Search Results (1,201)

The influence of stress on gas sorption behavior and sorption-induced swelling in coal is critical for the success of CO₂-enhanced coalbed methane recovery (CO₂-ECBM) and geological carbon sequestration—a key strategy for mitigating climate change and promoting clean energy transitions. However, this influence remains insufficiently understood, largely due to experimental limitations (e.g., overreliance on powdered coal samples) and conflicting theoretical frameworks in existing studies. To address this gap, this study systematically investigates the effects of two distinct stress constraints—constant confining pressure and constant volume—on CO₂ adsorption capacity, adsorption kinetics, and associated swelling deformation of intact anthracite coal cores. An integrated experimental apparatus was custom-designed for this study, combining volumetric sorption measurement with high-resolution strain monitoring via the confining fluid displacement (CFD) method and the confining pressure response (CPR) method. This setup enables the quantification of CO₂–coal interactions under precisely controlled stress environments. Key findings reveal that stress conditions exert a regulatory role in shaping CO₂–coal behavior: constant confining pressure conditions enhance CO₂ adsorption capacity and sustain adsorption kinetics by accommodating matrix swelling, thereby preserving pore accessibility for continuous gas uptake. In contrast, constant volume constraints lead to rapid internal stress buildup, which inhibits further gas adsorption and accelerates the attainment of kinetic saturation. Sorption-induced swelling exhibits clear dependence on both pressure and constraint conditions. Elevated CO₂ pressure leads to increased strain, while constant confining pressure facilitates more gradual, sustained expansion. This is particularly evident at higher pressures, where adsorption-induced swelling prevails over mechanical constraints. These results help resolve key discrepancies in the existing literature by clarifying the dual role of stress in modulating both pore accessibility (for gas transport) and mechanical response (for matrix deformation). These insights provide essential guidance for optimizing CO₂ injection strategies and improving the long-term performance and sustainability of CO₂-ECBM and geological carbon storage projects, ultimately supporting global efforts in carbon emission reduction and sustainable energy resource utilization. Full article

The Australian built environment is pivotal to achieving national net-zero targets, yet progress remains slow due to fragmented policy frameworks, low retrofit adoption, and uneven integration of emerging technologies. Despite these challenges, little research has applied a foresight perspective that both defines reproducible scenario thresholds and provides semi-quantitative comparisons tailored to Australia. This study integrates strategic foresight with international benchmarking to develop four scenarios for 2050: Business as Usual, Accelerated Sustainability, Technological Transformation, and Climate Resilience. Each scenario is underpinned by measurable thresholds for renovation rates, electrification, digital penetration, and low-carbon material uptake, and is evaluated through a scorecard spanning five outcome domains, with sensitivity and stress testing of high-leverage parameters. Findings indicate that an Accelerated Sustainability pathway, driven by deep retrofits of ≥3% annually, whole-life carbon policies, and renewable penetration of at least 70%, delivers the strongest combined performance across emissions reduction, liveability, and resilience. Technological Transformation offers adaptability and service quality but raises concerns over equity and cyber-dependence, while Climate Resilience maximises adaptation capacity yet risks under-delivering on mitigation. The study contributes a reproducible framework and transparent assumptions table to inform policy and industry road mapping, suggesting that a policy-led pathway coupling retrofits, electrification, and digital enablement provides the most balanced route towards a net zero and climate-resilient built environment by 2050. Full article

Microplastic (MP) pollution in urban areas is a growing global concern due to its health risks and environmental effects. This study investigates the sources, spatial distribution, and health risks of MPs in road dust across industrial, capital city, and peri-urban areas of Bangladesh. Street dust samples were collected from 15 heavily congested traffic sites across Dhaka and its surrounding areas. The samples were analyzed using fluorescence microscopy and Fourier Transform Infrared (FTIR) spectroscopy to identify MP types and their morphological characteristics. We have identified six types of polymers, including Polyvinyl alcohol (PVA), Polyethylene (PE), Polypropylene (PP), Polystyrene (PS), Low-Density Polyethylene (LDPE) and High-Density Polyethylene (HDPE), with industrial areas exhibiting the highest levels of MPs followed by capital city and peri-urban zones. PP was the most prevalent MP polymer, with the highest level in industrial areas (14.1 ± 1.7 MPs/g), followed by capital city (9.6 ± 1.92 MPs/g) and peri-urban areas (7.2 ± 1.56 MPs/g). Principal Component Analysis (PCA) identified traffic emissions, industrial activities, and mismanaged plastic waste as the primary sources of MPs. Health risk evaluations indicated that children are more susceptible to MP exposure through ingestion and inhalation, with industrial areas posing the highest carcinogenic risk. The findings underscore the pressing demand for better waste management systems and stricter regulatory measures to mitigate MP pollution and safeguard public health in urban environments. Addressing these challenges is essential to reduce the growing threat of MPs and their long-term effects on ecosystems and human well-being. Full article

Higher education institutions play a critical role in the transition to a low-carbon future due to their research capacity and societal influence. Accordingly, the calculation of greenhouse gas (GHG) emissions and the prioritization of mitigation strategies are of particular importance. In this study, a comprehensive campus-level GHG inventory was prepared for a public university in Türkiye in alignment with the ISO 14064-1:2018 standard, and mitigation strategies were evaluated. To prioritize these strategies, both the classical Policy Modeling Consistency (PMC) index and, for the first time in the literature, a fuzzy extension of the PMC model was applied. The results reveal that the total GHG emissions for 2023 amounted to 4888.63 tCO₂e (1.19 tCO₂e per capita), with the largest shares originating from investments (31%) and purchased electricity (28.38%). While the classical PMC identified only two high-priority actions, the fuzzy PMC reduced score dispersion, resolved ranking ties, and expanded the number of high-priority actions to seven. The top strategies include awareness programs, energy-efficiency measures, virtual meeting practices, advanced electricity monitoring, and improved data management systems. By comparing the classical and fuzzy approaches, the study demonstrates that integrating fuzzy logic enhances the transparency, reproducibility, and robustness of strategy prioritization, thereby offering a practical roadmap for campus decarbonization and sustainability policy in higher education institutions. Full article

Styrene is an aromatic compound widely used as a reactive monomer in polyester resins, which are among the most utilized resins in cured-in-place pipe (CIPP) technology, the most widely used trenchless pipe renewal method. Given that styrene is classified as a suspected human carcinogen, this study aims to evaluate styrene concentrations emitted into the air during sewer pipe rehabilitation using CIPP. This study included developing a comprehensive methodology to collect data from six different CIPP installations across the U.S. and document styrene emissions before, during, and after the curing process. The air samples were collected and analyzed using the USEPA method TO-15 and TO-17. Measured styrene emissions were then compared with exposure limits established by USEPA, NIOSH, and OSHA to assess potential occupational and worker health impacts. The result confirmed that high styrene concentrations, exceeding the established threshold, can be observed within the CIPP work zone. The result also indicated a considerable reduction in styrene concentration within five feet downwind of the work zone. In conclusion, while the health risk to the public appears to be low, there is a potential for health impact for the CIPP crew. Therefore, implementing real-time air quality monitoring during CIPP installation to mitigate these health risks is recommended. Additionally, the use of appropriate personal protective equipment (PPE) by the crew is essential. Full article

Rice (Oryza sativa) plays a fundamental role in the Ecuadorian diet. This study evaluated traceability and contamination by heavy metals in two rice-producing areas of Ecuador. Microwave-assisted digestion was used to process samples from rice agrosystems including irrigation water, soil, roots, stems, and leaves. Inductively coupled plasma optical emission spectroscopy (ICP-OES) was employed for elemental analysis. Arsenic (As), cadmium (Cd), lead (Pb), and chromium (Cr) were measured in samples collected in Daule and Ventanas. In soils, the concentrations of As (1.50–2.82 mg/kg) and Cd (1.22–1.45 mg/kg) exceeded the internationally recommended safety thresholds. In irrigation water, the content of As (0.85–1.12 mg/L), Pb (0.25–0.38 mg/L), and Cr (0.37–0.53 mg/L) surpass the international/national permissible limits. However, the limits established by Ecuadorian legislation indicate that As in soils did not exceed contamination thresholds. Additionally, the bioaccumulation of As and Pb in roots from Daule and Ventanas, respectively, was observed, along with the movement of Pb to aerial parts in Daule. Finally, preliminary As found in commercial rice grains suggest a potential health concern to the Ecuadorian population. These findings highlight the need for stricter heavy metal restrictions for rice agrosystems and effective agricultural pollution mitigation. Full article

The cement industry accounts for approximately 7–8% of global CO₂ emissions, primarily due to energy-intensive clinker production and limestone calcination. With cement demand continuing to rise, particularly in emerging economies, decarbonization has become an urgent global challenge. The objective of this study is to systematically map and synthesize existing evidence on technological pathways, policy measures, and economic barriers to four core decarbonization strategies: clinker substitution, energy efficiency, alternative fuels, as well as carbon capture, utilization, and storage (CCUS) in the cement sector, with the goal of identifying practical strategies that can align industry practice with long-term climate goals. A scoping review methodology was adopted, drawing on peer-reviewed journal articles, technical reports, and policy documents to ensure a comprehensive perspective. The results demonstrate that each mitigation pathway is technically feasible but faces substantial real-world constraints. Clinker substitution delivers immediate reduction but is limited by SCM availability/quality, durability qualification, and conservative codes; LC₃ is promising where clay logistics allow. Energy-efficiency measures like waste-heat recovery and advanced controls reduce fuel use but face high capital expenditure, downtime, and diminishing returns in modern plants. Alternative fuels can reduce combustion-related emissions but face challenges of supply chains, technical integration challenges, quality, weak waste-management systems, and regulatory acceptance. CCUS, the most considerable long-term potential, addresses process CO₂ and enables deep reductions, but remains commercially unviable due to current economics, high costs, limited policy support, lack of large-scale deployment, and access to transport and storage. Cross-cutting economic challenges, regulatory gaps, skill shortages, and social resistance including NIMBYism further slow adoption, particularly in low-income regions. This study concludes that a single pathway is insufficient. An integrated portfolio supported by modernized standards, targeted policy incentives, expanded access to SCMs and waste fuels, scaled CCUS investment, and international collaboration is essential to bridge the gap between climate ambition and industrial implementation. Key recommendations include modernizing cement standards to support higher clinker replacement, providing incentives for energy-efficient upgrades, scaling CCUS through joint investment and carbon pricing and expanding access to biomass and waste-derived fuels. Full article

Buildings significantly impact the environment, accounting for 36% of global final energy consumption and 37% of total carbon emissions. Therefore, reducing energy consumption and mitigating carbon emissions in the building sector is of paramount importance. To achieve this, several factors should be considered. Among them, building occupants are key drivers in the operation of building services that directly influence energy consumption and energy-related emissions. In this paper, one year of raw energy consumption data from a high-density higher education building in the UK was processed to study the correlation between energy consumption and occupancy level. Additionally, a simulation model was developed to measure the impact of occupancy numbers on building energy consumption. Various data analyses were performed, including correlation, regression, and sensitivity analysis. The results demonstrate a strong correlation between occupancy numbers and electricity consumption of 71.5%. Conversely, 18% was found between occupancy numbers and heat energy consumption, indicating no correlation. The sensitivity analysis results on the impact of changing occupancy numbers in the simulated model, ranging from –30% to +30%, aligned with the results of the analyses performed. Full article

Urban community gardens are valued for promoting sustainable food production, yet the accumulation of toxic heavy metals in city soils can present both ecological and public health risks. Therefore, this study was aimed at assessing the environmental and health risks of toxic heavy metals in community gardens soil contaminated by an industrial fire hazard in New Brunswick, Canada. Both top and subsoil soil samples were collected at Carleton community garden. The collected samples were examined for toxic heavy metals using inductively coupled plasma optical emission spectrometry and inductively coupled plasma mass spectrometry. Ecological risks were evaluated through the ecological risk factor and the potential ecological risk index, while human health risks were determined using a standard human health risk assessment approach. The mean concentration of Pb, Zn, Cu, and Sn exceeded permissible limits when compared to the Canadian soil quality guidelines and upper continental crust values. Findings from the ecological risk assessment showed that all metals were associated with low risk, except for nickel, which posed a high ecological risk across both soil layers. PERI results revealed a low overall ecological threat. The human health risk analysis indicated that children could face non-carcinogenic and carcinogenic risks from As exposure, while adults were not at risk from any of the studied metals. These findings identify arsenic as the primary contaminant of concern, with children representing the most vulnerable population, emphasizing the necessity for targeted mitigation strategies and protective measures to reduce their exposure. The results of this study can inform interventions aimed at safeguarding both environmental and public health, while also raising awareness about the presence and risks of toxic heavy metals, ultimately contributing to the protection of human health and the broader ecosystem. Full article

Tackling climate change in the public–private partnership (PPP) infrastructure sector requires radical transformation of projects to make them resilient against climate risks and free from excessive carbon emissions. Types of PPP infrastructure such as transport, power plants, hospitals, schools and residential buildings experience more than 30% of global climate change risks. Therefore, this study aims to examine the interrelationships between the climate risk management strategies in PPP infrastructure projects. The first step in conducting this research was to identify the strategies through a comprehensive literature review. The second step was data collection from 147 PPP stakeholders with a questionnaire. The third step was analysing the interrelationships between the strategies using a partial least square–structural equation model approach. The findings include green procurement, defined climate-resilient contract award criteria, the identification of climate-conscious projects and feasible contract management strategies. The results provide understanding of actionable measures to counter climate risks and they encourage PPP stakeholders to develop and promote climate-friendly strategies to mitigate climate crises in the PPP sector. The results also serve as foundational information for future studies to investigate climate change risk management strategies in PPP research. Full article

Background/Objectives: Behavioral variant frontotemporal dementia (bvFTD), the most prevalent clinical subtype within the frontotemporal lobar degeneration spectrum disorders, is characterized by early and prominent changes that significantly disrupt everyday functioning. This study aims to identify the key correlates of functional status in bvFTD by investigating the relative contributions of cognitive deficits, behavioral disturbances, personality changes, and brain perfusion abnormalities. Additionally, it seeks to develop a theoretical framework to elucidate how these factors may interconnect and shape unique functional profiles. Methods: A total of 26 individuals diagnosed with bvFTD were recruited from the 2nd Neurology Clinic of “AHEPA” University Hospital in Thessaloniki, Greece, and underwent a comprehensive neuropsychological assessment to evaluate their cognitive functions. Behavioral disturbances, personality traits, and functional status were rated using informant-based measures. Regional cerebral blood flow was assessed using Single Photon Emission Computed Tomography (SPECT) imaging to evaluate brain perfusion patterns. Penalized Least Absolute Shrinkage and Selection Operator (LASSO) regression analysis was performed to identify the most robust correlates of functional impairment, followed by path analyses using structural equation modeling to explore how these factors may interrelate and contribute to functional disability. Results: The severity of negative behavioral symptoms (e.g., apathy), conscientiousness levels, and performance on neuropsychological measures of semantic verbal fluency, visual attention, visuomotor speed, and global cognition were identified as the strongest correlates of performance in activities of daily living. Neuroimaging analysis revealed hypoperfusion in the right prefrontal (Brodmann area 8) and inferior parietal (Brodmann area 40) cortices as statistically significant neural correlates of functional impairment in bvFTD. Path analyses indicated that reduced brain perfusion was associated with attentional and processing speed deficits, which were further linked to more severe negative behavioral symptoms. These behavioral disturbances were subsequently correlated with declines in global cognition and conscientiousness, which were ultimately associated with poorer daily functioning. Conclusions: Hypoperfusion in key prefrontal and parietal regions, along with the subsequent cognitive and neuropsychiatric manifestations, appears to be associated with the pronounced functional limitations observed in individuals with bvFTD, even in early stages. Understanding the key determinants of the disease can inform the development of more targeted, personalized treatment strategies aimed at mitigating functional deterioration and enhancing the quality of life for affected individuals. Full article

Bulgaria continues to face serious challenges related to air quality. To mitigate traffic-related air pollution and in line with the European regulations, the Metropolitan Municipal Council of Sofia has adopted and introduced low-emission zones (LEZs) in the city centre. The goal of this study is to address the specific needs of urban planning in the city in support of local decision-making. A bespoke emission inventory was developed for the LEZs in Sofia, and high-resolution numerical simulations (100 m resolution) were carried out to assess the effect of the measures implemented to reduce emissions in the central part of the city. The results show a decrease in nitrogen dioxide concentrations along major roads and intersections, but projected concentrations will still be high. No significant improvement is expected for particulate matter pollution due to the limitations of this study. High-resolution (100 m) emission inventories of domestic heating, minor roads, and bare soil surfaces, the major sources of particulate matter pollution, are not included in this study. An integrated model is needed to analyse and compare different scenarios for the development of the transport system, and the gradual introduction of LEZs must be accompanied by a number of other additional measures and actions. Full article

Climate change is intensifying hydrological extremes, posing growing threats to the safety and operational reliability of embankment dams worldwide, particularly those in regions susceptible to heavy rainfall and flooding. This study evaluates the overtopping risk for Batu Dam, a critical flood mitigation and water supply structure near Kuala Lumpur, Malaysia, under future climate scenarios, with the aim of informing risk-informed dam safety strategies. Using historical hydrological data (1975–2020) and downscaled climate projections from the CMIP5 database under three Representative Concentration Pathways (RCP4.5, RCP6.0, RCP8.5), we conducted flood routing simulations and probabilistic risk assessments employing the iPRESAS software. Our results demonstrate that the annual probability of overtopping increases substantially under higher-emission scenarios, reaching up to 0.08% by the late century under RCP8.5, driven by increased frequency and intensity of extreme rainfall events. These projections highlight significant spillway capacity limitations and underscore the heightened risk of downstream consequences, including economic losses exceeding RM 200 million and potential loss of life surpassing 2900 individuals in worst-case scenarios. The findings confirm the urgent need for both structural adaptations, such as spillway expansion and crest elevation, and non-structural measures, including enhanced real-time monitoring and early warning systems. This integrated approach offers a robust and replicable framework for strengthening dam safety under evolving climate conditions. Full article

At the international level, new measures, policies, and technologies are being developed to reduce greenhouse gas emissions and, more broadly, air pollutants. Road transportation is one of the main contributors to such emissions, as vehicles are extensively used in logistics operations, and many fleet owners of fossil-fueled trucks are adopting new technologies such as electric, hybrid, and hydrogen-based vehicles. This paper addresses the Hybrid Fleet Capacitated Vehicle Routing Problem with Time Windows (HF-CVRPTW), with the objectives of minimizing costs and mitigating environmental impacts. A mixed-integer linear programming model is developed, incorporating split deliveries, scheduled arrival times at stores, and a carbon cap-and-trade mechanism. The model is tested on a real case study provided by Decathlon, evaluating the performance of internal combustion engine (ICE), electric (EV), and hydrogen fuel cell (HV) vehicles. Results show that when considering economic and emission trading costs, the optimal fleet deployment priority is to use ICE vehicles first, followed by EVs and then HVs, but considering only total emissions, the result is the reverse. Further analysis explores the conditions under which alternative fuel, electricity, or hydrogen prices can achieve competitiveness, and a further analysis investigates the impact of different electricity generation and hydrogen production pathways on overall indirect emissions. Full article

To comprehensively explore the net carbon balance within cropland systems subject to diverse tillage practices (Down-slope cultivation (CK), Subsoiling tillage (SF), Ridge to district field (RF), Ridge to district field + subsoiling tillage (RF-S), Transverse slope planting (TP), Transverse slope planting + ridge to district field (TP-R), Transverse slope planting + subsoiling tillage (TP-S)), a series of well-designed field experiments were meticulously carried out. The CO₂ emission intensity of soil heterotrophic respiration, CH₄ emission intensity, carbon loss in runoff, carbon emissions from farmland materials, dry matter mass and carbon content of different crop organs after harvest were measured for the six different tillage practices. Moreover, the annual and seasonal variations in farmland soil carbon pools under different treatments were analyzed using the net carbon flux (NCF) of the cropland system. The results indicated that, under different tillage practices, the CO₂ emission intensity of soil heterotrophic respiration in each regime across different years generally exhibited a pattern of increasing initially and then decreasing, reaching its peak during the filling stage (pod-setting stage). The RF regime significantly reduced the CO₂ emissions from soil heterotrophic respiration (p < 0.05). The CH₄ emissions in each regime across different years also demonstrated an overall tendency of rising initially and subsequently declining, with an alternating positive–negative pattern, reaching its peak during the jointing stage (branching stage). The SF regime significantly decreased the CH₄ emissions (p < 0.05). The regimes with cross-slope tillage significantly reduced the carbon loss in runoff (p < 0.05). Throughout every year, the NPP of crops under the TP-S regime attained its peak value (p < 0.05). The RF regime effectively increased the NPP of crops, reduced the soil heterotrophic respiration CO₂ emissions and the carbon loss in runoff, and its NCF value reached the maximum level (p < 0.05), presenting a weak carbon “source”. Overall, ridged-field (RF) effectively curbs greenhouse gas emissions, boosts farmland carbon sequestration, and mitigates soil fertility decline. Full article