Search Results (14,225)

In this study, the insufficient ability of tartary buckwheat protein (TBP) to stabilize Pickering emulsions was addressed by preparing TBP–sodium alginate (SA) composite particles via cross-linking and systematic optimization of the preparation parameters. The results showed that at a pH of 9.0 with 1.0% (w/v) TBP and 0.2% (w/v) SA, the zeta potential of the prepared TBP–SA composite particles was significantly more negative, and the particle size was significantly larger, than those of TBP, while emulsifying activity index and emulsifying stability index increased to 53.76 m²/g and 78.78%, respectively. Scanning electron microscopy confirmed the formation of a dense network structure; differential scanning calorimetry revealed a thermal denaturation temperature of 83 °C. Fourier transform infrared spectroscopy and surface hydrophobicity results indicated that the complex was formed primarily through hydrogen bonding and hydrophobic interactions between TBP and SA, which induced conformational changes in the protein. The Pickering emulsion prepared with 5% (w/v) TBP–SA composite particles and 60% (φ) oil phase was stable during 4-month storage, at a high temperature of 75 °C, high salt conditions of 600 mM, and pH of 3.0–9.0. The stabilization mechanisms may involve: (1) strong electrostatic repulsion provided by the highly negative zeta potential; (2) steric hindrance and mechanical strength imparted by the dense interfacial network; and (3) restriction of droplet mobility due to SA-induced gelation. Full article

Purpose: Timely removal of ureteral stents is critical to prevent complications such as infection, discomfort and stent encrustation or fragmentation, as well as stone formation associated with neglected stents. Current decisions, however, rely heavily on subjective interpretation of postoperative imaging. This study introduces a semi-automated image-processing algorithm that quantitatively evaluates stent morphology, aiming to support objective and reproducible decision-making in minimally invasive urological care. Methods: Two computational approaches were developed to analyze morphological changes in ureteral stents following surgery. The first method employed a vector-based analysis, using the FitLine function to derive unit vectors for each stent segment and calculating inter-vector angles. The second method applied a slope-based analysis, computing gradients between coordinate points to evaluate global straightening of the ureter over time. Results: The vector-angle method did not demonstrate significant temporal changes (p = 0.844). In contrast, the slope-based method identified significant ureteral straightening (p < 0.05), consistent with clinical observations. These results confirm that slope-based quantitative analysis provides reliable insight into postoperative morphological changes. Conclusions: This study presents an algorithm-based and reproducible imaging analysis method that enhances objectivity in postoperative assessment of ureteral stents. By aligning quantitative image processing with clinical decision support, the approach contributes to precision medicine and addresses the absence of standardized criteria for stent removal. Full article

Cancer-associated fibroblasts (CAFs) are a key constituent of the tumor microenvironment. CAFs may affect the development of tumor cells. The critical role of CAFs in the tumor microenvironment is linked to their epigenetic modifications, as a stable yet reversible regulation of cellular phenotypes. Current evidence indicates that their formation and function are closely linked to epigenetic mechanisms. Existing research indicates that the epigenetic alteration abnormalities are triggered by metabolic cues and stabilize the acquired phenotype of CAFs. This process is associated with transcriptional changes and patient outcomes in various tumors, providing a biological rationale and translational potential for reprogramming CAFs. Understanding of epigenetic modifications in CAFs remain insufficient, while DNA methylation in CAFs can alter CAF states through multiple pathways and thereby influence tumor progression. It is necessary to investigate the unique, identifiable epigenetic signatures of CAF. As an epigenetic reader couple histone acetylation to high-output oncogenic transcription; meanwhile, noncoding RNAs modulate CAF formation and therapeutic responses via bidirectional crosstalk between tumor cells and stroma. The interactions between different epigenetic modifications and their underlying regulatory logic may play a crucial role in developing new therapeutic strategies. This review focuses on the roles of DNA methylation, histone acetylation, and enhancer reprogramming in CAFs. Full article

Developing sustainable and high-performance sorbents for efficient CO₂ capture is essential for mitigating climate change and reducing industrial emissions. In this study, phosphorus-doped porous carbons (LPSP-T) were synthesized via a one-step activation–doping strategy using lotus petiole biomass as a precursor and sodium phytate as a dual-function activating and phosphorus-doping agent. The simultaneous activation and phosphorus incorporation at various temperatures (650–850 °C) under a nitrogen atmosphere produced carbons with tailored textural properties and surface functionalities. Among them, LPSP-700 exhibited the highest specific surface area (525 m²/g) and a hierarchical porous structure, with abundant narrow micropores (<1 nm) and phosphorus-containing surface groups that synergistically enhanced CO₂ capture performance. The introduction of P functionalities not only improved the surface polarity and binding affinity toward CO₂ but also promoted the formation of a well-connected pore network. As a result, LPSP-700 delivered a CO₂ uptake of 2.51 mmol/g at 25 °C and 1 bar (3.34 mmol/g at 0 °C), along with a high CO₂/N₂ selectivity, fast CO₂ adsorption kinetics and moderate isosteric heat of adsorption (Q_st). Furthermore, the dynamic CO₂ adsorption capacity (0.81 mmol/g) was validated by breakthrough experiments, and cyclic adsorption–desorption tests revealed excellent stability with negligible loss in performance over five cycles. Correlation analysis revealed pores < 2.02 nm as the dominant contributors to CO₂ uptake. Overall, this work highlights sodium phytate as an effective dual-role agent for simultaneous activation and phosphorus doping and validates LPSP-700 as a sustainable and high-performance sorbent for CO₂ capture under post-combustion conditions. Full article

This study explores the drying kinetics and film formation behavior of polyvinyl alcohol (PVA)-based and PVA–bentonite composite coatings with initial thicknesses of approximately 2500 µm and 2000 µm. Four coating formulations were investigated, varying in PVA concentration and presence of bentonite as an inorganic filler. The drying process was monitored through changes in solid concentration, residual solvent content, and film thickness over time. Results revealed that coatings with higher PVA content exhibit slower drying rates, due to the transition from evaporation-controlled to diffusion-limited mechanisms, attributed to polymer densification and reduced solvent diffusivity. In contrast, coatings incorporating bentonite dried more rapidly despite their similar or higher total solids content, indicating a beneficial role of bentonite in facilitating moisture transport. Thinner coatings demonstrated faster drying but retained the characteristic mechanistic transitions observed in thicker films. A simple realistic model to simulate the drying rate was also proposed. Overall, the study highlights the significant influence of formulation variables on drying behavior and final film properties, offering valuable guidance for the design and optimization of waterborne coatings in industrial applications. Full article

This article conducts intermittent tensile deformation on 304 stainless steel; observes the microstructure, mechanical properties, and corrosion performance evolution of stainless steel under different deformation conditions; and reveals its mechanisms. The results indicate that the performance of 304 stainless steel is significantly affected by the degree of intermittent deformation. Small intermittent deformation can produce a good microstructure with uniform distribution, low martensite content, and weak texture, optimizing comprehensive mechanical properties by improving ductility, yield strength, and tensile strength. On the contrary, excessive intermittent deformation increases martensitic transformation and enhances texture, leading to a transition from ductile fracture to brittle fracture. In addition, small intermittent deformations improve corrosion resistance by promoting the formation of a stable passivation film. The microstructural changes affect the deformation mechanism and surface passivation film of stainless steel, making its mechanical strength and corrosion resistance superior to larger intermittent deformation amounts. Small intermittent deformation can improve the mechanical and corrosion properties of 304 stainless steel. This study provides a reference for the formation and performance control of metal materials and has certain practical value. Full article

With the rapid advancement of energy storage technologies, there is a growing demand for affordable, efficient, and environmentally benign battery systems. Sodium-ion batteries (SIBs) present a promising alternative to lithium-ion systems due to sodium’s high abundance and similar electrochemical properties. Particular attention is given to developing NASICON -sodium (Na) super ionic conductor, type cathode materials, especially Na3V2(PO4)3, which exhibits high thermal and structural stability. This study focuses on the sol–gel synthesis of Na₃V₂(PO₄)₃ using citric acid and ethylene glycol, as well as investigating the effect of annealing temperature (400–1000 °C) on its structural and electrochemical properties. Phase composition, morphology, textural characteristics, and electrochemical performance were systematically analyzed. Above 700 °C, a highly crystalline NASICON phase free of secondary impurities was formed, as confirmed by X-ray diffraction (XRD). Microstructural evolution revealed a transition from a loose amorphous structure to a dense granular morphology, accompanied by changes in specific surface area and porosity. The highest surface area (67.40 m²/g) was achieved at 700 °C, while increasing the temperature to 1000 °C caused pore collapse due to sintering. X-ray photoelectron spectroscopy (XPS) confirmed the predominant presence of V³⁺ ions and the formation of V⁴⁺ at the highest temperature. The optimal balance of high crystallinity, uniform elemental distribution, and stable texture was achieved at 900 °C. Electrochemical testing in a Na/NVP half-cell configuration delivered an initial capacity of 70 mAh/g, which decayed to 55 mAh/g by the 100th cycle, attributed to solid-electrolyte interphase (SEI) formation and irreversible Na⁺ trapping. These results demonstrate that the proposed approach yields high-quality Na₃V₂(PO₄)₃ cathode materials with promising potential for sodium-ion battery applications. Full article

In response to the actual needs of pure copper bonding wires, it is crucial to develop a chromium-free passivator that is environmentally friendly and has excellent corrosion resistance. In this study, three different composite organic formulations of chromium-free passivation solutions are selected: 2-Amino-5-mercapto-1,3,4 thiadiazole (AMT) + 1-phenyl-5-mercapto tetrazolium (PMTA), 2-mercaptobenzimidazole (MBI) + PMTA, and Hexadecanethiol (CHS) + sodium dodecyl sulfate (SDS). The performance analysis and corrosion mechanism were compared with traditional hexavalent chromium passivation through characterization techniques such as XRD, SEM, and XPS. The results show that the best corrosion resistance formula is the combination of the PMTA and MBI passivation agent, and all its performances are superior to those of hexavalent chromium. The samples treated with this passivation agent corrode within 18 s in the nitric acid drop test, which is better than the 16 s for Cr⁶⁺ passivation. The samples do not change color after being immersed in salt water for 48 h. Electrochemical tests and high-temperature oxidation test also indicate better corrosion resistance than Cr⁶⁺ passivation. Through the analysis of functional groups and bonding, the excellent passivation effect is demonstrated to be achieved by the synergistic action of the chemical adsorption film formation of PMTA and the anchoring effect of MBI. Eventually, a dense Cu-PMTA-BMI film is formed on the surface, which effectively blocks the erosion of the corrosive medium and significantly improves the corrosion resistance. Full article

Augmented Reality (AR) continues to generate interest as a pedagogical tool in contexts where English is a Foreign Language (EFL). However, its role in developing higher-order cognitive skills, such as inferencing, remains underexplored. This exploratory, mixed-methods study investigates whether AR can scaffold inference-making in advanced EFL learners. Forty-seven university students in XX were assigned to either a control group (CG) or an experimental group (EG). Both groups read Edgar Allan Poe’s “The Tell-Tale Heart” in digital format. The CG received a conventional inference-based comprehension lesson, while the EG engaged with two interactive AR scenes developed using the Onirix Studio platform. Pre- and post-tests assessed inferential comprehension, and qualitative data were gathered through open-ended responses. While the CG demonstrated modest post-test gains and the EG showed a slight decline, neither change reached statistical significance. Notably, qualitative findings revealed that a salient AR element—a ticking clock—likely prompted misinterpretation in the EG, disrupting symbolic reasoning and contributing to schema misalignment. However, some learners exhibited metacognitive insight suggestive of productive struggle. These results suggest that AR may hold untapped potential for developing metacognitive reflection and critical literacy. Directions for future research are outlined. Full article

β-Hydroxy-β-methylbutyrate (HMB), a natural metabolite derived from the essential amino acid leucine, is primarily recognised for its anabolic and anti-catabolic effects on skeletal muscle tissue. Recent studies indicate that HMB may also play a role in influencing the structural organisation of extracellular matrix (ECM) components, particularly collagen, which is crucial for maintaining the mechanical integrity of connective tissues. In this investigation, bovine type I collagen was polymerised in the presence of two concentrations of HMB (0.025 M and 0.25 M) to explore its potential function as a molecular modulator of fibrillogenesis. The morphology of the resulting collagen fibres and their molecular architecture were examined using atomic force microscopy (AFM) and Fourier-transform infrared (FTIR) spectroscopy. The findings demonstrated that lower levels of HMB facilitated the formation of more regular and well-organised fibrillar structures, exhibiting increased D-band periodicity and enhanced stabilisation of the native collagen triple helix, as indicated by Amide I and III band profiles. Conversely, higher concentrations of HMB led to significant disruption of fibril morphology and alterations in secondary structure, suggesting that HMB interferes with the self-assembly of collagen monomers. These structural changes are consistent with a non-covalent influence on interchain interactions and fibril organisation, to which hydrogen bonding and short-range electrostatics may contribute. Collectively, the results highlight the potential of HMB as a small-molecule regulator for soft-tissue matrix engineering, extending its consideration beyond metabolic supplementation towards controllable, materials-oriented modulation of ECM structure. Full article

Zinc oxide (ZnO) is a wide bandgap semiconductor with optoelectronic and photocatalytic properties, which depend on its optical, structural, and morphological characteristics. In this study, we synthesized ZnO thin films by chemical bath deposition (CBD) and then thermally annealed them at 400 °C and 600 °C to evaluate the effect of thermal treatments. We characterized their structural, optical, morphological, and chemical properties using X-ray diffraction (XRD), UV–Vis spectroscopy, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The optical bandgap values were 3.20 eV for the as-grown thin films, and 3.23 eV and 3.21 eV after annealing at 400 °C and 600 °C, respectively. SEM micrographs revealed a change from elongated agglomerates in the as-grown thin films to uniform flower-like structures after annealing at 600 °C. XPS analysis confirmed ZnO formation in all samples, and we detected residual precursor species only in the as-grown thin films, which were completely removed by annealing at 600 °C. These results demonstrate that the CBD synthesis of ZnO can tune its optical and morphological properties through thermal annealing, making it suitable for optoelectronic, sensing, and photocatalytic applications. Full article

Existing research on live-streaming e-commerce consumption behavior is mostly limited by a single disciplinary framework, unable to systematically parse the mechanism of macro-policies and cultural values on intergenerational consumer psychology. This study takes ASEAN cross-border live-streaming e-commerce as a scenario, integrates theories of economics, political science, and sociology, and constructs an innovative three-layer analysis model of “macroeconomic system–meso-market–micro-behavior” based on multi-source data from 2020 to 2024. It empirically explores the formation mechanism of intergenerational differences in impulse buying. The results show that the behavior differences of different groups are significantly driven by income gradient, cross-border policies (tariff adjustment and consumer protection regulations), and collectivism/individualism cultural orientations. The innovative contribution of this study is reflected in three aspects: Firstly, it breaks through the limitation of a single discipline, and for the first time, it incorporates structural variables such as policy synergy effect and family structure change into the theoretical framework of impulse buying, quantifying and revealing the differentiated impact of institutional heterogeneity in ASEAN markets on intergenerational behavior. Secondly, it reconstructs the transmission path of “cultural values–family structure–intergenerational behavior” and finds that the inhibitory effect of collectivism on impulse buying tends to weaken with age. Thirdly, it proposes a “policy instrument–generational response” matching model and verifies the heterogeneous impact of the same policy (such as tariff reduction) on different generations. This study fills the gaps in related research and can provide empirical support for ASEAN enterprises to formulate stratified marketing strategies and for policymakers to optimize cross-border e-commerce regulation. which is of great significance to promote the sustainable development of the regional live-broadcast e-commerce ecology. Full article

In recent years, Bionic reading has been introduced as a means to combat superficial reading and low comprehension rates. This paper investigates eye movements between participants who read a passage in standard font and an additional Bionic font passage. It was found that Bionic font does not significantly change eye movements when reading. Fixation durations, number of fixations and reading speeds were not significantly different between the two formats. Furthermore, fixations were spread throughout the word and not only on leading characters, even when using Bionic font; hence, participants were not able to “auto-complete” the words. Additionally, Bionic font did not facilitate easier processing of low-frequency or unfamiliar words. Overall, it would appear that Bionic font, in the short term, does not affect reading. Further investigation is needed to determine whether a long-term intervention with Bionic font is more meaningful than standard interventions. Full article

The harsh conditions of the space environment necessitate advanced materials capable of withstanding extreme temperature fluctuations and ultraviolet (UV) radiation. While epoxy-based composites are widely utilized in aerospace due to their favorable strength-to-weight ratio, they are prone to degradation, especially under prolonged high-energy UV-C exposure. This study investigated the mechanical and chemical stability of epoxy composites reinforced with nanosilica at 0, 2, 5, and 10 wt% before and after UV-C irradiation. Dynamic mechanical analysis (DMA) revealed that increased nanosilica content enhanced the storage modulus below the glass transition temperature (Tg) but reduced both Tg and the damping factor. Following UV-C exposure, all samples showed a decrease in storage modulus and Tg; however, composites with higher nanosilica content maintained better property retention. Frequency sweeps corroborated these findings, indicating improved instantaneous modulus but accelerated relaxation with increased nanosilica. Fourier-transform infrared (FTIR) spectroscopy of UV-C-exposed samples demonstrated significant oxidation and carboxylic group formation in neat epoxy, contrasting with minimal spectral changes in nanosilica-modified composites, signifying improved chemical resistance. Overall, nanosilica incorporation substantially enhances the thermomechanical and oxidative stability of epoxy composites under simulated space conditions, highlighting their potential for more durable performance in low Earth orbit applications. Full article

This study evaluates the impact of mineralogy, elemental composition, and reaction pathways on hydrogen (H₂) generation in seven ultramafic and mafic (basaltic) rocks. Experiments were conducted under typical low-temperature hydrothermal conditions (150 °C) and captured early and evolving stages of fluid–rock interaction. Pre- and post-interactions, the solid phase was analyzed using X-ray Diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS), while Inductively Coupled Plasma Mass Spectrometry (ICP-MS) was used to determine the composition of the aqueous fluids. Results show that not all geologic H₂-generating reactions involving ultramafic and mafic rocks result in the formation of serpentine, brucite, or magnetite. Our observations suggest that while mineral transformation is significant and may be the predominant mechanism, there is also the contribution of surface-mediated electron transfer and redox cycling processes. The outcome suggests continuous H₂ production beyond mineral phase changes, indicating active reaction pathways. Particularly, in addition to transition metal sites, some ultramafic rock minerals may promote redox reactions, thereby facilitating ongoing H₂ production beyond their direct hydration. Fluid–rock interactions also regenerate reactive surfaces, such as clinochlore, zeolite, and augite, enabling sustained H₂ production, even without serpentine formation. Variation in reaction rates depends on mineralogy and reaction kinetics rather than being solely controlled by Fe oxidation states. These findings suggest that ultramafic and mafic rocks may serve as dynamic, self-sustaining systems for generating H₂. The potential involvement of transition metal sites (e.g., Ni, Mo, Mn, Cr, Cu) within the rock matrix may accelerate H₂ production, requiring further investigation. This perspective shifts the focus from serpentine formation as the primary driver of H₂ production to a more complex mechanism where mineral surfaces play a significant role. Understanding these processes will be valuable for refining experimental approaches, improving kinetic models of H₂ generation, and informing the site selection and design of engineered H₂ generation systems in ultramafic and mafic formations. Full article