Search Results (135)

Lithium niobate (LiNbO₃, LN) single crystal is widely used in optoelectronic fields due to its excellent performance. However, its low hardness, high brittleness, and strong anisotropy lead to low processing efficiency and poor surface quality. Hydrophilic fixed abrasive lapping technology was adopted for the thinning of LN wafers in this research. The effects of lapping pressure on the thinning process were investigated comprehensively in terms of the material removal rate (MRR), surface quality, and subsurface damage (SSD). The results show that lapping pressure exerted a significant influence on the machining performance. High pressure contributed to improving the MRR but aggravated surface roughness (Ra) and SSD. With low pressure, material removal was dominated by ductile removal machining, with fine scratches as the main damage form, which was favorable for obtaining low Ra and low SSD. The root mean square (RMS) of the acoustic emission (AE) signal rose with the increase in pressure, increasing slowly in the ductile removal regime and rising abnormally in the brittle removal regime. It was positively correlated with the MRR and SSD and can be used as an in situ monitoring indicator. After a comprehensive comparison of five groups of experiments, 7 kPa was determined to be the optimal lapping pressure, with the following corresponding parameters: wafer speed: 100 rpm; lapping table speed: 80 rpm; slurry flow rate: 100 mL/min; eccentricity: 60 mm; soft lapping pad; abrasive mass fraction: 50%; and lapping time: 5 min. Under these conditions, the Ra value was approximately 30 nm, the MRR exceeded 1 μm/min, and SSD was as low as 3.3 μm, realizing the synergistic optimization of high-efficiency and low-damage machining. It provides a favorable foundation for the subsequent processing of LN substrates, such as ultra-precision polishing, thin-film transfer, and bonding. Full article

A series of Hf co-doped uranium-doped lithium niobate (LN:U,Hf) crystals with a diameter of one inch were grown by the modified Bridgman method. XPS analysis showed that U ions coexist in mixed valence states of U⁴⁺, U⁵⁺, and U⁶⁺. At 442 nm, LN:U,Hf_1.0 exhibited a fast photorefractive response of 0.32 s together with a high saturation diffraction efficiency of 82.01%. With increasing Hf concentration, the optical damage resistance was significantly enhanced, and LN:U,Hf_5.0 achieved an optical damage threshold of 2.8 × 10⁵ W/cm². Two-beam coupling experiments indicated that electrons are the dominant charge carriers and diffusion is the main transport mechanism. It demonstrates that co-doping Hf⁴⁺ provides an effective route to simultaneously enhance photorefractive response and optical damage resistance in LN:U, offering potential for high-power and fast-response photonic devices. Full article

This paper provides a comprehensive overview of the progress in fiber-optic gyroscope technology, covering 260 key studies of the last ten years. A critical comparative analysis of fiber-optic gyroscope with alternative inertial sensors (Micro-Electro-Mechanical Systems, Hemispherical Resonator Gyroscope, Ring Laser Gyroscope) has been carried out. Confirming the unique advantages of fiber-optic gyroscope for autonomous navigation. Fundamental limitations of accuracy are considered in detail: temperature drifts, polarization noise, and Rayleigh backscattering. Modern hardware methods for suppressing these errors, including the use of photonic crystal and hollow fibers (Air-Core/Hollow-Core), are also considered in this work. The central place in the review is occupied by the analysis of the technological paradigm shift from bulky discrete circuits to hybrid integrated photonics (Indium Phosphide, Silicon Nitride, Lithium Niobate) and hybrid architectures to reduce weight and size characteristics. The role of artificial intelligence (Deep Learning, Long Short-Term Memory) methods in nonlinear drift compensation and calibration is discussed. The usage of the Brillouin effect and optomechanics promising areas are outlined, necessary to create a new generation of navigation systems operating in the absence of Global Navigation Satellite Systems signals. Full article

Thin-film lithium niobate electro-optic modulators exhibit outstanding advantages such as large bandwidth, low insertion loss, and low half-wave voltage, demonstrating broad application prospects. However, due to internal defects in lithium niobate crystals, modulators exhibit electro-optic relaxation phenomena, with the relaxation time of thin-film structures being reduced by more than two orders of magnitude compared to bulk materials. In this study, we fitted and simulated the electro-optic relaxation behavior of thin-film lithium niobate modulators based on RC circuit model, effectively explaining their time-domain response characteristics under low-frequency conditions. By comparing thin-film modulators with and without silica cladding structures, the fitting results indicate that the relaxation time of modulators with cladding is approximately 11.9 ms, showing positive DC drift, whereas the relaxation time of modulators without cladding is significantly shortened to about 88.6 μs and exhibits negative DC drift. Additionally, the enhancement of optical intensity alters the photoconductivity of the material, thereby affecting its low-frequency electro-optic response behavior. This research provides important ideas for the design and optimization of next-generation integrated lithium niobate photonic modulators with high stability and controllability. Full article

This work addresses the low pyroelectric coefficient that limits the practical application of lithium niobate (LN) crystals. A defect modulation process based on reduction annealing treatment is proposed. This reduction annealing treatment increased the pyroelectric coefficient of LN crystals maximally to 3.362 × 10⁻⁴ C/m²K. At room temperature, the voltage responsivity figure of merit (F_V) and detectivity figure of merit (F_D) were both improved more than three-fold. All material properties exceeded those of commercial lead zirconate titanate (PZT) ceramic. This process achieves the simultaneous modulation of high pyroelectric coefficients and low impedance in LN crystals. Based on the LN crystals with optimized properties, pyroelectric infrared detectors (center wavelength 9.4 μm) without external matching resistors were prepared. The response voltage of the detector reached 2.8 times that of commercial PZT detectors while exhibiting lower noise, and has achieved practical applicability. This work provides a simple and efficient method for developing environmentally friendly, low-cost, high-sensitivity pyroelectric infrared detectors. It also establishes the foundations for the application of LN crystals in emerging pyroelectric detection fields. Full article

Z-cut lithium niobate single crystal demonstrates considerable promise for contact-based ultrasonic nondestructive testing and structural health monitoring (SHM) transducers due to its high piezoelectric coefficients, strong electromechanical coupling capability, and environmentally friendly lead-free composition. As a simulation-based theoretical exploration, this study systematically investigates the impact of gap spacing and electrode width in concentric ring configurations on the resonant characteristics and pulse-echo response of ultrasonic transducers by establishing a parametrized finite element model. Numerical simulations reveal that electrode geometry plays a critical role in determining both the effective electromechanical coupling coefficient and echo signal strength. Optimizing the electrode ring width achieved an effective electromechanical coupling coefficient ($k_{\mathit{eff}}$) of 35.2%, while systematic enlargement of the electrode gap further enhanced this value to 50.8%. The study also demonstrates that optimized ring width and adjusted electrode spacing increased the echo signal’s peak-to-peak amplitude ($V_{pp}$) by factors of 4.94 and 2.03, respectively, compared to the poorest-performing configuration within each parameter group. This study establishes that precise design of concentric electrode configurations serves as an effective strategy for tuning lithium niobate ultrasonic transducer characteristics, providing critical design guidelines for developing high-performance ultrasonic transducers for solid medium coupling. Full article

Thin-film lithium niobate (TFLN) electro-optic modulators (EOMs) offer distinct advantages, including high speed, broad bandwidth, and low power consumption. However, their large size hinders the density of integration, which trades off with the half-wave voltage. Photonic crystal (PC) structures can effectively reduce the device footprint via the slow-light effect; however, they experience significant losses due to fabrication defects and sharp corners. Here, we theoretically demonstrate an ultracompact Mach–Zehnder interferometer (MZI) EOM based on a TFLN valley photonic crystal (VPC) structure. The design can achieve a high forward transmittance (>0.8) due to defect-immune unidirectional propagation in the VPC, enabled by the unique spin-valley locking effect. The EOM, with a small footprint of 21 μm × 17 μm, achieves an extinction ratio of 16.13 dB and a modulation depth of 80%. The design can be experimentally fabricated using current nanofabrication techniques, making it suitable for broad applications in optical communications. Full article

Precise control over defect structures is essential for tuning the functional properties of lithium niobate (LiNbO₃) crystals. Although the threshold effect of Hf⁴⁺ doping is well recognized, its underlying atomic-scale mechanism, especially in systems co-doped with luminescent rare earth ions, remains unclear. In this study, we combine experimental and theoretical approaches to elucidate the Hf⁴⁺ concentration-driven threshold behavior in Dy: LiNbO₃ crystals. A series of crystals with Hf⁴⁺ concentrations of 2, 4, 6, and 8 mol% were grown using the Czochralski method. Characterization through XRD and IR spectroscopy identified a threshold near 4 mol%, evidenced by an inflection in lattice constants and a pronounced blue shift of the OH⁻ absorption peak. UV–Vis–NIR absorption spectra revealed a systematic enhancement of Dy³⁺f–f transition intensities, linking the global defect structure to the local crystal field of the optical activator. First-principles calculations showed that Hf⁴⁺ ions preferentially occupy Li sites, repairing antisite Nb defects ($\mathrm{N}{\mathrm{b}}_{\mathrm{Li}}^{4+}$) below the threshold, and incorporate into Nb sites beyond it, inducing structural reorganization. Electron Localization Function analysis visualized strengthened Hf-O covalent bonding in the post-threshold regime. This work establishes a complete atomic-scale picture connecting dopant site preference, chemical bonding, and macroscopic properties, providing a foundational framework for the rational design of advanced LiNbO₃-based materials. Full article

The polar oxide Lithium Niobate Tantalate is probed using time-resolved luminescence spectroscopy with the goal of revealing an initial structural insight into the solid solution by analyzing the spectral properties and dynamics of radiatively decaying self-localization phenomena. A blue-green luminescence band can be induced by ultraviolet nanosecond laser pulses with a temperature-dependent intensity and spectral width, pointing to the radiative decay of optically generated self-trapped excitons as its origin, i.e., electron–hole pairs with strong coupling to either the NbO₆- or TaO₆-octahedra. The luminescence decay takes place in the microsecond time range and deviates significantly from a single exponential behavior, so the determined lifetime constants of up to ≈70 μs and stretching factors (1/3–1/5) are validated in more detail using alternative evaluation methods. We discuss our findings, considering the interplay of radiative and non-radiative decay channels, the transition from self-trapped to free excitons, and the presence of a structural disorder of the oxygen octahedra in the solid solutions. Overall, our results suggest self-trapped excitons as local probes for an initial structural elucidation and provide essential information about further experimental and theoretical studies on the atomic structure of Lithium Niobate Tantalate, but also for improving the crystal quality in the framework of applications in photonics and quantum optics. Full article

This study provides an in-depth analysis of the learning dynamics of multichannel optical neurons based on spatial solitons generated in lithium niobate crystals. Single-node and multi-node configurations with different topological complexities (3 × 3, 4 × 4, and 5 × 5) were compared, assessing how the number of channels, geometry, and optical parameters affect the speed and efficiency of learning. The simulations indicate that single-node neurons achieve the desired imbalance more rapidly and with lower energy expenditure, whereas multi-node structures require higher intensities and longer timescales, yet yield a greater variety of responses, more accurately reproducing the functional diversity of biological neural tissues. The results highlight how the plasticity of these devices can be entirely modulated through optical parameters, paving the way for fully optical photonic neuromorphic networks in which memory and computation are co-localized, with potential applications in on-chip learning, adaptive routing, and distributed decision-making. Full article

Non-mechanical beam steering is required for holographic displays, free-space optical communication, and chip-scale LiDAR. Optical phased arrays (OPAs), which allow for inertia-free, high-speed beam control via electronic phase control, are an important research topic. The present study investigates the primary material platform for on-chip OPAs: Liquid crystal OPAs (LC-OPAs) employ electrically tunable refractive indices for low-voltage operation; lithium niobate OPAs (LN-OPAs) utilize high electro-optic coefficients for high-speed, low-power consumption, and large-bandwidth operation; and silicon-based OPAs (Si-OPAs) apply mature photonic integration to achieve high integration density and GHz-range steering. The paper thoroughly examines OPA basics, recent material-specific advancements, performance benchmarks, outstanding issues, and future prospects. Full article

Lithium Niobate (LiNbO₃, LN) crystals are multifunctional optical materials with excellent electro-optical, acousto-optical, and nonlinear optical properties, and their broad spectral transparency makes them widely used in electro-optical modulators, tunable filters, and beam deflectors. Near Stoichiometric Lithium Niobate (NSLN) crystals have a lithium to niobium ratio ([Li]/[Nb]) close to 1:1,demonstrate superior performance characteristics compared to composition lithium niobate (Congruent Lithium Niobate (CLN), [Li]/[Nb] = 48.5:51.5) crystals. NSLN crystals have a lower coercive field (~4 kV/mm), higher electro-optic coefficient (${\gamma }_{33}$ = 38.3 pm/V), and better nonlinear optical properties. This paper systematically reviews the research progress on preparation methods, the physical properties of LN and NSLN crystals, and their applications in devices such as electro-optical modulators, optical micro-ring resonators, and holographic storage. Finally, the future development direction of NSLN crystals in the preparation process (large-size single-crystal growth and defect control) and new electro-optical devices (low voltage deflectors based on domain engineering) is envisioned. Full article

This paper presents the preparation of Z-cut near-stoichiometric lithium niobate (NSLN) wafers using a combined process of the lithium-rich Czochralski growth and diffusion methods. The fabricated Z-cut NSLN wafers exhibited outstanding comprehensive performance, including a high Curie temperature of up to 1200 °C, a refractive index gradient in the diameter direction below 1.5 × 10⁻⁴ cm⁻¹, and a UV absorption edge shifted 14 nm toward the ultraviolet region compared to congruent lithium niobate crystals, with a coercive field of 1268 V/mm. Additionally, the wafers demonstrated excellent processing characteristics, with the bow of 4-inch wafers controlled within 55 μm, surpassing the machining standards of traditional lithium niobate wafers of the same size. These results indicated the highly uniform chemical stoichiometry and crystallization quality of the wafers. Leveraging the high uniformity and low coercive field of the wafers, periodic triangular domain structure arrays were successfully fabricated, laying the foundation for domain engineering design in electro-optic deflectors and switching devices. This study not only achieves the scalable preparation of NSLN wafers but also provides a reliable technical solution for their practical applications in high-performance electro-optic devices. Full article

To investigate the evolution of the optothermal properties of lithium niobate with ion beam irradiation parameters, the thermal effect theory was analyzed, and ion beam irradiation technology was used to modify lithium niobate samples. The transmittance of lithium niobate crystals after ion beam irradiation and the relationship between their optothermal properties and transmittance were studied. The results show that the average surface optothermal signal of lithium niobate exhibits a significant dependence on ion beam parameters. When the ion beam voltage is 800 V, the ion beam current is 30 mA, and the irradiation time is 60 s, a distinct absorption peak is observed on the surface of lithium niobate, with an average surface optothermal signal of 5377.34 ppm, demonstrating potential for all-optical modulation. Full article

In this paper, we report on the growth and characterization of high doping concentration (2.1 at%) ytterbium (Yb) doped lithium niobate (Yb:LiNbO₃) crystal. By using a slightly modified Czochralski method, we have successfully grown a usable size (2 mm × 2 mm × 30 mm) Yb:LiNbO₃ single crystal. We also conducted the energy-dispersive X-ray spectroscopy (EDS) and the X-ray diffraction (XRD) analyses, which experimentally confirm that the grown crystal is a Yb:LiNbO₃ single crystal. We also measured the absorption and emission spectra of the grown crystal. It was found out that there is a near-flat broad emission within a spectral range of 1004–1030 nm when excited at 980 nm for this high doping concentration Yb:LiNbO₃ crystal. Such a near-flat broad emission can be very useful for realizing high slope efficiency ultrafast (femtosecond) lasing in the Yb:LiNbO₃ crystal due to the low quantum defect of the Yb:LiNbO₃ crystal. We also investigated the electro-optic effect of the Yb:LiNbO₃. The experimental result confirms that the electro-optic (EO) effect of a highly doped (2.1 at%) lithium niobate crystal is close to the EO value of the pure lithium niobate. Thus, the highly doped Yb:LiNbO₃ crystal can still be an effective electrically tunable lasing medium. It can enable electrically tunable, high slope efficiency femtosecond lasing due to the combined features, including (1) a near flat broad emission spectrum at the spectral range of 1004–1030 nm, (2) a non-compromised electro-optic effect at high doping concentration Yb:LiNbO₃ crystal, and (3) a low quantum defect. Full article