Search Results (27,315)

X-ray absorption spectroscopy (XAS) and X-ray emission spectroscopy (XES) are analytical techniques enabling precise analysis of the electronic structure and local atomic environment in chemical compounds and materials. Their application spans materials science, chemistry, biology, and environmental sciences, supporting studies on catalytic mechanisms, redox processes, and metal speciation. A key advantage of both techniques is element selectivity, allowing the analysis of specific elements without matrix interference. Their high sensitivity to chemical state and coordination enables determination of oxidation states, electronic configuration, and local geometry. These methods are applicable to solids, liquids, and gases without special sample preparation. Modern XAS and XES studies are typically performed using synchrotron radiation, which provides an intense, monochromatic X-ray source and allows advanced in situ and operando experiments. Sub-techniques such as XANES (X-ray absorption near-edge structure), EXAFS (Extended X-ray Absorption Fine Structure), and RIXS (resonant inelastic X-ray scattering) offer enhanced insights into oxidation states, local structure, and electronic excitations. Despite their broad scientific use, applications in pharmaceutical research remain limited. Nevertheless, recent studies highlight their potential in analyzing crystalline active pharmaceutical ingredients (APIs), drug–biomolecule interactions, and differences in drug activity. This review introduces the fundamental aspects of XAS and XES, with an emphasis on practical considerations for pharmaceutical applications, including experimental design and basic spectral interpretation. Full article

Eight different types of tea bags were investigated in this work using dynamic light scattering, electrophoretic mobility and nanoparticle tracking analysis methods to determine the concentration and size of released particles from the bag materials at different temperatures and times. Infrared spectroscopy and calorimetric methods confirmed that the bag material consisted of synthetic (nylon or polypropylene) or natural polymers (cellulose). The size of the released particles lies in the range of 200 nm^–1 µm with an initial bimodal distribution and with an average diameter of about 600 nm. The concentration of released particles increases with increasing temperature and brewing time. The released particles of synthetic polymers remain quite stable and are not affected by natural enzymes, while cellulose particles are easily degraded by the proteolytic complex Morikrase. When analyzing the electrophoretic mobility, it was found that the released particles have a negative surface charge, which probably determines the absence of cytotoxicity established on the epithelial cell line Caco-2 even at the maximum values of the observed particle concentrations (14 × 10⁹ particle/L for synthetic polymers and 170 × 10⁹ particle/L for cellulose). Full article

To increase and optimize the use of wood in structural elements, a deep understanding of its mechanical behavior is necessary. The transverse material properties of wood are particularly important for mass timber construction and for utilizing wood as a strengthening material in timber connections. This study experimentally determined the stiffness and strength of Scots pine wood under compression perpendicular to the grain and rolling shear loading, as well as their dependence on the annual ring structure. A previously established biaxial test configuration was employed for this purpose. The modulus of elasticity in the radial direction was found to be about twice that in the tangential direction (687 vs. 372 N/mm²), although the strength in the tangential direction (5.19 N/mm²) was comparatively higher than that in the radial direction (4.70 N/mm²). For rolling shear, especially for the rolling shear modulus, a large variation was found, and its relationship with annual ring structure was assessed. The obtained RS modulus ranged from 50 to 254 N/mm², while RS strength was found to be between 2.14 and 4.61 N/mm². The results aligned well with previous findings. Full article

Conventional characterization of ultrasonic testing (UT) transducers primarily focuses on determining centre frequency and usable bandwidth. However, the relative amplitude distribution across different frequency components—particularly in low-frequency transducers used for civil engineering applications—remains largely overlooked. This paper introduces a comprehensive methodology to assess the influence of transducer coupling and specimen geometry on ultrasonic pulse velocity signals. The novel approach combines high-frequency laser Doppler vibrometry, real-time photoelastic imaging, and computer simulations using commercial semi-analytical wave-propagation software. The methodology is applied to the characterization of a 250 kHz UT transducer, with particular emphasis on how coupling with a solid test medium alters its frequency response. A glass specimen with an acoustic impedance comparable to that of concrete is used to simulate practical testing conditions. Vibration patterns recorded at the distal end of the specimen are analysed through computer simulations and validated experimentally using a novel photoelastic system capable of capturing wave–specimen interactions at ultrasonic frequencies in real time. The findings offer valuable insights into frequency-dependent signal behaviour and transducer–medium interactions, providing practical guidance for the design and optimization of UT inspections in concrete and other highly attenuative materials commonly encountered in civil engineering. Full article

Driven by environmental concerns and aligned with the principles of the circular economy, urban plastic waste—including packaging materials, disposable items, non-functional objects, and industrial scrap—is increasingly being collected, recycled, and marketed as a potential substitute for virgin polymers. However, the use of recycled polymers introduces uncertainties that can significantly affect both the durability and the further recyclability of the resulting products. This paper demonstrates how spectroscopic analysis in the mid-infrared (MIR) and near-infrared (NIR) regions can be applied well beyond the basic identification of the main polymeric component, typically performed during the sorting stage of recycling processes. A detailed interpretation of spectral data, based on well-established correlations between spectroscopic response and material structure, enables the classification of recycled polymers according to specific physicochemical properties, such as chemical composition, molecular architecture, and morphology. In this context, infrared spectroscopy not only provides a reliable comparison with the corresponding virgin polymer references but also proves particularly effective in assessing the homogeneity of recycled materials and the reproducibility of their properties—factors not inherently guaranteed due to the variability of input sources. As a case study, we present a robust protocol for determining the polypropylene content in recycled polyethylene samples. Full article

Nano- and micro-indentation have become essential tools for quantifying the micromechanical behavior of rocks beyond traditional macroscopic tests. This review summarizes the historical evolution, experimental methodologies, and interpretation models (e.g., Oliver–Pharr, Doerner–Nix, energy-based methods, Hertz/ECM/Lawn), with a particular focus on rock-specific challenges such as heterogeneity, anisotropy, and surface roughness. A structured literature survey (1980–August 2025) covers representative studies on shale, limestone, marble, sandstone, claystone, and granite. The transition from classical hardness measurements to advanced instrumented indentation has enabled more reliable determination of localized properties, including hardness, elastic modulus, fracture toughness, and creep. Special attention is given to the applicability and limitations of different interpretation models when applied to heterogeneous and anisotropic rocks. Current challenges include high sensitivity to surface conditions and difficulties in capturing the full complexity of natural rock behavior. Looking forward, promising directions involve intelligent systems that integrate AI-driven data analytics, robotic automation, and multiscale modeling (from molecular dynamics to continuum FEM) to enable predictive material design. This review aims to provide geoscientists and engineers with a comprehensive foundation for the effective application and further development of indentation-based testing in rock mechanics and geotechnical engineering. Full article

The paper presents experimental results for a modified pulsed plasma thruster (PPT) with solid propellant, using a coaxial anode–cathode design. Graphite from pencil leads served as propellant, and a tungsten trigger electrode was tested to reduce carbonization effects. Experiments were performed in a vacuum chamber at 0.001 Pa, employing diagnostics such as discharge current/voltage recording, power measurement, ballistic pendulum, time-of-flight (TOF) method, and a Faraday cup. Current and voltage waveforms matched an oscillatory RLC circuit with variable plasma channel resistance. Key discharge parameters were measured, including current pulse duration/amplitude and plasma channel formation/decay dynamics. Impulse bit values, obtained with a ballistic pendulum, reached up to 8.5 μN·s. Increasing trigger capacitor capacitance reduced thrust due to unstable “pre-plasma” formation and partial pre-discharge energy loss. Using TOF and Faraday cup diagnostics, plasma front velocity, ion current amplitude, current density, and ion concentration were determined. Tungsten electrodes produced lower charged particle concentrations than graphite but offered better adhesion resistance, minimal carbonization, and stable long-term performance. The findings support optimizing trigger electrode materials and PPT operating modes to extend lifetime and stabilize thrust output. Full article

The growing demand for precision and consistency in the forging industry has heightened the need for predictive simulation tools. While extensive research has focused on parameters such as flow stress, die wear, billet fracture, and residual stresses, the phenomenon of billet buckling, especially during cold upset forging, remains underexplored. Most existing models address only elastic buckling for slender billets using classical approaches like Euler and Rankine-Gordon formulae, which are not suitable for inelastic deformation in shorter billets. This study presents a numerical model developed to analyze inelastic buckling during cold forging and to determine associated stresses and deflection characteristics. The model was validated through finite element simulations across a range of billet geometries (10–40 mm diameter, 120 mm length), materials (aluminum, stainless steel, and copper), and friction coefficients (µ = 0.12, 0.16, and 0.35). Stress distributions were evaluated against die stroke, with particular emphasis on the influence of strain hardening and geometry. The results showed that billet geometry and strain-hardening exponent significantly affect buckling behavior, whereas friction had a secondary effect, mainly altering overall stress levels. A nonlinear regression approach incorporating material properties, geometric parameters, and friction was used to formulate the numerical model. The developed model effectively estimated buckling stresses across various conditions but could not precisely predict buckling points based on stress differentials. This work contributes a novel framework for integrating material, geometric, and process variables into stress prediction during forging, advancing defect control strategies in industrial metal forming. Full article

Production industries create high-quality products through effective machining precision, lead times, productivity, cost benefits, and implementing sustainable manufacturing practices. This study compares the effect of cryogenic CO₂ as a cutting fluid with a flooded conventional system and dry turning on the surface roughness, early-stage tool phenomena (including adhesion, material transfer, and built-up edge (BUE) formation), and the chip morphology of aluminum 7075-T6. Taguchi’s L9 orthogonal array is applied to identify the optimal cutting parameters that minimize surface roughness (Ra). Cutting speed (Vc), feed rate (f), depth of cut (ap), and the type of cutting fluid condition were defined at three levels. The surface roughness (Ra) was determined, and the built-up edge (BUE) and chip morphology were evaluated. Moreover, SEM and energy-dispersive X-ray spectroscopy (EDX) were employed to characterize the machined surface and the cutting tools. The optimal values for the cryogenic cooling and cutting parameters are as follows: 220 m/min (Vc), 0.05 mm/rev (f), and 0.5 mm (ap). These conditions yield a surface roughness mean (Ra) of 0.736 µm, improving the surface roughness by 10.57% compared with the lowest Ra value from all of the tests. In addition, ANOVA showed the feed rate to be the most significant cutting parameter over surface roughness under the given conditions. Regarding chip morphology, snarled chip shapes are associated with low surface roughness values. The results indicate that cryogenic cutting fluid enhances the machined surface quality and reduces the built-up edge compared with dry and flooded conditions. Full article

In this study, TiC_xO_y was produced by sintering in an argon atmosphere using carbon–thermal reduction with TiO₂ and graphite powder as the initial materials. The sintered TiC_xO_y was analyzed using X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. As the oxygen content increased, the grain color of the sintered TiC_xO_y gradually shifted from gray to reddish-brown. The structure of TiC_xO_y resembles that of a coral, with a uniform distribution of Ti, C, and O throughout the sample. Analysis using X-ray photoelectron spectroscopy reveals the presence of bivalent, trivalent, and tetravalent titanium. Utilizing General Structure Analysis System software(GSAS-II), the X-ray Diffraction data obtained were refined, revealing a gradual decrease in lattice parameters as the oxygen atom content increased. Furthermore, the conductivity and density of the single phase, determined through the four-probe method and the Archimedes method, respectively, exhibited an increase in tandem with the rise in C content. Full article

In 2016, five fragments from a copy of “The Great Holy Family of Francis I” were brought to the Cologne Institute of Conservation Sciences (CICS) for research and conservation/restoration. A comprehensive technical and material analysis was carried out to assist provenance studies. From the analysis of pigments, binder, additives, and canvas fibres alongside radiocarbon dating of the lead white pigment, oil binder, and canvas support, as well as the lead stable isotope study, it could be determined that, with high probability, the copy was created in Northern Europe between the late 16th century and the mid-17th century. During this period the original painting was initially displayed in Fontainebleau in the “Chapelle Haute” before being transferred in the early 17th century to the newly built “Cabinet des Peintures”, also in Fontainebleau, where it would probably have been more accessible for copying. Interestingly, the written sources describe a copy made during this period to replace the original in the “Chapelle Haute”, the location of which is currently not known. However, the different overall dimensions of the present copy speak against it, having been created to replace the original. Full article

African horse sickness (AHS) is an arthropod-borne, severe equid disease caused by African horse sickness virus (AHSV). AHSV has high mortality and is endemic to sub-Saharan Africa. It has been classified into nine distinct serotypes (AHSV-1 to AHSV-9) based on VP2 immunogenicity. The AHS outbreak in Thailand in 2020, caused by AHSV-1, marked the first occurrence of this disease in Southeast Asia. It posed a substantial threat to the security of the equine industry in the nations across the region. To ensure the emergency reserve for AHS prevention and control, the AHSV strain imported to China from abroad over 60 years ago was characterized in this study. The strain was passaged in mice and then blind-passaged in Vero cells. The plaque purification method was then used to purify the strain and obtain its cell-adapted version, named AHSV/C. Neutralization tests confirmed that the virus belongs to AHSV-1. Whole-genome sequencing revealed that AHSV/C was highly homologous to AHSV-1 isolate 1180, with over 95% homology of major antigenic protein VP2, as compared to other AHSV-1 strains, including the prevalent strain in Thailand. In the mouse models, AHSV/C exhibited no clinical signs or histopathological lesions, suggesting low virulence and safety. This research for the first time characterized the in vitro growth characteristics and viral subtypes of the AHSV in China, determined its complete whole-genome sequence, and evaluated its safety using a mouse model. It provides crucial experimental materials and scientific foundations for the development of diagnostic methods and vaccines against AHSV-1. Full article

As a pivotal component of the single-gear reducer, the casing of the miniature car reducer not only safeguards the internal transmission system but also interfaces seamlessly with the external structure. Currently, the structural design of domestic single-stage reducers primarily leans on experience and standardized specifications. To guarantee the reliable and stable operation of the casing, a high safety factor is often incorporated, which inevitably results in increased weight and necessitates secure bolting connections. This study presents an innovative scheme to design the flange with the box and realize the lightweight nature of the box by finite element analysis to reduce the manufacturing cost. Based on the working state of maximum torque and maximum speed, this study obtains the stress distribution of each bearing seat under different working conditions and carries out static and dynamic analysis combined with other coupling constraints. The analysis results show that the structure has high stiffness and strength, which is suitable for lightweight design, and that the first ten spontaneous vibration frequencies are far away from the excitation frequency of the inner and outer boundary, avoiding the resonance phenomenon. Moreover, this study proposes a new structure design method, which effectively improves the stiffness of the structure. Through the calculation of volume ratio before and after three optimizations, the optimal volume ratio of 30% is selected, unnecessary materials around the bearing seat are removed, and the layout of ribs is determined. After structural optimization, the weight of the shell is reduced by 10.2%, and both the static and dynamic characteristics meet the design requirements. Full article

To date, the grinding behavior of saprolite and lateritic overburden mixtures remains poorly understood. The Bond Work Index (BWI) is the principal indicator used to determine the specific energy consumption during the grinding process. To establish the F₈₀ and P₈₀ values, granulometric distribution models—Rosin–Rammler (RR), Gates–Gaudin–Schuhmann (GGS), and the Swebrec function (SWEF)—were evaluated. The mineral phases of the feed samples were analyzed by X-ray powder diffraction. This study provides evidence that the RR function is the most suitable for simulating the particle size distribution of the feed material, with residual errors below 6.30% and a coefficient of determination (R²) exceeding 97%. After the grinding equilibrium cycle is reached, the SWEF model proves to be the most appropriate, exhibiting residual errors under 3.50% and R² values above 98%. BWI reveals that saprolite is the most difficult ore to grind, with specific energy consumption increasing from 16.38 kWh/t to 25.50 kWh/t as the proportion of saprolite in the mixture rises. This reflects a clear upward trend, as confirmed by a fitted model with an R² of 98.54%. In contrast, the grindability index (Gbp) decreases, indicating that the material becomes increasingly resistant to grinding as the saprolite content increases. This may be attributed to inherent material properties, such as hardness, or to physical phenomena related to fragmentation. The declining Gbp further suggests that greater energy input is required to achieve additional particle size reduction. Overall, the findings demonstrate that saprolite is inherently difficult to grind and behaves according to its own grinding characteristics, regardless of whether it is processed alone or in combination with lateritic overburden. Full article

A non-destructive method for determining the properties of laminated composite materials made of twill-weave glass fibre fabric is considered. To determine the elastic characteristics of the composite monolayer, a combined numerical–experimental method is used. The method combines the results of experimental tests and numerical modelling methods using optimization techniques. Firstly, the method for determining the properties is tested in a virtual experiment to determine the influence of the elastic characteristics of the material that do not affect the frequency response. The adequacy of the approximation equations and the influence of elastic constants on frequency response are evaluated using Analysis of Variance (ANOVA). Using the results obtained, the properties of the elastic characteristics of layered composite plates made of twill-weave glass fibre fabric using vacuum infusion are determined. To compare the properties obtained from the dynamic calculation, a series of static measurements of tensile samples were carried out. The results showed that the elastic modulus from the static test and the flexural test do not coincide by 4% and 23%, respectively. The technique demonstrates high accuracy and applicability for the non-destructive determination of dynamic material properties in engineering practice. Full article