Search Results (344)

In this study, AlGaN/GaN heterostructure field-effect transistors (HFETs) with an AlN cap layer and a GaN cap layer were fabricated. The devices were of different sizes. Capacitance–voltage (C-V) and current–voltage (I-V) curves were measured. Based on two-dimensional (2D) scattering theory, electron mobility corresponding to polarization Coulomb field (PCF) scattering and other primary scattering mechanisms was quantitatively determined. The influence of the AlN cap layer on PCF scattering in AlGaN/GaN HFETs was studied. It was found that the AlN cap layer suppresses the inverse piezoelectric effect (IPE) in the AlGaN barrier layer because of its greater polarization and larger Young’s modulus, thereby reducing the generation of additional polarization charge (APC) under the gate. In addition, the 2D electron gas (2DEG) density (n_2DEG) under the gate of the samples with an AlN cap layer is higher. Both factors help reduce PCF scattering intensity. Moreover, mobility analysis of samples with different gate–drain spacings (L_GD) showed that PCF scattering is less affected by L_GD variations in devices with AlN cap layers. This study offers new insights into the structural optimization of AlGaN/GaN HFETs. Full article

With the booming development of the 5G market in recent years, super-high frequency (SHF) resonators will play an increasingly critical role in 5G and future communication systems. Facing the growing market demand for miniaturized, high-bandwidth, and low insertion loss filters, the design of SHF resonators and filters with a high effective electromechanical coupling coefficient (K²_eff) and quality factor, low insertion loss, high passband flatness, strong out-of-band rejection, and high power handling capacity has placed high demands on piezoelectric material preparation, process optimization, and resonator design. The polarity-inverted Al(Sc)N multilayer substrate has become one of the key solutions for SHF resonators. This review provides a comprehensive overview of the recent advances in SHF Al(Sc)N bulk acoustic wave (BAW) resonators. It systematically discusses the device design methodologies, structural configurations, and material synthesis techniques for high-quality Al(Sc)N thin films. Particular emphasis is placed on the underlying mechanisms and engineering strategies for polarity control in Al(Sc)N-based periodically poled multilayer structures. The progress in periodically poled piezoelectric film (P3F) BAW resonators is also examined, with special attention to their ability to significantly boost the operating frequency of BAW devices without reducing the thickness of the piezoelectric layer, while maintaining a high K²_eff. Finally, the review outlines current challenges and future directions for achieving a higher quality factor (Q), improved frequency scalability, and greater integration compatibility in SHF acoustic devices, paving the way for next-generation radio frequency (RF) front-end technologies in 5G/6G and beyond. Full article

Polymer-based hybrid composites have emerged as promising platforms for multifunctional energy applications, combining structural versatility with tunable dielectric behavior. In this study, synthesized [Fe(bpy)₃]SO₄; (tris(2,2′-bipyridine)iron(II) sulfate) coordination compound was incorporated into a green epoxy resin matrix to fabricate nanocomposites aimed at enhancing dielectric permittivity (ε′), piezoelectric coefficient (d₃₃, pC/N), energy-storage efficiency (n_rel, %), and mechanical strength (σ, MPa). The integration of the Fe(II) complex via Scanning Electron Microscopy (SEM) confirmed a homogeneous dispersion within the matrix. Broadband Dielectric Spectroscopy (BDS) revealed the presence of three relaxation processes in the spectra of the tested systems, demonstrating enhanced dielectric permittivity with increasing Fe(II) content. Under progressively shorter relaxation times (τ, s), key processes such as interfacial polarization, the polymer matrix’s transition from a glassy to a rubbery state, and the dynamic reorganization of polar side groups along the polymer backbone are activated. The ability to store and retrieve electric energy was confirmed by varying filler content under direct current (dc) conditions. The nanocomposite with 10 phr (mass parts/100 mass parts of resin) filler achieved a piezoelectric coefficient of d₃₃ = 5.1 pC/N, an energy-storage efficiency of n_rel = 44%, and a tensile strength of σ = 55.5 MPa, all of which surpass values reported for conventional epoxy-based composites. These results confirm the ability of the system to store and retrieve electric energy under direct current (dc) fields, while maintaining mechanical robustness and thermal stability due to synergistic interactions between the epoxy matrix and the Fe(II) complex. The multifunctional behavior of the composites underscores their potential as advanced materials for integrated dielectric, piezoelectric, and energy storage and harvesting applications. Full article

A triboelectricity-enhanced piezoelectric nanogenerator (PENG) based on pressure-processed multi-electrospun polymeric layers is herein developed for efficient vibrational energy harvesting. The hybridization of piezoelectric and triboelectric mechanisms through electrospinning has been utilized to enhance electrical output by increasing contact areas and promoting alignment within piezoelectric materials. A multi-layer structure comprising alternating poly (vinylidene fluoride) (PVDF) and poly (hexamethylene adipamide) (PA 6/6) exhibits superior electrical performance. A lateral Janus configuration, providing distinct positive and negative triboelectric polarities, has further optimized device efficiency. This approach introduces a novel operational mechanism, enabling superior performance compared to conventional methods. The fiber-based architecture ensures exceptional flexibility, low weight, and a high surface-to-volume ratio, enabling enhanced energy harvesting. Experimentally, the PENG achieved an open-circuit voltage of 14.59 V, a short-circuit current of 205.7 nA, and a power density of 7.5 mW m⁻² at a resistance of 30 MΩ with a five-layer structure subjected to post-processing under pressure. A theoretical model has mathematically elucidated the output results. Long-term durability (over 345,600 cycles) has confirmed its robustness. Demonstrations of practical applications include monitoring human joint motion and respiratory activity. These results highlight the potential of the proposed triboelectricity-enhanced PENG for vibrational energy harvesting in flexible and wearable electronic systems. Full article

Dielectric crystals with switchable electric polarizations represent the key functional materials utilized for a broad range of practical applications. They allow for academically intriguing platforms, where the use of a strong external electric field can potentially unveil hidden crystal phases. Proton–π-electron correlated bistable systems turn out to be promising for exploring such electrically induced crystal polymorphisms, mainly because strong π-electronic polarization can be sensitively switched depending on mobile hydrogen locations. Pseudo-symmetry and hydrogen disorder are utilized as clues for the data mining of the Cambridge Structural Database in the search for molecular candidates with novel switchable dielectrics. The polarization hysteresis, electrostriction, and second harmonic generation of the candidates were experimentally evaluated, together with the re-inspection of crystal structure. This feature article highlights the rich variation and competition of some candidate polarization configurations and switching modes in close relation to high and efficient electrical energy storage/discharge, large electrostriction effects, polarization rotations, and multistage switching phenomena. The experimental findings are well-reproduced by the computational optimization of crystal structure and the simulation of the switchable polarization, piezoelectric coefficients, and relative stability for each of the real or hypothetical hydrogen-ordered crystal phases. Effective prediction and strategic design are thereby guaranteed by systematically understanding the appropriate integration of experimental, computational, and data sciences. Full article

Poly(lactic acid)/barium titanate (PLA/BT) composites exhibit piezoelectric properties desirable for bone tissue engineering, but their low biodegradability limits implant resorption. In this study, riboflavin (RF) is introduced as a dual-function additive that enhances biodegradation in PLA/BT composites. Its addition led to significantly increased microbial colonization and a five-fold higher mass loss compared to unmodified samples. These observations are consistent with the known polarity of RF and its role as a cofactor in microbial metabolism. The PLA/BT/RF composites are subjected to full characterization, including thermogravimetric analysis (TG), differential scanning calorimetry (DSC), tensile testing, dynamic mechanical analysis (DMA), dielectric permittivity measurements, and determination of piezoelectric coefficient d₃₃. Compared to PLA/BT, RF-containing composites exhibit significantly accelerated biodegradation, with mass loss reaching up to 16% after 28 days, while maintaining functional piezoelectricity (d₃₃ ≈ 3.9 pC/N). Scanning electron microscopy (SEM) performed after biodegradation reveals intensified microbial colonization and surface deterioration in the RF-modified samples. The data confirm that riboflavin serves as an effective modifier, enabling controlled biodegradation without compromising electromechanical performance. These results support the use of PLA-based piezoelectric composites for resorbable biomedical implants. Full article

This research focuses on designing polymer membranes as biocompatible materials using home-built electrospinning equipment, offering alternative solutions for tissue regeneration applications. This technological development supports cell growth on biomaterial substrates, including hepatocellular carcinoma (Hep-G2) cells. This work researches the compatibility of polymer membranes (fiber mats) made of polyvinylidene difluoride (PVDF) for possible use in cellular engineering. A standard culture medium was employed to support the proliferation of Hep-G2 cells under controlled conditions (37 °C, 4.8% CO₂, and 100% relative humidity). Subsequently, after the incubation period, electrochemical impedance spectroscopy (EIS) assays were conducted in a physiological environment to characterize the electrical cellular response, providing insights into the biocompatibility of the material. Scanning electron microscopy (SEM) was employed to evaluate cell adhesion, morphology, and growth on the PVDF polymer membranes. The results suggest that PVDF polymer membranes can be successfully produced through electrospinning technology, resulting in the formation of a dipole structure, including the possible presence of a polar β-phase, contributing to piezoelectric activity. EIS measurements, based on R_ct and C_dl values, are indicators of ion charge transfer and strong electrical interactions at the membrane interface. These findings suggest a favorable environment for cell proliferation, thereby enhancing cellular interactions at the fiber interface within the electrolyte. SEM observations displayed a consistent distribution of fibers with a distinctive spherical agglomeration on the entire PVDF surface. Finally, integrating piezoelectric properties into cell culture systems provides new opportunities for investigating the influence of electrical interactions on cellular behavior through electrochemical techniques. Based on the experimental results, this electrospun polymer demonstrates great potential as a promising candidate for next-generation biomaterials, with a probable application in tissue regeneration. Full article

The design and adjustable properties of nanoporous materials are important for current and future technological applications, research, and development. In addition, nanoporous ferroelectric materials have the potential to achieve competitive ferroelectric, dielectric, and piezoelectric characteristics. In this work, using the phase-field model, we found that the shape of pores in barium titanite ceramics governs the formation of the ferroelectric domain structure and the switching hysteresis loop. A remanent polarization-coercive field (P_r-E_c) diagram is introduced to denote the shape of the hysteresis loops. We performed a fundamental study in understanding how the domain structures affect the properties of domain-engineered porous ferroelectrics. Simulation results show that the hysteresis loop of porous ferroelectrics can be designed by controlling the shape/orientation of the ellipse-shaped pores. Numerical simulations also verify that the dielectric/piezoelectric properties can be improved with artificially designed porous structures. These phase-field results may be useful in the development of highly performing lead-free ferroelectric/piezoelectric materials. Full article

This work presents an innovative hydrothermal approach for fabricating flexible piezoelectric PZT thin films on 20 μm titanium foil substrates using TiO₂ and SrTiO₃ (STO) interlayers. Three heterostructures (Ti/PZT, Ti/TiO₂/PZT, and Ti/TiO₂/STO/PZT) were synthesized to enable low-temperature growth and improve ferroelectric performance for advanced flexible MEMS. Characterizations including XRD, PFM, and P–E loop analysis evaluated crystallinity, piezoelectric coefficient d₃₃, and polarization behavior. The results demonstrate that the multilayered Ti/TiO₂/STO/PZT structure significantly enhances performance. XRD confirmed the STO buffer layer effectively reduces lattice mismatch with PZT to ~0.76%, promoting stable morphotropic phase boundary (MPB) composition formation. This optimized film exhibited superior piezoelectric and ferroelectric properties, with a high d₃₃ of 113.42 pm/V, representing an ~8.65% increase over unbuffered Ti/PZT samples, and displayed more uniform domain behavior in PFM imaging. Impedance spectroscopy showed the lowest minimum impedance of 8.96 Ω at 10.19 MHz, indicating strong electromechanical coupling. Furthermore, I–V measurements demonstrated significantly suppressed leakage currents in the STO-buffered samples, with current levels ranging from 10⁻¹² A to 10⁻⁹ A over ±3 V. This structure also showed excellent fatigue endurance through one million electrical cycles, confirming its mechanical and electrical stability. These findings highlight the potential of this hydrothermally engineered flexible heterostructure for high-performance actuators and sensors in advanced MEMS applications. Full article

This study evaluates the effect of zirconium (Zr) incorporation on the structural, microstructural, and functional properties of lead-free ceramics based on the 0.95(Bi_0.5Na_0.5)TiO₃–0.05BaTiO₃ (BNT–5BT) system. Two distinct doping strategies were investigated: (i) the substitutional incorporation of Zr⁴⁺ at the Ti⁴⁺ site (BNT–5BT–xZr_sub), and (ii) the addition of ZrO₂ in excess (BNT–5BT–xZr_exc). The samples were synthesized via conventional solid-state reaction and characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM/EDS), and electrical measurements, including dielectric, ferroelectric, and piezoelectric responses. Both doping routes were found to influence phase stability and electromechanical performance. Substitutional doping notably reduced the coercive field while preserving high remanent polarization, resulting in an enhanced piezoelectric coefficient (d₃₃). These results highlight the potential of Zr-modified BNT–5BT ceramics for lead-free energy harvesting applications. Full article

The propagation of interface acoustic waves (IAWs) along rotated YX-LiNbO₃/SU-8/ZX-Si structures is theoretically investigated to identify the Y-rotation angles that support the efficient propagation of low-loss modes guided along the structure’s interface. A three-dimensional finite element analysis was performed to simulate IAW propagation in the layered structure and to optimize design parameters, specifically the thicknesses of the platinum (Pt) interdigital transducers (IDTs) and the SU-8 adhesive layer. The simulations revealed the existence of two types of IAWs travelling at different velocities under specific Y-rotated cuts of the LiNbO₃ half-space. These IAWs are faster than the surface acoustic wave (SAW) and slower than the leaky SAW (LSAW) propagating on the surface of the bare LiNbO₃ half-space. The mechanical displacement fields of both IAWs exhibit a rapid decay to zero within a few wavelengths from the LiNbO₃ surface. The piezoelectric coupling coefficients of the IAWs were found to be as high as approximately 7% and 31%, depending on the Y-rotation angle. The theoretical results were experimentally validated by measuring the velocities of the SAW and LSAW on a bare 90° YX-LiNbO₃ substrate, and the velocities of the IAWs in a 90° YX-LiNbO₃/SU-8/Si structure featuring 330 nm thick Pt IDTs, a 200 µm wavelength, and a 15 µm thick SU-8 layer. The experimental data showed good agreement with the theoretical predictions. These combined theoretical and experimental findings establish design principles for exciting two interface waves with elliptical and quasi-shear polarization, offering enhanced flexibility for fluidic manipulation and the integration of sensing functionalities. Full article

This study presents an analytical and experimental approach to enhance cantilever-based piezoelectric energy harvesters by optimizing thickness distribution. Using a gradient projection algorithm within a state-space framework, the unimorph beam’s geometry is tailored while constraining the first natural frequency. The objective is to amplify axial strain within the piezoelectric layers, thereby increasing electric polarization and maximizing the conversion efficiency of mechanical vibrations into electrical energy. The steady-state response under harmonic base excitation at resonance was modeled to evaluate the harvester’s dynamic behavior against uniform-thickness counterparts. Results show that the optimized beam achieves significantly higher output voltage and energy harvesting efficiency. Simulations reveal effective strain concentration in regions of high piezoelectric sensitivity, enhancing power generation under resonant conditions. Two independent experimental setups were employed for empirical validation: a non-contact laser vibrometry system (Polytec 3D) and a first resonant base excitation setup. Eigenfrequencies matched within 5% using a Polytec multipath interferometry system, and constant excitation tests showed approximately 30% higher in optimal shapes electrical potential value generation. The outcome of this study highlights the efficacy of geometric tailoring—specifically, non-linear thickness shaping—as a key strategy in achieving enhanced energy output from piezoelectric harvesters operating at their fundamental frequency. This work establishes a practical route for optimizing unimorph structures in real-world applications requiring efficient energy capture from low-frequency ambient vibrations. Full article

This paper considers the uniaxial orientation effect on the structure and piezoelectric properties of vinylidene fluoride-tetrafluoroethylene copolymer ferroelectric films. The films were exposed to uniaxial orientation stretching in a temperature range from 20 °C to 60 °C; then, they were contact polarized under normal conditions. The temperature dependence of the electric strength was determined. The longitudinal piezoelectric coefficient d₃₃ values were measured by the quasi-static Berlincourt method. The piezoresponse force microscopy (PFM) method was used to investigate the film domain structure before and after polarization, and the local piezoelectric coefficient values were also calculated. Phase composition was studied using differential scanning calorimetry and infrared spectroscopy with the Fourier transform. It was found that uniaxial orientation stretching contributed to an increase in the piezoelectric coefficient d₃₃ from 5 pC/N to 16–20 pC/N. The results obtained indicate the importance of the amorphous phase contribution to the formation of the piezoelectric properties in polymeric materials. Full article

Phased-array ultrasonic transducers using sol–gel composites face challenges in terms of polarization uniformity when using conventional corona poling. Pb(Zr, Ti)O₃ (PZT)/PZT composites with a thickness of 25 µm were fabricated on 3 mm thick titanium substrates, and the samples were poled by AC poling, DC poling, and corona discharge poling at RT. It was found that the polarization direction could be controlled by the voltage off-phase angle. When poling was performed with a voltage off-phase angle of 90°, applied voltage of 200 V (rms), 10 cycles, and frequency of 1 Hz, average values and standards of measured piezoelectric constant d₃₃ of −35.1 ± 0.8 pC/N and ultrasonic sensitivity of 11.4 ± 0.1 dB were obtained. Furthermore, the AC-poled samples demonstrated smaller variations in d₃₃ and ultrasonic sensitivity compared with the corona-poled samples, and higher values of d₃₃ and ultrasonic sensitivity compared with the DC-poled samples, indicating the potential of AC poling for PZT/PZT sol–gel composites with large areas. Full article

This study presents the successful fabrication of lead zirconate titanate (PZT) thin films on silicon (Si) substrates using a hybrid deposition method combining spin-coating and RF sputtering techniques. Initially, a PZT layer was deposited through four successive spin-coating cycles, followed by an additional layer formed via RF sputtering. The resulting multilayer structure was annealed at ${700 }^{°}$C for 2 h to improve crystallinity. Comprehensive material characterization was conducted using XRD, SEM, cross-sectional SEM, EDX, and UV–VIS absorbance spectroscopy. The analyses confirmed the formation of a well-crystallized perovskite phase, a uniform surface morphology, and an optical band gap of approximately 3.55 eV, supporting its suitability for sensing applications. Building upon these findings, a multilayer PZT-based touch sensor was fabricated and electrically characterized. Low-frequency I–V measurements demonstrated consistent and repeatable polarization behavior under cyclic loading conditions. In addition, $\left|Z\right|$–f measurements were performed to assess the sensor’s dynamic electrical behavior. Although expected dielectric responses were observed, the absence of distinct anti-resonance peaks suggested non-idealities linked to ${\mathrm{Ag}}^{+}$ ion diffusion from the electrode layers. To account for these effects, the classical Butterworth–Van Dyke (BVD) equivalent circuit model was extended with additional inductive and resistive components representing parasitic pathways. This modified model provided excellent agreement with the measured impedance and phase data, offering deeper insight into the interplay between material degradation and electrical performance. Overall, the developed sensor structure exhibits strong potential for use in piezoelectric sensing applications, particularly for tactile and pressure-based interfaces. Full article