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Search Results (5,142)

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Keywords = high-performance polymer

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17 pages, 2260 KB  
Article
Fabrication of 3D Porous and Flexible Thermoplastic Polyurethane/Carbon Nanotube Composites Towards High-Performance Microwave Absorption
by Yanfang Li, Yandong Xu, Guangming Wen and Junwei Wang
Molecules 2025, 30(17), 3610; https://doi.org/10.3390/molecules30173610 - 3 Sep 2025
Abstract
Materials with the characteristics of lightweight, thinness, flexibility, strong absorption, and broad bandwidth are of great concern in the microwave absorption field. Herein, a novel and facile technique, the vapor-induced phase separation (VIPS) method, was adopted to fabricate flexible thermoplastic polyurethane (TPU)/carbon nanotube [...] Read more.
Materials with the characteristics of lightweight, thinness, flexibility, strong absorption, and broad bandwidth are of great concern in the microwave absorption field. Herein, a novel and facile technique, the vapor-induced phase separation (VIPS) method, was adopted to fabricate flexible thermoplastic polyurethane (TPU)/carbon nanotube (CNT) composites with a three-dimensional (3D) porous structure. The microstructure and electromagnetic wave absorption properties of the composites were tuned by varying the CNT weight ratio. The results show that the CNT established strong interfacial bonding with the TPU matrix. Different CNT weight ratios had a significant effect on the microstructure and electromagnetic parameters of the composites. The TPU/CNT composites achieved the minimum reflection loss (RLmin) of −25.33 dB at 2.35 mm and an effective absorption bandwidth (EAB) of 4.89 GHz at 1.6 mm with a relatively low CNT weight ratio of 1 wt%. The conductive loss, dielectric loss, and multiple scattering synergistically contribute to favorable microwave absorption performances. This study showcases the use of a facile fabrication approach for the generation of flexible and porous TPU-based or other polymer counterparts-based functional composites via the VIPS method; it also paves the way for the large-scale application of high-performance microwave absorption materials. Full article
(This article belongs to the Section Materials Chemistry)
28 pages, 5175 KB  
Article
Buckling Characteristics of Bio-Inspired Helicoidal Laminated Composite Spherical Shells Under External Normal and Torsional Loads Subjected to Elastic Support
by Mohammad Javad Bayat, Amin Kalhori, Masoud Babaei and Kamran Asemi
Buildings 2025, 15(17), 3165; https://doi.org/10.3390/buildings15173165 - 3 Sep 2025
Abstract
Spherical shells exhibit superior strength-to-geometry efficiency, making them ideal for industrial applications such as fluid storage tanks, architectural domes, naval vehicles, nuclear containment systems, and aeronautical and aerospace components. Given their critical role, careful attention to the design parameters and engineering constraints is [...] Read more.
Spherical shells exhibit superior strength-to-geometry efficiency, making them ideal for industrial applications such as fluid storage tanks, architectural domes, naval vehicles, nuclear containment systems, and aeronautical and aerospace components. Given their critical role, careful attention to the design parameters and engineering constraints is essential. The present paper investigates the buckling responses of bio-inspired helicoidal laminated composite spherical shells under normal and torsional loading, including the effects of a Winkler elastic medium. The pre-buckling equilibrium equations are derived using linear three-dimensional (3D) elasticity theory and the principle of virtual work, solved via the classical finite element method (FEM). The buckling load is computed using a nonlinear Green strain formulation and a generalized geometric stiffness approach. The shell material employed in this study is a T300/5208 graphite/epoxy carbon fiber-reinforced polymer (CFRP) composite. Multiple helicoidal stacking sequences—linear, Fibonacci, recursive, exponential, and semicircular—are analyzed and benchmarked against traditional unidirectional, cross-ply, and quasi-isotropic layups. Parametric studies assess the effects of the normal/torsional loads, lamination schemes, ply counts, polar angles, shell thickness, elastic support, and boundary constraints on the buckling performance. The results indicate that quasi-isotropic (QI) laminate configurations exhibit superior buckling resistance compared to all the other layup arrangements, whereas unidirectional (UD) and cross-ply (CP) laminates show the least structural efficiency under normal- and torsional-loading conditions, respectively. Furthermore, this study underscores the efficacy of bio-inspired helicoidal stacking sequences in improving the mechanical performance of thin-walled composite spherical shells, exhibiting significant advantages over conventional laminate configurations. These benefits make helicoidal architectures particularly well-suited for weight-critical, high-performance applications in aerospace, marine, and biomedical engineering, where structural efficiency, damage tolerance, and reliability are paramount. Full article
(This article belongs to the Special Issue Computational Mechanics Analysis of Composite Structures)
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11 pages, 1251 KB  
Article
AI-Enhanced Model for Integrated Performance Prediction and Classification of Vibration-Reducing Gloves for Hand-Transmitted Vibration Control
by Yumeng Yao, Wei Xiao, Alireza Moezi, Marco Tarabini, Paola Saccomandi and Subhash Rakheja
Actuators 2025, 14(9), 436; https://doi.org/10.3390/act14090436 - 3 Sep 2025
Abstract
This study presents a human-centric, data-driven modeling framework for the intelligent evaluation and classification of vibration-reducing (VR) gloves used in hand-transmitted vibration environments. Recognizing the trade-offs between protection and functionality, the integrated performance assessment incorporates three critical and often conflicting metrics: manual dexterity, [...] Read more.
This study presents a human-centric, data-driven modeling framework for the intelligent evaluation and classification of vibration-reducing (VR) gloves used in hand-transmitted vibration environments. Recognizing the trade-offs between protection and functionality, the integrated performance assessment incorporates three critical and often conflicting metrics: manual dexterity, grip strength, and distributed vibration transmissibility at the palm and fingers. Three independent experiments involving fifteen participants were conducted to evaluate the individual performance of ten commercially available VR gloves fabricated from air bladders, polymers, and viscoelastic gels. The effects of VR gloves on manual dexterity, grip strength, and distributed vibration transmission were investigated. The resulting experimental data were used to train and tune seven different machine learning models. The results suggested that the AdaBoost model demonstrated superior predictive performance, achieving 92% accuracy in efficiently evaluating the integrated performance of VR gloves. It is further shown that the proposed data-driven model could be effectively applied to classify the performances of VR gloves in three workplace conditions based on the dominant vibration frequencies (low-, medium-, and high-frequency). The proposed framework demonstrates the potential of AI-enhanced intelligent actuation systems to support personalized selection of wearable protective equipment, thereby enhancing occupational safety, usability, and task efficiency in vibration-intensive environments. Full article
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11 pages, 1951 KB  
Review
Recent Advances in Materials for Uranium Extraction from Salt Lake Brine: A Review
by Panting Wang, Miao Lei, Junhang Huang, Yuanhao Li, Ye Li and Junpeng Guo
Chemistry 2025, 7(5), 142; https://doi.org/10.3390/chemistry7050142 - 3 Sep 2025
Abstract
With the rising importance of nuclear energy in the global energy landscape, the sustainable development of uranium resources has garnered increasing attention. Salt lake brine, as an unconventional uranium source, holds significant potential due to its relatively high uranium concentration and the co-occurrence [...] Read more.
With the rising importance of nuclear energy in the global energy landscape, the sustainable development of uranium resources has garnered increasing attention. Salt lake brine, as an unconventional uranium source, holds significant potential due to its relatively high uranium concentration and the co-occurrence of valuable elements such as lithium, boron, and potassium. However, the high salinity and complex ionic composition of brine environments pose considerable challenges for the efficient and selective extraction of uranium. In recent years, the rapid advancement of novel adsorbent materials has provided promising technological pathways for uranium extraction from salt lake brine. This review systematically summarizes recent progress in the application of inorganic and carbon-based materials, organic polymers with functional group modifications, and biomass-derived and green adsorbents in this field. The construction strategies, performance characteristics, and adsorption mechanisms of these materials are discussed in detail, with particular emphasis on their selectivity and stability under complex saline conditions. Furthermore, the application status and future prospects of emerging materials and techniques—such as photocatalysis and electrochemistry—are also explored. This review aims to offer theoretical insights and technical references to support the sustainable exploitation of uranium resources from salt lake brines. Full article
(This article belongs to the Section Green and Environmental Chemistry)
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19 pages, 1827 KB  
Review
A Review of Polymer Composites and Adhesives for Aircraft Landing Gear Applications
by Hasan Caglar, David Ayre, Andrew Mills, Yigeng Xu and Martin Skote
Aerospace 2025, 12(9), 794; https://doi.org/10.3390/aerospace12090794 - 2 Sep 2025
Abstract
This review paper explores the transformative potential of polymer composites and adhesives in reducing the weight of aircraft landing gear, thereby improving fuel efficiency and lowering emissions. The replacement of conventional metallic materials and mechanical fastenings with advanced thermoset/thermoplastic composites and adhesives can [...] Read more.
This review paper explores the transformative potential of polymer composites and adhesives in reducing the weight of aircraft landing gear, thereby improving fuel efficiency and lowering emissions. The replacement of conventional metallic materials and mechanical fastenings with advanced thermoset/thermoplastic composites and adhesives can significantly enhance durability and performance in demanding operational environments. Unlike traditional fastening methods, the structural adhesives eliminate the weight penalties associated with mechanical fasteners, offering a lighter and more reliable solution that meets the rigorous demands of modern aerospace engineering. Furthermore, the review highlights a variety of manufacturing techniques and innovative materials, including bio-based polymers, self-healing materials, noobed composites, helicoid composites, and hybrid composites. The use of thermosets and vitrimers in adhesive bonding are presented, illustrating their ability to create robust and durable joints that enhance the structural integrity of landing gear systems. The paper also addresses current challenges, including recycling limitations and high material costs. Sustainability considerations, including the integration of self-healing materials, structural health monitoring systems, and circular economy principles, are discussed as essential for aligning the aerospace sector with global climate goals. Full article
(This article belongs to the Section Aeronautics)
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22 pages, 14069 KB  
Article
Assessment of Atmospheric Correction Algorithms for Landsat-8/9 Operational Land Imager over Inland and Coastal Waters
by Yiqiang Hu, Haigang Zhan, Qingyou He and Weikang Zhan
Remote Sens. 2025, 17(17), 3055; https://doi.org/10.3390/rs17173055 - 2 Sep 2025
Abstract
Atmospheric correction (AC) over inland and coastal waters remains a key challenge in ocean color remote sensing, often limiting the effective use of satellite data for aquatic monitoring. AC algorithm performance is highly sensitive to water type and optical properties. To address this, [...] Read more.
Atmospheric correction (AC) over inland and coastal waters remains a key challenge in ocean color remote sensing, often limiting the effective use of satellite data for aquatic monitoring. AC algorithm performance is highly sensitive to water type and optical properties. To address this, we systematically evaluated six state-of-the-art AC algorithms—ACOLITE, C2RCC, iCOR, L2GEN, OC-SMART, and POLYMER—using Landsat-8/9 OLI data. This study leverages 440 high-quality in situ radiometric matchups spanning a wide range of aquatic environments, including inland lakes from China’s Satellite-Ground Synchronous Campaign and coastal waters from the globally distributed GLORIA dataset. These complementary datasets provide a robust benchmark for evaluating AC algorithm performance. A unified Optical Water Type (OWT) classification framework ensured consistency across environmental conditions. Results highlight significant variability in algorithm performance based on water type. In coastal waters, L2GEN demonstrated the lowest errors in visible bands, whereas OC-SMART achieved superior overall accuracy in inland waters. Notably, ACOLITE exhibited better performance than other algorithms in the blue spectral region (443 and 482 nm) for inland waters. OWT-specific analysis showed that OC-SMART maintained robust accuracy across the turbidity gradient, while ACOLITE and iCOR excelled in highly turbid waters (OWTs 5–6). In contrast, L2GEN, C2RCC, and POLYMER were more effective in clearer waters (OWTs 3–4). The study further discusses the applicability of each algorithm and offers recommendations for mitigating adjacency effects (AE) to improve AC accuracy. These findings provide valuable guidance for selecting and optimizing AC strategies for inland and coastal water monitoring. Full article
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15 pages, 3389 KB  
Article
Preparation, Performance Research and Field Application Practice of Temperature-Sensitive Lost Circulation Material for Shale Oil Wells
by Wenzhe Zhang, Jinsheng Sun, Feng Shen, Wei Li, Xianbin Huang, Kaihe Lv, Meichun Li, Shaofei Xue, Shiyu Wang and Hongmei Li
Polymers 2025, 17(17), 2395; https://doi.org/10.3390/polym17172395 - 2 Sep 2025
Abstract
Drilling fluid losses into formation voids are among the major issues that lead to increases in the costs and nonproductive time of operations. Lost circulation materials have been widely used to stop or mitigate losses. In most cases, the size of the loss [...] Read more.
Drilling fluid losses into formation voids are among the major issues that lead to increases in the costs and nonproductive time of operations. Lost circulation materials have been widely used to stop or mitigate losses. In most cases, the size of the loss zone is not known, making conventional lost circulation materials unsuitable for plugging the loss zone. In this study, novel temperature-sensitive LCM (TS-LCM) particles composed of diglycidyl ether of bisphenol A (DGEBA) and 4,4′-diaminodiphenyl methane were prepared. It is a thermal-response shape-memory polymer. The molecular structure was analyzed by Fourier transform infrared spectroscopy. The glass transition temperature (Tg) was tested by Different scanning calorimetry (DSC). The shape-memory properties were evaluated by a bend-recovery test instrument. The expansion and mechanical properties of particles were investigated under high temperature and high pressure. Fracture sealing testing apparatus was used to evaluate sealing performance. The mechanism of sealing fracture was discussed. Research results indicated that the Tg of the TS-LCM was 70.24 °C. The shape fixation ratio was more than 99% at room temperature, and the shape recovery ratio was 100% above the Tg. The particle was flaky before activation. It expanded to a cube shape, and the thickness increased when activated. The rate of particle size increase for D90 was more than 60% under 120 °C and 20 MPa. The activated TS-LCM particles had high crush strength. The expansion of the TS-LCM particles could self-adaptively bridge and seal the fracture without knowing the width. The addition of TS-LCM particles could seal the tapered slot with entrance widths of 2 mm, 3 mm and 4 mm without changing the lost circulation material formulation. The developed TS-LCM has good compatibility with local saltwater-based drilling fluid. In field tests in the Yan’an area of the Ordos Basin, 15 shale oil horizontal wells were plugged with excellent results. The equivalent circulating density of drilling fluid leakage increased by an average of 0.35 g/cm3, and the success rate of plugging malignant leakage increased from 32% to 82.5%. The drilling cycle was shortened by an average of 14.3%, and the effect of enhancing the pressure-bearing capacity of the well wall was significant. The prepared TS-LCM could cure fluid loss in a fractured formation efficiently. It has good prospects for promotion. Full article
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18 pages, 5631 KB  
Article
Large-Scale Molecular Dynamics of Anion-Exchange Membranes: Molecular Structure of QPAF-4 and Water Transport
by Tetsuro Nagai, Takumi Kawaida and Koji Yoshida
Membranes 2025, 15(9), 266; https://doi.org/10.3390/membranes15090266 - 2 Sep 2025
Abstract
Understanding the molecular structure and water transport behavior in anion-exchange membranes (AEMs) is essential for advancing efficient and cost-effective alkaline fuel cells. In this study, large-scale all-atom molecular dynamics simulations of QPAF-4, a promising AEM material, were performed at multiple water uptakes ( [...] Read more.
Understanding the molecular structure and water transport behavior in anion-exchange membranes (AEMs) is essential for advancing efficient and cost-effective alkaline fuel cells. In this study, large-scale all-atom molecular dynamics simulations of QPAF-4, a promising AEM material, were performed at multiple water uptakes (λ = 2, 3, 6, and 13). The simulated systems comprised approximately 1.4 to 2.1 million atoms and spanned approximately 26 nm, thus enabling direct comparison with both wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS) experiments. The simulations successfully reproduced experimentally observed structure factors, accurately capturing microphase-separated morphologies at the mesoscale (~8 nm). Decomposition of the SAXS profile into atom pairs suggests that increasing water uptake may facilitate the aggregation of fluorinated alkyl chains. Furthermore, the calculated pair distribution functions showed excellent agreement with WAXS data, suggesting that the atomistic details were accurately reproduced. The water dynamics exhibited strong dependence on hydration level: At low water uptake, mean squared displacement showed persistent subdiffusive behavior even at long timescales (~200 ns), whereas almost normal diffusion was observed when water uptake was high. These results suggest that water mobility may be significantly influenced by nanoconfinement and strong interactions exerted by polymer chains and counterions under dry conditions. These findings provide a basis for the rational design and optimization of high-performance membrane materials. Full article
(This article belongs to the Special Issue Design, Synthesis and Applications of Ion Exchange Membranes)
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14 pages, 3061 KB  
Article
High–Energy–Density Fiber Supercapacitor Based on Graphene-Enhanced Hierarchically Nanostructured Conductive Polymer Composite Electrodes
by Chuangen Ye, Qingfeng Yang, Mingxian Xu, Haitang Qiu, Xiaozhen Zhang, Jianping Ma, Haiyang Gao, Xuansheng Feng and Yong Li
Nanomaterials 2025, 15(17), 1350; https://doi.org/10.3390/nano15171350 - 2 Sep 2025
Abstract
The development of portable and wearable electronics has promoted the advancement of fiber supercapacitors (FSCs), but their low energy density still limits their application in flexible devices. Herein, we incorporated micron-sized graphene dispersions at varying concentrations into the polyaniline (PANI) precursor solution prepared [...] Read more.
The development of portable and wearable electronics has promoted the advancement of fiber supercapacitors (FSCs), but their low energy density still limits their application in flexible devices. Herein, we incorporated micron-sized graphene dispersions at varying concentrations into the polyaniline (PANI) precursor solution prepared via electrochemical polymerization and subsequently electrodeposited PANI/graphene composites onto the surface of carbon nanotube (CNT) fibers, ultimately obtaining fibrous PANI/graphene@CNT composite electrodes. This electrode material not only exhibits the superior electrochemical activity characteristic of conducting polymers synthesized by electrochemical polymerization but also possesses a relatively high specific surface area. Furthermore, we fabricated coaxial fiber supercapacitors using PANI/graphene@CNT composite fibers and CNT films as the positive and negative electrode materials, respectively. The maximum energy density and power density could reach 160.5 µWh cm−2 and 13 mW cm−2 respectively, proving its excellent energy storage and output capabilities. More importantly, the prepared CFASC device showed remarkable mechanical and electrochemical durability. Even after 3000 bending cycles, it retained 89.77% of its original capacitance, highlighting its promising applicability in the realm of flexible electronics. The resulting devices demonstrate excellent electrochemical performance and mechanical stability. Full article
(This article belongs to the Special Issue Application of Nanostructures in Electrochemical Energy Storage)
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29 pages, 9470 KB  
Review
Millimeter-Wave Antennas for 5G Wireless Communications: Technologies, Challenges, and Future Trends
by Yutao Yang, Minmin Mao, Junran Xu, Huan Liu, Jianhua Wang and Kaixin Song
Sensors 2025, 25(17), 5424; https://doi.org/10.3390/s25175424 - 2 Sep 2025
Abstract
With the rapid evolution of 5G wireless communications, millimeter-wave (mmWave) technology has become a crucial enabler for high-speed, low-latency, and large-scale connectivity. As the critical interface for signal transmission, mmWave antennas directly affect system performance, reliability, and application scope. This paper reviews the [...] Read more.
With the rapid evolution of 5G wireless communications, millimeter-wave (mmWave) technology has become a crucial enabler for high-speed, low-latency, and large-scale connectivity. As the critical interface for signal transmission, mmWave antennas directly affect system performance, reliability, and application scope. This paper reviews the current state of mmWave antenna technologies in 5G systems, focusing on antenna types, design considerations, and integration strategies. We discuss how the multiple-input multiple-output (MIMO) architectures and advanced beamforming techniques enhance system capacity and link robustness. State-of-the-art integration methods, such as antenna-in-package (AiP) and chip-level integration, are examined for their importance in achieving compact and high-performance mmWave systems. Material selection and fabrication technologies—including low-loss substrates like polytetrafluoroethylene (PTFE), hydrocarbon-based materials, liquid crystal polymer (LCP), and microwave dielectric ceramics, as well as emerging processes such as low-temperature co-fired ceramics (LTCC), 3D printing, and micro-electro-mechanical systems (MEMS)—are also analyzed. Key challenges include propagation path limitations, power consumption and thermal management in highly integrated systems, cost–performance trade-offs for mass production, and interoperability standardization across vendors. Finally, we outline future research directions, including intelligent beam management, reconfigurable antennas, AI-driven designs, and hybrid mmWave–sub-6 GHz systems, highlighting the vital role of mmWave antennas in shaping next-generation wireless networks. Full article
(This article belongs to the Special Issue Millimeter-Wave Antennas for 5G)
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29 pages, 6036 KB  
Review
Green Composites in Additive Manufacturing: A Combined Review and Bibliometric Exploration
by Maria Tănase and Cristina Veres
J. Manuf. Mater. Process. 2025, 9(9), 301; https://doi.org/10.3390/jmmp9090301 - 1 Sep 2025
Abstract
This review provides a comprehensive analysis of recent developments in the additive manufacturing of green composites, with a particular focus on their mechanical behavior. A bibliometric analysis of 482 research articles indexed in the Web of Science Core Collection and published between 2015 [...] Read more.
This review provides a comprehensive analysis of recent developments in the additive manufacturing of green composites, with a particular focus on their mechanical behavior. A bibliometric analysis of 482 research articles indexed in the Web of Science Core Collection and published between 2015 and 2025 reveals a sharp increase in publications, with dominant contributions from countries such as China, India, and the United States, as well as strong collaboration networks centered on materials science and polymer engineering. Thematic clustering highlights a growing emphasis on natural fiber reinforcement, biodegradable matrices, and performance optimization. Despite these advances, few studies have combined bibliometric analysis with a technical evaluation of mechanical performance, leaving a gap in understanding the relationship between research trends and material or process optimization. Building on these insights, the review synthesizes current knowledge on material composition, print parameters, infill design, and post-processing, identifying their combined effects on tensile strength, stiffness, and durability. The study concludes that multi-variable optimization—encompassing fiber-matrix compatibility, print architecture, and thermal control—is essential to achieving eco-efficient and high-performance green composites in additive manufacturing. Full article
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17 pages, 1914 KB  
Systematic Review
Fatigue Resistance of RAP-Modified Asphalt Mixes Versus Conventional Mixes Using the Indirect Tensile Test: A Systematic Review
by Giuseppe Loprencipe, Laura Moretti and Mario Saltaren Daniel
Designs 2025, 9(5), 104; https://doi.org/10.3390/designs9050104 - 1 Sep 2025
Viewed by 9
Abstract
The use of Reclaimed Asphalt Pavement (RAP) in asphalt mixtures offers environmental and economic advantages by reducing reliance on virgin aggregates and minimizing construction waste. However, the aged binder in RAP increases mixture stiffness, which can compromise fatigue resistance. This systematic review evaluates [...] Read more.
The use of Reclaimed Asphalt Pavement (RAP) in asphalt mixtures offers environmental and economic advantages by reducing reliance on virgin aggregates and minimizing construction waste. However, the aged binder in RAP increases mixture stiffness, which can compromise fatigue resistance. This systematic review evaluates the influence of RAP content on fatigue performance compared to conventional mixtures, with a focus on the Indirect Tensile Test (IDT) as the primary assessment method. Following the parameters of Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines, five studies published between 2014 and 2024 were identified through searches in Web of Science, ScienceDirect, ASCE, and Scopus. Study quality was assessed using the Cochrane Risk of Bias tool. The results indicate that although RAP enhances rutting resistance, higher contents (>30%) often lead to reduced fatigue performance due to binder hardening and reduced mixture flexibility. The incorporation of rejuvenators—such as heavy paraffinic extracts—and modifiers, including high-modulus agents, polymers, and epoxy binders, can partially restore aged binder properties and improve performance. Sustainable innovations, such as lignin-based industrial by-products and warm-mix asphalt technologies, show promise in balancing mechanical performance with reduced environmental impact. Variability in material sources, modification strategies, and test protocols limits direct comparability among studies, underscoring the need for standardized evaluation frameworks. Overall, this review highlights that optimizing RAP content and selecting effective rejuvenation or modification strategies are essential for achieving durable, cost-effective, and environmentally responsible asphalt pavements. Future research should integrate advanced laboratory methods with performance-based design to enable high RAP utilization without compromising fatigue resistance. Full article
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17 pages, 4862 KB  
Article
Enzymatic SPR Approach for the Detection of Nano and Microplastic Particles Using Rainwater as Matrices
by Denise Margarita Rivera-Rivera, Gabriela Elizabeth Quintanilla-Villanueva, Donato Luna-Moreno, Jonathan Muthuswamy Ponniah, José Manuel Rodríguez-Delgado, Erika Iveth Cedillo-González, Garima Kaushik, Juan Francisco Villarreal-Chiu and Melissa Marlene Rodríguez-Delgado
Microplastics 2025, 4(3), 57; https://doi.org/10.3390/microplastics4030057 - 1 Sep 2025
Viewed by 25
Abstract
The increasing presence of microplastics (MPs) and nanoplastics (NPs) in environmental matrices presents substantial analytical challenges due to their small size and chemical diversity. This study introduces a novel enzymatic biosensor based on the Surface Plasmon Resonance (SPR) platform for the sensitive detection [...] Read more.
The increasing presence of microplastics (MPs) and nanoplastics (NPs) in environmental matrices presents substantial analytical challenges due to their small size and chemical diversity. This study introduces a novel enzymatic biosensor based on the Surface Plasmon Resonance (SPR) platform for the sensitive detection of MPs and NPs, utilizing laccase as the recognition element. Standard plastic particles, including polystyrene (PS, 0.1 µm), polymethyl methacrylate (PMMA, 1.0 µm and 100 µm), and polyethylene (PE, 34–50 µm), were analyzed using SPR angular interrogation along with a fixed-angle scheme. The angular approach revealed a clear relationship between the resonance angle, particle size, and refractive index, while the fixed-angle method, combined with immobilized laccase, facilitated specific detection through enzyme/substrate interactions. The analytical parameters showed detection limits ranging from 7.5 × 10−4 µg/mL (PE, 34–50 µm) to 253.2 µg/mL (PMMA, 1 µm), with significant differences based on polymer type and enzymatic affinity. Application of the biosensor to real rainwater samples collected from two regions in Mexico (Tula and Molango) confirmed its functionality, although performance varied depending on matrix composition, exhibiting inhibition in samples with high manganese (Mn2+), chromium (Cr2+), and zinc (Zn2+) content. Despite these limitations, the sensor achieved a 113% recovery rate in Tula rainwater, demonstrating its potential for straightforward in situ environmental monitoring. This study highlights the capabilities of laccase-based SPR biosensors in enhancing microplastic detection and underscores the necessity of considering matrix effects for real-world applications. Full article
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27 pages, 6990 KB  
Review
Multiscale Insights into Inorganic Filler Regulation, Ion Transport Mechanisms, and Characterization Advances in Composite Solid-State Electrolytes
by Xinhao Xu, Dingyuan Lu, Sipeng Huang, Fuming Wang, Yulin Min and Qunjie Xu
Processes 2025, 13(9), 2795; https://doi.org/10.3390/pr13092795 - 1 Sep 2025
Viewed by 30
Abstract
All-solid-state lithium batteries (ASSLBs) are emerging as a promising alternative to conventional lithium-ion batteries, offering solutions to challenges related to energy density and safety. Their core advancement relies on breakthroughs in solid-state electrolytes (SEs). SEs can be broadly grouped into two main types: [...] Read more.
All-solid-state lithium batteries (ASSLBs) are emerging as a promising alternative to conventional lithium-ion batteries, offering solutions to challenges related to energy density and safety. Their core advancement relies on breakthroughs in solid-state electrolytes (SEs). SEs can be broadly grouped into two main types: inorganic solid electrolytes (ISEs) and organic solid electrolytes (OSEs). ISEs offer high ionic conductivity (0.1~1 mS cm−1), a lithium-ion transference number close to 1, and excellent thermal stability, but their intrinsic brittleness leads to poor interfacial wettability and processing difficulties, limiting practical applications. In contrast, OSEs exhibit good flexibility and interfacial compatibility but suffer from poor ionic conductivity (10−4~10−2 mS cm−1) due to high crystallinity at room temperature, in addition to poor thermal stability and weak mechanical integrity, making it difficult to match high-voltage cathodes and suppress lithium dendrite growth. Against this backdrop, the stability of the organic–inorganic interface plays a crucial role. However, challenges such as low overall conductivity and unstable interfaces still limit their performance. This review provides a microscopic perspective on lithium-ion transport pathways across the polymer phase, the inorganic filler phase, and their interfacial regions. It categorizes inert fillers and active fillers, analyzing their structure–performance relationships and emphasizing the synergistic effects of filler dimensionality, surface chemistry, and interfacial interactions. In addition, cutting-edge analytical methods such as time-of-flight secondary ion mass spectrometry (TOF-SIMS) and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) have also been employed and are summarized into their roles for revealing the microstructures and dynamic interfacial behaviors of OICSEs. Finally, future directions are proposed, such as hierarchical pore structure design, surface functionalization, and simulation-guided optimization, aiming to provide theoretical insights and technological strategies for the development of high-performance composite electrolytes for ASSLBs. Full article
(This article belongs to the Section Chemical Processes and Systems)
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18 pages, 4673 KB  
Article
Influence of Electrical Parameters in a Composite Wing Actuated by Shape Memory Alloys Wires: A Numerical–Experimental Study
by Miriam Battaglia, Valerio Acanfora and Aniello Riccio
J. Compos. Sci. 2025, 9(9), 460; https://doi.org/10.3390/jcs9090460 - 1 Sep 2025
Viewed by 35
Abstract
This study investigates the influence of electrical actuation parameters on the performance of a morphing composite aerodynamic profile actuated by Shape Memory Alloy (SMA) wires. A fully coupled electro-thermo-mechanical finite element model has been developed to simulate the transient response of NiTi SMA, [...] Read more.
This study investigates the influence of electrical actuation parameters on the performance of a morphing composite aerodynamic profile actuated by Shape Memory Alloy (SMA) wires. A fully coupled electro-thermo-mechanical finite element model has been developed to simulate the transient response of NiTi SMA, capturing the nonlinear interplay between temperature evolution, phase transformation, and mechanical deformation under Joule heating. The model incorporates phase-dependent material properties, heat effects, and geometric constraints, enabling accurate prediction of actuation dynamics. To validate the model, a morphing spoiler prototype has been fabricated using high-performance additive manufacturing with a carbon fibre-reinforced polymer. The SMA wires have been pretensioned and electrically actuated at different current levels (3 A and 6 A), and the resulting deformation has been recorded through video analysis with embedded timers. Experimental measurements confirmed the model’s ability to predict both actuation time and displacement, with maximum deflections of 33 mm and 40 mm corresponding to different current inputs. This integrated approach demonstrates an efficient and compact solution for active aerodynamic surfaces without the need for mechanical linkages, enabling future developments in adaptive structures for automotive and aerospace applications. Full article
(This article belongs to the Special Issue Metal Composites, Volume II)
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