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28 pages, 5175 KB  
Article
Buckling Characteristics of Bio-Inspired Helicoidal Laminated Composite Spherical Shells Under External Normal and Torsional Loads Subjected to Elastic Support
by Mohammad Javad Bayat, Amin Kalhori, Masoud Babaei and Kamran Asemi
Buildings 2025, 15(17), 3165; https://doi.org/10.3390/buildings15173165 - 3 Sep 2025
Abstract
Spherical shells exhibit superior strength-to-geometry efficiency, making them ideal for industrial applications such as fluid storage tanks, architectural domes, naval vehicles, nuclear containment systems, and aeronautical and aerospace components. Given their critical role, careful attention to the design parameters and engineering constraints is [...] Read more.
Spherical shells exhibit superior strength-to-geometry efficiency, making them ideal for industrial applications such as fluid storage tanks, architectural domes, naval vehicles, nuclear containment systems, and aeronautical and aerospace components. Given their critical role, careful attention to the design parameters and engineering constraints is essential. The present paper investigates the buckling responses of bio-inspired helicoidal laminated composite spherical shells under normal and torsional loading, including the effects of a Winkler elastic medium. The pre-buckling equilibrium equations are derived using linear three-dimensional (3D) elasticity theory and the principle of virtual work, solved via the classical finite element method (FEM). The buckling load is computed using a nonlinear Green strain formulation and a generalized geometric stiffness approach. The shell material employed in this study is a T300/5208 graphite/epoxy carbon fiber-reinforced polymer (CFRP) composite. Multiple helicoidal stacking sequences—linear, Fibonacci, recursive, exponential, and semicircular—are analyzed and benchmarked against traditional unidirectional, cross-ply, and quasi-isotropic layups. Parametric studies assess the effects of the normal/torsional loads, lamination schemes, ply counts, polar angles, shell thickness, elastic support, and boundary constraints on the buckling performance. The results indicate that quasi-isotropic (QI) laminate configurations exhibit superior buckling resistance compared to all the other layup arrangements, whereas unidirectional (UD) and cross-ply (CP) laminates show the least structural efficiency under normal- and torsional-loading conditions, respectively. Furthermore, this study underscores the efficacy of bio-inspired helicoidal stacking sequences in improving the mechanical performance of thin-walled composite spherical shells, exhibiting significant advantages over conventional laminate configurations. These benefits make helicoidal architectures particularly well-suited for weight-critical, high-performance applications in aerospace, marine, and biomedical engineering, where structural efficiency, damage tolerance, and reliability are paramount. Full article
(This article belongs to the Special Issue Computational Mechanics Analysis of Composite Structures)
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17 pages, 3444 KB  
Article
Determination of Orbital Parameters of Binary Star Systems Using the MCMC Method
by Nadezhda L. Vaidman, Shakhida T. Nurmakhametova, Anatoly S. Miroshnichenko, Serik A. Khokhlov, Aldiyar T. Agishev, Azamat A. Khokhlov, Yeskendyr K. Ashimov and Berik S. Yermekbayev
Galaxies 2025, 13(5), 101; https://doi.org/10.3390/galaxies13050101 - 2 Sep 2025
Abstract
We present new spectroscopic orbits for the bright binaries Mizar B, 3 Pup, ν Gem, 2 Lac, and ϕ Aql. Our analysis is based on medium-resolution (R 12,000) échelle spectra obtained with the 0.81-m telescope and fiber-fed eShel spectrograph of the [...] Read more.
We present new spectroscopic orbits for the bright binaries Mizar B, 3 Pup, ν Gem, 2 Lac, and ϕ Aql. Our analysis is based on medium-resolution (R 12,000) échelle spectra obtained with the 0.81-m telescope and fiber-fed eShel spectrograph of the Three College Observatory (Greensboro, NC, USA) between 2015 and 2024. Orbital elements were inferred with an affine-invariant Markov-chain Monte-Carlo sampler; convergence was verified through the integrated autocorrelation time and the Gelman–Rubin statistic. Errors quote the 16th–84th-percentile credible intervals. Compared with previously published orbital solutions for the studied stars, our method improves the root-mean-square residuals by 25–50% and bring the 1σ uncertainties on the radial velocity (RV) semi-amplitudes down to 0.02–0.15 km s1. These gains translate into markedly tighter mass functions and systemic RVs, providing a robust dynamical baseline for future interferometric and photometric studies. A complete Python analysis pipeline is openly available in a GitHub repository, ensuring full reproducibility. The results demonstrate that a Bayesian RV analysis with well-motivated priors and rigorous convergence checks yields orbital parameters that are both more precise and more reproducible than previous determinations, while offering fully transparent uncertainty budgets. Full article
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13 pages, 9181 KB  
Article
Characterization of Submicron Ni-, Co-, and Fe-Doped ZnO Fibers Fabricated by Electrospinning and Atomic Layer Deposition
by Blagoy Spasov Blagoev, Borislava Georgieva, Albena Paskaleva, Ivalina Avramova, Peter Tzvetkov, Kirilka Starbova, Nikolay Starbov, Krastyo Buchkov, Vladimir Mehandzhiev, Lyubomir Slavov, Penka Terziyska and Dencho Spasov
Coatings 2025, 15(9), 1022; https://doi.org/10.3390/coatings15091022 - 2 Sep 2025
Abstract
Hollow coaxial double-shell submicron fibers were fabricated by combining electrospinning and atomic layer deposition (ALD). Polyvinyl alcohol (PVA) fibers were electrospun to serve as templates for the subsequent atomic layer deposition (ALD) of ZnO doped with transition metals (TM: Ni, Co, and Fe). [...] Read more.
Hollow coaxial double-shell submicron fibers were fabricated by combining electrospinning and atomic layer deposition (ALD). Polyvinyl alcohol (PVA) fibers were electrospun to serve as templates for the subsequent atomic layer deposition (ALD) of ZnO doped with transition metals (TM: Ni, Co, and Fe). An inner shell of amorphous Al2O3 was first deposited at low-temperature ALD to protect the polymer template. The PVA core was then removed through high-temperature annealing in air. Finally, a top shell of TM-doped ZnO was deposited at an elevated temperature within the ALD window for ZnO. The morphology, microstructure, elemental composition, and crystallinity of these submicron hollow double-shell fibers were thoroughly investigated using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Full article
(This article belongs to the Section Surface Characterization, Deposition and Modification)
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23 pages, 4160 KB  
Article
Numerical Evaluation of Embedded I-Section Strengthening in Axially Loaded Composite Concrete-Filled Stainless Steel Tubes
by Murtadha Noori Sadeq, Hussein Kareem Mohammad, Abbas A. Allawi, Ahmed W. Al Zand, Mohammed Riyadh Khalaf, Ali Hussain Ali Al-Ahmed, Teghreed Hassan Ibrahim and Ayman El-Zohairy
J. Compos. Sci. 2025, 9(9), 470; https://doi.org/10.3390/jcs9090470 - 2 Sep 2025
Abstract
To enhance the structural performance of concrete-filled steel tube (CFST) columns, various strengthening techniques have been proposed, including the use of internal steel stiffeners, external wrapping with carbon fiber-reinforced polymer (CFRP) sheets, and embedded steel elements. However, the behavior of concrete-filled stainless-steel tube [...] Read more.
To enhance the structural performance of concrete-filled steel tube (CFST) columns, various strengthening techniques have been proposed, including the use of internal steel stiffeners, external wrapping with carbon fiber-reinforced polymer (CFRP) sheets, and embedded steel elements. However, the behavior of concrete-filled stainless-steel tube (CFSST) columns remains insufficiently explored. This study numerically investigates the axial performance of square CFSST columns internally strengthened with embedded I-section steel profiles under biaxial eccentric loading. Finite element (FE) simulations were conducted using ABAQUS v. 6.2, and the developed models were validated against experimental results from the literature. A comprehensive parametric study was performed to evaluate the effects of several variables, including concrete compressive strength (fcu), stainless-steel yield strength (fy), the depth ratio between the stainless-steel tube and the internal I-section (Dst/Dsi), biaxial eccentricities (ex and ey), and tube thickness (t). The results demonstrated that the axial performance of CFSST columns was most significantly influenced by increasing the Dst/Dsi ratio and load eccentricities. In contrast, increasing the concrete strength and steel yield strength had relatively modest effects. Specifically, the ultimate axial capacity increased by 9.97% when the steel yield strength rose from 550 MPa to 650 MPa and by 33.72% when the tube thickness increased from 3.0 mm to 5.0 mm. A strength gain of only 10.23% was observed when the concrete strength increased from 30 MPa to 60 MPa. Moreover, the energy absorption index of the strengthened columns improved in correlation with the enhanced axial capacities. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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11 pages, 3753 KB  
Article
Design and Characteristic Study of Terahertz Photonic Crystal Fiber for Orbital Angular Momentum Modes
by Jingxuan Yang and Wei Li
Photonics 2025, 12(9), 881; https://doi.org/10.3390/photonics12090881 - 31 Aug 2025
Viewed by 93
Abstract
In this paper, we design a new type of terahertz orbital angular momentum (OAM) optical fiber with excellent transmission characteristics over a wide frequency range. Within the 0.8–1.8 THz frequency band, it shows stable support for transmission of the fifth-order OAM mode. Its [...] Read more.
In this paper, we design a new type of terahertz orbital angular momentum (OAM) optical fiber with excellent transmission characteristics over a wide frequency range. Within the 0.8–1.8 THz frequency band, it shows stable support for transmission of the fifth-order OAM mode. Its dispersion control effect is excellent; it maintains the confinement loss of most modes at the extremely low level of 10−10 dB/m; its maximum dispersion is only 5.57 ps/THz/cm; and its effective mode field area is greater than 1.11 × 10−7 m2. These characteristics jointly endow this optical fiber with broad application prospects and significant research value in the field of terahertz communication. With the continuous advancement of technology in this field, this optical fiber is expected to become a key component when building efficient, reliable, and large-capacity communication systems. Full article
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26 pages, 3290 KB  
Article
Numerical Analysis on Mechanical Properties of Different Fiber-Reinforced Cold-Formed Steel–Concrete Composite Corner Columns
by Mengyao Li, Yi Hu, Lanzhe Rao, Liqiang Jiang, Jingbin Li, Shizhong Zhou, Hongyu Sun, Shi Peng, Xia Pang, Yuanjun Chen, Jun Hu and Ping Xie
Polymers 2025, 17(17), 2365; https://doi.org/10.3390/polym17172365 - 30 Aug 2025
Viewed by 149
Abstract
To overcome brittle failure in conventional cold-formed steel–concrete (CFS-C) corner columns, this paper used fiber-reinforced concrete to replace ordinary concrete, investigating failure mechanisms and performance through systematic numerical simulations. A finite element model (FEM) was established and validated by experiments, and the errors [...] Read more.
To overcome brittle failure in conventional cold-formed steel–concrete (CFS-C) corner columns, this paper used fiber-reinforced concrete to replace ordinary concrete, investigating failure mechanisms and performance through systematic numerical simulations. A finite element model (FEM) was established and validated by experiments, and the errors for ultimate capacity were within 10%. A series of numerical models was established for parametric analyses focusing on the effects of the parameters of polypropylene fiber (PF), carbon fiber (CF), steel fiber (SF), and bamboo fiber (BF) with different volume dosages and the thickness of cold-formed steel (CFS) on the axial compression ultimate capacity and corresponding displacement of CFS composite corner columns. The results indicated that (1) PF effectiveness was dependent on steel thickness: thicker steel suppressed micro-defects, activated the toughening potential of PF, and increased the ultimate capacity of the columns by 24.8%. (2) CF had a critical dosage of 0.4%: at this dosage, CF increased the column’s ultimate capacity by 14.1% through stress redistribution, while when the dosage exceeded this value, fiber agglomeration caused a reduction in the column’s strength, with a maximum decrease of 16.2%. (3) SF effectiveness showed a linear increase: at a dosage of 1.6%, SF formed a synergistic three-dimensional bridging network and generated a confinement effect, increasing the column’s ultimate capacity by 36.5% and displacement by 92.2%. (4) BF mainly improved the ductility of columns: through crack bridging and pull-out energy dissipation, BF increased column displacement by 33.2%. (5) The modified Eurocode 4 formula could reduce the calculation error of ultimate capacity from 6.3% to within 1%. The findings guide optimal fiber selection and dosage in practice, promoting such columns’ use in seismic and load-bearing structures. Full article
19 pages, 3164 KB  
Article
Deteriorated Cyclic Behaviour of Corroded RC Framed Elements: A Practical Proposal for Their Modelling
by José Barradas-Hernández, Dariniel Barrera-Jiménez, Irving Ramírez-González, Franco Carpio-Santamaría, Alejandro Vargas-Colorado, Sergio Márquez-Domínguez, Rolando Salgado-Estrada, José Piña-Flores and Abigail Zamora-Hernández
Buildings 2025, 15(17), 3110; https://doi.org/10.3390/buildings15173110 - 29 Aug 2025
Viewed by 155
Abstract
Corrosion is a phenomenon that significantly impacts the durability of reinforced concrete (RC) structures, particularly in highly corrosive environments like coastal regions. The existing numerical modelling often relies on complex approaches that are impractical for structural assessment. For this reason, this study proposes [...] Read more.
Corrosion is a phenomenon that significantly impacts the durability of reinforced concrete (RC) structures, particularly in highly corrosive environments like coastal regions. The existing numerical modelling often relies on complex approaches that are impractical for structural assessment. For this reason, this study proposes a simplified numerical modelling approach to simulate the cyclic behaviour of existing RC framed structures with corrosion levels (η) below 25%. The proposed modelling employs concentrated plasticity hinges for beams and fiber sections for columns, incorporating corrosion-induced degradation through modified backbone curves and material properties based on the corrosion level of the structural element. The modelling approach was validated against experimental results from the literature; the proposed model adequately captures hysteretic energy, lateral load, and deformation capacities, with maximum errors of 11% for maximum lateral load, 12% for ultimate load, and 33% for dissipated energy in RC frames. For isolated columns, the errors were 11, 12, and 22%, respectively. In addition, a maximum difference of 7% was found in the lateral load capacity of the corroded frames associated with the Life Safety limit state. Finally, it was concluded that the proposed methodology is suitable for representing the cyclic behaviour of corroded RC columns and frames and provides engineers with a tool to evaluate the behaviour of corroded structures without resorting to complex models. Full article
(This article belongs to the Special Issue Seismic Performance and Durability of Engineering Structures)
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15 pages, 3722 KB  
Article
Effect of Curing Parameter on the Performance of Electric-Induced Heating-Cured Carbon Fiber-Reinforced Conductive Cement-Based Materials: Experiment and Finite Element Method Analysis
by Jiabin Xie, Yishu Zhang, Weichen Tian, Zhanlin Zhang and Wei Wang
Materials 2025, 18(17), 4057; https://doi.org/10.3390/ma18174057 - 29 Aug 2025
Viewed by 186
Abstract
Winter concrete construction is a pivotal engineering issue that needs to be addressed due to the failure of cementitious materials to hydrate under severely low temperatures. To solve the problem, the electric-induced heating curing (EIH) method was presented to prepare cement mortar (CF-CM) [...] Read more.
Winter concrete construction is a pivotal engineering issue that needs to be addressed due to the failure of cementitious materials to hydrate under severely low temperatures. To solve the problem, the electric-induced heating curing (EIH) method was presented to prepare cement mortar (CF-CM) at an environmental temperature of −20 °C. The influence of some key parameters, including carbon fiber (CF) content (0–0.9 vol%), preparation methods, and EIH curing regimes (constant power vs. constant voltage; frequency: 30–70 Hz), on the performance of CF-CM were examined. Furthermore, the curing temperature of EIH-cured specimens were simulated based on COMSOL Multiphysics software. The results demonstrated that the electrical percolation threshold of CFs inside the specimen was 0.6 vol%. EIH curing achieved 1-day early strength equivalent to 2 days of standard curing, and increasing CF content showed little influence on the mechanical properties of CF-CM specimens. Moreover, constant-power EIH maintained stable curing temperatures (>50 °C), outperforming unstable constant voltage curing. Applied frequency (30–70 Hz) exhibited negligible impact on compressive strength, validating standard 50 Hz AC for practical application. Furthermore, the optimal EIH power density identified based on COMSOL Multiphysics software was 667 W/m2, successfully maintaining specimen temperatures between 60 °C and 70 °C to enable rapid strength development under sub-zero conditions, laying a foundation for the use of COMSOL in the guidance of EIH curing regime design. This work provides a scientifically grounded and applicable solution for winter concrete construction. Full article
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15 pages, 4033 KB  
Article
Microstructural and Chemical Analysis of PBT/Glass Fiber Composites: Influence of Fiber Content and Manufacturing on Composite Performance
by Oumayma Hamlaoui, Riadh Elleuch, Hakan Tozan, Imad Tawfiq and Olga Klinkova
Fibers 2025, 13(9), 117; https://doi.org/10.3390/fib13090117 - 28 Aug 2025
Viewed by 208
Abstract
This paper provides an in-depth analysis of the microstructural characteristics and the chemical content of Polybutylene Terephthalate (PBT) composites that have different contents of Glass Fiber (GF). Blending of VALOX 420 (30 wt% GF/PBT) with unreinforced VALOX 310 allowed the composites to be [...] Read more.
This paper provides an in-depth analysis of the microstructural characteristics and the chemical content of Polybutylene Terephthalate (PBT) composites that have different contents of Glass Fiber (GF). Blending of VALOX 420 (30 wt% GF/PBT) with unreinforced VALOX 310 allowed the composites to be prepared, with control of the concentration and distribution of the GF. The GF reinforcement and PBT matrix were characterized by an advanced microstructural spectrum and spatial analysis to show the influence of fiber density, dispersion, and chemical composition on performance. Findings indicate that GF content has a profound effect on microstructural properties and damage processes, especially traction effects in various regions of the specimen. These results highlight the significance of accurate control of GF during fabrication to maximize durability and performance, which can be used to inform the design of superior PBT/GF composites in challenging engineering applications. The implications of these results are relevant to a number of high-performance sectors, especially in automotive, electrical, and consumer electronic industries, where PBT/GF composites are found in extensive use because of their outstanding mechanical strength, dimensional stability, and thermal resistance. The main novelty of the current research is both the microstructural and chemical assessment of PBT/GF composites in different fiber contents, and this aspect is rather insufficiently studied in the literature. Although the mechanical performance or macro-level aging effects have been previously assessed, the Literature usually did not combine elemental spectroscopy or spatial microstructural mapping to correlate the fiber distribution with the damage mechanisms. Further, despite the importance of GF reinforcement in achieving the right balance between mechanical, thermal, and electrical performance, not much has been conducted in detail to describe the correlation between the microstructure and the evolution of damage in short-fiber composites. Conversely, this paper will use the superior spatial elemental analysis to bring out the effects of GF content and dispersion on micro-mechanisms like interfacial traction, cracking of the matrix, and fiber fracture. We, to the best of our knowledge, are the first to systematically combine chemical spectrum analysis with spatial mapping of PBT/GF systems with varied fiber contents—this allows us to give actionable information on material design and optimized manufacturing procedures. Full article
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23 pages, 4352 KB  
Article
Quantifying Inter-Ply Friction and Clamping Effects via an Experimental–Numerical Framework: Advancing Non-Coherent Deformation Control of Uncured Metal–Fiber-Reinforced Polymer Laminates
by Yunlong Chen and Shichen Liu
Polymers 2025, 17(17), 2330; https://doi.org/10.3390/polym17172330 - 28 Aug 2025
Viewed by 249
Abstract
Pre-stacked uncured metal–fiber-reinforced polymer (FRP) laminates, which are critical for aerospace components like double-curved fuselage panels, wing ribs, and engine nacelles, exhibit better deformation behavior than their fully cured counterparts. However, accurate process simulation requires precise material characterization and process optimization to achieve [...] Read more.
Pre-stacked uncured metal–fiber-reinforced polymer (FRP) laminates, which are critical for aerospace components like double-curved fuselage panels, wing ribs, and engine nacelles, exhibit better deformation behavior than their fully cured counterparts. However, accurate process simulation requires precise material characterization and process optimization to achieve a defect-free structural design. This study focuses on two core material behaviors of uncured laminates—inter-ply friction at metal–prepreg interfaces and out-of-plane bending—and optimizes process parameters for their non-coherent deformation. Experimental tests included double-lap sliding tests (to quantify inter-ply friction) and clamped-beam bending tests (to characterize out-of-plane bending); a double-curved dome part was designed to assess the effects of the material constituent, fiber orientation, inter-ply friction, and clamping force, with validation via finite element modeling (FEM) in Abaqus software. The results indicate that the static–kinetic friction model effectively predicts inter-ply friction behavior, with numerical friction coefficient–displacement trends closely matching experimental data. Additionally, the flexural bending model showed that greater plastic deformation in metal layers increased bending force while reducing post-unloading spring-back depth. Furthermore, for non-coherent deformation, higher clamping forces improve FRP prepreg deformation and mitigate buckling, but excessive plastic deformation raises metal cracking risk. This work helps establish a combined experimental–numerical framework for the defect prediction and process optimization of complex lightweight components, which address the core needs of modern aerospace manufacturing. Full article
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16 pages, 3217 KB  
Article
Design of a Hybrid 3D-Printed Composite Material Based on Non-Woven Needle-Punched Fabrics with Radio-Absorbing Properties
by Victor Nazarov, Fedor Doronin, Alexander Dedov, Andrey Evdokimov, Georgy Rytikov and Mikhail Savel’ev
Polymers 2025, 17(17), 2324; https://doi.org/10.3390/polym17172324 - 27 Aug 2025
Viewed by 376
Abstract
The paper proposes a manufacturing technology for the non-woven/3D-printed (N3DP) hybrid material (HM) with improved radio-absorbing properties. We have fabricated the needle-punched non-woven felt and impregnated it with the carbon fibers containing UV-curable photopolymer resin. The functional 3D-printed layer was attached to the [...] Read more.
The paper proposes a manufacturing technology for the non-woven/3D-printed (N3DP) hybrid material (HM) with improved radio-absorbing properties. We have fabricated the needle-punched non-woven felt and impregnated it with the carbon fibers containing UV-curable photopolymer resin. The functional 3D-printed layer was attached to the highly porous, deformable polymer substrate by the fused deposition modeling (FDM) technique. The preliminary bulk modification of the filament was realized with the IR- and UV-pigment microcapsules filling. The combination of additive prototyping and non-woven needle-punched fabrics surface modification (by the electrically conductive elements 2D-periodic system applying) expands the frequency range of the electromagnetic radiation effective absorption. It provides the possibility of a reversible change in the color characteristics of the hybrid material surface under the influence of the UV and IR radiation. Full article
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11 pages, 1549 KB  
Article
Synthesis and Characterization of Titanium Layer with Fiber-like Morphology on HDPE by Plasma Treatment
by Erick Yair Vargas-Oliva, Carolina Hernández-Navarro, Violeta Guzman-Ayon, María del Pilar Jadige Ceballos-Muez, Ernesto David García-Bustos, Marco Antonio Doñu-Ruiz, Noé López-Perrusquia, Martin Flores-Martínez and Stephen Muhl-Saunders
Coatings 2025, 15(9), 995; https://doi.org/10.3390/coatings15090995 - 27 Aug 2025
Viewed by 390
Abstract
High-density polyethylene (HDPE) is widely used for different applications, but its low resistance to ultraviolet radiation, plastic deformation, chemical stability, and wear re-sistance limits its use in high-demand work environments. Modifying of the surface characteristics could improve the work efficiency of the parts [...] Read more.
High-density polyethylene (HDPE) is widely used for different applications, but its low resistance to ultraviolet radiation, plastic deformation, chemical stability, and wear re-sistance limits its use in high-demand work environments. Modifying of the surface characteristics could improve the work efficiency of the parts exposed to an aggressive environment. Plasma treatments change the surface characteristics with deposition of a coating or by modifying the surface’s energy, varying the surface properties. This study presents the mechanical and tribological properties of a titanium (Ti) layer with fiber-like morphology produced on HDPE surfaces by plasma treatment involving plasma etching and the deposition of Ti atoms, through DC magnetron sputtering. On the HDPE substrates grew up Ti layer with fibers-like morphology with a diameter of 1.6 ± 0.44 μm. These fibers were elemental composed by 91.5 ± 0.9% Ti and 8.5 ± 0.6% O with α-Ti phase combined with HDPE crystalline structure. The Ti coating increased the hardness of the substrate and showed a good adhesion to HDPE surface. During the sliding test, the Ti layer with fiber-like morphology exhibited plastic deformation and debris accumulation, leading to the formation of a tribolayer without layer detachment. Notably, no detachment of the layer was observed, effectively protected the polymer surface, and enhanced its performance for tribological applications. Full article
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19 pages, 1833 KB  
Article
Exploring the Underlying Mechanisms of Reduced Elasticity in PA6/PA66 Bicomponent Melt-Spun Fibers: An Investigation of Viscoelastic Properties and Simulation Analysis
by Ali Abbas, Shengming Zhang, Huaping Wang, Jing Wu, Peng Ji and Chaosheng Wang
Polymers 2025, 17(17), 2312; https://doi.org/10.3390/polym17172312 - 27 Aug 2025
Viewed by 331
Abstract
This study conducts a detailed viscoelastic simulation of the side-by-side PA6/PA66 bicomponent melt spinning process to investigate the mechanisms behind reduced fiber elasticity. A two-dimensional (2D) axisymmetric finite element model was developed using ANSYS Polyflow, incorporating the Phan–Thien–Tanner (PTT) constitutive equation and a [...] Read more.
This study conducts a detailed viscoelastic simulation of the side-by-side PA6/PA66 bicomponent melt spinning process to investigate the mechanisms behind reduced fiber elasticity. A two-dimensional (2D) axisymmetric finite element model was developed using ANSYS Polyflow, incorporating the Phan–Thien–Tanner (PTT) constitutive equation and a non-isothermal crystallization model. Simulation outcomes were validated with experimental and published data, showing close agreement in fiber radius, velocity, and temperature profiles (within 8% deviation). Results indicate that the dominance of the higher-viscosity PA66 phase induces uneven stress distributions and localized crystallization, leading to decreased elastic recovery. Higher winding speeds amplify this effect. This work offers a predictive framework for optimizing industrial melt spinning conditions to improve elasticity in bicomponent fibers. Key results indicate that the dominance of the PA66 component—due to its higher melt viscosity—leads to uneven stress distribution, elevated tensile stress, and localized crystallinity peaks along the spin line. These factors collectively contribute to reduced elastic recovery in the fiber. Moreover, increased winding speeds amplify axial stress and crystallinity disparities, further exacerbating the stiffness of the final product. In contrast, better elasticity was associated with lower pressure drop, balanced crystallinity, and minimized axial velocity differences between the two polymer phases. The findings offer valuable insights into optimizing industrial melt spinning processes to enhance fiber elasticity. This research not only improves fundamental understanding of viscoelastic flow behavior in bicomponent spinning but also provides a predictive framework for tailoring mechanical properties of fibers through process and material parameter adjustments. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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27 pages, 9585 KB  
Article
Shock Response Characteristics and Equation of State of High-Mass-Fraction Pressed Tungsten Powder/Polytetrafluoroethylene-Based Composites
by Wei Zhu, Weihang Li, Wenbin Li, Xiaoming Wang and Wenjin Yao
Polymers 2025, 17(17), 2309; https://doi.org/10.3390/polym17172309 - 26 Aug 2025
Viewed by 344
Abstract
Tungsten powder/polytetrafluoroethylene (W/PTFE) composites have the potential to replace traditional metallic materials as casings for controllable power warheads. Under explosive loading, they generate high-density and relatively uniformly distributed metal powder particles, thereby enhancing close-range impact effects while reducing collateral damage. To characterize the [...] Read more.
Tungsten powder/polytetrafluoroethylene (W/PTFE) composites have the potential to replace traditional metallic materials as casings for controllable power warheads. Under explosive loading, they generate high-density and relatively uniformly distributed metal powder particles, thereby enhancing close-range impact effects while reducing collateral damage. To characterize the material’s response under impact loading, plate impact tests were conducted to investigate the effects of tungsten content (70 wt%, 80 wt%, and 90 wt%) and tungsten particle size (200 μm, 400 μm, and 600 μm) on the impact behavior of the composites. The free surface velocity histories of the target plates were measured using a 37 mm single-stage light gas gun and a full-fiber laser interferometer (DISAR), enabling the determination of the shock velocity–particle velocity relationship to establish the equation of state. Experimental data show a linear relationship between shock velocity and particle velocity, with the 80 wt% and 90 wt% composites exhibiting similar shock velocities. The fitted slope increases from 2.792 to 2.957 as the tungsten mass fraction rises from 70 wt% to 90 wt%. With particle size increasing from 200 μm to 600 μm, the slope decreases from 3.204 to 2.756, while c0 increases from 224.7 to 633.3. Comparison of the Hugoniot pressure curves of different specimens indicated that tungsten content significantly affects the impact behavior, whereas variations in tungsten particle size have a negligible influence on the Hugoniot pressure. A high tungsten content with small particle size (e.g., 90 wt% with ~200 μm) improves the overall compressive properties of composite materials. Based on the experimental results, a mesoscale finite element model consistent with the tests was developed. The overall error between the numerical simulations and experimental results was less than 5% under various conditions, thereby validating the accuracy of the model. Numerical simulations revealed the coupling mechanism between tungsten particle plastic deformation and matrix flow. The strong rarefaction unloading effect initiated at the composite’s free surface caused matrix spallation and jetting. Multiple wave systems were generated at the composite–copper interface, whose interference and coupling ultimately resulted in a nearly uniform macroscopic pressure field. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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18 pages, 3724 KB  
Article
Failure Mechanisms of Basalt Fiber Concrete Under Splitting Tensile Tests and DEM Simulations
by Linlin Jiang, Chuan Zhao, Shaoxiong Zhang, Mingyue Qiu, Ruitong Zhang, Yifei Li, Wenbing Zhang and Shuyang Yu
Buildings 2025, 15(17), 3035; https://doi.org/10.3390/buildings15173035 - 26 Aug 2025
Viewed by 293
Abstract
To address the cracking problem caused by the weak tensile performance of concrete, this study investigates the failure mechanisms of basalt fiber-reinforced concrete under different fiber contents, single-blend, and mixed-blend schemes through splitting tensile tests and discrete element method (DEM) simulations. The tests [...] Read more.
To address the cracking problem caused by the weak tensile performance of concrete, this study investigates the failure mechanisms of basalt fiber-reinforced concrete under different fiber contents, single-blend, and mixed-blend schemes through splitting tensile tests and discrete element method (DEM) simulations. The tests employ 0.1–0.3% of 18 mm single-blend fibers and 6 mm:12 mm:18 mm (3:4:3) mixed-blend schemes, and PFC software is used to simulate crack propagation in fiber-reinforced concrete. The results show that the optimal 0.2% content of 18 mm single-blend fibers enhances the splitting tensile strength by 10.8%, whereas excessive 0.3% content reduces the strength by 7.8% due to poor dispersion. The mixed-blend scheme, via gradient crack-resisting effects of multi-scale fibers, increases the strength by 7.43% compared with the single-blend group at the same fiber content. DEM simulations reveal that fibers delay crack propagation through stress concentration transfer: single-blend fibers render tortuous crack paths, while mixed-blend fibers form three-dimensional crack networks, transforming the failure energy dissipation mode from single pull-out to multi-stage consumption. This research provides theoretical basis and optimization strategies for the anti-cracking design of basalt fiber-reinforced concrete. Full article
(This article belongs to the Special Issue Low Carbon and Green Materials in Construction—3rd Edition)
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