2025, 15(17), 9528; https://doi.org/10.3390/app15179528 - 29 Aug 2025
Viewed by 196
Abstract
This study presents an integrated geomechanical modeling framework for predicting multi-scale fracture networks and their activity in the Longmaxi Formation shale reservoir, northern Luzhou region, southeastern Sichuan Basin—an area shaped by complex, multi-phase tectonic deformation that poses significant challenges for resource prospecting. The [...] Read more.
This study presents an integrated geomechanical modeling framework for predicting multi-scale fracture networks and their activity in the Longmaxi Formation shale reservoir, northern Luzhou region, southeastern Sichuan Basin—an area shaped by complex, multi-phase tectonic deformation that poses significant challenges for resource prospecting. The workflow begins with quantitative characterization of key mechanical parameters, including uniaxial compressive strength, Young’s modulus, Poisson’s ratio, and tensile strength, obtained from core experiments and log-based inversion. These parameters form the foundation for multi-phase finite element simulations that reconstruct paleo- and present-day stress fields associated with the Indosinian (NW–SE compression), Yanshanian (NWW–SEE compression), and Himalayan (near W–E compression) deformation phases. Optimized Mohr–Coulomb and tensile failure criteria, coupled with a multi-phase stress superposition algorithm, enable quantitative prediction of fracture density, aperture, and orientation through successive tectonic cycles. The results reveal that the Longmaxi Formation’s high brittleness and lithological heterogeneity interact with evolving stress regimes to produce fracture systems that are strongly anisotropic and phase-dependent: initial NE–SW-oriented domains established during the Indosinian phase were intensified during Yanshanian reactivation, while Himalayan uplift induced regional stress attenuation with limited new fracture formation. The cumulative stress effects yield fracture networks concentrated along NE–SW fold axes, fault zones, and intersection zones. By integrating geomechanical predictions with seismic attributes and borehole observations, the study constructs a discrete fracture network that captures both large-scale tectonic fractures and small-scale features beyond seismic resolution. Fracture activity is further assessed using friction coefficient analysis, delineating zones of high activity along fold–fault intersections and stress concentration areas. This principle-driven approach demonstrates how mechanical characterization, stress field evolution, and fracture mechanics can be combined into a unified predictive tool, offering a transferable methodology for structurally complex, multi-deformation reservoirs. Beyond its relevance to shale gas development, the framework exemplifies how advanced geomechanical modeling can enhance resource prospecting efficiency and accuracy in diverse geological settings. Full article
(This article belongs to the Special Issue Recent Advances in Prospecting Geology)
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14 pages, 3390 KB  
Article
Research on Spatial Optical Path System for Evaluating the Reflection Performance of Quartz-Based Volume Bragg Grating Applied to Fabry–Perot Cavity
by Jiamin Chen, Gengchen Zhang, Hejin Wang, Qianyu Ren, Yongqiu Zheng and Chenyang Xue
Micromachines 2025, 16(9), 998; https://doi.org/10.3390/mi16090998 - 29 Aug 2025
Viewed by 174
Abstract
In the field of high-temperature in situ sensing, highly reflective Fabry–Perot (F-P) cavity mirrors with thermal stress matching are urgently needed. The quartz-based volume Bragg grating (VBG) can replace the dielectric high-reflection film to prepare a high-temperature and high-precision F-P cavity sensitive unit [...] Read more.
In the field of high-temperature in situ sensing, highly reflective Fabry–Perot (F-P) cavity mirrors with thermal stress matching are urgently needed. The quartz-based volume Bragg grating (VBG) can replace the dielectric high-reflection film to prepare a high-temperature and high-precision F-P cavity sensitive unit by virtue of the integrated structure of homogeneous materials. The reflectivity of the VBG is a key parameter determining the performance of the F-P cavity, and its accurate measurement is very important for the pre-evaluation of the device’s sensing ability. Based on the reflectivity measurement of quartz-based VBG with a large aspect ratio, a free-space optical path reflective measurement system is proposed. The ZEMAX simulation is used to optimize the optical transmission path and determine the position of each component when the optimal spot size is achieved. After completing the construction of the VBG reflectivity measurement system, the measurement error is calibrated by measuring the optical path loss, and the maximum error is only 1.2%. Finally, the reflectivity of the VBG measured by the calibrated system is 30.84%, which is basically consistent with the multi-physical field simulation results, showing a deviation as low as 0.85%. The experimental results fully verify the availability and high measurement accuracy of the reflectivity measurement system. This research work provides a new method for testing the characteristics of micron-scale grating size VBGs. Additionally, this work combines optical characterization methods to verify the good effect of VBG preparation technology, providing core technical support for the realization of subsequent homogeneous integrated Fabry–Perot cavity sensors. Furthermore, it holds important application value in the field of optical sensing and micro-nano integration. Full article
(This article belongs to the Section E:Engineering and Technology)
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21 pages, 8835 KB  
Article
Effect of Shellac–Rosin Microcapsules on the Self-Healing Properties of Waterborne Primer on Wood Surfaces
by Jingyi Hang, Yang Han, Xiaoxing Yan and Jun Li
Coatings 2025, 15(9), 1003; https://doi.org/10.3390/coatings15091003 - 29 Aug 2025
Viewed by 291
Abstract
Microcapsules with self-healing properties were synthesized via emulsion polymerization, with melamine formaldehyde resin serving as the microcapsule wall and a mixture of shellac and rosin solutions encapsulated as the core. The core–wall ratio was tested as a variable, and two ratios of 0.59:1 [...] Read more.
Microcapsules with self-healing properties were synthesized via emulsion polymerization, with melamine formaldehyde resin serving as the microcapsule wall and a mixture of shellac and rosin solutions encapsulated as the core. The core–wall ratio was tested as a variable, and two ratios of 0.59:1 and 0.68:1 were selected for the preparations. Microcapsules were added to the waterborne paint films at concentrations of 0%, 5.0%, 10.0%, 15.0%, 20.0%, and 25.0%, respectively, to obtain self-healing waterborne paint films with different microcapsule contents. The effects of microcapsules with different core–wall ratios and concentrations in the paint films on the optical, mechanical, and self-healing properties of the paint film were investigated. The results showed that an increase in microcapsule content led to a corresponding rise in the paint film ∆E. The coating-film glossiness exhibited a decreasing tendency with an increase in microcapsule concentration. When the content of microcapsules was below 15.0%, the coating maintained a high level of adhesion and hardness. However, once the concentration surpassed 20.0%, coating adhesion began to decline. The addition of microcapsules effectively enhanced the thermal-aging resistance of the paint film. At the core–wall ratio of 0.68:1 and a microcapsule content of 20.0%, the paint film exhibited the best aging resistance, and the repair rate reached 16.1%, indicating good self-healing performance. Full article
(This article belongs to the Section Functional Polymer Coatings and Films)
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21 pages, 7311 KB  
Article
Thermal State Simulation and Parameter Optimization of Circulating Fluidized Bed Boiler
by Jin Xu, Kaixuan Zhou, Fengchao Li, Zongyan Zhou, Yuelei Wang and Wenbin Huang
Processes 2025, 13(9), 2776; https://doi.org/10.3390/pr13092776 - 29 Aug 2025
Viewed by 189
Abstract
In order to solve the problem of low thermal efficiency of a 130 t/h industrial circulating fluidized bed boiler, a computational particle fluid dynamic approach was used in this work to study two-phase gas–solid flow, heat transfer, and combustion. The factors influencing coal [...] Read more.
In order to solve the problem of low thermal efficiency of a 130 t/h industrial circulating fluidized bed boiler, a computational particle fluid dynamic approach was used in this work to study two-phase gas–solid flow, heat transfer, and combustion. The factors influencing coal particle size distributions, air distribution strategies, and operational loads are addressed. The results showed that particle distribution exhibits “core–annulus” flow with a dense-phase bottom region and dilute-phase upper zone. A higher primary air ratio (0.8–1.5) enhances axial gas velocity and bed temperature but reduces secondary air zone (2.5–5.8 m) temperature. A higher primary air ratio also decreases outlet O2 mole fraction and increases fly ash carbon content, with optimal thermal efficiency at a ratio of 1.0. In addition, as the coal PSD decreases and the load increases, the overall temperature of the furnace increases and the outlet O2 mole fraction decreases. Full article
(This article belongs to the Section Chemical Processes and Systems)
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23 pages, 11634 KB  
Article
Optimization of the Chitosan-Assisted Extraction for Phillyrin and Forsythoside A from Forsythia suspensa Leaves Using Response Surface Methodology
by Teng Wang, Zexi Zhang, Jiayu Wang, Yuanyuan Fu, Xiaolin Zou, Wei Li, Zhaolun Zhang, Youting Liu, Zhaojun Jia, Zhenguo Wen and Yong Chen
Molecules 2025, 30(17), 3528; https://doi.org/10.3390/molecules30173528 - 29 Aug 2025
Viewed by 257
Abstract
In this study, a green and efficient extraction methodology was developed by leveraging the unique properties of chitosan—namely its non-toxicity, biocompatibility, and adhesive nature—to enhance the recovery of bioactive ingredients from Forsythia suspensa leaves. The core mechanism involves the formation of complexes between [...] Read more.
In this study, a green and efficient extraction methodology was developed by leveraging the unique properties of chitosan—namely its non-toxicity, biocompatibility, and adhesive nature—to enhance the recovery of bioactive ingredients from Forsythia suspensa leaves. The core mechanism involves the formation of complexes between chitosan and the target bioactive ingredients, which significantly boosts their extraction efficiency. To substantiate this mechanism, comprehensive characterization was performed using Powder X-ray Diffraction (PXRD), Fourier Transform Infrared Spectroscopy (FT-IR), Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM), and molecular docking analyses. The results provided robust evidence of a strong interaction between chitosan and the bioactive ingredients, leading to a marked enhancement in both the stability and aqueous solubility of the target compounds. For process optimization, a multi-objective approach was implemented using the Non-dominated Sorting Genetic Algorithm II (NSGA-II) to simultaneously maximize the extraction yields of phillyrin and forsythoside A. The algorithm identified the optimal parameters as a leaf-to-chitosan mass ratio of 10:11.75, a solid-to-liquid ratio of 1:52 g/mL, a temperature of 80 °C, and a duration of 120 min. Under these optimized conditions, the corresponding extraction yields for phillyrin and forsythoside A were 1.68 ± 0.16% and 3.23 ± 0.27%, respectively. These findings collectively indicate that chitosan-assisted extraction represents a highly promising and advanced technology for the sustainable and effective extraction of bioactive ingredients from botanical sources. Full article
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