Search Results (19)

This paper focuses on delineating and charactering of the magma crystallization conditions of the post-collision Lavarab Alkaline Basaltic Lavas in East Iran. The lavas consist mainly of alkali basalt and basanite, with subordinate trachybasalt. Olivine mostly shows forsterite, chrysolite and hyalo-siderite compositions. Clinopyroxenes are diopside and augite, belonging to peralkaline to subalkaline magmatic series within post-collisional tectonic settings. Estimates of temperature and pressure obtained from single clinopyroxene thermobarometers suggest that crystallization temperatures vary between approximately 1110 and 1260 °C, with pressures ranging from about 0.05 to 1.35 GPa, which correspond to depths of roughly 2 to 51 km at high oxygen fugacity in both the lower and upper continental crust. Olivine-liquid thermometry yields temperatures of ~1385 to ~1393 °C for basanites and ~1275 to ~1339 °C for alkali basalts, assuming a constant pressure of 1.4 GPa. The chemical compositions of phenocrysts in the studied basaltic lavas provide evidence of magma recharge, occurring through multiple pulses of new magma injected into the existing reservoir prior to eruptions. Petrographic evidence, including absorption features, rounded crystal morphologies, patchy zones in olivine, and sieve textures in clinopyroxene, support this interpretation. Additionally, microprobe analyses reveal oscillatory variations in crystal composition from core to rim, confirming the hypothesis of dynamic magma replenishment. Full article

The quantitative pressure (P)–temperature (T) conditions of low-grade metamorphic rocks, such as pumpellyite–actinolite and greenschist facies, are largely unknown mainly owing to the difficulty in applying thermodynamic methods despite their importance in understanding the protolith and metamorphism within subducting oceanic crusts. In this study, Raman spectroscopy was applied to constrain the peak metamorphic conditions independent of thermodynamic methods for the lowest grade part (chlorite zone) of the Sanbagawa schists in the Shibukawa area, central Japan, where research on metamorphic conditions is limited. The metamorphic peak temperature of the pelitic schists estimated by Raman carbonaceous material geothermometry was 307 ± 27 °C to 395 ± 16 °C, which increased towards the northern fault (Median Tectonic Line). Raman geobarometry using the quartz-inclusions-in-spessartine system on a siliceous schist sample estimated a peak metamorphic pressure of 0.78–0.94 GPa at 360–390 °C. These results suggest that the rocks in the Shibukawa area were subducted to a depth equivalent to that of the garnet zone in central Shikoku and were then exhumed without experiencing further heating. The combination of Raman carbonaceous material geothermometry and Raman geobarometry (Raman geothermobarometry) can be effectively applied to estimate the metamorphic conditions of low-grade metamorphic rocks independent of thermodynamic methods. Full article

The Virunga Volcanic Province (VVP), located in the western branch of the East African Rift System, hosts a variety of alkaline lavas erupted from closely spaced volcanic centers. However, the magmatic system of this region, particularly in its eastern sector, remains insufficiently constrained. In this study, we present a petrological and geochemical investigation of basaltic to trachytic lavas from the eastern VVP. Thermobarometric analysis of mineral phases indicates that basalts originated from magma storage zones between 4 and 30 km deep, with crystallization temperatures of ~1200 °C and melt H₂O contents lower than 1 wt%. In contrast, more evolved magmas crystallized at similar depths, but at lower temperatures (~1050 °C) and higher H₂O contents, ranging from 2 to 4 wt%. Thermodynamic modelling suggests that extensive (up to 70%) fractional crystallization of an assemblage dominated by olivine, clinopyroxene, and plagioclase can produce the more evolved trachytic derivatives from basaltic parental melts. When integrated with previous studies from other VVP volcanoes, our findings deepen the understanding of the architecture of the magmatic system beneath the region, suggesting it resembles a well-developed multi-level plumbing system. Full article

The intensive variables, geochemical, mineralogical, and petrogenetic constraints of the Iberian peraluminous rare metal granites (RMGs), many of them unknown, are presented. The mineral chemistry of ore and gangue minerals, whole rock analyses, geothermobarometry, melt water and phosphorus contents, mass balance, and Rayleigh modeling were performed to achieve these objectives. These procedures allow us to distinguish two main contrasting granitic types: Nb-Ta-rich and Nb-Ta-poor granites. The former have lower crystallization temperatures, higher water contents, and lower emplacement pressures than Nb-Ta-poor granites. Nb-Ta-rich granites also have higher fluoride contents, strong fractionation into geochemical twins, higher Na contents, and different evolutionary trends. At the deposit scale, the fractional crystallization of micas properly explains the variation in the Ta/Nb ratio in both Nb-Ta-poor and Nb-Ta-rich RMGs, although in higher-grade granites, the variation is not as clear due to the action of fluids. Fluid phase separation processes especially occurred in the Nb-Ta rich granites, thus transporting halogens and metals that increased the grades in the top and sometimes in the core of granites. Gas-driven filter pressing processes facilitated the migration of fluid and melt near solidus melt in Nb-Ta-rich granites. The geochemical signature of the Iberian rare metal granites mainly follows the trends of two-mica granites and P-rich cordierite granites, but also of granodiorites. Full article

The Ozren ophiolite complex (OOC) of the Dinaridic Ophiolite Belt is one of the six ophiolite complexes in Bosnia and Herzegovina. This paper deals with the mineral chemistry of amphiboles determined by electron probe micro-analysis and micro-Raman spectroscopy. The detected amphibole generations and types in mafic, ultramafic, and metamorphic rocks suggest a polystage evolution and are therefore useful petrogenetic indicators of the investigated OOC. Most gabbroic rocks and dolerites contain primary magmatic amphibole1 (magnesio-hornblende to pargasite, occasionally hastingsite) and prismatic to needle-like aggregates of late magmatic amphibole2 (magnesio-hornblende), while plagiogranite contains ferri-winchite and ferro-ferri-winchite as primary magmatic amphibole. Post-magmatic amphiboles were detected in dolerites, troctolites, and lesser in peridotites. The Na-(Ti)-rich amphibole3 (ferri-winchite and ferro-ferri-winchite to katophorite and ferri-katophorite) with amphibole4 (grunerite) rim formed along the grain boundaries of clinopyroxene, amphibole1, and plagioclase in dolerites. A part of these amphiboles grows into amphibole1, 2. Kaersutite to ferri-kaersutite, associated with phlogopite, occur in troctolites and dunites, while Mhbl was detected in harzburgite. The ultramafic rocks (lherzolites, harzburgites, and dunites) and the gabbroic layer are crosscut by clinopyroxene–plagioclase gabbroic and clinopyroxene–plagioclase–amphibole gabbro–dolerite dykes, suggesting ‘dry’ and ‘hydrated’ percolating melts generated in inferred subridge and supra-subduction settings, respectively. The amphibole3 and 4 in gabbros and dolerites and similar amphibole types in ultramafic rocks could be related to inferred arc-type basaltic and plagiogranitic percolating melts and fluids. Low-Al amphibole5 (tremolite and actinolite) and associated chlorite, albite, and clinozoisite represent the ocean-floor alterations in mafic rocks. Amphibole6 (magnesio-hornblende to pargasite) was identified in metamorphic sole amphibolites. Micro-Raman spectroscopy provided typical Raman spectra for the studied amphiboles, highlighting distinct features such as bands related to ^CMg content, ^CFe³⁺ presence, TO₄ ring-breathing mode, TiO₆ stretching mode, presence > 0.3 apfu of ^CTi, and TO₄ stretching indicating ^CFe²⁺ in the structure. Applied amphibole geothermobarometry revealed the formation P–T conditions of amphibole (Amp)1 (avg. 863 °C at 0.23 GPa), Amp2 (avg. 747 °C at 0.17 GPa), Amp in the mantle rocks (avg. 853 °C at 0.64 GPa), Amp5 (avg. 349 °C at 0.03 GPa), and Amp6 (avg. 694 °C at 0.46 GPa). Full article

Granulite facies rocks provide important keys to evaluating collisional metamorphism in orogenic belts. The mafic granulites of Baoding in the Fuping Complex of the North China Craton occur within the Trans-North China Orogen (TNCO), a major Paleoproterozoic collisional orogen. Here, we present results from detailed investigations on newly discovered garnet pyroxenite, garnet two-pyroxene granulite, and garnet-bearing-plagioclase amphibolite using petrographic, mineralogical, geochemical, and zircon U-Pb dating methods. Our results show that the Fuping Complex metamorphic evolution in this study evolved in four stages: prograde (M₁), high-pressure granulite facies (M₂), granulite facies (M₃), and retrograde (M₄) stages. The mineral assemblage of the prograde stage (M₁) consists of Amp + Pl + Q within garnet cores. The mineral assemblage of high-pressure granulite facies at the peak stage (M₂) consists of Gt + Cpx + Pl + Q ± Amp, forming the garnet pyroxenite. The granulite facies stage M₃ is characterized by the occurrence of orthopyroxene, with a mineral assemblage of Gt + Cpx + Opx + Amp+ Pl + Q. The early retrograde stage M_4-1 includes clinopyroxenes scattered inside amphiboles, following the breakdown of garnet and clinopyroxene. The mineral assemblage of this stage comprises Amp + Pl + Q + Ilm ± Cpx. Later, in the late retrograde stage M_4-2, the composition of amphiboles changed to actinolite, and epidote and chlorite started to appear in the matrix. Traditional geothermobarometry yielded P-T conditions of 700~706 °C and 6.0~6.2 kbar for prograde stage M₁, 854~920 °C and 13.0~13.8 kbar for high-pressure granulite facies stage M₂, 912~939 °C and 8.1~9.9 kbar for M₃, 661~784 °C and 3.1~4.4 kbar for M_4-1, and 637~638 °C, 1.1~1.3 kbar for M_4-2, along a clockwise P-T path with a nearly isothermal decompression (ITD) and slight heating. Zircon LA-ICP-MS U-Pb dating constrains the timing of the high-pressure granulite facies metamorphic event to be between 1.83 and 1.86 Ga. Geochemical features suggest that the protoliths of the high-pressure granulites may have formed in an island arc environment within a convergent margin setting. Together with results from previous studies, our data suggest that the ~1.85 Ga metamorphic age recorded in the Fuping Complex represents a regional metamorphism in the TNCO, associated with the subduction–collision and assembly of the Eastern and Western Blocks of the NCC. Full article

The metamorphism and geological significance of amphibolites in the Diebusige and Bayanwulashan Complexes of the eastern Alxa Block, North China Craton, were poorly understood until now. This study presents the results of petrology, laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb analysis, phase equilibrium modeling and geothermobarometry for these rocks. The peak mineral assemblage of clinopyroxene + hornblende + plagioclase + K-feldspar + ilmenite + quartz + melt is inferred for amphibolite sample ALS2164 in the Diebusige Complex. Correspondingly, the peak mineral assemblage of clinopyroxene + hornblende + plagioclase ± K-feldspar + ilmenite + quartz + melt is identified for amphibolite sample ALS2191 in the Bayanwulshan Complex. Phase equilibrium modelling constrained the peak metamorphic condition of amphibolite sample ALS2164 in the Diebusige Complex to be 825–910 °C/7.2–10.8 kbar, which is similar to that (800–870 °C/7.0–10.7 kbar) of amphibolite sample ALS2191 in the Bayanwulashan Complex. Hbl–pl–qz thermobarometry yielded the metamorphic PT conditions of 732–810 °C/3.0–6.7 kbar for these amphibolites, which are consistent with the average temperatures of 763 °C, 768 °C and 780 °C calculated by Ti-zircon thermometry. As a result, phase equilibrium modelling yielded wide PT condition ranges of 800–910 °C/7.0–10.8 kbar, the lower limit of which is consistent with the upper limit of estimates by the hbl–pl–qz thermobarometer. In addition, LA-ICP-MS U–Pb analysis on metamorphic zircons yielded weighted mean ²⁰⁷Pb/²⁰⁶Pb ages of 1901 ± 22–1817 ± 21 Ma, which represent the timing of amphibolite-facies metamorphism. As a whole, the PT estimates display a high geothermal gradient, which is consistent with coeval ultrahigh-temperature metamorphism and associated mantle-derived mafic-ultramafic rocks in the Diebusige Complex. Combing this information with the previously published data from the Diebusige Complex, an extensional setting after continental collision is inferred for the eastern Alxa Block during the late Paleoproterozoic. The HREE enrichment patterns of metamorphic zircons from the amphibolites in this study are in agreement with that these amphibolites formed at relatively shallower crust than the garnet-bearing mafic granulites in the Diebusige Complex. Full article

Accretionary and collisional orogeny are often accompanied by the disturbance of the geothermal gradient, leading to high-temperature metamorphism. High-temperature metamorphic rocks are significant in their ability to help the reconstruction of the thermal histories of orogenic belts. The Tianshan Orogenic Belt, at the southwest margin of the Central Asian Orogenic Belt, is a record of the long-term subduction–collision–post-collision orogenic process that has taken place in the Phanerozoic Eon. Here, we report the discovery of mafic granulites in the Muzhaerte area, SW Tianshan. Petrographic observation reveals that the mafic granulites underwent two metamorphic stages. The peak mineral assemblage of the first stage is dominated by clinopyroxene + orthopyroxene + plagioclase + quartz + hornblende (hb¹) ± biotite, and the post-peak mineral assemblage of the second stage is dominated by clinopyroxene + plagioclase + quartz + hornblende (hb²) + biotite. The calculated results obtained from the two-pyroxene thermobarometers and the Al-in-hornblende barometer for the mafic granulites indicate that the metamorphic conditions of mafic granulites are 760–860 °C, <0.39–0.41 Gpa. The mafic granulites recorded a high-grade granulite facies thermal metamorphic event with the highest temperature limit currently recorded in the Central Tianshan Block. Full article

This paper presents major and trace element compositions of the clinopyroxene phenocrysts from variably altered basaltic rocks from the Yüksekova Complex from E Anatolia (Elazığ) to reveal the geochemical affinity of the basaltic magmatism and the intensive parameters during magmatic crystallization. The Yüksekova Complex crops out over extensive areas to the north of the Bitlis suture. The investigated samples come from an area of ca. 2500 km² in the Elazığ province. Petrographically, the basaltic rocks are represented by basalt, porphyric basalt and dolerite. The rocks are characterized by plagioclase, clinopyroxene, magnetite and ilmenite and are devoid of any hornblende and biotite, whereby clinopyroxene and plagioclase form phenocrysts. Generally, the groundmass is variably altered, whereas clinophenocrysts are comparatively fresh. The clinopyroxene is represented by the composition Wo_37–48En_43–53Fs_4–17, with Mg/(Mg + Fe²⁺) ratios of 0.93–0.73. Compositionally, the clinopyroxenes resemble those from island arc tholeiitic, calc-alkaline and anorogenic tholeiitic rocks. Clinopyroxene-melt geothermobarometry yielded temperatures of 1146 and 1193 °C and pressures of 1.4 to 7.0 kbar, suggesting that the clinopyroxene phenocrysts started to grow at variable crustal depths. There is no apparent difference of magma temperatures between different magma affinities. The Fe–Mg partition coefficient between clinopyroxene and melt (K_D ^Fe−Mg_Cpx-Melt = 0.27) suggests that the parental magmas in equilibrium with clinopyroxene were mostly primitive, with Mg# of 65–79. The REE patterns of parental melts in equilibrium with clinopyroxene phenocrysts resemble those of low-K tholeiitic to middle- to high-K calc-alkaline rocks from the magmatic arcs. The results of this study are mostly consistent with the inferences from the whole-rock geochemistry, and indicate that the major and trace element geochemistry can be effectively used to infer the geochemical affinities of the highly altered basaltic rocks. Full article

The Susong metamorphic complex (SSC) in the southern margin of the Dabie orogenic belt (DOB) in central-eastern China is a key metamorphic unit for understanding subduction and exhumation processes in the DOB. However, the formation age and metamorphic grade of the SSC remain uncertain, hampering our understanding of the mechanism of the formation of the DOB. An integrated study of field survey, regional metamorphic petrology, geothermobarometry, and U–Pb dating of zircon was carried out in this study. Our results reveal that the SSC was metamorphosed under epidote amphibolite- to amphibolite-facies conditions with average metamorphic P–T values of 0.98 ± 0.07 GPa and 531 ± 35 °C. The smooth spatial variation in peak P–T conditions and an apparent geothermal gradient of ~17 °C/km indicate that the SSC as a whole fall into Barrovian-type metamorphic environments. Zircon U–Pb dating for garnet–mica schists of sample ZT003, ZT005 and ZT006 yield five (Groups I to V), six (Groups I to VI) and five (Groups I to V) age groups, respectively, concentrating on the Meso-Neoarchean, early-middle Paleoproterozoic, middle Mesoproterozoic, early Neoproterozoic, Palaeozoic and Triassic-lower Jurassic. Therein, a 259–190 Ma (Group V) from zircons with Th/U ratios of <0.1 in sample ZT006 record the timing of both peak and retrograde metamorphism for the SSC. All other ages are detrital zircon ages, and from age provenances in the DOB or the Yangtze Block (YZB), indicating the YZB affinity of the SSC. The two youngest age populations of 427–415 Ma (Group VI) and 475–418 Ma (Group V) from samples ZT005 and ZT006, respectively, suggest that the formation age of the SSC could be Middle Devonian. The similarity of formation age and peak P-T conditions of the SSC to Foziling Group, located in the northernmost DOB, implies that both units formed the sedimentary cover on the passive continental margin of the YZB during the late Palaeozoic, and subducted into the middle-lower crust of 20–40 km depth as a whole, corresponding to the shallow subduction. Compared to the deep subduction defined by high-pressure (HP) and ultrahigh-pressure (UHP) units, larger differences in peak P–T conditions, age and geothermal gradient between two different tectonic environments happen. Accordingly, it is speculated that a transitional subduction from shallow to deep levels occurred at Moho depths during the Early Triassic, and is due to a change in subduction dip angle. Full article

The eruptions of Campi Flegrei (Southern Italy), one of the most studied and dangerous active volcanic areas of the world, are fed by mildly potassic alkaline magmas, from shoshonite to trachyte and phonotrachyte. Petrological investigations carried out in past decades on Campi Flegrei rocks provide crucial information for understanding differentiation processes in its magmatic system. However, the compositional features of rocks are a palimpsest of many processes acting over timescales of 10⁰–10⁴ years, including crystal entrapment from multiple reservoirs with different magmatic histories. In this work, olivine, clinopyroxene and feldspar crystals from volcanic rocks related to the entire period of Campi Flegrei’s volcanic activity are checked for equilibrium with combined and possibly more rigorous tests than those commonly used in previous works (e.g., Fe–Mg exchange between either olivine or clinopyroxene and melt), with the aim of obtaining more robust geothermobarometric estimations for the magmas these products represent. We applied several combinations of equilibrium tests and geothermometric and geobarometric methods to a suite of rocks and related minerals spanning the period from ~59 ka to 1538 A.D. and compared the obtained results with the inferred magma storage conditions estimated in previous works through different methods. This mineral-chemistry investigation suggests that two prevalent sets of T–P (temperature–pressure) conditions, here referred to as “magmatic environments”, characterized the magma storage over the entire period of Campi Flegrei activity investigated here. These magmatic environments are ascribable to either mafic or differentiated magmas, stationing in deep and shallow reservoirs, respectively, which interacted frequently, mostly during the last 12 ka of activity. In fact, open-system magmatic processes (mixing/mingling, crustal contamination, CO₂ flushing) hypothesized to have occurred before several Campi Flegrei eruptions could have removed earlier-grown crystals from their equilibrium melts. Moreover, our new results indicate that, in the case of complex systems such as Campi Flegrei’s, in which different pre-eruptive processes can modify the equilibrium composition of the crystals, one single geothermobarometric method offers little chance to constrain the magma storage conditions. Conversely, combined methods yield more robust results in agreement with estimates obtained in previous independent studies based on both petrological and geophysical methods. Full article

Three samples of meta-acidic rocks with pre-Alpine metamorphic relicts from the Sesia-Lanzo Zone eclogitic continental crust were investigated using stepwise controlled elemental maps by means of the Quantitative X-ray Maps Analyzer (Q-XRMA). Samples were chosen with the aim of analysing the reacting zones along the boundaries between the pre-Alpine and Alpine mineral phases, which developed in low chemically reactive systems. The quantitative data treatment of the X-ray images was based on a former multivariate statistical analytical stage followed by a sequential phase and sub-phase classification and permitted to isolate and to quantitatively investigate the local paragenetic equilibria. The parageneses thus observed were interpreted as related to the pre-Alpine metamorphic or magmatic stages as well as to local Alpine re-equilibrations. On the basis of electron microprobe analysis, specific compositional ranges were defined in micro-domains of the relict and new paragenetic equilibria. In this way calibrated compositional maps were obtained and used to contour different types of reacting boundaries between adjacent solid solution phases. The pre-Alpine and Alpine mineral parageneses thus obtained allowed to perform geothermobarometry on a statistically meaningful and reliable dataset. In general, metamorphic temperatures cluster at 600–700 °C and 450–550 °C, with lower temperatures referred to a retrograde metamorphic re-equilibration. In all the cases described, pre-Alpine parageneses were overprinted by an Alpine metamorphic mineral assemblage. Pressure-temperature estimates of the Alpine stage averagely range between 420 to 550 °C and 12 to 16.5 kbar. The PT constraints permitted to better define the pre-Alpine metamorphic scenario of the western Austroalpine sectors, as well as to better understand the influence of the pre-Alpine metamorphic inheritance on the forthcoming Alpine tectonic evolution. Full article

The composite Albian–Eocene orogenic wedge of the northern part of the Inner Western Carpathians (IWC) comprises the European Variscan basement with the Upper Carboniferous–Triassic cover and the Jurassic to Upper Cretaceous sedimentary successions of a large oceanic–continental Atlantic (Alpine) Tethys basin system. This paper presents an updated evolutionary model for principal structural units of the orogenic wedge (i.e., Fatricum, Tatricum and Infratatricum) based on new and published white mica ⁴⁰Ar/³⁹Ar geochronology and P–T estimates by Perple_X modeling and geothermobarometry. The north-directed Cretaceous collision led to closure of the Jurassic–Early Cretaceous basins, and incorporation of their sedimentary infill and a thinned basement into the Albian–Cenomanian/Turonian accretionary wedge. During this compressional D1 stage, the subautochthonous Fatric structural units, including the present-day higher Infratatric nappes, achieved the metamorphic conditions of ca. 250–400 °C and 400–700 MPa. The collapse of the Albian–Cenomanian/Turonian wedge and contemporary southward Penninic oceanic subduction enhanced the extensional exhumation of the low-grade metamorphosed structural complexes (D2 stage) and the opening of a fore-arc basin. This basin hemipelagic Coniacian–Campanian Couches-Rouges type marls (C.R.) spread from the northern Tatric edge, throughout the Infratatric Belice Basin, up to the peri-Pieniny Klippen Belt Kysuca Basin, thus tracing the south-Penninic subduction. The ceasing subduction switched to the compressional regime recorded in the trench-like Belice “flysch” trough formation and the lower anchi-metamorphism of the C.R. at ca. 75–65 Ma (D3 stage). The Belice trough closure was followed by the thrusting of the exhumed low-grade metamorphosed higher Infratatric complexes and the anchi-metamorphosed C.R. over the frontal unmetamorphosed to lowest anchi-metamorphosed Upper Campanian–Maastrichtian “flysch” sediments at ca. 65–50 Ma (D4 stage). Phengite from the Infratatric marble sample SRB-1 and meta-marl sample HC-12 produced apparent ⁴⁰Ar/³⁹Ar step ages clustered around 90 Ma. A mixture interpretation of this age is consistent with the presence of an older metamorphic Ph1 related to the burial (D1) within the Albian–Cenomanian/Turonian accretionary wedge. On the contrary, a younger Ph2 is closely related to the late- to post-Campanian (D3) thrust fault formation over the C.R. Celadonite-enriched muscovite from the subautochthonous Fatric Zobor Nappe meta-quartzite sample ZI-3 yielded a mini-plateau age of 62.21 ± 0.31 Ma which coincides with the closing of the Infratatric foreland Belice “flysch” trough, the accretion of the Infratatricum to the Tatricum, and the formation of the rear subautochthonous Fatricum bivergent structure in the Eocene orogenic wedge. Full article

Garnet-bearing metapelites in the Helvetic and Austroalpine pre-Mesozoic polymetamorphic basement are characterised by pressure-temperature path segments reconstructed by microstructurally controlled geothermobarometry, and the Th-U-Pb monazite age distribution pattern revealed by the electron probe microanalyser (EPMA). In the Helvetic Aiguilles Rouges Massif and the Austroalpine Oetztal-Stubai basement to the NW an Ordovician-to-Silurian high temperature event preceded a pressure-dominated Carboniferous metamorphism. In the Austroalpine basement units to the south of the Tauern Window, the maximal pressures of the Carboniferous amphibolite-facies metamorphism range from 12 to 6 kbar. The decompressional P-T path segments signal a transition to low pressure conditions. A subsequent high pressure overprint is restricted to the Prijakt Subgroup unit in the Schobergruppe and documented by Cretaceous monazite crystallisation at 88 ± 6 Ma. In the Austroalpine Saualpe basement to the SE, a distinct early Permian metamorphism which started at low pressures of ~4 kbar/500 °C and reached maximal 6 kbar/600–650 °C predated the intrusion of Permian pegmatites. Permian monazite crystallised in line with the intrusion of pegmatites. Corona microstructures around the Permian monazites indicate retrogression previous to a Cretaceous high pressure metamorphism. That way, pressure-temperature-time paths resolve the spatial and temporal evolution in the polymetamorphic Alpine basement prior to the Tertiary collision. Full article

The basement of eastern Mexico comprises Grenvillian-age granulite-facies metamorphic rocks. The Oaxacan Complex represents the largest outcrop belt of this basement in Mexico. In this work, southwestern Oaxacan Complex garnets are studied from a petrographical, geochemical, and geothermobarometrical perspective for the first time. The studied garnets display different grain sizes nucleated in a polyphase evolution. The almandine end member proportion is similar in all of the studied lithotypes. The highest pyrope concentrations are found in Qz Fsp paragenesis and ultramafic rocks and the lowest pyrope concentrations are found in amphibolite. The highest grossular and spessartine concentrations are found in the amphibolite lithotype. Southwestern Oaxacan Complex garnets from paraderivate samples are more enriched in Rb, Ba, Pb, Ni, and Zn than those from orthoderivate samples enriched in Ti and V. This fact is related to the nature of the protoliths and the mineral phases that fractionate the same minor and trace elements. Garnets from para- and orthoderivate samples display 0.02–1.1 Eu/Eu* anomalies. This fact indicates that almost all of the garnets formed while the plagioclase was stable, and it does not rule out the interpretation that some garnets were peritectic. The pressure obtained using a Grt-Opx-Pl-Qz geobarometer in the southwestern Oaxacan Complex is higher than the pressure obtained in the northern part of the Complex, and it is consistent with the pressure obtained in the Grenvillian-age granulites of the Novillo Gneiss from northeastern Mexico. Geothermobarometric studies reveal different P-T features at the study site, so different structural levels of the orogen are inferred. Full article