Search Results (335)

Background/Objectives: This paper presents a bi-objective mathematical programming model for sizing hybrid renewable energy systems (HRESs) in isolated mini-grids and compares the optimized solutions with the first-year operation of a real system deployed in La Miel, Panama. Methods: The model minimizes the levelized cost of energy (LCOE) and the expected energy not served (EENS), using an $\epsilon$-constraint approach over a one-year time series (8760 h) of measured demand. For La Miel, the annual demand is 132,578 kWh with a peak load of 28.4 kW. Four configurations are evaluated: (A) diesel-only, (B) photovoltaic (PV)+diesel, (C) PV+batteries, and (D) PV+diesel+batteries. The results are compared with the installed plant (E) including 107 kWp PV, a 40 kVA diesel generator, and lead-acid battery banks (4560 Ah nominal capacity). Results: The optimized hybrid configuration (D) achieves near-zero EENS with an LCOE of 41.4–41.8 cts-USD/kWh, compared to 56.6 cts-USD/kWh for diesel-only. The real system achieves EENS = 0% with LCOE = 48.3 cts-USD/kWh and an annual renewable penetration of 53.2% (up to 68.4% in March 2020), while the optimized case reaches 79.6% on average (up to 95.3% in March). Conclusions: The distinctive contribution of the study is the direct ex ante versus ex post comparison between optimized planning outcomes and the documented first-year operation of the installed system. Operational constraints observed on site (e.g., minimum battery SoC of 60% to comply with voltage quality limits) and demand growth explain part of the LCOE gap between optimized and real performance. Full article

Electric two-wheelers (E2Ws) are promoted as lower-emission options in emerging economies. Their long-term cost competitiveness depends mainly on battery durability and how batteries are managed at the end of their life. This research examines Li-ion and nickel-cobalt-manganese (NCM)-type batteries versus the previously common lead-acid batteries in these markets. The study uses a 12-year total cost of ownership (TCO) framework that includes battery degradation, estimated first-life duration, and alternative lifecycle pathways. It covers three sensitivity analysis cases: conservative, base case, and optimistic. Three scenarios are evaluated: (1) no lifecycle management, (2) refurbishment for first-life extension, and (3) integrated lifecycle management with refurbishment, second-life utilisation, and recycling. Results show that managing the battery lifecycle can reduce TCO. The amount of reduction depends on first-life duration, ownership horizon, refurbishment cost, downstream residual value, and use intensity. The greatest TCO gains are found in battery categories with short first-life duration, allowing substantial residual value recovery during ownership. Batteries with first-life durations of 12 years or more provide smaller benefits. These findings support optimising lifecycle pathways for maximum residual value. Improved TCO performance, along with supportive infrastructure, policies, and market development, is critical for broader E2W adoption. Full article

Stationary energy storage (SES) is increasingly needed to integrate variable renewable generation and improve consumer self-consumption, but technology choices involve associated trade-offs between cost, efficiency, and life-cycle impacts. This study evaluates the role of second-life lithium-ion (Li-ion) batteries repurposed from electric vehicles for stationary applications, compared to lead-acid (Pb-acid) batteries and power-to-hydrogen-to-power (PtH₂P) systems. We develop an optimization-based sizing and dispatch framework using measured PV–load profiles and hourly market electricity prices, and evaluate performance per 1 MWh delivered to the load over a 10-year life cycle. Economic performance is quantified through discounted cash flows equal to levelized cost of storage (LCOS), while environmental performance is assessed through life-cycle metrics with explicit representation of recycling and second-life credits. In addition to global warming potential (GWP), the analysis considers additional resource and impact metrics, as well as key operational efficiency metrics, including bidirectional consumption efficiency, autonomy, and share of self-consumption/export of photovoltaic systems. Scenario and sensitivity analyses examine the impact of policy and financial parameters, in particular feed-in tariff remuneration and discount rate, on the comparative ranking of technologies. The results highlight how circular economy pathways, especially second-life distribution for Li-ion batteries and high end-of-life recovery for lead-acid batteries, have a significant impact on the life-cycle burden for delivered energy, while market-driven conditions for dispatching and export activities shape economic outcomes. Overall, the proposed workflow provides a transparent, circularity-aware basis for selecting stationary storage technologies associated with photovoltaic systems, under realistic operational constraints. Full article

An improved optimizer based on projection-iterative methods (IPIMO) is proposed to address the optimal configuration problem of multi-type energy storage systems (MT-ESS), with the objective of achieving synergistic minimization of comprehensive costs, including both investment and operational expenditures. A comprehensive energy system model is established, integrating photovoltaic power, wind power, and six typical energy storage technologies—lithium-ion battery, flywheel energy storage, supercapacitors, valve-regulated lead-acid battery, compressed air energy storage, and redox flow battery. Four typical operational scenarios are designed to validate the adaptability and robustness of the algorithm. A systematic evaluation of IPIMO’s comprehensive performance is conducted by comparing it with the weighted average method (WA), the single-energy storage optimization method (SEO), the projection-iterative-methods-based optimizer algorithm (PIMO), and the genetic algorithm (GA). Simulation results demonstrate that IPIMO exhibits superior convergence performance, achieving stable convergence rapidly and significantly outperforming PIMO and GA. Moreover, IPIMO achieves the lowest total cost across all four scenarios, with an average of $46,837, representing reductions of 6.54% compared to the benchmark weighted average method and 11.8% compared to the SEO. Additionally, IPIMO adaptively adjusts the allocation ratios of energy storage types based on scenario characteristics, prioritizing energy-type storage in stable scenarios while increasing the proportion of fast-response storage to 49.1% in fluctuating scenarios, thereby demonstrating its strong scenario adaptability. Full article

Electric vehicles (EVs) represent a key pathway toward reducing greenhouse gas emissions and fossil fuel dependence. Although significant advances have been achieved in energy storage technologies for EVs, a structured comparative assessment that jointly evaluates batteries, supercapacitors, and their hybridisation remains lacking. This review addresses that gap by systematically comparing lithium-ion, lead-acid, and nickel-based batteries with electrochemical double-layer capacitors (EDLCs), pseudocapacitors, and hybrid capacitors across ten performance and sustainability criteria. A literature-informed scoring framework, supplemented by sensitivity analysis under alternative weighting scenarios, is employed to rank the technologies. Particular attention is given to Hybrid Energy Storage Systems (HESS), which combine the high energy density of lithium-ion batteries with the high power density and long cycle life of supercapacitors. The review synthesises evidence that HESS can improve overall energy efficiency by up to 20% and extend battery lifetime by 30–50%, thereby reducing raw-material extraction, electronic waste, and lifecycle cost. Second-life pathways and circular-economy implications are discussed in depth. The findings demonstrate that neither batteries nor supercapacitors alone can satisfy the full spectrum of EV energy demands; instead, their integration within HESS offers the most balanced, sustainable, and economically viable solution. This work provides actionable insights for engineers, policymakers, and stakeholders engaged in next-generation sustainable mobility. Full article

Antimony (Sb) is a key element used in flame retardants, lead–acid batteries, and polymer catalysis, and it is classified as a critical raw material. Its quantity for the worldwide economy is limited due to restricted natural resources and partial recycling of by-products. This is why recovering Sb from secondary sources is becoming increasingly important in terms of technological and economic aspects for ensuring its sustainable and safety supply. In this paper, we review the possibilities for extraction of antimony from various waste sources, such as ore processing and metal recovery residues, electronic and plastic waste, lead-antimony-containing waste, spent catalysts, fluorescent lamps, incinerated municipal waste, and the applied methods of waste processing (pyrometallurgy, hydrometallurgy, solvometallurgy) used to achieve recovery in high yield and purity. The methods for antimony quantification and speciation are also discussed and described in terms of principle of the technique, linear concentration range, limit of detection, and coupling with other techniques. As the concentration of Sb in environmental and biological samples is usually very low and requires good selectivity and sensitivity of the analytical method, suitable techniques for sample preparation and subsequent instrumental measurement are also included. Full article

Electric Vehicles (EVs) can contribute significantly to reducing greenhouse gas emissions and addressing climate change problems. Modern EVs are primarily powered by electrochemical batteries such as lead-acid (Pb-acid), nickel-metal hydride (NiMH), sodium-ion (Na-ion), solid-state and lithium-ion (Li-ion) batteries. When compared to other battery types, Li-ion batteries are the most suitable for EV applications due to their practical features such as their high energy density, high charging and discharging efficiency and extended lifetime. However, the main risk of Li-ion batteries is that they are exposed to thermal runaway phenomena, which raises severe concerns about the safety of EV propulsion systems. Thermal runaways should be considered carefully as they cannot be stopped once they start and can lead to battery explosion. One of the main reasons leading to this phenomenon is abusing the state of charge (SoC) of the battery. Therefore, the battery management system (BMS) plays a crucial role in mitigating the stimulation of the thermal runaway process by accurately estimating and properly managing the battery cells. To help researchers and designers with understanding this matter, this paper proposes a review of the most effective SoC estimation methods for EV Li-ion batteries and links these methods with practical energy management systems in the EV market. Full article

Lithium-rich manganese-based cathode materials (LRMs, Li_1.2Mn_0.54Ni_0.13Co_0.13O₂) are promising prospects for subsequent-generation lithium-ion batteries owing to their elevated operating voltage, large specific capacity, and affordability. Nonetheless, their actual implementation is significantly impeded by irreversible lattice-oxygen redox reactions, surface structural disorder, and interfacial phase collapse, leading to low initial Coulombic efficiency (ICE), inadequate rate capability, and sluggish Li⁺ transport. Herein, we report a simple and mild glycolic acid-assisted surface-engineering strategy to enhance the electrochemical performance of LRM. Glycolic acid treatment induces controlled H⁺/Li⁺ ion exchange at the particle surface and anchors surface transition metals through the formation of transition metals (TM)–OH and TM–O–C=O bonds. Subsequent calcination constructs an in situ carbon layer-spinel-layered heterostructure, accompanied by the generation of coupled anionic and cationic vacancies. This reconstructed surface provides fast Li⁺ diffusion pathways and stabilized ion-transport channels, while the dual-vacancy configuration enhances lattice-oxygen reversibility and suppresses structural disorder. Consequently, the modified LRM delivers a high initial discharge capacity of 285.3 mAh⋅g⁻¹ with an ICE of 89.9%, while maintaining 81% capacity retention after 100 cycles. Notably, it exhibits a significantly suppressed voltage decay of only 1.7 mV/cycle at 3C, markedly outperforming the pristine LRM. Density Functional Theory (DFT) calculations reveal that the surface-modified sample possesses enhanced electronic conductivity, as evidenced by the improved Density of States (DOS), and achieves superior structural stability through increased binding energies. This environmentally benign surface-engineering strategy offers a practical and efficient route toward the industrial application of LRM. Full article

Ports located within dense urban environments face a major challenge in achieving deep decarbonization without compromising the reliability and safety of critical maritime operations. This study develops and validates a resilience-oriented control and sizing typology for Hybrid Renewable Energy Systems (HRESs), supporting the transition of a medium-sized Mediterranean port toward a Nearly Zero Energy Port (nZEP). The framework integrates five years of measured electrical demand at 15 min resolution to capture stochastic load variability, seasonal effects, and safety-critical peak events. Thirty-five HRES configurations are simulated using HOMER Pro, assessing photovoltaic and wind generation combined with alternative Energy Storage System (ESS) technologies under two grid-interface control strategies: Net Metering (NM) and non-NM curtailment-based operation. Conventional Lead–Acid batteries are compared with inherently safer Vanadium Redox Flow Batteries (VRFBs), while autonomy constraints of 24 h and 48 h are imposed to represent operational resilience. System performance is evaluated through a multi-criteria framework encompassing economic viability (Levelized Cost of Energy), environmental impact (Lifecycle Assessment-based carbon footprint), and operational reliability. Results indicate that NM-enabled HRES architectures significantly outperform non-NM configurations by exploiting the external grid as an active balancing layer. The optimal NM configuration achieves a Levelized Cost of Energy of 0.063 €/kWh under a 24 h autonomy constraint, while reducing operational carbon intensity to approximately 70 gCO₂,eq/kWh, corresponding to a reduction exceeding 90% relative to baseline grid-dependent operation. In contrast, non-NM systems require substantial storage and generation oversizing to maintain resilience, resulting in higher curtailment losses and Levelized Cost of Energy values of 0.12–0.15 €/kWh. Across both control regimes, VRFB-based systems consistently exhibit superior robustness and safety performance compared to Lead–Acid alternatives. The proposed typology provides a transferable framework for resilient and low-carbon port microgrid design under real-world operational constraints. Full article

This study presents a modular battery charging system based on a DC–DC buck converter with proportional–integral (PI) control, developed to support hands-on learning in power electronics education. In response to the need for flexible experimental platforms, the system is designed to bridge theoretical concepts of power conversion and control with practical implementation. The proposed setup employs cascaded current and voltage control loops to achieve constant current (CC) and constant voltage (CV) charging modes, while its modular hardware architecture allows modification of key parameters such as inductance, capacitance, and circuit topology. The control algorithms are implemented on a microcontroller, and real-time data acquisition is integrated using the ThingSpeak platform for monitoring system behaviour. Experimental results show that the current control loop recovers to its reference value within approximately 6 ms under abrupt load variations, whereas the voltage control loop settles within approximately 15 ms, demonstrating stable closed-loop performance. In addition, the system successfully charges a 12 V lead-acid battery following a standard CC–CV charging profile. Overall, the proposed experiment kit provides an effective educational platform and a practical basis for further exploration of battery charging strategies and power converter control. Full article

Abnormal electrolyte levels can lead to failures in lead-acid batteries. The capacitive method, as a non-invasive liquid level inspection technique, can be applied to the nondestructive detection of electrolyte level abnormalities in lead-acid batteries. However, due to the high viscosity of sulfuric acid in lead-acid batteries, residual liquid films are easily adhered to the tube walls during rapid liquid level drops, resulting in significant dynamic measurement errors in capacitive methods. To eliminate dynamic measurement errors caused by residual liquid film adhesion, this study proposes a hybrid deep learning model—Poly-LSTM. This model combines polynomial feature generation with a Long Short-Term Memory (LSTM) network. First, polynomial features are generated to explicitly capture the complex nonlinear and coupling effects in the sensor inputs. Subsequently, the LSTM network processes these features to model their temporal dependencies. Finally, the time information encoded by the LSTM is used to generate accurate liquid level predictions. Experimental results show that this method outperforms other comparative models in terms of liquid level estimation accuracy. At a rapid drop rate of 0.12 mm/s, the average absolute error (MAE) is 0.5319 mm, the root mean square error (RMSE) is 0.7180 mm, and the mean absolute percentage error (MAPE) is 0.1320%. Full article

The automotive industry is under pressure to reduce greenhouse gas emissions. While the growth of electric vehicles is crucial, optimizing low-voltage batteries for conventional powertrain architecture (12–48 V) can help reduce carbon dioxide emissions. Currently, lithium iron phosphate (LFP) batteries dominate the low-voltage battery market due to their stability, safety, and ecological benefits as replacement to lead-acid. However, sodium-ion batteries (SIB) are emerging as a promising alternative to LFP, offering advantages in power, lifespan, cold temperature performance, integration, cost, material availability, and sustainability. These advantages of sodium-ion batteries make them a perfect candidate for fulfilling the requirements typically associated with 48 V applications as well. This contribution evaluates low-voltage SIB prototypes developed by the company IAV GmbH and its partners and explores their potential for automotive applications, aiming to share insights and assess future prospects. Full article

Lead-acid batteries (LAB) continue to be one of the most widely used energy storage technologies worldwide, especially in the automotive sector and in backup systems. However, their use is a significant source of lead and sulfuric acid pollution, with negative impacts on the environment and human health. This review analyzes the environmental and health effects of LAB manufacturing, use, and recycling, and evaluates sustainable alternatives through life cycle analysis. A search was conducted in the Multidisciplinary Digital Publishing Institute (MDPI), Science Direct, and Springer databases, yielding more than 247 documents, from which 84 technical and scientific articles were selected, mostly from the last five years, excluding duplicates and irrelevant texts or those in languages other than English. The results reveal that conventional pyrometallurgical processes release between 30 and 50 kg of lead fumes per ton processed, causing concentrations of up to 5000 mg/kg of Pb in soils near informal plants, exceeding international limits by more than 25 times. In contrast, closed-loop hydrometallurgical technologies reduce emissions by more than 70% and increase secondary lead recovery, making them an environmentally friendly option. It is concluded that the sustainability of the LAB system requires technological innovation, effective regulation, and extended responsibility within an eco-friendly circular economy model. Full article

The global adoption of solar-powered streetlights has grown significantly, driven by their cost-effectiveness and potential to reduce dependence on fossil fuels associated with conventional street lighting. Battery storage represents a substantial portion of the total capital cost in solar-powered streetlight systems. Therefore, selecting an efficient charge regulator is crucial to protect battery lifespan and reduce energy losses. In this context, the choice of an appropriate charge regulator plays a vital role in enhancing system reliability and overall performance. This study presents a practical approach for evaluating three commercially available 6 A-rated Pulse Width Modulation (PWM) solar charge regulators intended for recharging lead-acid batteries in a proposed 12 V off-grid solar photovoltaic (PV) street lighting system. The regulators were evaluated concurrently in separate circuits, each experiencing similar meteorological conditions, including similar temperature and solar irradiance. The measured data for each regulator were acquired using LabVIEW-based virtual instruments. The performance comparison was conducted using the Linear Regression Algorithm (LRA) to support decision-making. Based on the analysis, the most suitable PWM charge regulator was identified as the one offering the best charging performance due to low internal losses. Hence, solar battery charge regulators with identical load current ratings do not necessarily deliver equivalent charge/discharge performance. Full article

Deep-Cycle Lead-Acid Batteries (DCLA) are widely known in stationary applications such as backup power and off-grid systems. However, their faster capacity decline compared to emerging batteries limits their efficiency and lifespan. This research investigates the potential of ultrasonication to enhance the performance of DCLA by reducing sulfation and internal resistance, thereby improving capacity retention and state of health (SOH). A system-level MATLAB/Simulink model was created to simulate a photovoltaic (PV) system under three load conditions: constant, variable, and realistic load. An ultrasonic device operating at 1700 kHz was implemented during the charging phase, and simulations were conducted to evaluate systems before and after ultrasonication. State of charge (SoC) and battery voltage were performance measures over 31 days. The results showed that the ultrasonication system maintained an average SoC up to twice that of the control system (78.8% vs. 37.9%) and sustained a higher average voltage (13.2 V vs. 12.6 V). Under realistic light-load conditions, the test system retained energy better and had a 38.37% percentage improvement. These findings indicate that ultrasonic integration is a viable retrofitting strategy to improve DCLA operation, particularly for off-grid and renewable energy storage applications. Full article