Search Results (50)

This study evaluates the role of groundwater in the dynamics of the Slano blato landslide using hydrogeochemical and stable isotope data. Results show that deep groundwater inflow significantly affected the landslide behavior, as demonstrated by pronounced hydrogeochemical and isotopic differences among springs. Springs within the landslide differ markedly from those in similar geological settings of the Vipava Valley, indicating a distinct local groundwater system. Groundwater is present within the landslide body even during dry periods. Waters originate mainly from a higher karstic recharge area and flow through deep flysch strata, particularly fractured sandstones, where they become enriched in dissolved ions, especially K⁺ and SO₄²⁻, and show increased mineralization in the lower parts of the landslide. Saturation indices indicate slight oversaturation with calcite and dolomite and equilibrium with quartz for most samples, reflecting interaction with carbonates and flysch sandstones. Elevated sulphate concentrations and near-equilibrium conditions for mirabilite and thenardite suggest salt-related deterioration of landslide material, enhanced by evaporation. Stable isotope data (δ¹³C_DIC, δ¹⁸O, δ²H) indicate dominant carbonate recharge, meteoric origin, evaporation effects, and long-term water–rock interaction. This study highlights the need for additional isotope tracers, groundwater age indicators, seasonal monitoring, and on-site meteorological measurements to improve interpretation. Full article

Earthquakes are among the most catastrophic natural disasters, primarily due to their immediate potential to cause loss of human life. However, their impact extends beyond the initial seismic event, particularly in karst systems, where groundwater resources are highly sensitive to geodynamic disturbances. The abundance of karst springs within these terrains makes them critical water sources for many communities, yet earthquakes can significantly disrupt their discharge patterns and degrade water quality. This study examines the vulnerability of karst springs to seismic activity, focusing on two case studies that illustrate distinct earthquake-induced hydrogeological effects. The first case investigates the temporary failure of the Opačac Spring near Imotski, Croatia, following the Mw 3.7 earthquake on 7 September 2018. This spring experienced a complete cessation of discharge for four days, as recorded by continuous hydrograph monitoring, before recovering due to the release of accumulated groundwater behind a temporarily blocked conduit. The second case explores the impact of seismic activity on water quality, focusing on the sensitive freshwater lens of the karstic Island of Vis in response to the Mw 6.1 earthquake on 22 April 2022, near Stolac, Bosnia and Herzegovina. Despite the epicenter being over 150 km away, water quality monitoring revealed notable changes, emphasizing the influence of seismic disturbances on fragile groundwater systems in carbonate island environments. Using a multidisciplinary approach, integrating seismic data analysis with hydrological and hydrogeological observations, this study investigates the mechanisms through which earthquakes alter karst water systems. A proposed vulnerability assessment framework is introduced, aiming to correlate earthquake intensity, proximity, and hydrogeological response to better predict karst spring failure and water quality degradation. This model provides valuable insights for disaster preparedness, water resource management, and risk mitigation strategies in karst terrains, highlighting the necessity of incorporating karst hydrogeology into regional earthquake response planning. Full article

Karstic dolines are unique geomorphological and ecological features of limestone landscapes, characterised by strong microclimatic and edaphic gradients. These concave landforms form natural microrefugia that harbour a variety of plant species. In this study, dolines in the northern Dinarides on the Kras Plateau were investigated to assess the horticultural potential of their flora. Vegetation surveys along edge-to-bottom transects revealed a pronounced species turnover and differentiation of functional traits. Shade-tolerant geophytes and early-flowering perennials dominate the bottoms of the dolines, while the edges harbour drought-tolerant aromatic herbs. Not only do dolines serve biodiversity conservation by acting as microrefugia, but they also preserve cultural heritage through ethnobotanical species and provide a species pool for the selection of plants with horticultural potential. We selected horticultural important plants (HPs) and analysed them within the dolines. Depending on their morphology and seasonal occurrence, they can be divided into woody species, early and late spring flowering species, orchids, and structural species. By linking biodiversity conservation with applied horticulture, this study emphasises the multifunctional role of dolines as small natural features of disproportionate ecological and horticultural importance. We suggest that integrating doline species into horticultural utilisation could improve sustainability, diversify plantings, and strengthen climate adaptation strategies. Full article

The investigation of complex karst systems has always been a difficult task for hydrogeologists, especially related to the spatial position of karst channels. The city of Pirot, which is located in southeastern Serbia, taps karst water for water supply from three karstic springs (Kavak, Krupac and Gradište), which are characterized by extremely good and stable groundwater regime and quality. According to the general water regime, it can be concluded that in addition to the development of shallow and large karst conduits (as proven by tracer tests), there are also deeper karst channels, in which water circulates very slowly and remains for much longer. In order to understand the genesis and characteristics of karst springs used for water supply, multi-parameter research was conducted, which, in addition to monitoring the yield on a daily basis, also included detailed hydrochemical research together with an analysis of microelements and stable and radioactive isotopes. Water from springs has a stable hydrochemical composition highlighting prolonged contact with the host rock. Isotopic analysis showed that the water is a mixture of young waters (residing in the system for a few days, as determined by tracer tests); semi-young waters that, based on the radioactive isotopes ³T and ³He, have resided in the system for 53 years; and very old waters that have spent more than 3000 years in the system. Finally, such new data on significant dynamic as well as static reserves of quality drinking water are of particular importance for long-term sustainable water utilization. Full article

Co- and post-seismic earthquake-induced hydrogeological anomalies (EQHAs) in Greece are mainly associated with moderate to strong earthquakes (M_w = 6.0–7.0), particularly when seismic intensities reach IX or above. The highest frequencies are observed in the Peloponnese and Ionian Islands, followed by Central Greece and the North Aegean, characterized by dense faulting and frequent strong earthquakes. EQHAs are classified into six main types, with hydraulic variations being the most common. About 77% of earthquakes produced only one or two types of EQHA, suggesting localized hydrogeological effects, while only a few induced multiple types. Strong events (M_w = 6.0–7.0), often historic, generated the broadest variety, highlighting the influence of local geological, hydrological, and tectonic conditions on magnitude alone. Springs and wells, representing 81% of the cases, dominate the affected systems, while lakes and rivers respond less often but significantly. Most EQHAs occur in Greece’s second seismic hazard zone (74%) due to its larger geographic area. EQHAs primarily develop in karstic and porous formations but also appear in impermeable rocks due to fracturing or karst. Larger earthquakes trigger anomalies at greater distances (>100 km). Though rarely fatal, EQHAs can damage water infrastructure, contaminate supplies, and cause shortages, underscoring the need for systematic monitoring and post-earthquake water resource management. Full article

Fractal dimensions for the daily discharge data series of several karstic springs in northeast Hungary have recently been computed and analyzed. We model four of those series with similar fractal dimensions using a superposition of a fractional Ornstein–Uhlenbeck process and a jump process of renewal–reward type. Beyond some usual goodness-of-fit measures, simulations of the model show an visually appealing good fit. When the fractal dimension is not taken into account in the modeling, the simulated accumulated discharges tend to significantly exceed realistic values. Full article

Utilizing a multi-biomarker approach, we assessed the potential adverse effects of pollutants on subcellular responses in the digestive gland of the freshwater mussel Unio crassus from a historically contaminated lowland section (KIZ) of the river Mrežnica compared to its less impacted upstream karstic section (REF) and their seasonality (spring vs. autumn). This approach accounted for the diverse modes of action of pollutants by including biomarkers of metal exposure (metallothioneins, MT), general stress (total cytosolic proteins, TP), antioxidative capacity (catalase, CAT; glutathione, GSH; glutathione-S-transferase, GST), oxidative damage (malondialdehyde, MDA), and neurotoxicity (acetylcholinesterase, AChE). Only in spring, MT concentrations were 15% higher at the REF site (4.38 ± 1.06 µg mg proteins⁻¹) compared to the KIZ site (3.69 ± 0.63 µg mg proteins⁻¹), likely related to elevated Cd bioaccumulation due to the karstic substrate. Regardless of the season, mussels from KIZ showed consistently lower TP and GSH, with significantly higher CAT, GST, and MDA levels, indicating elevated stress, activation of antioxidant defenses, and oxidative damage from chronic exposure to pro-oxidant pollutants, including metal(loid)s and organic contaminants (e.g., ibuprofen, nicotine). Compared to the REF site, AChE activity at the KIZ site was higher in late spring and lower in early autumn, indicating seasonal variability in AChE activity at the contamination-impacted location driven by fluctuating exposure to neurotoxicants, such as drugs and insecticides. Overall, biomarker responses indicated that mild historical pollution, reinforced by current low-capacity sources, has an observable impact on mussel health, posing long-term risks to sediment-dwelling aquatic organisms. Full article

Karst water supplies freshwater to approximately a quarter of the global population and plays a crucial role in supporting the socioeconomic development of karst regions. As a key indicator for assessing and managing karst water resources, karstic water storage variation is influenced not only by the complex structure of karst aquifer media but also by the variability in natural precipitation infiltration. Based on the hydrogeological conditions of a typical karst aquifer system in northern China, this study developed a three-dimensional physical experimental setup and established a corresponding groundwater flow numerical model coupled with equivalent porous media and conduits. The factors affecting spring flow recession were investigated from a source–sink perspective. Precipitation events were categorized into two types: those with the same duration but different intensities and those with the same total volume but different intensities. The influence of varying precipitation events on the estimation of karstic water storage variation was quantitatively evaluated using the exponential fitting method, based on the analysis of spring flow recession curves. These findings could provide scientific guidance for the development, utilization, and protection of karst water resources. Full article

Karst aquifers can be highly productive water sources but are vulnerable to contamination by pathogens because of integrated surface and subsurface drainage. Our study focuses on the karstic Royal Spring basin in Kentucky, encompassing urban and agricultural land uses. The city of Georgetown distributes treated water from Royal Spring to over 33,000 customers. We examined E. coli dynamics at Royal Spring from June 2021 through June 2022, assessing variability under wet versus dry weather conditions. We also used quantitative microbial risk assessment (QMRA) to estimate potential health risks from the pathogenic bacterium E. coli O157:H7. E. coli concentrations in weekly water samples varied from 12 to 1732.8 MPN/100 mL, with a geometric mean of 117.2 MPN/100 mL. The mean concentration in wet periods was approximately double that during dry conditions. Because the pathogen was not detected by quantitative PCR (qPCR), we conducted QMRA based on literature data for water treatment plant operations (occupational) and recreational activities near the spring. The median probability of annual infection was 5.11 × 10⁻³ for occupational exposure and 1.45 × 10⁻² for recreational exposure. Uncertainty and sensitivity analyses revealed that health risks were most sensitive to the pathogen/E. coli ratio and ingestion rate. Although the pathogen was not detected by qPCR, the presence of E. coli suggests potential fecal contamination. This highlights the importance of continued monitoring and investigation of different detection methods to better understand potential health risks in karst systems. Full article

The Mataranka Springs Complex is a regional groundwater discharge for the Cambrian Limestone Aquifer (CLA) of the Northern Territory (Australia) and forms the headwaters for the environmentally sensitive Roper River. Whilst a regional groundwater contribution to the spring flow is well established, the absence of cover over the CLA in the vicinity of the springs and the prevalence of karst suggest that a component of quick flow during the wet season is possible. A quick flow contribution to the springs was evaluated using a biweekly monitoring programme for several environmental tracers (major ions, stable isotopes of water, and ²²²Rn) at two large springs (Rainbow Spring and Bitter Spring) and at one minor spring (Fig Tree Spring) over a two-year period that included a relatively dry (2019–2020) and a relatively wet (2020–2021) rainy season. There were limited variations in all tracers at Rainbow and Bitter springs throughout the monitoring programme, indicating an absence or a minimal contribution from quick flow. In contrast, all tracers responded to large rainfall events at a scale of days to weeks in Fig Tree Spring, consistent with a component of quick flow. However, the tracer response at Fig Tree was complex and possibly involved a combination of quick flow, unsaturated zone processes, and changes in the geochemical environment in the aquifer. Quick flow may be favoured in the parts of the Mataranka Springs Complex, where flow paths flow through the karstic tufa layer overlying the CLA. Full article

The integration of different sources of geological and hydrogeological information and the application of interdisciplinary methods have informed the origin of the thermal springs of Alhama de Aragón and Jaraba, as well as other associated semi thermal springs (1200 L/s of combined flow, 711 L/s at over 30 °C), which is the main objective of this article. These springs come mainly from the autogenous recharge that occurs in the Cretaceous calcareous outcrops that border the Almazán Basin to the north, both in the Ebro Basin (Jalón Valley) and in the Duero Basin. The aquifer, shaped by upper Cretaceous limestones under the Palaeogene and Neogene rocks of the Almazán Basin, has extensive depths of more than 4000 m in the NE sector. This hydrostratigraphic unit has been affected by a generalized pre-Paleogene karstification that provides the main porosity to the aquifer. The underground flow moves in a NW–SE direction, crossing the Duero–Ebro divide, favoured by the topographic difference in elevation between the two basins. The regional flow is coherent with the progressive increase in temperature, infiltrating recharge water age (about 20–25 years in the semi-thermal springs, and more than 60 years in the Alhama and Jaraba springs), mineralization, and flow of the springs through which the system discharges. This issue is key to being able to design any sustainable conservation strategy in terms of quantity and quality of resources within the recharge area of the most important thermal springs in Spain. The Jaraba and Alhama de Aragón hot springs share the same or similar temperature, chemical composition, and geological contact of the spring. Their tritium isotopic composition and its evolution over time are practically the same. Their isotopic composition in D and ¹⁸O is also very similar. Both springs share the same recharge zone of similar altitude and constitute the end of flow tubes of similar length and flow rate. Full article

The underground flow of a karstic aquifer within one of Spain and Europe’s most important thermal systems (Alhama and Jaraba thermal springs, with a combined flow rate of 1200 L/s, 711 L/s at more than 30 °C) was simulated. In the simulation process, it was important to consider how temperature (a very sensitive parameter when calibrating the numerical model) and depth influence the variation in hydraulic conductivity in the aquifer. The location of previously unknown high recharge zones was also essential in the calibration. It was verified that some fault jumps break the hydraulic continuity of the aquifer, and the role of most of the existing faults in the regional flow is generally unimportant since they are incapable of explaining by themselves the large volume of water evacuated. It is relevant to highlight the importance of the orientation of the strata when calibrating the model, which become vertical in the area of the outcrops. In the end, the modelled regional flow as well as the simulated groundwater contour lines are consistent with the progressive increase in temperature, the age of the water, the mineralization, the piezometric values measured in the observation wells, and the springs’ flow through which the system discharges. The most significant finding is the validation of the conceptual hydrogeological model through regional flow simulations from numerical models, confirming the recharge area and supporting the inferred origins of the springs. Full article

Effective management of Water Supply Systems (WSSs) is crucial for ensuring safe drinking water. The WSS of Varaždin County is a complex network involving three groundwater sources: Bartolovec and Vinokovščak wellfields (alluvial aquifers) and Bela karstic spring. To achieve a comprehensive characterization of WSSs, routine laboratory data was integrated with stable isotopes and geochemical modeling. Within this study, all measured parameters remain below the Maximum Contaminant Level (MCL), ensuring water safety for human consumption. The Piper diagram identified variations in water sources based on their chemical composition, providing a simplified overview of mixing patterns within WSSs. Among the modeling approaches, inverse modeling (IM) was found to be more reliable than forward modeling (FM) and mass balance modeling (MB). Despite the limited capacity of δ¹⁸O to provide accurate mixing results, it was revealed that the reservoir water was in equilibrium with the air (no evaporation effects), indicating well-sealed reservoirs. Mixing modeling showed that the western, southwestern, and northern parts of the WSS mixed all three sources, whereas the eastern and southeastern areas primarily relied on the deeper aquifer of the Bartolovec source, indicating potential vulnerability. Strict validation criteria ensured the reliability of results, demonstrating the effectiveness and applicability of geochemical modeling in water security management plans. Full article

This study highlights the geochemistry of water and sediments of the karstic springs of the transboundary aquifer (TBA) Žumberak–Samoborsko Gorje Mt. (NW Croatia). After calculating pollution indices, the analysis showed that the sediments are unpolluted. The geo-accumulation index (Igeo) showed only the elements Ba and Rb, indicating moderate levels of pollution, with the highest values in springs Vapnik and Bistrac. Statistical analysis confirmed their natural origin. The water of these springs is under possible anthropogenic influence as indicated by elevated concentrations of total nitrogen (TN) and total phosphorus (TP). According to a principal component analysis (PCA) for elements in sediments, PC1 described a combined lithogenic and oxidative–reductive influence, PC2 described a combined geological background including total organic carbon (TOC) content and oxidative–reductive influence, while TOC had the greatest influence on PC3. Depending on element composition, the factor scores related to PC1 and PC2 resulted in two different groups of sites, while the factor scores concerning PC1 and PC3 did not show separation in two groups. The hierarchical cluster analysis showed three clusters in relation to the content of the elements. The correlation coefficient between the sediment and related water samples showed that the springs placed in a low-permeability formation (dolomite) had a strong positive coefficient of correlation. Full article

Tabular Middle Atlas of Morocco holds the main water reservoir that serves many cities across Morocco. Dolomite and limestone are the most dominant geologic formations in this region in which water resources are contained. The recent studies conducted to evaluate the quality of this water suggest that it is very vulnerable to pollutants resulting from both anthropogenic and natural phenomenon. High and very high-resolution satellite imagery have been used in an attempt to gain a better understanding of this karstic system and suggest a strategy for its protection in order to reduce the impact of these phenomenon. Based on the surface reflectance of land cover benchmarks, the karstic system has been horizontally delineated, as well as regions with intense human activities. Using band combination in the portion of the infrared, shortwave infrared, and visible parts of the electromagnetic spectrum, we identified bare lands which have been interpreted as carbonate rocks, clay minerals, uncultivated fields, basalts rocks, and built-up areas. Other classes such as water and vegetation have been identified. Carbonate rocks have been identified as areas with a high rate of water infiltration through their fracture system. Using a Sobel operator filter, these fractures have been mapped and their results have revealed new and existing faults in two major fracture directions, NE-SW and NW-SE, where NE-SW is the preferable pathway for surface water infiltration towards the groundwater reservoir, while the NW-SE direction drains groundwater from the Cause to the basin of Saiss. Over time, the infiltration of surface water through fractures has contributed to a gradual erosion of the carbonate rocks, which in turn developed karst landforms. This karst system is vulnerable due to the flow of pollutants in areas with shallow sinkholes. Using GDEM imagery, we extracted karst depressions, and their analysis shows that they are distributed along the fracture system and many of them were located on curvilinear or linear axes along the NE-SW fracture direction. We found also dolines scattered in areas with a high intensity of fractures. This distribution has been validated by both on-the-ground measurements and very high-resolution satellite images, and depressions of different forms and shapes dominated by dolines, poljes, lapiez, and avens have been identified. We also found many water springs with a highly important water output, such as the Ain Maarrouf water spring. The aim of this study is to enhance the understanding of the hydrogeological system of TMA, to improve the existence of the fracture database in the Cause of Agourai, and to establish a new morpho-structural picture of the Ain Maarrouf water spring. Full article