Search Results (30)

We present frequency- and magnetic field-dependent measurements of the complex dielectric permittivity ε*(f, H) of a kerosene-based ferrofluid, containing Mn₀.₆Fe₀.₄Fe₂O₄ nanoparticles, over 0.8–5 GHz and static fields up to ~91 kA/m. The imaginary part, ${\epsilon }_F^{″}$, shows a peak at a characteristic frequency that shifts towards higher frequencies with increasing H, revealing a magnetic field-dependent relaxation process, interpreted using the Maxwell–Wagner–Sillars model. The dielectrophoretic extraction of nanoparticles was evaluated via the squared electric field gradient, and a threshold, ${\left(\nabla E^2\right)}_{\min }$, dependent on particle size was determined. Below that threshold, Brownian forces dominate, so the ferrofluid acts as a homogeneous dielectric. For this case, the Clausius–Mossotti factor (CM) was calculated for ferrofluid droplets in air and in water as a function of frequency and magnetic field. In air, CM exhibits modest but systematic magnetic field dependence, indicating a magnetically modulated dielectric response at GHz frequencies. In contrast, when water is used as the reference medium, CM remains negative and essentially independent of H across the entire frequency range, suggesting that the high permittivity of water masks the magneto-dielectric effects in the ferrofluid. These findings provide insight into the interplay between the magnetic field and the permittivity of ferrofluids, with implications for high-frequency applications. Moreover, using a λ/4 antenna connected to a network analyzer, the existence of the dielectrophoretic force acting on a ferrofluid-impregnated textile thread at microwave frequencies was experimentally demonstrated. Full article

Spintronics, an interdisciplinary field merging magnetism and electronics, has attracted considerable interest due to its potential to transform data storage, logic devices, and emerging quantum technologies. Among the materials explored for spintronic applications, metal oxide nanostructures synthesized via sol–gel methods offer a unique combination of low-cost processing, structural tunability, and defect-mediated magnetic control. This comprehensive review presents a critical overview of recent advances in sol–gel-derived magnetic oxides, such as Co-doped ZnO, La_1−xSr_xMnO₃, Fe₃O₄, NiFe₂O₄, and transition-metal-doped TiO₂, with emphasis on synthesis strategies, the dopant distribution, and room-temperature ferromagnetic behavior. Key spintronic functionalities, including magnetoresistance, spin polarization, and magnetodielectric effects, are systematically examined. Importantly, this review differentiates itself from the prior literature by explicitly connecting sol–gel chemistry parameters to spin-dependent properties and by offering a comparative analysis of multiple oxide systems. Critical challenges such as phase purity, reproducibility, and defect control are also addressed. This paper concludes by outlining future research directions, including green synthesis, the integration with 2D materials, and machine-learning-assisted optimization. Overall, this work bridges sol–gel synthesis and spintronic material design, offering a roadmap for advancing next-generation oxide-based spintronic devices. Full article

The effect of strontium substitution on the crystal tructure, as well as the magnetic, and electrical properties of lanthanum ferrite (LaFeO₃) synthesized by high-energy ball milling, is studied, with an emphasis on magnetodielectric coupling. X-ray diffraction (XRD) confirmed the successful synthesis of orthorhombic La_1−xSr_xFeO₃ for doping levels up to 0.2 mol. At 0.3 mol Sr²⁺, two phases appear: La_0.6Sr_0.4FeO_2.976 and La_0.8Sr_1.2FeO_3.714, the latter being metastable. This phase vanishes at 0.5 mol. The Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy coupled with Energy Dispersive X-ray Spectroscopy (SEM-EDS) analysis confirmed these results using a vibrating sample magnetometer (VSM), whose measurements show ferromagnetism at 0.1 and 0.3 mol Sr²⁺, attributed to crystal distortion, magnetic spin rearrangement, and as consequence, modifications in the double-exchange interactions. Dielectric tests reveal that higher Sr²⁺ concentrations lead to increased relative permittivity, dielectric losses, and conductivity, linked to oxygen vacancy formation. This study demonstrates a room-temperature magnetodielectric coupling of 32% in Sr-doped lanthanum ferrite, highlighting its potential for technological applications. Full article

Composites of ferromagnetic and ferroelectric phases are of interest for studies on mechanical strain-mediated coupling between the two phases and for a variety of applications in sensors, energy harvesting, and high-frequency devices. Nanocomposites are of particular importance since their surface area-to-volume ratio, a key factor that determines the strength of magneto-electric (ME) coupling, is much higher than for bulk or thin-film composites. Core–shell nano- and microcomposites of the ferroic phases are the preferred structures, since they are free of any clamping due to substrates that are present in nanobilayers or nanopillars on a substrate. This review concerns recent efforts on ME coupling in coaxial fibers of spinel or hexagonal ferrites for the magnetic phase and PZT or barium titanate for the ferroelectric phase. Several recent studies on the synthesis and ME measurements of fibers with nickel ferrite, nickel zinc ferrite, or cobalt ferrite for the spinel ferrite and M-, Y-, and W-types for the hexagonal ferrites were considered. Fibers synthesized by electrospinning were found to be free of impurity phases and had uniform core and shell structures. Piezo force microscopy (PFM) and scanning microwave microscopy (SMM) measurements of strengths of direct and converse ME effects on individual fibers showed evidence for strong coupling. Results of low-frequency ME voltage coefficient and magneto-dielectric effects on 2D and 3D films of the fibers assembled in a magnetic field, however, were indicative of ME couplings that were weaker than in bulk or thick-film composites. A strong ME interaction was only evident from data on magnetic field-induced variations in the remnant ferroelectric polarization in the discs of the fibers. Follow-up efforts aimed at further enhancement in the strengths of ME coupling in core–shell composites are also discussed in this review. Full article

In a first theoretical investigation of the multiferroic properties of ${\mathrm{Pb}}_5$${\mathrm{Fe}}_3$${\mathrm{F}}_{19}$ (PFF) and ${\mathrm{Pb}}_5$${\mathrm{Cr}}_3$${\mathrm{F}}_{19}$ (PCF), we analyze their magnetic, ferroelectric, and dielectric characteristics as functions of temperature, magnetic field, and ion doping concentration using a microscopic model and Green’s function theory. The temperature-dependent polarization in PFF and PCF shows a distinctive kink at the magnetic Neel temperature $T_N$, which vanishes when an external magnetic field is applied, indicating the multiferroic behavior of these two compounds. Ion doping effectively tunes the properties of PFF and PCF. In PFF, Cr ion doping leads to a decrease in the Neel temperature $T_N$, while Cr and Al ion doping lowers the ferroelectric Curie temperature $T_C$. In the case of PCF, we observe the enhancement of $T_C$ by Fe ion doping and the reduction by Al ion doping. The last result coincides well quantitatively with the experimental data. Additionally, the magnetodielectric coefficient of PFF is enhanced with the increasing magnetic field. Full article

This study aims to develop low-cost, eco-friendly, and circular economy-compliant composite materials by creating three types of magnetorheological suspensions (MRSs) utilizing lard, carbonyl iron (CI) microparticles, and varying quantities of gelatin particles (GP). These MRSs serve as dielectric materials in cylindrical cells used to fabricate electric capacitors. The equivalent electrical capacitance (C) of these capacitors is measured under different magnetic flux densities ($B\le 160$ mT) superimposed on a medium-frequency electric field (f = 1 kHz) over a period of 120 s. The results indicate that at high values of B, increasing the GP content to 20 vol.% decreases the capacitance C up to about one order of magnitude compared to MRS without GP. From the measured data, the average values of capacitance $C_{\mathrm{m}}$ are derived, enabling the calculation of relative dielectric permittivities (${ϵ}_{\mathrm{r}}^{\prime }$) and the dynamic viscosities ($\eta$) of the MRSs. It is demonstrated that ${ϵ}_{\mathrm{r}}^{\prime }$ and $\eta$ can be adjusted by modifying the MRS composition and fine-tuned through the magnetic flux density B. A theoretical model based on the theory of dipolar approximations is used to show that ${ϵ}_{\mathrm{r}}^{\prime }$, $\eta$, and the magnetodielectric effect can be coarsely adjusted through the composition of MRSs and finely adjusted through the values B of the magnetic flux density. The ability to fine-tune these properties highlights the versatility of these materials, making them suitable for applications in various industries, including electronics, automotive, and aerospace. Full article

This paper presents the fabrication and characterization of plane capacitors utilizing magnetodielectric materials composed of magnetizable microfibers dispersed within a silicone oil matrix. The microfibers, with a mean diameter of about 0.94 $\mathsf{\mu }$m, comprise hematite ($\alpha$-Fe₂O₃), maghemite ($\gamma$-Fe₂O₃), and magnetite (Fe₃O₄). This study investigates the electrical behavior of these capacitors under the influence of an external magnetic field superimposed on a medium-frequency alternating electric field, across four distinct volume concentrations of microfibers. Electrical capacitance and resistance measurements were conducted every second over a 60-s interval, revealing significant dependencies on both the quantity of magnetizable phase and the applied magnetic flux density. Furthermore, the temporal stability of the capacitors’ characteristics is demonstrated. The obtained data are analyzed to determine the electrical conductance and susceptance of the capacitors, elucidating their sensitivity to variations in microfiber concentration and magnetic field strength. To provide theoretical insight into the observed phenomena, a model based on dipolar approximations is proposed. This model effectively explains the underlying physical mechanisms governing the electrical properties of the capacitors. These findings offer valuable insights into the design and optimization of magnetodielectric-based capacitors for diverse applications in microelectronics and sensor technologies. Full article

The magnetic permeability (μ), dielectric permittivity (ε) and electrical conductivity (σ) of six elastomer samples obtained by mixing silicone rubber (RTV-530) with a kerosene-based ferrofluid in different volume fractions (φ), 1.31%, 2.59% and 3.84%, were determined using complex impedance measurements over a frequency range of 500 Hz–2 MHz. Three samples (A₀, B₀ and C₀) were manufactured in the absence of a magnetic field, and the other three samples (A_h, B_h and C_h) were manufactured in the presence of a magnetic field, H = 43 kA/m. The component μ″ of the complex effective magnetic permeability of all samples presents a maximum at a frequency, f_max, that moves to higher values by increasing φ, with this maximum being attributed to Brownian relaxation processes. The conductivity spectrum, σ (f), of all samples follows the Jonscher universal law, which allows for both the determination of the static conductivity, σ_DC, and the barrier energy of the electrical conduction process, W_m. For the same φ, W_m is lower, and σ_DC is higher in the samples A_h, B_h and C_h than in the samples A₀, B₀ and C₀. The performed study is useful in manufacturing elastomers with predetermined properties and for possible applications such as magneto-dielectric flexible electronic devices, which can be controlled by the volume fraction of particles or by an external magnetic field. Full article

Inverse problems for line sources radiating inside a homogeneous magneto-dielectric cylinder are investigated. The developed algorithms concern the determination of the location and the current of each source. These algorithms are mostly analytical and are based on proper exploitation of the moments obtained by integrating the product of the total field on the cylindrical boundary with complex exponential functions. The information on the unknown parameters of the problem is encoded in these moments, and hence all parameters can be recovered by means of relatively simple explicit expressions. The cases of one and two sources are considered and analyzed. Under certain conditions, the permittivity and permeability of the cylinder are also recovered. The results from two types of numerical experiments are presented: (i) for a single source, the effect of noise on the boundary data is studied, (ii) for two sources, the pertinent nonlinear system of equations is solved numerically and the accuracy of the derived solution is discussed. Full article

This paper is concerned with the free and forced vibration responses of a magneto/electroactive dielectric elastomer, emphasizing the chaotic phenomena. The dielectric elastomers under external magnetic and electrical excitations undergo large elastic deformation. The magnetodielectric elastomer is modeled based on the Gent–Gent strain energy function to incorporate the influence of the second invariant and the strain stiffening. The viscoelasticity of the active polymer is also considered in the form of Rayleigh’s dissipation function. The equation of motion is governed with the aid of the Lagrangian equation in terms of a physical quantity, namely, the stretch of the elastomer. An energy-based approach is utilized to re-evaluate the static and DC voltage instabilities of the resonator. Time-stretch response (time history behavior), phase plane diagram, Poincaré map, and fast Fourier transform are numerically obtained and presented to explore the chaotic oscillation behavior of the active polymer actuators. The results reveal that the magnetic field may tune the stability and instability regions of the active polymeric membrane. It has also been shown that the applied magnetic field may lead to chaotic vibration responses when a sinusoidal voltage is applied simultaneously to the system. The results presented in this paper can be effectively used to design magnetic and electrical soft robotic actuators and elastomer membranes under electrical and magnetic stimulants. Full article

The energy level schema of the ground term of the nickel ion in NiCr${}_2$O${}_4$ was calculated. The parameters of the interaction with the electric field were determined, and the distribution pattern of the electric dipole moments over different positions of nickel in the unit cell was calculated. The model of the NiCr${}_2$O${}_4$ magnetoelectric structure at T < T${}_c$ was constructed taking into account the data on neutron scattering and the results of the electric polarization measurements. The origin of the magnetodielectric effect was attributed to the peculiarities of the ground state of the nickel ion. Full article

Magnetodielectric properties of prepared ordered microstructured polydimethylsiloxane-based magnetorheological elastomer with the Fe₃O₄@rGO (Fe₃O₄@rGO/PDMS-MRE) were investigated to expand the application of magnetorheological elastomer (MRE) in magnetic sensing fields by improving the magnetodielectric effect. Five types of Fe₃O₄@rGO electromagnetic biphasic composite particles were synthesized by the solvothermal method, and their characterization and magnetic properties were also tested. Microstructurally ordered Fe₃O₄@rGO/PDMS-MRE samples with different Fe₃O₄@rGO concentrations were obtained through the magnetic field orientation technique, an experimental platform for magnetodielectric properties was built, and the relative permittivity of the samples was tested under magnetic flux density from 0 to 500 mT. The results show when the ratio of modified Fe₃O₄ to GO reaches 10:1, the Fe₃O₄@rGO composite particles exhibit uniform distribution with a flaky structure and strong magnetic properties and have the best bonding effect of composite particles. The relative permittivity of Fe₃O₄@rGO/PDMS-MRE increases with the rise of Fe₃O₄@rGO concentration and applied magnetic flux density. The relative permittivity of Fe₃O₄@rGO/PDMS-MRE with Fe₃O₄@rGO concentration of 60 wt% reaches 12.934 under the action of 500 mT magnetic flux density, and the magnetodielectric effect is as high as 92.4%. A reasonable mechanism for improving the magnetodielectric effect of ordered microstructured Fe₃O₄@rGO/PDMS-MRE is proposed. Full article

Magnetoelectric (ME) laminated composites with strong ME coupling are becoming increasingly prevalent in the electron device field. In this paper, an enhancement of the ME coupling effect via transition-layer implantation for co-fired lead-free laminated composite (80Bi_0.5Na_0.5TiO₃-20Bi_0.5K_0.5TiO₃)/(Ni_0.8Zn_0.2)Fe₂O₄ (BNKT/NZFO) was demonstrated. A transition layer composed of particulate ME composite 0.5BNKT-0.5NZFO was introduced between the BNKT piezoelectric layer and the NZFO magnetostrictive layer, effectively connecting the two-phase interface and strengthening interface stress transfer. In particular, an optimal ME voltage coefficients (α_ME) of 144 mV/(cm·Oe) at 1 kHz and 1.05 V/(cm·Oe) at the resonant frequency in the composite was achieved, with a layer thickness ratio (BNKT:0.5BNKT-0.5NZFO:NZFO) of 3:1:6. The static elastic model was used to determine strong interface coupling. A large magnetodielectric (MD) response of 3.95% was found under a magnetic field excitation of 4 kOe. These results demonstrate that transition-layer implantation provides a new path to enhance the ME response in co-fired laminated composite, which can play an important role in developing magnetic field-tuned electronic devices. Full article

The appearance of antiferroelectrics (AFE) in the ferrimagnetism (FM) system would give birth to a new type of multiferroic candidate, which is significant to the development of novel devices for energy storage. Here we demonstrate the realization of full antiferroelectrics in a magnetic La_0.5Sr_0.5Fe₁₂O₁₉ system (AFE+FM), which also presents a strong magnetodielectric response (MD) and magnetoresistance (MR) effect. The antiferroelectric phase was achieved at room temperature by replacing 0.5 Sr²⁺ ions with 0.5 La²⁺ ions in the SrFe₁₂O₁₉ compound, whose phase transition temperature of ferroelectrics (FE) to antiferroelectrics was brought down from 174 °C to −141 °C, while the temperature of antiferroelectrics converting to paraelectrics (PE) shifts from 490 °C to 234 °C after the substitution. The fully separated double P-E hysteresis loops reveal the antiferroelectrics in La_0.5Sr_0.5Fe₁₂O₁₉ ceramics. The magnitude of exerting magnetic field enables us to control the generation of spin current, which induces MD and MR effects. A 1.1T magnetic field induces a large spin current of 15.6 n A in La_0.5Sr_0.5Fe₁₂O₁₉ ceramics, lifts up dielectric constants by 540%, and lowers the resistance by −89%. The magnetic performance remains as usual. The multiple functions in one single phase allow us to develop novel intelligent devices. Full article

Single-phase multiferroics that allow the coexistence of ferroelectric and magnetic ordering above room temperature are highly desirable, and offer a fundamental platform for novel functionality. In this work, a double perovskite multiferroic Pr₂FeAlO₆ ceramic is prepared using a sol-gel process followed by a quenching treatment. The well-crystallized and purified Pr₂FeAlO₆ in trigonal structure with space group R3c is confirmed. A combination of the ferroelectric (2P_r = 0.84 μC/cm², E_c = 7.78 kV/cm at an applied electric field of 20 kV/cm) and magnetic (2M_r = 433 memu/g, H_c = 3.3 kOe at an applied magnetic field of 1.0 T) hysteresis loops reveals the room-temperature multiferroic properties. Further, the magnetoelectric effect is observed from the measurements of magnetically induced dielectric response and polarization. The present results suggest a new complex oxide candidate for room-temperature multiferroic applications. Full article