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Keywords = fine particulate matter

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26 pages, 1487 KiB  
Article
The Impact of Smart City Construction on PM2.5 Concentrations: Empirical Analysis from Chinese Counties
by Chenxue Li, Yuxin Duan, Zhicheng Zhou and Shen Zhong
Sustainability 2025, 17(11), 5100; https://doi.org/10.3390/su17115100 - 2 Jun 2025
Abstract
Fine particulate matter (PM2.5) pollution poses a major threat to human physical and mental health. Smart cities (SCs) provide innovative paths for PM2.5 pollution prevention and control through Internet of Things (IoT) monitoring, intelligent transportation optimization, and other technological means. [...] Read more.
Fine particulate matter (PM2.5) pollution poses a major threat to human physical and mental health. Smart cities (SCs) provide innovative paths for PM2.5 pollution prevention and control through Internet of Things (IoT) monitoring, intelligent transportation optimization, and other technological means. Based on the panel data of 2,141 counties in China between 2006 and 2021, this paper constructs a difference-in-differences with multiple time periods (MDID) to systematically assess the impact of SC on PM2.5 concentration and analyze its mechanism of action by combining the satellite remote sensing PM2.5 concentration (PM2.5C) and the list of smart city pilots. This study finds the following: (1) SC significantly reduced the PM2.5 concentration in the test area by about 3.58%. This conclusion was verified through rigorous robustness testing; (2) SC can effectively reduce PM2.5C through the innovation effect; (3) High-quality economic development can strengthen the emission reduction effect of SC on PM2.5C; (4) The environmental benefits of SC show significant spatial heterogeneity, with the largest PM2.5 reductions occurring in the western regions (4.3% reduction), followed by regions with mature digital infrastructure and cities in high administrative level cities. The results of this study provide a reference for the regional differentiated implementation of the “14th Five-Year Plan for the Development of Innovative Smarter Cities”, and make targeted recommendations for the synergistic management of air quality under the “dual-carbon” goal. Full article
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18 pages, 2949 KiB  
Article
Ozone Aggravated the Toxicity of Fine Particulate Matter by Impairing Membrane Stability and Facilitating Particle Internalization
by Jing He, Tong Wang, Han Li, Yemian Zhou, Yun Liu and An Xu
Toxics 2025, 13(6), 446; https://doi.org/10.3390/toxics13060446 - 28 May 2025
Viewed by 64
Abstract
The combined pollution of fine particulate matter (PM2.5) and ozone (O3) is increasing synergistically on a global scale, posing a serious threat to human health. However, the joint toxicity and the underlying mechanisms associated with co-exposure to PM2.5 [...] Read more.
The combined pollution of fine particulate matter (PM2.5) and ozone (O3) is increasing synergistically on a global scale, posing a serious threat to human health. However, the joint toxicity and the underlying mechanisms associated with co-exposure to PM2.5 and O3 remain poorly understood. Through complementary in vivo animal models and in vitro cellular assays, the results demonstrate that although there was no synergistic cytotoxicity effect between PM2.5 and O3, the presence of O3 significantly enhanced the genotoxicity of PM2.5 by inducing severe DNA double-strand breaks. Furthermore, O3 exposure significantly exacerbated the bioaccumulation of PM2.5 by disturbing the cellular membrane integrity, thus leading to synergistic toxicity in bronchial cells and mouse lungs. Astaxanthin (AST) effectively antagonized the adverse effects of PM2.5 and O3 co-exposure by maintaining cell membrane integrity. These findings enhance our understanding of the pathophysiological mechanisms induced by co-exposure to PM2.5 and O3, and provide a promising therapeutic strategy for treating respiratory diseases caused by unavoidable exposure to these pollutants. Full article
(This article belongs to the Section Air Pollution and Health)
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25 pages, 6290 KiB  
Article
Precipitation-Related Atmospheric Nutrient Deposition in Farmington Bay: Analysis of Spatial and Temporal Patterns
by Gustavious P. Williams, A. Woodruff Miller, Amin Aghababaei, Abin Raj Chapagain, Pitamber Wagle, Yubin Baaniya, Rachel H. Magoffin, Xueyi Li, Taylor Miskin, Peter D. Oldham, Samuel J. Oldham, Tyler Peterson, Lyle Prince, Kaylee B. Tanner, Anna C. Cardall and Daniel P. Ames
Hydrology 2025, 12(6), 131; https://doi.org/10.3390/hydrology12060131 - 27 May 2025
Viewed by 139
Abstract
This study quantifies the atmospheric deposition (AD) of nutrient loads into the Farmington Bay ecosystem via wet deposition over a three-year period. We analyzed nutrient concentrations from 509 total phosphorus (TP), 507 orthophosphate (OP), and 511 total nitrogen (TN) samples collected at seven [...] Read more.
This study quantifies the atmospheric deposition (AD) of nutrient loads into the Farmington Bay ecosystem via wet deposition over a three-year period. We analyzed nutrient concentrations from 509 total phosphorus (TP), 507 orthophosphate (OP), and 511 total nitrogen (TN) samples collected at seven locations around the Bay. We estimated AD loads using two different spatial interpolation methods, Kriging and Inverse Distance Weighting (IDW), as well as average concentrations. The loads computed using Kriging and IDW were similar, but the loads computed using sample averages were about 70% smaller. We estimated that annual atmospherically deposited nutrient loads range from 306 to 594 Mg for TN, 73 to 195 Mg for TP, and 43 to 144 Mg for OP. The loads in 2023 were significantly higher than those in 2021 and 2022, a phenomenon we attribute to higher precipitation and a major loading event that occurred on 13 April 2023. Based on comparison with studies concerning nearby Utah Lake, the total loads could be two to three times larger than our estimates. These studies suggest that fine particulate matter may significantly contribute to AD nutrient loads, but these loads are not captured by our sampling method. However, the inclusion of non-water surfaces in Farmington Bay may mitigate this difference. Full article
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17 pages, 2017 KiB  
Article
Polygonum multiflorum Inhibits Pulmonary Inflammation and Fibrosis in PM2.5-Induced Dysfunction Through the Regulation of the TLR4/TGF-β1 Signaling Pathway in Mice
by Hye Ji Choi, Hyo Lim Lee, In Young Kim and Ho Jin Heo
Int. J. Mol. Sci. 2025, 26(11), 5080; https://doi.org/10.3390/ijms26115080 - 25 May 2025
Viewed by 272
Abstract
Industrial development has improved living standards; however, mortality associated with fine particulate matter (PM2.5) exposure continues to rise. Despite increasing awareness of its health risks, effective strategies to mitigate PM2.5-induced pulmonary damage remain limited. This study examines the protective [...] Read more.
Industrial development has improved living standards; however, mortality associated with fine particulate matter (PM2.5) exposure continues to rise. Despite increasing awareness of its health risks, effective strategies to mitigate PM2.5-induced pulmonary damage remain limited. This study examines the protective properties of an ethanolic extract from Polygonum multiflorum (EPM) in preventing pulmonary dysfunction induced by PM2.5, as well as its possible use as a dietary intervention to improve respiratory health. The physiological compounds in EPM were identified using ultra-performance liquid chromatography, and its protective effects were evaluated via in vitro assays using A549 and RPMI 2650 cells. The antioxidant system and mitochondrial function were further analyzed in the lung tissues of PM2.5-exposed BALB/c mice, with molecular mechanisms elucidated by Western blot analysis. The main bioactive compounds identified in EPM included 2,3,5,4′-tetrahydroxystilbene-2-O-β-D-glucoside. EPM modulated the Nrf2 signaling pathway, enhancing antioxidant defense by regulating the expression of antioxidant-related proteins. Furthermore, EPM exhibited protective effects against inflammation, apoptosis, and fibrosis through the TLR4/p-JNK and TGF-β1 signaling pathways. These findings suggest that EPM exerts protective effects against PM2.5-induced oxidative stress and inflammation and may be used as a functional food ingredient for respiratory health. Full article
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15 pages, 2203 KiB  
Article
Pre- and Postnatal Fine Particulate Matter Exposure and Renal Fibrogenesis in Adult Male Rats: The Role of Vitamin D Supplementation
by Min-Hwa Son, Hyung-Eun Yim, Yu-Seon Lee, Yoon-Jeong Nam and Ju-Han Lee
Curr. Issues Mol. Biol. 2025, 47(6), 387; https://doi.org/10.3390/cimb47060387 - 22 May 2025
Viewed by 270
Abstract
Prolonged exposure to fine particulate matter (PM2.5) has been implicated in accelerated aging, including organ fibrosis. This study aimed to investigate whether prenatal and postnatal PM2.5 exposure promotes renal fibrogenesis in adulthood and whether long-term vitamin D supplementation alleviates associated [...] Read more.
Prolonged exposure to fine particulate matter (PM2.5) has been implicated in accelerated aging, including organ fibrosis. This study aimed to investigate whether prenatal and postnatal PM2.5 exposure promotes renal fibrogenesis in adulthood and whether long-term vitamin D supplementation alleviates associated renal injury. Pregnant Sprague-Dawley rats were randomly assigned to three groups: control (normal saline, NS), PM2.5 exposure, and PM2.5 exposure with vitamin D supplementation during gestation and lactation (n = 3/group). Male offspring were subsequently exposed to the same conditions from postnatal weeks 3 to 8 (n = 7/group). On postnatal day 56, PM2.5-exposed rats showed lower body weight and more severe glomerular and tubulointerstitial damage compared to controls. Serum calcium levels were elevated in the PM2.5 group. The expression of intrarenal renin, transforming growth factor-β1, α-smooth muscle actin, and vimentin was upregulated, accompanied by increased collagen deposition. Long-term vitamin D supplementation reversed most of these changes, except for intrarenal vimentin expression and serum calcium levels. These findings indicate that prenatal and postnatal PM2.5 exposure can activate intrarenal renin signaling and fibrogenic pathways, contributing to renal fibrosis later in life. Long-term vitamin D supplementation may provide partial protective effects against PM2.5-induced renal fibrogenesis. Full article
(This article belongs to the Section Biochemistry, Molecular and Cellular Biology)
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21 pages, 7991 KiB  
Article
Machine Learning–Based Calibration and Performance Evaluation of Low-Cost Internet of Things Air Quality Sensors
by Mehmet Taştan
Sensors 2025, 25(10), 3183; https://doi.org/10.3390/s25103183 - 19 May 2025
Viewed by 501
Abstract
Low-cost air quality sensors (LCSs) are increasingly being used in environmental monitoring due to their affordability and portability. However, their sensitivity to environmental factors can lead to measurement inaccuracies, necessitating effective calibration methods to enhance their reliability. In this study, an Internet of [...] Read more.
Low-cost air quality sensors (LCSs) are increasingly being used in environmental monitoring due to their affordability and portability. However, their sensitivity to environmental factors can lead to measurement inaccuracies, necessitating effective calibration methods to enhance their reliability. In this study, an Internet of Things (IoT)-based air quality monitoring system was developed and tested using the most commonly preferred sensor types for air quality measurement: fine particulate matter (PM2.5), carbon dioxide (CO2), temperature, and humidity sensors. To improve sensor accuracy, eight different machine learning (ML) algorithms were applied: Decision Tree (DT), Linear Regression (LR), Random Forest (RF), k-Nearest Neighbors (kNN), AdaBoost (AB), Gradient Boosting (GB), Support Vector Machines (SVM), and Stochastic Gradient Descent (SGD). Sensor performance was evaluated by comparing measurements with a reference device, and the best-performing ML model was determined for each sensor. The results indicate that GB and kNN achieved the highest accuracy. For CO2 sensor calibration, GB achieved R2 = 0.970, RMSE = 0.442, and MAE = 0.282, providing the lowest error rates. For the PM2.5 sensor, kNN delivered the most successful results, with R2 = 0.970, RMSE = 2.123, and MAE = 0.842. Additionally, for temperature and humidity sensors, GB demonstrated the highest accuracy with the lowest error values (R2 = 0.976, RMSE = 2.284). These findings demonstrate that, by identifying suitable ML methods, ML-based calibration techniques can significantly enhance the accuracy of LCSs. Consequently, they offer a viable and cost-effective alternative to traditional high-cost air quality monitoring systems. Future studies should focus on long-term data collection, testing under diverse environmental conditions, and integrating additional sensor types to further advance this field. Full article
(This article belongs to the Special Issue Intelligent Sensor Calibration: Techniques, Devices and Methodologies)
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17 pages, 3896 KiB  
Article
Disparities in Fine Particulate Matter Air Pollution Exposures at the US–Mexico Border: The Intersection of Race/Ethnicity and Older Age
by Timothy W. Collins, Colby M. Child, Sara E. Grineski and Mathilda Scott
Atmosphere 2025, 16(5), 610; https://doi.org/10.3390/atmos16050610 - 17 May 2025
Viewed by 272
Abstract
Environmental justice research in the United States (US) documents greater air pollution exposures for Hispanic/Latino vs. non-Hispanic White groups. EJ research has not focused on the intersection of race/ethnicity and older age nor short-term fine particulate matter (PM2.5) exposures. We address [...] Read more.
Environmental justice research in the United States (US) documents greater air pollution exposures for Hispanic/Latino vs. non-Hispanic White groups. EJ research has not focused on the intersection of race/ethnicity and older age nor short-term fine particulate matter (PM2.5) exposures. We address these knowledge gaps by studying US metropolitan area census tracts within 100 km of the US–Mexico border, a region with serious air quality issues. We use US Census American Community Survey data to construct sociodemographic variables and Environmental Protection Agency Downscaler data to construct long-term and short-term measures of PM2.5 exposure. Using multivariable generalized estimating equations, we test for differences in PM2.5 exposures between census tracts with higher vs. lower proportions of older Hispanic/Latino residents and older non-Hispanic White residents. The results indicate that as the proportion of the Hispanic/Latino population ≥ 65 years of age increases, long-term and short-term PM2.5 exposures significantly increase. In contrast, as the proportion of the non-Hispanic White population ≥ 65 years of age increases, changes in long-term and short-term PM2.5 exposures are statistically non-significant. These findings illuminate how race/ethnicity and older age intersect in shaping PM2.5 exposure disparities and may inform efforts to mitigate air pollution exposures for overburdened people along the US–Mexico border. Full article
(This article belongs to the Section Air Quality)
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18 pages, 3713 KiB  
Article
Estimation of Biomass Burning Emissions in South and Southeast Asia Based on FY-4A Satellite Observations
by Yajun Wang, Yu Tian and Yusheng Shi
Atmosphere 2025, 16(5), 582; https://doi.org/10.3390/atmos16050582 - 13 May 2025
Viewed by 300
Abstract
In recent years, frequent open biomass burning (OBB) activities such as agricultural residue burning and forest fires have led to severe air pollution and carbon emissions across South and Southeast Asia (SSEA). We selected this area as our study area and divided it [...] Read more.
In recent years, frequent open biomass burning (OBB) activities such as agricultural residue burning and forest fires have led to severe air pollution and carbon emissions across South and Southeast Asia (SSEA). We selected this area as our study area and divided it into two sub-regions based on climate characteristics and geographical location: the South Asian Subcontinent (SEAS), which includes India, Laos, Thailand, Cambodia, etc., and Equatorial Asia (EQAS), which includes Indonesia, Malaysia, etc. However, existing methods—primarily emission inventories relying on burned area, fuel load, and emission factors—often lack accuracy and temporal resolution for capturing fire dynamics. Therefore, in this study, we employed high-resolution fire point data from China’s Feng Yun-4A (FY-4A) geostationary satellite and the Fire Radiative Power (FRP) method to construct a daily OBB emission inventory at a 5 km resolution in this region for 2020–2022. The results show that the average annual emissions of carbon (C), carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), non-methane organic gases (NMOGs), hydrogen (H2), nitrogen oxide (NOX), sulfur dioxide (SO2), fine particulate matter (PM2.5), total particulate matter (TPM), total particulate carbon (TPC), organic carbon (OC), black carbon (BC), ammonia (NH3), nitric oxide (NO), nitrogen dioxide (NO2), non-methane hydrocarbons (NMHCs), and particulate matter ≤ 10 μm (PM10) are 178.39, 598.10, 33.11, 1.44, 4.77, 0.81, 1.02, 0.28, 3.47, 5.58, 2.29, 2.34, 0.24, 0.58, 0.43, 0.99, 1.87, and 3.84 Tg/a, respectively. Taking C emission as an example, 90% of SSEA’s emissions come from SEAS, especially concentrated in Laos and western Thailand. Due to the La Niña climate anomaly in 2021, emissions surged, while EQAS showed continuous annual growth at 16.7%. Forest and woodland fires were the dominant sources, accounting for over 85% of total emissions. Compared with datasets such as the Global Fire Emissions Database (GFED) and the Global Fire Assimilation System (GFAS), FY-4A showed stronger sensitivity and regional adaptability, especially in SEAS. This work provides a robust dataset for carbon source identification, air quality modeling, and regional pollution control strategies. Full article
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17 pages, 9155 KiB  
Article
Long-Term Alterations of Renal Microvasculature in Rats Following Maternal PM2.5 Exposure: Vitamin D Effects
by Eujin Park, Hyung-Eun Yim, Min-Hwa Son, Yoon-Jeong Nam, Yu-Seon Lee, Sang-Hoon Jeong and Ju-Han Lee
Biomedicines 2025, 13(5), 1166; https://doi.org/10.3390/biomedicines13051166 - 10 May 2025
Viewed by 244
Abstract
Background: This study aimed to investigate the long-term effects of maternal exposure to fine particulate matter (PM2.5) with or without vitamin D supplementation on the renal microvasculature in adult rat offspring. Methods: Pregnant Sprague–Dawley rats were exposed to normal [...] Read more.
Background: This study aimed to investigate the long-term effects of maternal exposure to fine particulate matter (PM2.5) with or without vitamin D supplementation on the renal microvasculature in adult rat offspring. Methods: Pregnant Sprague–Dawley rats were exposed to normal saline, PM2.5, and PM2.5 with vitamin D for one month during nephrogenesis. Male offspring kidneys were taken for analyses on postnatal day 56. Results: Adult offspring rats exposed to maternal PM2.5 exhibited lower body weights and greater glomerular and tubular injury scores compared to control rats. Semi-quantitative analysis revealed a significant reduction in glomerular and peritubular capillary endothelial cells, along with a decrease in the number of glomeruli in the PM2.5 group. Maternal vitamin D supplementation reduced these changes. In offspring rats exposed to maternal PM2.5, intrarenal expression of renin, angiotensin-converting enzyme (ACE), cytochrome P450 27B1, and vascular endothelial growth factor-A (VEGF-A) increased, while expression of the vitamin D receptor, Klotho, VEGF receptor 2, angiopoietin-1, and Tie-2 decreased. Maternal vitamin D supplementation restored VEGF receptor 2 and angiopoietin-1 activities and reduced ACE and VEGF-A protein expression in adult offspring kidneys. Conclusions: Early-life exposure to PM2.5 may lead to long-term alterations in renal microvasculature and nephron loss. Maternal vitamin D supplementation during renal development can ameliorate PM2.5-induced capillary rarefaction and nephron loss in the kidneys of adult offspring. Full article
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22 pages, 3844 KiB  
Article
Number Concentration, Size Distribution, and Lung-Deposited Surface Area of Airborne Particles in Three Urban Areas of Colombia
by Fabian L. Moreno Camacho, Daniela Bustos Quevedo, David Archila-Peña, Jorge E. Pachón, Néstor Y. Rojas, Lady Mateus-Fontecha and Karen Blanco
Atmosphere 2025, 16(5), 558; https://doi.org/10.3390/atmos16050558 - 7 May 2025
Viewed by 213
Abstract
Airborne particulate matter is a major pollutant globally due to its impact on atmospheric processes and human health. Depending on their aerodynamic size, particles can penetrate the respiratory system, with ultrafine particles (UFPs) reaching the bloodstream and affecting vital organs. This study investigates [...] Read more.
Airborne particulate matter is a major pollutant globally due to its impact on atmospheric processes and human health. Depending on their aerodynamic size, particles can penetrate the respiratory system, with ultrafine particles (UFPs) reaching the bloodstream and affecting vital organs. This study investigates the particle number size distribution (PNSD), particle number concentration (PNC), and lung-deposited surface area (LDSA) in Bogotá, Cali, and Palmira, Colombia. Measurements were conducted at four sites representing different urban and industrial backgrounds using an Electrical Low-Pressure Impactor (ELPI+). Due to the availability and operation of the device, observations were limited to a few days, so the results of this study are indicative and not generalized for the cities. UFP concentrations were highest in Cali (28,399 cm−3), three times higher than in San Cristóbal, Bogotá. Fine particles (FPs) exhibited similar patterns across the three cities, with higher concentrations in San Cristóbal (2421 cm−3). Coarse particles (CPs) were most prevalent in Palmira (41.37 cm−3), and the highest LDSA values were recorded in Palmira and Cali (>80 µm2/cm3), indicating a higher potential for respiratory deposition. These findings highlight the importance of PNSD in health risk assessment in urban areas, providing valuable insights for future studies and strategies to manage air quality in Colombia. Full article
(This article belongs to the Special Issue Air Quality in Metropolitan Areas and Megacities (Second Edition))
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21 pages, 13372 KiB  
Article
Long-Term (2015–2024) Daily PM2.5 Estimation in China by Using XGBoost Combining Empirical Orthogonal Function Decomposition
by Jiacheng Jiang, Jiaxin Dong, Yu Ding, Wenjia Ni, Jie Yang and Siwei Li
Remote Sens. 2025, 17(9), 1632; https://doi.org/10.3390/rs17091632 - 4 May 2025
Viewed by 426
Abstract
Fine particulate matter (PM2.5) has garnered significant scientific and public health concern owing to its capacity for deep penetration into the human respiratory system, presenting significant health risks. Despite the implementation of strict environmental policies in China over the past decade [...] Read more.
Fine particulate matter (PM2.5) has garnered significant scientific and public health concern owing to its capacity for deep penetration into the human respiratory system, presenting significant health risks. Despite the implementation of strict environmental policies in China over the past decade to reduce PM2.5 levels, long-term public health concerns remain a serious issue. Our study aims to provide a high-quality, seamless daily PM2.5 dataset for China covering the years 2015 to 2024. A two-step PM2.5 estimation model is established based on a machine learning algorithm and a spatio-temporal decomposition method. First, we utilize the machine learning algorithm XGBoost (EXtreme Gradient Boosting) to address gaps in the daily MAIAC (Multi-Angle Implementation of Atmospheric Correction) AOD (Aerosol Optical Depth), with R2/RMSE (coefficient of determination/Root Mean Square Error) of 0.67/0.2678 compared to AERONET (Aerosol Robotic Network) AOD. Then, a novel approach by integrating XGBoost with EOF (Empirical Orthogonal Function) decomposition is introduced for PM2.5 estimation. The integration of EOF allows for the incorporation of entire meteorological field information into the PM2.5 estimation model, significantly enhancing its accuracy: spatial CV (cross-validation)-R2 improved from 0.8340 to 0.8935, and spatial CV-RMSE reduced from 13.8177 to 11.0668. Leveraging the newly produced dataset, we analyze the spatio-temporal variations of PM2.5 across China with EOF decomposition, particularly noting that PM2.5 levels in the eastern anthropogenic intensive regions continuously declined from 2015 to 2020, and fluctuated steadily during 2020–2024. This research underscores the critical need for sustained and effective air quality management strategies in China. Full article
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13 pages, 3274 KiB  
Article
Performance Evaluation of PM2.5 Forecasting Using SARIMAX and LSTM in the Korean Peninsula
by Chae-Yeon Lee, Ju-Yong Lee, Seung-Hee Han, Jin-Goo Kang, Jeong-Beom Lee and Dae-Ryun Choi
Atmosphere 2025, 16(5), 524; https://doi.org/10.3390/atmos16050524 - 29 Apr 2025
Viewed by 285
Abstract
Air pollution, particularly fine particulate matter (PM2.5), poses significant environmental and public health challenges in South Korea. The National Institute of Environmental Research (NIER) currently relies on numerical models such as the Community Multiscale Air Quality (CMAQ) model for PM2.5 [...] Read more.
Air pollution, particularly fine particulate matter (PM2.5), poses significant environmental and public health challenges in South Korea. The National Institute of Environmental Research (NIER) currently relies on numerical models such as the Community Multiscale Air Quality (CMAQ) model for PM2.5 forecasting. However, these models exhibit inherent uncertainties due to limitations in emission inventories, meteorological inputs, and model frameworks. To address these challenges, this study evaluates and compares the forecasting performance of two alternative models: Long Short-Term Memory (LSTM), a deep learning model, and Seasonal Auto Regressive Integrated Moving Average with Exogenous Variables (SARIMAX), a statistical model. The performance evaluation was focused on Seoul, South Korea, and took place over different forecast lead times (D00–D02). The results indicate that for short-term forecasts (D00), SARIMAX outperformed LSTM in all statistical metrics, particularly in detecting high PM2.5 concentrations, with a 19.43% higher Probability of Detection (POD). However, SARIMAX exhibited a sharp performance decline in extended forecasts (D01–D02). In contrast, LSTM demonstrated relatively stable accuracy over longer lead times, effectively capturing complex PM2.5 concentration patterns, particularly during high-concentration episodes. These findings highlight the strengths and limitations of statistical and deep learning models. While SARIMAX excels in short-term forecasting with limited training data, LSTM proves advantageous for long-term forecasting, benefiting from its ability to learn complex temporal patterns from historical data. The results suggest that an integrated air quality forecasting system combining numerical, statistical, and machine learning approaches could enhance PM2.5 forecasting accuracy. Full article
(This article belongs to the Special Issue Novel Insights into Air Pollution over East Asia (Second Edition))
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21 pages, 3086 KiB  
Article
Measuring Ammonia Concentration Distributions with Passive Samplers to Evaluate the Impact of Vehicle Exhaust on a Roadside Environment in Tokyo, Japan
by Hiroyuki Hagino
Atmosphere 2025, 16(5), 519; https://doi.org/10.3390/atmos16050519 - 29 Apr 2025
Viewed by 295
Abstract
Evaluating the impact on roadside environments of NH3 from vehicle emissions is important for protecting the ecosystem from air pollution by fine particulate matter and nitrogen deposition. This study used passive samplers to measure NH3 and NOX at multiple points [...] Read more.
Evaluating the impact on roadside environments of NH3 from vehicle emissions is important for protecting the ecosystem from air pollution by fine particulate matter and nitrogen deposition. This study used passive samplers to measure NH3 and NOX at multiple points near a major road to observe the distribution of these gases in the area. The impact of NH3 emitted from vehicles on a major road on the environmental concentration of NH3 at different distances from the roadside was found to be similar to that of NOX and NO2. The concentration of NH3 rapidly decreased due to dilution and diffusion within approximately 50 m of the road, and after 100 m the concentration remained almost the same or decreased slowly. Furthermore, CO2 observations taken in the same period along the roadside and in the background yielded a vehicular emission factor of 4–50 mg/km for NH3, which is comparable with previous research. This emission factor level contributes 4–11 ppb to the NH3 concentrations in roadside air through the dilution and diffusion process. A correlation was found between the emission factors of NH3 and NOX that was different from the trade-off relationship seen when single-vehicle exhaust is measured. Full article
(This article belongs to the Special Issue Ammonia Emissions and Particulate Matter (2nd Edition))
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16 pages, 5654 KiB  
Article
Sizing Accuracy of Low-Cost Optical Particle Sensors Under Controlled Laboratory Conditions
by Prakash Gautam, Andrew Ramirez, Salix Bair, William Patrick Arnott, Judith C. Chow, John G. Watson, Hans Moosmüller and Xiaoliang Wang
Atmosphere 2025, 16(5), 502; https://doi.org/10.3390/atmos16050502 - 26 Apr 2025
Viewed by 415
Abstract
Low-cost particulate matter sensors have seen increased use for monitoring at personal and local levels due to their affordability, ease of operation, and high time resolution. However, the quality of data reported by these sensors can be questionable, and a thorough evaluation of [...] Read more.
Low-cost particulate matter sensors have seen increased use for monitoring at personal and local levels due to their affordability, ease of operation, and high time resolution. However, the quality of data reported by these sensors can be questionable, and a thorough evaluation of their performance is necessary. This study evaluated the particle sizing accuracy of several commonly used optical sensors, including the Alphasense optical particle counter (OPC), TSI DustTrak DRX aerosol monitor, Plantower PMS5003 sensor, and Sensirion SPS30 sensor, using laboratory-generated monodisperse particles. The OPC and DRX agreed partially with reference instruments and showed promise in detecting coarse-size particles. However, the PMS5003 and SPS30 did not correctly size fine and coarse particles. Furthermore, their reported mass distributions do not directly correspond to their number distribution. Despite these limitations, field measurements involving a dust storm period showed that the SPS30 correlated reasonably well with reference instruments for both PM2.5 and PM10, though the regression slopes differed significantly. These findings underscore the need for caution when interpreting data from low-cost optical sensors, particularly for coarse particles. Recommendations for improving the performance of these sensors are also provided. Full article
(This article belongs to the Section Aerosols)
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15 pages, 2303 KiB  
Article
Identification and Characterization of Atmospheric Nickel-Containing Particles in Guangzhou After the Implementation of the Clean Fuel Policy
by Zaihua Wang, Xuanxiao Chen, Cheng Wu, Hong Ju, Zhong Fu, Xin Xiong, Ting Qiu, Yuchen Lu, Junjie He, Yaxi Liu, Haining Wu, Chunlei Cheng and Mei Li
Toxics 2025, 13(5), 345; https://doi.org/10.3390/toxics13050345 - 26 Apr 2025
Viewed by 272
Abstract
Nickel, as a toxic trace element in fine particulate matter (PM2.5), has detrimental effects on both air quality and human health. Based on measurements from 2020 to 2021 using a single-particle aerosol mass spectrometer (SPAMS), this study investigates the properties of [...] Read more.
Nickel, as a toxic trace element in fine particulate matter (PM2.5), has detrimental effects on both air quality and human health. Based on measurements from 2020 to 2021 using a single-particle aerosol mass spectrometer (SPAMS), this study investigates the properties of nickel-containing particles (NCPs) in Guangzhou. The composition, sources, and temporal trends of NCPs were evaluated and the impact of the clean ship fuel policy introduced in 2020 was also examined. The key findings include: (1) Nickel particles account for 0.08% number fraction of PM2.5, which is consistent with previously reported mass fraction in PM2.5. (2) Three distinct types of NCPs were identified, including Ni-fresh, Ni-aged, and Ni-ash. Each type exhibits unique characteristics in size distribution, wind direction dependence, sources, and temporal variations. Ni-fresh particles originate from shipping emissions in the Huangpu Port area 2 km away and are the major contributors to fine nickel particles in the region. (3) Ni-aged and Ni-ash particles, which carry secondary components, tend to be larger (>500 nm) and are representative of regional or background nickel particles. (4) The implementation of the clean ship fuel policy has effectively reduced the number concentrations of NCPs and is beneficial to regional and local air quality. Full article
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