Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (18)

Search Parameters:
Keywords = magma mingling

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
26 pages, 6608 KB  
Article
From Mantle to Cratonic Reactivation: Petrological Insights from Kimberlites and Lamproites of the São Francisco Craton, Brazil
by Matheus Andrade Nascimento, Debora Correia Rios, Nivea Maria Assis Magalhães and Francisco Valdir Silveira
Minerals 2026, 16(1), 19; https://doi.org/10.3390/min16010019 - 24 Dec 2025
Viewed by 498
Abstract
This study redefines the Nordestina Kimberlite Province (PKN), in the northeastern sector of the São Francisco Craton (SFC), as a composite kimberlitic–lamproitic system that hosts two genetically distinct magma types: (1) the primitive Braúna kimberlite and (2) hybridized phlogopite-rich lamproites belonging to the [...] Read more.
This study redefines the Nordestina Kimberlite Province (PKN), in the northeastern sector of the São Francisco Craton (SFC), as a composite kimberlitic–lamproitic system that hosts two genetically distinct magma types: (1) the primitive Braúna kimberlite and (2) hybridized phlogopite-rich lamproites belonging to the SFC lamproite variety. Braúna kimberlites represent an olivine-rich kimberlite sourced from a metasomatized lithospheric mantle, as reflected by its high MgO (15%–30.6%), Ni (up to 1172 ppm), and Cr (up to 2500 ppm). These geochemical signatures are consistent with a primitive melt capable of preserving diamond stability conditions. In contrast, the SFC lamproite variety exhibits strong crustal overprinting, marked by hydrothermal barite–carbonate–silica veining, cristobalite, elevated SiO2 (up to 80 wt.%), and high LOI (up to 27.5%). These features indicate significant post-magmatic alteration, felsic crust assimilation, and melt hybridization. Textural and mineralogical features found in both magma types, including olivine-phlogopite aggregates, irregular zoning, and disequilibrium assemblages, suggest magma mingling between compositionally distinct melts and/or crystallization under polybaric conditions. These findings clarify long-standing classification controversies by demonstrating that PKN magmatism is not represented by a single rock type but instead spans a continuum spectrum from primitive kimberlite to strongly hybridized lamproite. Regionally, the data reveal that PKN magmatism reflects Paleoproterozoic mantle metasomatism reactivated during Neoproterozoic tectonism. This dual-stage evolution explains the contrasting degrees of primitiveness and hybridization melt signatures observed across the province. Full article
Show Figures

Figure 1

19 pages, 7428 KB  
Article
Petrology of the 1952 Eruption and Ancient Lava and Pyroclastic Flows of Krenitsyn Peak Volcano, Onekotan Island, Kuril Arc, Russia
by Vesta O. Davydova, Anton A. Nuzhdaev, Ilya E. Bolshakov, Ruslan A. Kuznetsov, Andrey B. Ermolinskiy, Elena S. Zhitova and Vasiliy O. Yapaskurt
Geosciences 2025, 15(9), 358; https://doi.org/10.3390/geosciences15090358 - 12 Sep 2025
Viewed by 1953
Abstract
Krenitsyn Peak is one of the two active volcanoes on Onekotan Island (Greater Kuril Ridge). The inaccessibility of the island, along with the volcano being situated within a sizeable (7 km in diameter) and cold (3.7 °C) caldera lake, has led to minimal [...] Read more.
Krenitsyn Peak is one of the two active volcanoes on Onekotan Island (Greater Kuril Ridge). The inaccessibility of the island, along with the volcano being situated within a sizeable (7 km in diameter) and cold (3.7 °C) caldera lake, has led to minimal research on the area. We present the first detailed characterization of the rocks from the only historical eruption of Krenitsyn Peak (November 1952) and a brief description of the ancient lava and pyroclastic density current (PDC) deposits that make up the building of the volcano. The 1952 eruptive products are represented by two-pyroxene andesites (59.2–63.3 wt.% SiO2), and the older lava and pyroclastic flow rocks consist of two-pyroxene andesites and dacites (62–67.6 wt.% SiO2). Almost all samples belong to the calc-alkaline, medium-K, and medium-Fe series, and the pumiceous lapilli from the 1952 eruption fall into the low-Fe series. The minerals exhibit signs of magma mingling, including relic high-Ca (up to An92) plagioclase cores with signs of dissolution and recrystallization, and oscillatory-zoned pyroxene. Full article
(This article belongs to the Section Geochemistry)
Show Figures

Figure 1

30 pages, 15713 KB  
Article
Magma Mixing Origin for the Menyuan Granodioritic Pluton in the North Qilian Orogenic Belt, China
by Shugang Xia, Yu Qi, Shengyao Yu, Xiaocong Jiang, Xiangyu Gao, Yue Wang, Chuanzhi Li, Qian Wang, Lintao Wang and Yinbiao Peng
Minerals 2025, 15(4), 391; https://doi.org/10.3390/min15040391 - 8 Apr 2025
Cited by 1 | Viewed by 1477
Abstract
Magma mixing or mingling is not just a geological phenomenon that widely occurs in granitoid magmatism, but a complex dynamic process that influences the formation of mafic microgranular enclaves (MMEs) and the diversity of granitic rocks. Herein, we carried out a comprehensive study [...] Read more.
Magma mixing or mingling is not just a geological phenomenon that widely occurs in granitoid magmatism, but a complex dynamic process that influences the formation of mafic microgranular enclaves (MMEs) and the diversity of granitic rocks. Herein, we carried out a comprehensive study that encompassed the petrology, mineral chemistry, zircon U-Pb ages, Lu-Hf isotopes, whole-rock elements, and Sr-Nd isotope compositions of the Menyuan Granodioritic Pluton in the northern margin of the Qilian Block, to elucidate the petrogenesis and physical and chemical processes occurring during magma mixing. The Menyuan Granodioritic Pluton is mainly composed of granodiorites accompanied by numerous mafic microgranular enclaves (MMEs) and is intruded by minor gabbro dikes. LA-ICP-MS zircon U-Pb dating reveals that these rocks possess a similar crystallization age of ca. 456 Ma. The Menyuan host granodiorites, characterized as metaluminous to weakly peraluminous, belong to subduction-related I-type calc-alkaline granites. The MMEs and gabbroic dikes have relatively low SiO2 contents and high Mg# values, probably reflecting a mantle-derived origin. They are enriched in large ion lithophile elements (LILEs) and light, rare earth elements (LREEs) but are depleted in high field strength elements (HFSEs), indicating continental arc-like geochemical affinities. The host granodiorites yield relatively enriched whole-rock Sr-Nd and zircon Hf isotopic compositions (87Sr/86Sri = 0.7072–0.7158; εNd(t) = −9.21 to −4.23; εHf(t) = −8.8 to −1.2), implying a derivation from the anatexis of the ancient mafic lower continental crust beneath the Qilian Block. The MMEs have similar initial Sr isotopes but distinct whole-rock Nd and zircon Hf isotopic compositions compared with the host granodiorites (87Sr/86Sri = 0.7078–0.7089; εNd(t) = −3.88 to −1.68; εHf(t) = −0.1 to +4.1). Field observation, microtextural and mineral chemical evidence, geochemical characteristics, and whole-rock Nd and zircon Hf isotopic differences between the host granodiorites and MMEs suggest insufficient magma mixing of lithospheric mantle mafic magma and lower continental crust felsic melt. In combination with evidence from regional geology, we propose that the anatexis of the ancient mafic lower continental crust and subsequent magma mixing formed in an active continental arc setting, which was triggered by the subducted slab rollback and mantle upwelling during the southward subduction of the Qilian Proto-Tethys Ocean during the Middle-Late Ordovician. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
Show Figures

Figure 1

39 pages, 71974 KB  
Article
Geology, Petrology and Geochronology of the Late Cretaceous Klaza Epithermal Deposit: A Window into the Petrogenesis of an Emerging Porphyry Belt in the Dawson Range, Yukon, Canada
by Well-Shen Lee, Daniel J. Kontak, Patrick J. Sack, James L. Crowley and Robert A. Creaser
Minerals 2025, 15(1), 38; https://doi.org/10.3390/min15010038 - 31 Dec 2024
Cited by 1 | Viewed by 3675
Abstract
Geologic understanding of the richly mineralized Dawson Range gold belt (DRGB) in the central Yukon, Canada is hindered by: (1) limited outcrop exposure due to thick soil cover; and (2) low resolution age-constraints despite a long history of porphyry Cu–Au–Mo deposit (PCD) exploration. [...] Read more.
Geologic understanding of the richly mineralized Dawson Range gold belt (DRGB) in the central Yukon, Canada is hindered by: (1) limited outcrop exposure due to thick soil cover; and (2) low resolution age-constraints despite a long history of porphyry Cu–Au–Mo deposit (PCD) exploration. Here, the well-preserved Klaza Au–Ag–Pb–Zn porphyry–epithermal deposit is used as a type-example of Late Cretaceous magmatic–hydrothermal mineralization to address the complex metallogeny of the DRGB. U–Pb zircon dating defines four magmatic pulses of Late Triassic to Late Cretaceous ages with the latter consisting of the Casino (80–72 Ma) and Prospector Mt. (72–65 Ma) suites. The Casino suite has five phases of intermediate-to-felsic calc-alkaline composition, correspond with older (77 Ma) porphyry mineralization, and displays evidence of magma mingling. The intermediate-to-mafic, slightly alkalic Prospector Mt. suite shows evidence of mingling with the youngest Casino suite phases, correlates with younger (71 Ma), intermediate-sulfidation epithermal and porphyry-type mineralization, and shoshonitic basalts of the Carmacks Group. Zircon trace element data suggest a common melt source for these suites; however, the younger suite records features (e.g., high La/Yb) that indicate a higher pressure melt source. The results from this study highlight the Prospector Mt. suite as a historically overlooked causative magma event linked to Au-rich PCDs in the DRGB and extends the temporal window of PCD prospectivity in this area. The transition from mid-Cretaceous Whitehorse suite magmas to Late Cretaceous Casino-Prospector Mt. suite magmas is proposed to reflect a transition from subduction to localized extension, which is becoming more recognized as a common characteristic of productive porphyry belts globally. Full article
Show Figures

Figure 1

28 pages, 18261 KB  
Article
Composite Granitic Plutonism in the Southern Part of the Wadi Hodein Shear Zone, South Eastern Desert, Egypt: Implications for Neoproterozoic Dioritic and Highly Evolved Magma Mingling during Volcanic Arc Assembly
by Khaled M. Abdelfadil, Sherif Mansour, Asran M. Asran, Mohammed H. Younis, David R. Lentz, Abdel-Rahman Fowler, Mohammed S. Fnais, Kamal Abdelrahman and Abdelhady Radwan
Minerals 2024, 14(10), 1002; https://doi.org/10.3390/min14101002 - 1 Oct 2024
Cited by 8 | Viewed by 3175
Abstract
The Abu Farayed Granite (AFG), located in the southeastern desert of Egypt, was intruded during the early to late stages of Pan-African orogeny that prevailed within the Arabian–Nubian Shield. The AFG intrudes an association of gneisses, island arc volcano–sedimentary rocks, and serpentinite masses. [...] Read more.
The Abu Farayed Granite (AFG), located in the southeastern desert of Egypt, was intruded during the early to late stages of Pan-African orogeny that prevailed within the Arabian–Nubian Shield. The AFG intrudes an association of gneisses, island arc volcano–sedimentary rocks, and serpentinite masses. Field observations, supported by remote sensing and geochemical data, reveal a composite granitic intrusion that is differentiated into two magmatic phases. The early granitic phase comprises weakly deformed subduction-related calc–alkaline rocks ranging from diorite to tonalite, while the later encloses undeformed granodiorite and granite. Landsat-8 (OLI) remote sensing data have shown to be highly effective in discriminating among the different varieties of granites present in the area. Furthermore, the data have provided important insights into the structural characteristics of the AFG region. Specifically, the data indicate the presence of major tectonic trends with ENE–WSW and NW–SE directions transecting the AFG area. Geochemically, the AFG generally has a calc–alkaline metaluminous affinity with relatively high values of Cs, Rb, K, Sr, Nd, and Hf but low contents of Nb, Ta, P, and Y. The early magmatic phase has lower alkalis and REEs, while the later phases have higher alkalis and REEs with distinctly negative Eu anomalies. The AFG is structurally controlled, forming a N–S arch, which may be due to the influence of the wadi Hodein major shear zone. The diorite and tonalite are believed to have been originally derived from subduction-related magmatism during regional compression. This began with the dehydration of the descending oceanic crust with differential melting of the metasomatized mantle wedge. Magma ascent was long enough to react with the thickened crust and therefore suffered fractional crystallization and assimilation (AFC) to produce the calc–alkaline diorite–tonalite association. The granodiorite and granites were produced due to partial melting, assimilation, and fractionation of lower crustal rocks (mainly diorite–tonalite of the early stage) after subduction and arc volcanism during a late orogenic relaxation–rebound event associated with uplift transitioning to extension. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

26 pages, 7119 KB  
Article
Genesis of the Sartohay Podiform Chromitite Based on Microinclusions in Chromite
by Xingying Wen and Yongfeng Zhu
Minerals 2024, 14(6), 530; https://doi.org/10.3390/min14060530 - 21 May 2024
Cited by 4 | Viewed by 2247
Abstract
Here, we present a petrographic and microanalytical study of microinclusions in chromite from podiform chromitites hosted by the Sartohay ophiolitic mélange in west Junggar, northwestern China, to investigate the parental magma evolution and chromitite genesis. These silicate inclusions comprise olivine, enstatite, diopside, amphibole, [...] Read more.
Here, we present a petrographic and microanalytical study of microinclusions in chromite from podiform chromitites hosted by the Sartohay ophiolitic mélange in west Junggar, northwestern China, to investigate the parental magma evolution and chromitite genesis. These silicate inclusions comprise olivine, enstatite, diopside, amphibole, and Na-phlogopite. Their morphological characteristics suggest that most inclusions crystallized directly from the captured melt, with a few anhydrous inclusions (olivines and pyroxenes) as solid silicates trapped during the chromite crystallization. Equilibrium pressure–temperature conditions of coexisting enstatite–diopside inclusions are 8.0–21.6 kbar, and 874–1048 °C. The high Na2O and TiO2 contents of hydrous minerals indicate that the parental magma of chromitites was hydrous and enriched in Mg, Na, Ca, and Ti. The calculated Al2O3 content and FeO/MgO ratio of the parental melts in equilibrium with chromite showed MORB affinity. However, the TiO2 values of parental melts, TiO2 contents of chromite, and estimated fO2 values for chromitites (1.3–2.0 log units above the FMQ buffer) evoked parental MORB-like tholeiitic melts. The composition of olivine inclusion was determined, and it was revealed that the primary melts of the Sartohay podiform chromitites had MgO contents of ~22.7 wt %. This aligns with the observed high magnesian signature in mineral inclusions (Fo = 96–98 in olivine, Mg# = 0.91–0.97 in diopside, and Mg# = 0.92–0.97 in enstatite). We propose that Sartohay podiform chromitites initially formed through the mixing/mingling of primary hydrous Mg-rich melt and the evolved MORB-like melt derived from the melt–peridotite reaction in the upper mantle. In this process, the continuous crystallization of chromite captured micro-silicate mineral inclusions, finally leading to the formation of the Sartohay podiform chromitites. Full article
Show Figures

Figure 1

21 pages, 11697 KB  
Article
Origin of Quartz Diorite and Mafic Enclaves in the Delong Gold-Copper Deposit and Evaluation of the Gold-Copper Mineralization Potential
by Jiajie Chen, Lebing Fu, Chengbiao Leng, Xu Zhao, Jian Ma, Hongze Gao and Yu Xia
Minerals 2023, 13(9), 1202; https://doi.org/10.3390/min13091202 - 13 Sep 2023
Cited by 4 | Viewed by 2589
Abstract
The Triassic Paleo-Tethyan magmatic belt in the East Kunlun Orogen (EKO) hosts a small number of porphyry-skarn deposits. The controls of these deposits, especially those in the eastern EKO, are poorly understood. In this contribution, we report new petrological, zircon U-Th-Pb-Hf isotopic, whole-rock [...] Read more.
The Triassic Paleo-Tethyan magmatic belt in the East Kunlun Orogen (EKO) hosts a small number of porphyry-skarn deposits. The controls of these deposits, especially those in the eastern EKO, are poorly understood. In this contribution, we report new petrological, zircon U-Th-Pb-Hf isotopic, whole-rock elemental with Sr-Nd isotopic, and mineral chemistry data of the Delong quartz diorite and mafic enclaves to constrain their petrogenesis and metal fertility. The quartz diorite and mafic enclaves are emplaced in the Late Triassic (ca. 234 Ma). They are medium-K, metaluminous, enriched in large-ion lithophile elements (e.g., Rb, Ba, Th) and light rare earth elements (e.g., La, Ce, Nd), and relatively depleted in high field strength elements (e.g., Nb, Ta, Ti, P) and heavy rare earth elements (e.g., Gd, Er, Tm, Yb). The quartz diorite show similar (87Sr/86Sr)i (0.712584~0.713172) and more depleted εNd(t) (−6.4~−5.7) and εHf(t) (−2.3~+2.6) to those of mafic enclaves ((87Sr/86Sr)i = 0.712463~0.713093; εNd(t) = −6.4~−6.0; εHf(t) = −9.4~−4.8). Geochemical compositions of zircon, amphibole, and biotite yield high water content (5.3 wt.%~6.9 wt.% and 6.1 wt.%~7.3 wt.% based on amphibole, respectively) and high redox state for both the quartz diorite and mafic enclaves. These data, together with petrography, indicate the Delong intrusion was formed by mingling of magmas from enriched mantle and lower continental crust with juvenile materials. The oxidized and water-rich features of these magmas denote they have potential for porphyry Cu (±Au ± Mo) deposits, as do some Triassic magmatic rocks in the eastern EKO that show similar geochemical and petrographic characteristics with the Delong intrusion. Full article
(This article belongs to the Section Mineral Deposits)
Show Figures

Figure 1

24 pages, 7489 KB  
Article
Origin of Amphibole-Biotite-Fluorite-Rich Enclaves from Gabal El-Ineigi Fluorite-Bearing Granite, Central Eastern Desert of Egypt: Insights into Fluoride–Calcium and Silicate Liquid Immiscibility
by Hanaa A. El-Dokouny, Nasser M. Mahdy, Hany H. El Hadek, Mabrouk Sami, Rainer Abart, Mohamed S. Ahmed, Tehseen Zafar and Ioan V. Sanislav
Minerals 2023, 13(5), 670; https://doi.org/10.3390/min13050670 - 13 May 2023
Cited by 8 | Viewed by 4032
Abstract
Gabal El-Ineigi fluorite-bearing rare-metal granite with A-type affinity, located in the Central Eastern Desert of Egypt, is distinguished by its abundance of large fluorite-quartz veins and mafic enclaves. Plagioclase (labradorite to oligoclase), Mg-rich biotite, and Mg-rich hornblende are the main components of mafic [...] Read more.
Gabal El-Ineigi fluorite-bearing rare-metal granite with A-type affinity, located in the Central Eastern Desert of Egypt, is distinguished by its abundance of large fluorite-quartz veins and mafic enclaves. Plagioclase (labradorite to oligoclase), Mg-rich biotite, and Mg-rich hornblende are the main components of mafic enclaves, with significant amounts of fluorite as essential phases, and titanite and Fe-Ti oxides (Nb-free rutile and ilmenite-rutile solid solution) as the main accessories. These enclaves are monzodioritic in composition, Si-poor, and highly enriched in Ca, Fe, Mg, and F compared to the host alkali feldspar F-poor Si-rich granites. Given the conflicting evidence for a restitic, xenolithic, magma mixing/mingling, cumulate, or bimodal origin for these enclaves, we propose that the mafic enclaves and felsic host granites are two conjugate liquids, with contrasting compositions, of a single parental melt. This is inferred by the normalized REE patterns that are similar. As a result, liquid immiscibility is proposed as a probable explanation for this mafic–felsic rock association. These enclaves can be interpreted as transient melt phases between pure silicate and calcium-fluoride melts that are preserved from the early stages of separation before evolving into a pure fluoride (Ca-F) melt during magma evolution. Due to element partitioning related to melt unmixing, the enclaves are preferentially enriched in Ca, F, Li, Y, and REE and depleted in HFSE (such as Zr, U, Th, Ta, Nb, Hf, and Ga) in comparison to the host granites. Furthermore, mafic enclaves exhibit W-type tetrad effects, while host granites exhibit M-type tetrad effects, implying that the REE partitioning, caused by liquid immiscibility, is complementary. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

20 pages, 8764 KB  
Article
Cogenetic Origin of Magmatic Enclaves in Peralkaline Felsic Volcanic Rocks from the Sanshui Basin, South China
by Peijia Chen, Bo Qian, Zhiwei Zhou and Nianqiao Fang
Minerals 2023, 13(5), 590; https://doi.org/10.3390/min13050590 - 24 Apr 2023
Cited by 1 | Viewed by 2883
Abstract
Centimeter-scale magmatic enclaves are abundant in peralkaline felsic volcanic rocks in the Sanshui Basin. Their lithology is mainly syenite and syenitic porphyry, and they mainly comprise alkali feldspar and amphibole, which is similar to the mineral assemblage of the host trachyte and comendite. [...] Read more.
Centimeter-scale magmatic enclaves are abundant in peralkaline felsic volcanic rocks in the Sanshui Basin. Their lithology is mainly syenite and syenitic porphyry, and they mainly comprise alkali feldspar and amphibole, which is similar to the mineral assemblage of the host trachyte and comendite. The SiO2 content in the syenitic enclaves is ~63 wt%, which is similar to that of the host trachyte but lower than that of the comendite. Thermobarometric calculations showed that the syenitic enclaves crystallized at similar temperature and pressure conditions as their host trachyte. The results of mass-balance modeling and MCS modeling indicate that the syenitic enclaves likely experienced an approximately 74% fractional crystallization from the basaltic parental magma. Combined with the similar mineral assemblages and geochemical characteristics of the host trachyte, we think that the enclaves resulted from the in situ crystallization of trachytic magma in the shallow crust and that they had a cogenetic origin with their host volcanic rocks, which means that they were likely to derived from the identical magma chamber which was formed from different batches of magma mixing/mingling. The recharge and mixing of basaltic magma triggered the eruption of trachytic magma eruption. The syenitic crust may have been disaggregated by the ascending trachytic magma and brought to the surface as syenitic enclaves. The syenitic enclaves in volcanic rocks provide unique information on the magmatism of the shallow crust as evidence of magma mixing/mingling. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

33 pages, 5585 KB  
Article
Mineral-Melt Equilibria and Geothermobarometry of Campi Flegrei Magmas: Inferences for Magma Storage Conditions
by Carlo Pelullo, Raffaella Silvia Iovine, Ilenia Arienzo, Valeria Di Renzo, Lucia Pappalardo, Paola Petrosino and Massimo D’Antonio
Minerals 2022, 12(3), 308; https://doi.org/10.3390/min12030308 - 28 Feb 2022
Cited by 15 | Viewed by 6569
Abstract
The eruptions of Campi Flegrei (Southern Italy), one of the most studied and dangerous active volcanic areas of the world, are fed by mildly potassic alkaline magmas, from shoshonite to trachyte and phonotrachyte. Petrological investigations carried out in past decades on Campi Flegrei [...] Read more.
The eruptions of Campi Flegrei (Southern Italy), one of the most studied and dangerous active volcanic areas of the world, are fed by mildly potassic alkaline magmas, from shoshonite to trachyte and phonotrachyte. Petrological investigations carried out in past decades on Campi Flegrei rocks provide crucial information for understanding differentiation processes in its magmatic system. However, the compositional features of rocks are a palimpsest of many processes acting over timescales of 100–104 years, including crystal entrapment from multiple reservoirs with different magmatic histories. In this work, olivine, clinopyroxene and feldspar crystals from volcanic rocks related to the entire period of Campi Flegrei’s volcanic activity are checked for equilibrium with combined and possibly more rigorous tests than those commonly used in previous works (e.g., Fe–Mg exchange between either olivine or clinopyroxene and melt), with the aim of obtaining more robust geothermobarometric estimations for the magmas these products represent. We applied several combinations of equilibrium tests and geothermometric and geobarometric methods to a suite of rocks and related minerals spanning the period from ~59 ka to 1538 A.D. and compared the obtained results with the inferred magma storage conditions estimated in previous works through different methods. This mineral-chemistry investigation suggests that two prevalent sets of T–P (temperature–pressure) conditions, here referred to as “magmatic environments”, characterized the magma storage over the entire period of Campi Flegrei activity investigated here. These magmatic environments are ascribable to either mafic or differentiated magmas, stationing in deep and shallow reservoirs, respectively, which interacted frequently, mostly during the last 12 ka of activity. In fact, open-system magmatic processes (mixing/mingling, crustal contamination, CO2 flushing) hypothesized to have occurred before several Campi Flegrei eruptions could have removed earlier-grown crystals from their equilibrium melts. Moreover, our new results indicate that, in the case of complex systems such as Campi Flegrei’s, in which different pre-eruptive processes can modify the equilibrium composition of the crystals, one single geothermobarometric method offers little chance to constrain the magma storage conditions. Conversely, combined methods yield more robust results in agreement with estimates obtained in previous independent studies based on both petrological and geophysical methods. Full article
Show Figures

Figure 1

17 pages, 7778 KB  
Article
Petrogenesis of Garnet Clinopyroxenite and Associated Dunite in Hujialin, Sulu Orogenic Belt, Eastern China
by Jianguo Liu, Jian Wang, Keiko Hattori and Zeli Wang
Minerals 2022, 12(2), 162; https://doi.org/10.3390/min12020162 - 28 Jan 2022
Cited by 2 | Viewed by 3142
Abstract
The origin of ultramafic rocks, especially those in suture zones, has been a focus because they are not only important mantle sources of magma, but also provide substantial information on metamorphism and melt/fluid–peridotite interaction. Ultramafic rocks in Hujialin, in the central part of [...] Read more.
The origin of ultramafic rocks, especially those in suture zones, has been a focus because they are not only important mantle sources of magma, but also provide substantial information on metamorphism and melt/fluid–peridotite interaction. Ultramafic rocks in Hujialin, in the central part of the Sulu orogen, include peridotite and pyroxenite. Although many papers on their origin and tectonic evolution have been published in the past few decades, these questions are still highly debated. Here, we present mineralogy, mineral composition, and bulk-rocks of these ultramafic rocks to evaluate their origin and tectonic evolution. The garnet clinopyroxenite is low in heavy rare-earth elements (HREE, 5.97–10.6 ppm) and has convex spoon-shaped chondrite-normalized REE patterns, suggesting the garnet formed later, and its precursor is clinopyroxenite. It is high in incompatible elements (i.e., Cs, Rb, Ba) and shows negative to positive U, Nb, and Ta anomalies, without pronounced positive Sr or Eu anomalies. Clinopyroxene in garnet clinopyroxenite contains high MgO (Mg# 0.90–0.97). The mineral chemistry and bulk-rock compositions are similar to those of reactive clinopyroxenite, suggesting that it originally formed via peridotite–melt interaction, and that such silicic and calcic melt might derive from the subducted Yangtze continent (YZC). Dunite contains olivine with high Fo (93.0–94.1), low NiO (0.11–0.29 wt.%) and MnO (≤0.1 wt.%), chromite with high Cr# (0.75–0.96), TiO2 (up to 0.88 wt.%), and Na2O (0.01–0.10 wt.%). It has negatively sloped chondrite-normalized REE patterns. Mineral chemistry and bulk rocks suggest dunite likely represent residual ancient lithosperic mantle peridotite beneath the North China Craton (NCC) that was overprinted by aqueous fluids. The lack of prograde and retrograde metamorphic minerals in dunite and irregular shaped mineral inclusions in chromite suggest dunite did not subduct to deep levels. Dunite mingled with garnet clinopyroxenite during exhumation of the latter at shallow depths. These ultramafic rocks, especially hydrated peridotite, may be important sources of Au for the Jiaodong gold province in the NCC. Full article
(This article belongs to the Special Issue Petrology, Mineralogy, Geochemistry and Geochronology of Granites)
Show Figures

Figure 1

20 pages, 4975 KB  
Article
A Crystal Mush Perspective Explains Magma Variability at La Fossa Volcano (Vulcano, Italy)
by Simone Costa, Matteo Masotta, Anna Gioncada and Marco Pistolesi
Minerals 2021, 11(10), 1094; https://doi.org/10.3390/min11101094 - 5 Oct 2021
Cited by 9 | Viewed by 4981
Abstract
The eruptive products of the last 1000 years at La Fossa volcano on the island of Vulcano (Italy) are characterized by abrupt changes of chemical composition that span from latite to rhyolite. The wide variety of textural features of these products has given [...] Read more.
The eruptive products of the last 1000 years at La Fossa volcano on the island of Vulcano (Italy) are characterized by abrupt changes of chemical composition that span from latite to rhyolite. The wide variety of textural features of these products has given rise to several petrological models dealing with the mingling/mixing processes involving mafic-intermediate and rhyolitic magmas. In this paper, we use published whole-rock data for the erupted products of La Fossa and combine them in geochemical and thermodynamic modelling in order to provide new constrains for the interpretations of the dynamics of the active magmatic system. The obtained results allow us to picture a polybaric plumbing system characterized by multiple magma reservoirs and related crystal mushes, formed from time to time during the differentiation of shoshonitic magmas, to produce latites, trachytes and rhyolites. The residing crystal mushes are periodically perturbated by new, fresh magma injections that, on one hand, induce the partial melting of the mush and, on the other hand, favor the extraction of highly differentiated interstitial melts. The subsequent mixing and mingling of mush-derived melts ultimately determine the formation of magmas erupted at La Fossa, whose textural and chemical features are otherwise not explained by simple assimilation and fractional crystallization models. In such a system, the compositional variability of the erupted products reflects the complexity of the physical and chemical interactions among recharging magmas and the crystal mushes. Full article
(This article belongs to the Special Issue Magma Ascent and Evolution: Insights from Petrology and Geochemistry)
Show Figures

Figure 1

21 pages, 7211 KB  
Article
Sulphide Globules in a Porcellanite–Buchite Composite Xenolith from Stromboli Volcano (Aeolian Islands, Southern Italy): Products of Open-System Igneous Pyrometamorphism
by Alberto Renzulli, Marco Taussi, Frank J. Brink, Stefano Del Moro and Richard W. Henley
Minerals 2021, 11(6), 639; https://doi.org/10.3390/min11060639 - 16 Jun 2021
Cited by 1 | Viewed by 4423
Abstract
Pyrometamorphism is the highest temperature end-member of the sanidinite facies (high-temperature, low-pressure contact metamorphism) and comprises both subsolidus and partial melting reactions which may locally lead to cryptocrystalline-glassy rocks (i.e., porcellanites and buchites). A wide range of pyrometamorphic ejecta, with different protoliths from [...] Read more.
Pyrometamorphism is the highest temperature end-member of the sanidinite facies (high-temperature, low-pressure contact metamorphism) and comprises both subsolidus and partial melting reactions which may locally lead to cryptocrystalline-glassy rocks (i.e., porcellanites and buchites). A wide range of pyrometamorphic ejecta, with different protoliths from Stromboli volcano, have been investigated over the last two decades. Among these, a heterogeneous (composite) glassy sample (B1) containing intimately mingled porcellanite and buchite lithotypes was selected to be studied through new FESEM–EDX and QEMSCAN™ mineral mapping investigations, coupled with the already available bulk rock composition data. This xenolith was chosen because of the unique and intriguing presence of abundant Cu–Fe sulphide globules within the buchite glass in contrast with the well-known general absence of sulphides in Stromboli basalts or their subvolcanic counterparts (dolerites) due to the oxygen fugacity of NNO + 0.5–NNO + 1 (or slightly lower) during magma crystallization. The investigated sample was ejected during the Stromboli paroxysm of 5 April 2003 when low porphyritic (LP) and high porphyritic (HP) basalts were erupted together. Both types of magmas are present as coatings of the porcellanite–buchite sample and were responsible for the last syn-eruptive xenoliths’s rim made of a thin crystalline-glassy selvage. The complex petrogenetic history of the B1 pyrometamorphic xenolith is tentatively explained in the framework of the shallow subvolcanic processes and vent system dynamics occurred shortly before (January–March 2003) the 5 April 2003 paroxysm. A multistep petrogenesis is proposed to account for the unique occurrence of sulphide globules in this composite pyrometamorphic xenolith. The initial stage is the pyrometamorphism of an already hydrothermally leached extrusive/subvolcanic vent system wall rock within the shallow volcano edifice. Successively, fragments of this wall rock were subject to further heating by continuous gas flux and interaction with Stromboli HP basalt at temperatures above 1000 °C to partially melt the xenolith. This is an open system process involving continuous exchange of volatile components between the gas flux and the evolving silicate melt. It is suggested that the reaction of plagioclase and ferromagnesian phenocrysts with SO2 and HCl from the volcanic gas during diffusion into the melt led to the formation of molecular CaCl in the melt, which then was released to the general gas flux. Sulphide formation is the consequence of the reaction of HCl dissolved into the melt from the gas phase, resulting in the release of H2 into the melt and lowering of fO2 driving reduction of the dissolved SO2. Full article
Show Figures

Figure 1

19 pages, 3928 KB  
Article
Magma Mingling in Kimberlites: Evidence from the Groundmass Cocrystallization of Two Spinel-Group Minerals
by Jingyao Xu, Joan Carles Melgarejo, Qiuli Li, Lisard Torró i Abat and Montgarri Castillo-Oliver
Minerals 2020, 10(9), 829; https://doi.org/10.3390/min10090829 - 20 Sep 2020
Cited by 3 | Viewed by 3948
Abstract
We present the results of a detailed petrographic study of fresh coherent samples of the Menominee kimberlite sampled at site 73, located in Menominee County, MI, USA. Our objective is to account for its unusual and complex paragenetic sequence. Several generations of olivine, [...] Read more.
We present the results of a detailed petrographic study of fresh coherent samples of the Menominee kimberlite sampled at site 73, located in Menominee County, MI, USA. Our objective is to account for its unusual and complex paragenetic sequence. Several generations of olivine, ilmenite, and spinel-group minerals are described. Early olivine and ilmenite are xenocrystic and were replaced or overgrown by primary minerals. Zoned microcrysts of olivine have a xenocrystic core mantled by a first rim in which rutile, geikielite, and spinel s.s. (spinel sensu stricto) cocrystallized. The in situ U–Pb dating of a microcryst of primary rutile yielded 168.9 ± 4.4 Ma, which was interpreted as the age of emplacement. The groundmass consists of olivine, spinel s.s., a magnesian ulvöspinel–ulvöspinel–magnetite (MUM) spinel, calcite, and dolomite. An extremely low activity of Si is suggested by the crystallization of spinel s.s. instead of phlogopite in the groundmass. The presence of djerfisherite microcrysts indicates high activities of Cl and S during the late stages of melt crystallization. The occurrence of two distinct spinel-group minerals (spinel s.s. and qandilite-rich MUM) in the groundmass is interpreted as clear evidence of the mingling of a magnesiocarbonatitic melt with a dominant kimberlitic melt. Full article
(This article belongs to the Special Issue Spinel Group Minerals, Volume II)
Show Figures

Figure 1

30 pages, 7876 KB  
Article
In-Situ Crystallization and Continuous Modification of Chromian Spinel in the “Sulfide-Poor Platinum-Group Metal Ores” of the Norilsk-1 Intrusion (Northern Siberia, Russia)
by Ivan F. Chayka, Liudmila M. Zhitova, Tatiana N. Antsiferova, Adam Abersteiner, Artem Ya. Shevko, Andrey E. Izokh, Nadezhda D. Tolstykh, Marina P. Gora, Valery M. Chubarov and Vadim S. Kamenetsky
Minerals 2020, 10(6), 498; https://doi.org/10.3390/min10060498 - 30 May 2020
Cited by 15 | Viewed by 4594
Abstract
Layers rich in chromian spinel (Cr-spinel) occur in numerous differentiated and layered intrusions. These layers are often characterized by elevated and even economic concentrations of platinum-group-elements (PGEs), but only scarce sulfide mineralization. One particular type of such lithology occurs in the roof parts [...] Read more.
Layers rich in chromian spinel (Cr-spinel) occur in numerous differentiated and layered intrusions. These layers are often characterized by elevated and even economic concentrations of platinum-group-elements (PGEs), but only scarce sulfide mineralization. One particular type of such lithology occurs in the roof parts of the Norilsk-type differentiated intrusions (Russia) and is referred to as the “sulfide-poor PGE ores”. We investigated rocks containing variable enrichments in Cr-spinel, sulfides, and platinum-group minerals (PGMs) from two sections of the upper zone of the Norilsk-1 intrusion, with a focus on Cr-spinel. The rocks are dominated by two lithological types: (1) leucogabbro/troctolitic and (2) olivine-gabbro. Fine-grained (5–100 μm) disperse disseminations with varying modal abundances of Cr-spinel are characteristic for the rocks studied. Those abundances range from scarce mineralization through to very dense (up to 30 vol. % Cr-spinel) cloud-like accumulations. However, compact-grained accumulations and cumulate-like textures, which are typical for chromitites of layered intrusions, are not characteristic for the studied rocks. Instead, the disseminations exhibit chain- and trail-like alignments of Cr-spinel grains, which cross the boundaries between enclosing silicates, and sub-circular arrangements. The study revealed millimeter-scaled patchy distribution of Cr-spinel compositions within a given dissemination with Cr-spinel chemistry being strongly correlated with a kind of the enclosing silicate. (1) In unaltered rocks, plagioclase hosts more magnesian Cr-spinel (Mg# 30–60), while Cr-spinel in mafic minerals is less magnesian (Mg# 18–35). (2) In altered rocks, more magnesian Cr-spinel is hosted by less altered silicates, while strongly altered silicates mainly host less magnesian Cr-spinel. Systematics of trivalent cations exhibits divergent trends, even on a scale of a thin section, and depends on a kind of hosting lithology. Leucogabbro/troctolite lithologies contain Cr-spinel with anomalously low Fe3+ and extremely high Ti contents, whereas Cr-spinel from olivine-gabbro lithologies have moderate Fe3+ and moderately-high Ti contents. It is envisaged that crystallization of Cr-spinel and their host rocks occurred from viscous mingled magmas, which had different compositions and redox state. Subsequent processes involved (1) high-temperature re-equilibration of Cr-spinel with enclosing silicates and (2) post-magmatic alteration and partial recrystallization of Cr-spinel. During these processes, Cr-spinel was losing Mg and Al and gaining Fe and Ti. These chemical trends are generally coincident with those established for other intrusions worldwide, but the upper zone of the Norilsk-1 intrusion seems to possess an exceptional variety of Cr-spinel compositions, not recorded elsewhere. Full article
(This article belongs to the Special Issue Spinel Group Minerals, Volume II)
Show Figures

Figure 1

Back to TopTop