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Keywords = fiber-reinforced thermoplastic (FRTP)

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19 pages, 3437 KB  
Article
Sustainable Acrylic Thermoplastic Composites via Vacuum-Assisted Resin Infusion Molding: Evaluation and Comparison of Fabrics and Recycled Non-Woven Carbon Fiber as Reinforcement
by Sara Taherinezhad Tayebi, Tommaso Pini, Bruno Caruso, Matteo Sambucci, Irene Bavasso, Fabrizio Sarasini, Jacopo Tirillò and Marco Valente
J. Compos. Sci. 2025, 9(8), 441; https://doi.org/10.3390/jcs9080441 - 17 Aug 2025
Cited by 1 | Viewed by 2282
Abstract
Recently, environmental issues have compelled people worldwide to pursue sustainability and adopt circular economy practices across all engineering sectors, including polymer engineering and composite fabrication. A transition towards fabric-reinforced thermoplastics (FRTPs), a greener solution, has been recommended in recent years. On the other [...] Read more.
Recently, environmental issues have compelled people worldwide to pursue sustainability and adopt circular economy practices across all engineering sectors, including polymer engineering and composite fabrication. A transition towards fabric-reinforced thermoplastics (FRTPs), a greener solution, has been recommended in recent years. On the other hand, utilizing recovered reinforcing phases, such as recycled carbon fiber (rCF), has attracted tremendous attention. In this framework, the aim of this research is to investigate the performance of acrylic-based FRTPs (Elium® resin developed by Arkema). Woven virgin carbon fiber (vCF) and non-woven recycled carbon fiber (rCF) fabrics were used as reinforcement architectures for the fabrication of composites via resin infusion. The optimized formulation selected for the matrix showed flexural modulus and flexural strength of 5 GPa and 78 MPa, respectively. Composites prepared with woven vCF reached 36 GPa and 620 MPa values of flexural modulus and strength, respectively. The study of non-woven fabric is of particular interest, because the web is composed of recycled carbon fibers obtained from end-of-life (EoL) thermoset composite components. The results were promising; the flexural modulus reached 8 GPa, and the flexural strength was 113 MPa. Improvements are anticipated, especially in the parameters and conditions of the molding process. Full article
(This article belongs to the Special Issue Carbon Fiber Composites, 4th Edition)
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20 pages, 5397 KB  
Article
Continuously Formed Fiber-Reinforced Thermoplastic Composite Rebar for Concrete Reinforcement
by Jacob C. Clark, William G. Davids, Roberto A. Lopez-Anido, Andrew P. Schanck and Cody A. Sheltra
J. Compos. Sci. 2025, 9(7), 378; https://doi.org/10.3390/jcs9070378 - 18 Jul 2025
Cited by 2 | Viewed by 3481
Abstract
Despite the strength and ductility of steel reinforcing bars, their susceptibility to corrosion can limit the long-term durability of reinforced concrete structures. Fiber-reinforced polymer (FRP) reinforcing bars made with a thermosetting matrix offer corrosion resistance but cannot be field-bent, which limits flexibility during [...] Read more.
Despite the strength and ductility of steel reinforcing bars, their susceptibility to corrosion can limit the long-term durability of reinforced concrete structures. Fiber-reinforced polymer (FRP) reinforcing bars made with a thermosetting matrix offer corrosion resistance but cannot be field-bent, which limits flexibility during construction. FRP reinforcing bars made with fiber-reinforced thermoplastic polymers (FRTP) address this limitation; however, their high processing viscosity presents manufacturing challenges. In this study, the Continuous Forming Machine, a novel pultrusion device that uses pre-consolidated fiber-reinforced thermoplastic tapes as feedstock, is described and used to fabricate 12.7 mm nominal diameter thermoplastic composite rebars. Simple bend tests on FRTP rebar that rely on basic equipment are performed to verify its ability to be field-formed. The manual bending technique demonstrated here is practical and straightforward, although it does result in some fiber misalignment. Subsequently, surface deformations are introduced to the rebar to promote mechanical bonding with concrete, and tensile tests of the bars are conducted to determine their mechanical properties. Finally, flexural tests of simply-supported, 6 m long beams reinforced with FRTP rebar are performed to assess their strength and stiffness as well as the practicality of using FRTP rebar. The beam tests demonstrated the prototype FRTP rebar’s potential for reinforcing concrete beams, and the beam load–deformation response and capacity agree well with predictions developed using conventional structural analysis principles. Overall, the results of the research reported indicate that thermoplastic rebars manufactured via the Continuous Forming Machine are a promising alternative to both steel and conventional thermoset composite rebar. However, both the beam and tension test results indicate that improvements in material properties, especially elastic modulus, are necessary to meet the requirements of current FRP rebar specifications. Full article
(This article belongs to the Section Fiber Composites)
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13 pages, 10154 KB  
Article
An Improved Mampel Model of the Non-Isothermal Crystallization Kinetics of Fiber-Reinforced Thermoplastic Composites
by Zengrui Song, Huiming Ning, Feng Liu, Ning Hu and Youkun Gong
Materials 2024, 17(19), 4747; https://doi.org/10.3390/ma17194747 - 27 Sep 2024
Cited by 4 | Viewed by 1482
Abstract
Fiber-reinforced thermoplastic composites (FRTPs) are gaining increasing attention and widespread use in engineering applications due to their high specific strength and stiffness, excellent toughness, and recyclability. The mechanical properties of these composites are closely tied to their crystallization process, making it crucial to [...] Read more.
Fiber-reinforced thermoplastic composites (FRTPs) are gaining increasing attention and widespread use in engineering applications due to their high specific strength and stiffness, excellent toughness, and recyclability. The mechanical properties of these composites are closely tied to their crystallization process, making it crucial to accurately describe this phenomenon. Existing theoretical models for analyzing the non-isothermal crystallization of thermoplastic composites often face challenges relating to the complexity of obtaining multiple parameters and the difficulty of achieving a final relative crystallinity of 1. To address these issues, this paper introduces a novel functional form of the crystallization rate parameter K(T), tailored for engineering applications, and proposes an improved Mampel model. This model assumes K(T) to be zero before the onset of crystallization and also to be linearly dependent on temperature thereafter, ensuring that the final relative crystallinity reaches 1. The model requires only two easily accessible parameters: the initial crystallization temperature (Ts) and the linear slope (k). The simplicity of the model makes it particularly well suited to engineering applications. This provides a straightforward and effective tool for describing the non-isothermal crystallization kinetics of fiber-reinforced thermoplastic composites. Full article
(This article belongs to the Special Issue Advances in Functional Polymers and Nanocomposites)
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30 pages, 13814 KB  
Review
Advances in Resistance Welding of Fiber-Reinforced Thermoplastics
by Zhanyi Geng, Shibao Yu, Shiyuan Wang, Zengtai Tian, Zhonglin Gao, Kaifeng Wang and Yang Li
Materials 2024, 17(19), 4693; https://doi.org/10.3390/ma17194693 - 24 Sep 2024
Cited by 13 | Viewed by 3621
Abstract
Fiber-reinforced thermoplastics (FRTPs) have become a new generation of lightweight materials due to their superior mechanical properties, good weldability and environmental resistance, potential for recycling, etc. The market for FRTPs is expected to grow at a compound annual growth rate (CAGR) of 7.8% [...] Read more.
Fiber-reinforced thermoplastics (FRTPs) have become a new generation of lightweight materials due to their superior mechanical properties, good weldability and environmental resistance, potential for recycling, etc. The market for FRTPs is expected to grow at a compound annual growth rate (CAGR) of 7.8% from 2022 to 2030. Many researchers have been trying to solve the problems in their processing and joining process, and gradually expand their application. Resistance welding is one of the most suitable techniques to join FRTPs. This paper summarizes the research progress of FRTP resistance welding in terms of the basic process of FRTP resistance welding, factors affecting joint performance, joint failure behavior, numerical simulation, weld quality control, and resistance welding of thermoplastic/thermoset composites. The objective of this paper is to provide a deeper insight into the knowledge of FRTP resistance welding and provide reference for the further development and application of FRTP resistance welding. Full article
(This article belongs to the Special Issue Advanced Welding in Alloys and Composites)
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17 pages, 10597 KB  
Article
Effect of Carbon Nanofiber Distribution on Mechanical Properties of Injection-Molded Aramid-Fiber-Reinforced Polypropylene
by Tetsuo Takayama, Shunsuke Kobayashi, Yuuki Yuasa and Quan Jiang
Polymers 2024, 16(8), 1110; https://doi.org/10.3390/polym16081110 - 16 Apr 2024
Cited by 10 | Viewed by 3818
Abstract
The mechanical recycling of discarded plastic products as resources for environmental preservation has recently gained research attention. In this context, it is necessary to use waste materials for fiber-reinforced thermoplastics (FRTP). Glass and carbon fibers are often damaged by shear and compression during [...] Read more.
The mechanical recycling of discarded plastic products as resources for environmental preservation has recently gained research attention. In this context, it is necessary to use waste materials for fiber-reinforced thermoplastics (FRTP). Glass and carbon fibers are often damaged by shear and compression during melt-forming processes. To achieve a sustainable society, it is necessary for thermal recycling to produce minimal to no residue and for mechanical recycling to maintain the length of fibers used in FRTP to preserve their performance as a reinforcing agent. Aramid fibers (AFs) do not shorten during the melt-molding process, and their composites have excellent impact strength. On the other hand, plastics reinforced with glass or carbon fibers are reported to have a superior strength and modulus of elasticity compared to aramid fibers. This study investigates the dispersion of a carbon nanofiber (CNF), a whisker, as the third component in aramid-fiber-reinforced polypropylene (PP/AF). The results and discussion sections demonstrate how the dispersion of CNF in PP/AF can enhance the mechanical properties of injection-molded products without compromising their impact resistance. The proposed composition will have excellent material recyclability and initial mechanical properties compared to glass-fiber-reinforced thermoplastics. Full article
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13 pages, 4060 KB  
Article
Optimization of a Tapered Specimen Geometry for Short-Term Dynamic Tensile Testing of Continuous Fiber Reinforced Thermoplastics
by Florian Mischo and Sebastian Schmeer
J. Compos. Sci. 2024, 8(3), 93; https://doi.org/10.3390/jcs8030093 - 3 Mar 2024
Cited by 2 | Viewed by 2700
Abstract
Continuous fiber reinforced thermoplastics (cFRTP) are one of the most promising lightweight materials. For their use in structural components, reproducible and comparable material values have to be evaluated, especially at high strain rates. Due to their high stiffness and outstanding strength properties, the [...] Read more.
Continuous fiber reinforced thermoplastics (cFRTP) are one of the most promising lightweight materials. For their use in structural components, reproducible and comparable material values have to be evaluated, especially at high strain rates. Due to their high stiffness and outstanding strength properties, the evaluation of the material behavior at high strain rates is complex. In the presented work, a new tensile specimen geometry for strain rate testing is virtually optimized using a metamodel approach with an artificial neural network. The final specimen design is experimentally validated and compared with rectangular specimen results for a carbon fiber reinforced polycarbonate (CF-PC). The optimized specimen geometry leads to 100% valid test results in experimental validation of cross-ply laminates and reaches 9% higher tensile strength values than the rectangle geometry with applied end tabs at a strain rate of 40 s−1. Through the optimization, comparable material parameters can be efficiently generated for a successful cFRTP strain rate characterization. Full article
(This article belongs to the Special Issue Characterization and Modelling of Composites, Volume III)
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16 pages, 7169 KB  
Article
Effects of the Injection Material and Resin Layer on the Mechanical Properties of Carbon Fiber-Reinforced Thermoplastic (CFRTP) Press and Injection Hybrid Molded Parts
by Kazuto Tanaka and Masaki Taniguchi
J. Compos. Sci. 2024, 8(2), 56; https://doi.org/10.3390/jcs8020056 - 1 Feb 2024
Cited by 3 | Viewed by 3159
Abstract
In the press and injection hybrid molded parts of fiber-reinforced thermoplastics (FRTPs), failure at the interface between the surface material (the outer shell) and the ribs (the injection part) or that at the injection part has become an issue. Adding a resin layer [...] Read more.
In the press and injection hybrid molded parts of fiber-reinforced thermoplastics (FRTPs), failure at the interface between the surface material (the outer shell) and the ribs (the injection part) or that at the injection part has become an issue. Adding a resin layer to the rib roots at the same time that the ribs are molded through injection has been proposed, which may increase the mechanical properties and reduce the material cost. To prevent failure at the injection part, the use of fiber-reinforced resin as an injection material has been suggested. This approach contributes to a higher bond strength by lowering the molding shrinkage rate. In this study, the hat-shaped parts of carbon fiber-reinforced thermoplastics (CFRTPs) with fiber-reinforced and neat resin layers at the rib root were fabricated through press and injection hybrid molding, and their mechanical properties were evaluated through three-point bending tests. The effects of the resin layer at the rib root and the existence or nonexistence of fiber reinforcement on the mechanical properties, as well as the relationship between the material cost and the mechanical properties, were clarified through an experiment and FEM analysis. The bond strength was also evaluated through tensile tests that were undertaken at the rib root. Molded parts with neat PA6 and glass fiber-reinforced PA6 resin layers at the rib roots showed higher bond strength than those without resin layers. In a three-point bending test of a CFRTP hat-shaped part with a resin layer at the rib roots, the use of a 1 mm thick CFRTP laminate for the outer shell and glass fiber-reinforced PA6 resin as the injection material showed the same stiffness as a part that used a 2 mm thick CFRTP laminate for the outer shell. FEM analysis showed that the resin layer prevented the concentration of strain at the rib roots, and the model that used a 1 mm thick CFRTP laminate for the outer shell and glass fiber-reinforced PA6 resin as the injection material showed the best specific stiffness in this study. By adding a resin layer to the rib roots, the fabrication of molded parts with excellent specific stiffness was enabled at a small increase in cost. Full article
(This article belongs to the Special Issue Carbon Fiber Composites, Volume III)
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13 pages, 5094 KB  
Article
A Facile Molding Method of Continuous Fiber-Reinforced Thermoplastic Composites and Its Mechanical Property
by Jian Shi, Mamoru Mizuno, Limin Bao and Chunhong Zhu
Polymers 2022, 14(5), 947; https://doi.org/10.3390/polym14050947 - 26 Feb 2022
Cited by 17 | Viewed by 5330
Abstract
The mechanical properties of continuous fiber-reinforced thermoplastic (C-FRTP) composites are commonly lower than those of continuous fiber-reinforced thermosetting plastic (C-FRP) composites. We have developed a new molding method for C-FRTP. In this study, pre-impregnated materials were successfully prepared by polymer solution impregnation method [...] Read more.
The mechanical properties of continuous fiber-reinforced thermoplastic (C-FRTP) composites are commonly lower than those of continuous fiber-reinforced thermosetting plastic (C-FRP) composites. We have developed a new molding method for C-FRTP. In this study, pre-impregnated materials were successfully prepared by polymer solution impregnation method and, finally, C-FRTP was fabricated. The viscosity of the thermoplastic matrix was decreased to approximately 3dPa×s, the same level of epoxy, and the fiber volume fraction was increased from approximately 45 to 60%. The cross-section of specimens were polished by an ion milling system and impregnation condition was investigated by scanning electron microscopy (SEM). The micrographs suggested that thermoplastic polymer was impregnated to every corner of the fiber, and no void was found on the cross-section. It revealed that void-free composites with perfect mechanical properties can be manufactured with this new molding method. All specimens were submitted to a mechanical measuring equipment, and the mechanical properties of the composite specimens were investigated. Mechanical analysis revealed that tensile property and flexural property of C-FRTP were enhanced up to the same level with C-FRP. Full article
(This article belongs to the Special Issue Surfaces and Aesthetic Properties of Polymers)
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18 pages, 8713 KB  
Article
Effects of Heating and Cooling of Injection Mold Cavity Surface and Melt Flow Control on Properties of Carbon Fiber Reinforced Semi-Aromatic Polyamide Molded Products
by Yasuhiko Murata and Ryota Kanno
Polymers 2021, 13(4), 587; https://doi.org/10.3390/polym13040587 - 15 Feb 2021
Cited by 12 | Viewed by 6093
Abstract
Fiber reinforced thermoplastics (FRTP), reinforced with glass or carbon fibers, are used to improve the mechanical strength of injection-molded products. However, FRTP has problems such as the formation of weld lines, the deterioration of appearance due to the exposure of fibers on the [...] Read more.
Fiber reinforced thermoplastics (FRTP), reinforced with glass or carbon fibers, are used to improve the mechanical strength of injection-molded products. However, FRTP has problems such as the formation of weld lines, the deterioration of appearance due to the exposure of fibers on the molded product surface, and the deterioration of the strength of molded products due to the fiber orientation in the molded products. We have designed and fabricated an injection mold capable of melt flow control and induction heating and cooling. This mold can both heat and cool the injection mold. It can also control the melt flow direction using a movable core pin. In this study, the above-mentioned mold was used for the molding of carbon fiber reinforced semi-aromatic polyamide. As a result, we found that increasing the heating temperature of the mold and increasing melt flow control volume contribute to the prevention of the generation of a weld line and the exposure of fibers on the molded product surface, as well as to the formation of a flat surface and increased bending strength. The relationships of these results with the carbon fiber orientation in the molded products and the crystallization of semi-aromatic polyamide were also examined in this study. Full article
(This article belongs to the Special Issue Precise Polymer Processing Technology)
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10 pages, 2473 KB  
Article
Application of Glass Fiber and Carbon Fiber-Reinforced Thermoplastics in Face Guards
by Takahiro Wada, Hiroshi Churei, Mako Yokose, Naohiko Iwasaki, Hidekazu Takahashi and Motohiro Uo
Polymers 2021, 13(1), 18; https://doi.org/10.3390/polym13010018 - 23 Dec 2020
Cited by 9 | Viewed by 3181
Abstract
Face guards (FGs) are protectors that allow for the rapid and safe return of athletes who are to play after sustaining traumatic facial injuries and orbital fractures. Current FGs require significant thickness to achieve sufficient shock absorption abilities. However, their weight and thickness [...] Read more.
Face guards (FGs) are protectors that allow for the rapid and safe return of athletes who are to play after sustaining traumatic facial injuries and orbital fractures. Current FGs require significant thickness to achieve sufficient shock absorption abilities. However, their weight and thickness render the FGs uncomfortable and reduce the field of vision of the athlete, thus hindering their performance. Therefore, thin and lightweight FGs are required. We fabricated FGs using commercial glass fiber-reinforced thermoplastic (GFRTP) and carbon fiber-reinforced thermoplastic (CFRTP) resins to achieve these requirements and investigated their shock absorption abilities through impact testing. The results showed that an FG composed of CFRTP is thinner and lighter than a conventional FG and has sufficient shock absorption ability. The fabrication method of an FG comprising CFRTP is similar to the conventional method. FGs composed of commercial FRTPs exhibit adequate shock absorption abilities and are thinner and lower in weight as compared to conventional FGs. Full article
(This article belongs to the Special Issue Fiber-Reinforced Thermoplastics)
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14 pages, 76708 KB  
Article
Mechanical Behavior of GFRP Connection Using FRTP Rivets
by Takayoshi Matsui, Yoshiyuki Matsushita and Yukihiro Matsumoto
Materials 2021, 14(1), 7; https://doi.org/10.3390/ma14010007 - 22 Dec 2020
Cited by 5 | Viewed by 4094
Abstract
In recent years, the application of fiber-reinforced plastics (FRPs) as structural members has been promoted. Metallic bolts and rivets are often used for the connection of FRP structures, but there are some problems caused by corrosion and stress concentration at the bearing position. [...] Read more.
In recent years, the application of fiber-reinforced plastics (FRPs) as structural members has been promoted. Metallic bolts and rivets are often used for the connection of FRP structures, but there are some problems caused by corrosion and stress concentration at the bearing position. Fiber-reinforced thermoplastics (FRTPs) have attracted attention in composite material fields because they can be remolded by heating and manufactured with excellent speed compared with thermosetting plastics. In this paper, we propose and evaluate the connection method using rivets produced of FRTPs for FRP members. It was confirmed through material tests that an FRTP rivet provides stable tensile, shear, and bending strength. Then, it was clarified that non-clearance connection could be achieved by the proposed connection method, so initial sliding was not observed, and connection strength linearly increased as the number of FRTP rivets increased through the double-lapped tensile shear tests. Furthermore, the joint strength of the beam using FRTP rivets could be calculated with high accuracy using the method for bolt joints in steel structures through a four-point beam bending test. Full article
(This article belongs to the Special Issue Testing of Materials and Elements in Civil Engineering)
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20 pages, 4680 KB  
Article
Combining Simulation and Machine Learning as Digital Twin for the Manufacturing of Overmolded Thermoplastic Composites
by André Hürkamp, Sebastian Gellrich, Tim Ossowski, Jan Beuscher, Sebastian Thiede, Christoph Herrmann and Klaus Dröder
J. Manuf. Mater. Process. 2020, 4(3), 92; https://doi.org/10.3390/jmmp4030092 - 11 Sep 2020
Cited by 83 | Viewed by 11950
Abstract
The design and development of composite structures requires precise and robust manufacturing processes. Composite materials such as fiber reinforced thermoplastics (FRTP) provide a good balance between manufacturing time, mechanical performance and weight. In this contribution, we investigate the process combination of thermoforming FRTP [...] Read more.
The design and development of composite structures requires precise and robust manufacturing processes. Composite materials such as fiber reinforced thermoplastics (FRTP) provide a good balance between manufacturing time, mechanical performance and weight. In this contribution, we investigate the process combination of thermoforming FRTP sheets (organo sheets) and injection overmolding of short FRTP for automotive structures. The limiting factor in those structures is the bond strength between the organo sheet and the overmolded thermoplastic. Within this process chain, even small deviations of the process settings (e.g., temperature) can lead to significant defects in the structure. A cyber physical production system based framework for a digital twin combining simulation and machine learning is presented. Based on parametric Finite-Element-Method (FEM) studies, training data for machine learning methods are generated and a FEM surrogate is developed. A comparison of different data-driven methods yields information on the estimation accuracy of task-specific data-driven methods. Finally, in accordance with experimental cross tension tests, the investigated FEM surrogate model is able to predict the interface bond strength quality in dependence of the process settings. The visualization into different quality domains qualifies the presented approach as decision support. Full article
(This article belongs to the Special Issue Cyber Physical Production Systems)
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