Search Results (14)

This study analyzes the concentration of radioactive material in the soil near the Maanshan nuclear power plant (NPP). Out of the thirty samples, only one sample was found to have ¹³⁷Cs radioactivity measuring 2.58 Bq/kg. The activity concentrations were 77.2–517.7 Bq/kg, 3.9–31.6 Bq/Kg, and 5.3–39.1 Bq/kg, respectively, with mean values of 344.4 Bq/kg, 18.6 Bq/kg, and 26.5 Bq/kg for ⁴⁰K, ²²⁶Ra, and ²³²Th, respectively. These levels are lower than the global average of soil activity concentrations. The activity concentrations varied, with the highest levels being 7–8 times greater than the lowest levels. Clay content had a positive correlation and sand content had a negative correlation with ⁴⁰K, ²²⁶Ra, and ²³²Th activity concentrations. The activity concentrations followed a normal distribution for ⁴⁰K, ²²⁶Ra, and ²³²Th. The activity ratios for ²³²Th/²²⁶Ra, ⁴⁰K/²³²Th, and ⁴⁰K/²²⁶Ra were 1.43 ± 0.22, 13.1 ± 1.9, and 18.8 ± 4.1, respectively, and ratios show light minerals in the soils. The average values for external hazard indices (H_ex) and radium equivalent activity (Ra_eq) were 0.22 Bq/kg and 83.0 Bq/kg, respectively, both of which are below the recommended limit values of 1.0 Bq/kg and 370 Bq/kg, respectively. The outdoor absorbed dose rate (D_Rex) and annual effective dose equivalent (AED_ex) were 39.0 nGy/h and 47.8 μSv/y, respectively, both of which are lower than the global soil average of 59 nGy/h and 70 μSv/y, respectively. These results indicate that local residents and tourists are not at significant risk of radiological hazards from the soil. The soil activity concentrations can serve as a baseline for continuous monitoring, even after the Maanshan NPP is decommissioned in 2025. Full article

In the present paper, an investigation on the natural and anthropic radioactivity and heavy metals content in a basalt aggregate for concrete from Sicily, Southern Italy, was performed as a case study. In particular, the evaluation of the specific activity of radium-226, thorium-232, potassium-40 and caesium-137 radionuclides was performed by using High-Purity Germanium (HPGe) γ-ray spectrometry, together with the estimation of several indexes developed to evaluate the radiological risk for the population related to radiation exposure, i.e., the alpha index (I_α), the radium equivalent activity (Ra_eq), the absorbed γ-dose rate (D) and the annual effective dose equivalent outdoor (AEDE_out) and indoor (AEDE_in). Moreover, measurements of the average heavy metals (arsenic, cadmium, copper, mercury, nickel, lead, antimony, thallium and zinc) concentrations in the analyzed sample were performed by using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Furthermore, with the aim to investigate any possible chemical pollution, the Enrichment Factor (EF), Geo-accumulation Index (I_geo), Contamination Factor (CF) and Pollution Load Index (PLI) were assessed. Finally, the identification of the source of the aforementioned radioisotopes of natural origin was carried out by X-ray diffraction (XRD), thus identifying the major mineralogical phases present in the investigated basalt aggregate for concrete. Full article

The specific activity and spatial distribution of ²³⁸U, ²³²Th and ⁴⁰K were determined in the surface soil from the Lișava uranium mining sector. This sector belongs to the Banat district, an historically important uranium mining area in Romania (an area with closed uranium mines and a radioactive waste dump). Gamma-ray spectrometry using a high-purity germanium (HPGe) detector was used to measure the activity of naturally occurring radionuclides in the soil. The average specific activities of ²³⁸U, ²³²Th and ⁴⁰K in the soil were 197.21 Bq/kg for ²³⁸U, 16.21 Bq/kg for ²³²Th and 543.21 Bq/kg for ⁴⁰K. The mineral contents of selected waste rock samples (sandstones) were examined using a scanning electron microscope (SEM), which revealed that brannerite, pitchblende and coffinite were the most important uranium-bearing minerals. The means of the radiological hazard parameters were calculated to be 262.22 Bq/kg radium equivalent activity (Raeq), 123.72 nGy/h absorbed gamma dose rates (DR), 0.7 external hazard index (Hex) and 1.8 representative level index (RLI). The spatial distribution of the risk assessment indices associated with the investigated soils exceeded the median values provided by UNSCEAR and reflected the geological settings and influences of anthropic activities such as uranium mining practices and the tipping of radioactive mining waste. Full article

Radiological aspects such as natural radioactivity of ²³⁸U, ²³²Th, ²²⁶Ra, ⁴⁰K combined with potentially toxic metal(loid) (PTM) distribution features were seldom simultaneously investigated in rare earth element (REE) processing activities. This work was designed to investigate the distribution levels of natural radioactivity, air-absorbed dose rate of γ radiation as well as PTMs at a typical REE plant in Guangdong, China. Ambient soils around REE processing facilities were sampled, measured and assessed. The natural radioactivity of radionuclides of the samples was determined using a high-purity germanium γ-energy spectrometer while the air-absorbed dose rate of γ radiation was measured at a height of 1 m above the ground using a portable radiometric detector. The PTM content was measured by inductively coupled plasma mass spectrometry (ICP-MS). The results showed that the specific activities of the radionuclides ranged from 80.8 to 1990.2, 68.2 to 6935.0, 78.4 to 14,372.4, and 625.4 to 2698.4 Bq·kg⁻¹ for ²³⁸U, ²²⁶Ra, ²³²Th, and ⁴⁰K, respectively, representing overwhelmingly higher activity concentrations than worldwide soil average natural radioactivity. The radium equivalent activity and external hazard index of most samples exceeded the limits of 370 Bq·kg⁻¹ and 1, respectively. The measured air-absorbed dose rate of γ radiation was in a range of 113~4004 nGy·h⁻¹, with most sites displaying comparatively higher values than that from some other REE-associated industrial sites referenced. The content levels of PTMs of Cu, Ni, Zn, Mn, Pb, Cd, Cr, and As were 0.7~37.2, 1.8~16.9, 20.4~2070.5, 39.4~431.3, 2.3~1411.5, 0.1~0.7, 6.7~526.1, and 59.5~263.8 mg·kg⁻¹, respectively. It is important to note that the PTM contents in the studied soil samples were 2.1~5.4 times higher for Zn-As and 1.4 times higher for Pb than the third level of the China soil standard while 2.5~13 times higher for Zn-As and 1.2 times higher for Pb than Canadian industry standard. The findings call for subsequent site remediation to secure the ecological environment and human health after the REE processing plant was decommissioned. Full article

In this article, an investigation of the natural radioactivity content of pyroclastic products from Mt. Etna, eastern Sicily, Southern Italy, was carried out. In particular, the assessment of the average activity concentration of the investigated radionuclides, related to the mineralogical phase composition of the analyzed samples, and the radiological health risk for the population, was performed. High Purity Germanium (HPGe) gamma-ray spectrometry was employed in order to quantify the average specific activity of ²²⁶Ra, ²³²Th, and ⁴⁰K natural radioisotopes. The absorbed gamma dose rate (D), the radium equivalent activity (Ra_eq), the hazard indices (H_in and H_ex), the annual effective dose equivalent outdoor (AEDE_out), and the excess lifetime cancer risk (ELCR) were also estimated in order to assess any possible radiological hazard for the population. In our case, they were found to be lower than the maximum recommended values for the population members, thus reasonably excluding radiological hazard effects. Moreover, the identification of the source of the aforementioned naturally occurring radionuclides was attempted by X-ray Diffraction (XRD) and Micro-Raman Scattering (MRS), thereby recognizing the main radioisotope-bearing minerals present in the investigated pyroclastic products. Finally, Pearson correlation, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA) were performed by processing observed radioactivity and radiological parameters in order to determine their correlation with the sampling locations. Full article

The current contribution goal is to measure the distribution of the radionuclide within the exposed rock units of southwestern Sinai, Seih-Sidri area, and assess the radiological risk. Gneisses, older granites, younger gabbro, younger granites, and post granitic dikes (pegmatites) are the main rock units copout in the target area. Radioactivity, as well as radiological implications, were investigated for forty-three samples from gneisses (seven hornblende biotite gneiss and seven biotite gneiss), older granites (fourteen samples), and younger granites (fifteen samples of syenogranites) using NaI (Tl) scintillation detector. External and internal hazard index (H_ex, H_in), internal and external level indices (Iα, Iγ), absorbed dose rates in the air (D), the annual effective dose equivalent (AED), radium equivalent activity (Ra_eq), annual gonadal dose (AGDE), excess lifetime cancer risk (ELCR), and the value of Upper Continental Core ²³²Th/²³⁸U mass fractions were determined from the obtained values of ²³⁸U, ²³²Th and ⁴⁰K for the examined rocks of Seih-Sidri area. The average ²³⁸U mg/kg in hornblende biotite gneiss and biotite gneiss, older granites, and syenogranites is 2.3, 2.1, 2.7, and 8.4 mg/kg, respectively, reflecting a relatively higher concentration of uranium content in syenogranites. The results suggest that using these materials may pose risks to one’s radiological health. Full article

High-level natural radioactivity, geochemical, geological, and radiological hazard assessment of the poorly investigated Wadi Gebeiy Dokhan volcanics rocks are discussed. Wadi Gebeiy Dokhan volcanics are located in Southwestern Sinai, Egypt, covering an area of ~1.3 km². Dokhan volcanics rocks are represented by porphyritic dacite. Geochemically, they have medium-k characters and originate from calc-alkaline magma within a volcanics arc environment. Along the fault plane striking NNE-SSW, and at its intersection with the NW-SE fault plane, altered Dokhan volcanics occur with high radioactive anomalies. Radiological parameters (absorbed dose rate, radium equivalent, activity annual effective dose, external and internal hazard indices) are used to evaluate their suitability as an ornamental stone. Except for the absorbed dose rate, all the radiological hazard indices show that unaltered Dokhan volcanics can be used as an ornamental stone. Controversially, the applied radiological indices reveal that altered Dokhan volcanics have a higher content than the recommended values of UNSCEAR, reflecting their risk on human organs. Full article

The existence of radioactivity linked to the heavy-bearing minerals in building materials—such as granite—has increased attention to the extraction procedure. Granite rocks play an essential economic role in various areas of Egypt. Thus, this study intended to detect the ²³⁸U, ²³²Th, and ⁴⁰K activity concentrations in the examined granite samples and to determine the corresponding radiological risks associated with the granite. The studied rocks were collected in the Gabal Qash Amir area (south Eastern Desert, Egypt). The obtained results of the activity concentrations for ²³⁸U (193 ± 268) Bq/kg, ²³²Th (63 ± 29) Bq/kg, and ⁴⁰K (1034 ± 382) Bq/kg indicated that there were moderate concentrations in the investigated samples, which were greater than the worldwide average. The radioactivity levels in the studied granite samples are due to the secondary alteration of radioactive-bearing minerals associated with cracks of granites (secondary minerals in muscovite granites are wolframite, uraninite, uranophane, beta-uranophane, autunite, xenotime, columbite, zircon, and monazite). The radiological risk assessment for the public from the radionuclides that were associated with the studied granite samples was predicted via estimating the radiological hazard factors, such as the radium equivalent content (362 Bq kg⁻¹), compared with the recommended limit. The dosing rate D_air in the air (169.2 nGy/h), the annual effective dose both outdoors (AED_out ~ 0.21 ± 0.17 mSv) and indoors (AED_in ~ 0.83 ± 0.67 mSv), the annual gonadal dose equivalent (AGDE ~ 1.18 ± 0.92 mSv), as well as the external (H_ex) and internal (H_in) hazard indices (>1), and another factor were associated with excess lifetime cancer risk. According to the statistical investigation, the studied granites were inappropriate for use in construction and infrastructure fields. They may induce health problems due to the radioactivity levels, which exceed the recommended limits. Full article

Arranged from oldest to youngest, the main granitic rock units exposed in Khour Abalea are metagabbros, cataclastic rocks, ophiolitic melange, granitic rocks, pegmatite and lamprophyre dykes. The presence of radioactivity associated with the heavy bearing minerals in construction materials—like granite—increased interest in the extraction process. As it turns out, granitic rocks play an important economic part in the examination of an area’s surroundings. The radionuclide content is measured by using an NaI (Tl)-detector. In the mineralized pegmatites, U (326 to 2667 ppm), Th (562 to 4010 ppm), RaeU (495 to 1544 ppm) and K (1.38 to 9.12%) ranged considerably with an average of 1700 ppm, 2881.86 ppm, 1171.82 ppm and 5.04%, respectively. Relationships among radioelements clarify that radioactive mineralization in the studied pegmatites is magmatic and hydrothermal. A positive equilibrium condition confirms uranium addition to the studied rocks. This study determined ²²⁶Ra, ²³²Th and ⁴⁰K activity concentrations in pegmatites samples and assessed the radiological risks associated with these rocks. The activity concentrations of ²²⁶Ra (13,176 ± 4394 Bq kg⁻¹), ²³²Th (11,883 ± 5644 Bq kg⁻¹) and ⁴⁰K (1573 ± 607 Bq kg⁻¹) in pegmatites samples (P) are greater than the global average. The high activity of the mineralized pegmatite is mainly attributed to the presence of uranium mineral (autunite), uranophane, kasolite and carnotite, thorium minerals (thorite, thorianite and uranothorite) as well as accessories minerals—such as zircon and monazite. To assess the dangerous effects of pegmatites in the studied area, various radiological hazard factors (external, internal hazard indices, radium equivalent activity and annual effective dose) are estimated. The investigated samples almost surpassed the recommended allowable thresholds for all of the environmental factors. Full article

The occurrence of heavy radioactive minerals in construction supplies such as granite has drawn attention to the extraction of heavy radioactive minerals. Granitic rocks were identified to serve an essential economic role in the study area’s surrounding locations. As a result, the current study attempted to detect the activity concentrations of ²³⁸U, ²³²Th, and ⁴⁰K in the granitic rock samples tested and estimate the radiological dangers associated with these rocks. The obtained data on activity concentrations for ²³⁸U (610 ± 1730 Bq kg⁻¹), ²³²Th (110 ± 69 Bq kg⁻¹) and ⁴⁰K (1157 ± 467 Bq kg⁻¹) in the granitic samples (GR) were higher than the recommended worldwide average. The radioactive levels found in the samples were caused by radioactive materials being altered and trapped inside granite faults. The exposure to gamma radiation from the granitic rocks were assessed via various radiological parameters, such as radium equivalent content (856 Bq kg⁻¹), absorbed dose rate (Dair) in the air (396 nGy/h), and annual effective dose for either outdoor (0.48 mSv y⁻¹) or indoor (1.9 mSv y⁻¹). Statistical analysis was performed to detect the correlations between radioactive concentrations and radiological parameters. The radioactive effects contributed by the uranium minerals were associated with the granitic rocks. Based on the analysis, the radioactive levels in the examined granitic surpassed the acceptable limits; therefore, they are not safe to use in building and infrastructure applications and may cause adverse health effects. Full article

The presence of heavy radioactive minerals in the studied granitoids from which the Wadi sediments leads to the study of the exposure to emitted gamma rays from the terrestrial radionuclides, such as ²³⁸U, ²³²Th, and ⁴⁰K. The geological study revealed that the Wadi sediments derived from the surrounding granitoids, such as syenogranite, alkali feldspar granite, and quartz syenite. The mineral analysis confirmed that the granitoids were enriched with radioactive minerals, such as uranothorite as well as monazite, zircon, yttrocolumbite, and allanite. The mean activity of the ²³⁸U, ²³²Th, and ⁴⁰K concentrations are 62.2 ± 20.8, 84.2 ± 23.3, and 949.4 ± 172.5 Bq kg⁻¹, respectively, for the investigated Wadi sediments, exceeding the reported limit of 33, 45 and 412 Bq kg⁻¹, respectively. Public exposure to emitted gamma radiation is detected by estimating many radiological hazard indices, such as the radium equivalent content (Ra_eq), external and internal hazard indices (H_ex and H_in), annual effective dose (AED), annual gonadal dose equivalent (AGDE), and excess lifetime cancer (ELCR). The obtained results of the radiological hazards parameters showed that public exposure to emitted gamma radiation can induce various dangerous health effects. Thus, the application of the investigated sediments in different building materials and infrastructures fields is not safe. A multivariate statistical analysis (MSA) was applied to detect radionuclide correlations with the radiological hazard parameters estimated in the granite samples. Full article

The level of radionuclides is an important index for the preparation of building materials from industrial solid waste. In order to investigate the radiological hazard of five kinds of typical general industrial solid wastes in Guizhou, China, including fly ash (FA), red mud (RM), phosphorus slag (PS), phosphogypsum (PG), and electrolytic manganese residue (EMR), the radiation intensity and associated radiological impact were studied. The results show that concentrations of ²³⁸U, ²³⁵U, ²³²Th, ²²⁶Ra, ²¹⁰Pb, and ⁴⁰K for different samples vary widely. The concentration of ²³⁸U was both positively correlated with ²³⁵U and ²²⁶Ra, and the uranium contents in the measured samples were all of natural origin. The radiation levels of PG, EMR, EMR-Na (EMR activated by NaOH), and EMR-Ca (EMR activated by Ca(OH)₂) were all lower than the Chinese and the world’s recommended highest levels for materials allowed to be directly used as building materials. The values of the internal and external illumination index (I_Ra and I_γ, respectively) for FA and RM were higher (I_Ra > 1.0 and I_γ > 1.3 for FA, I_Ra > 2.0 and I_γ > 2.0 for RM). The radium equivalent activity (Ra_eq), indoor and outdoor absorbed dose (D_in and D_out, respectively), and corresponding annual effective dose rate (E_in and E_out) of RM, PS, and FA were higher than the recommended limit values (i.e., 370 Bq/kg, 84 nGy/h, 59 nGy/h, 0.4 mSv/y, and 0.07 mSv/y, respectively), resulting from the higher relative contribution of ²²⁶Ra and ²³²Th. The portion of RM, FA, and PS in building materials should be less than 75.44%, 29.72%, and 66.01%, respectively. This study provides quantitative analysis for the safe utilization of FA, RM, PS, PG, and EMR in Guizhou building materials. Full article

Various commercially imported ceramic materials used in the building of Sudanese dwellings were examined in order to determine their natural radioactivity and radiological hazard parameters. In this context, twenty-five different consignments were sampled and analyzed using (3″ × 3″) sodium iodide gamma spectrometry system NaI(Tl). The identified average activity concentrations of ²³⁸U, ²³²Th, and ⁴⁰K were 183 ± 70, 51 ± 44, and 238 ± 77 Bq/kg dry-weights, respectively. A positive correlation between ²³⁸U and ²³²Th in the investigated samples was identified from the observed significant correlation (R² = 0.8). Interestingly, a low Th/U ratio (~0.3) was recorded, which could be related to the systematic loss of thorium during the fabrication process. The measured activity concentrations for these radionuclides were comparable with the reported data obtained from similar materials used in other countries showing similarity in ceramic materials used in buildings. Five different radiation indices, such as the average radium equivalent (Ra_eq), the absorbed dose rate (D), the annual effective dose equivalent (AEDE), the external hazard index (H_ex), and the radioactivity level index (l_γ), which indicate hazardous radiation, were estimated from these measurements. The obtained results revealed average values of 274 ± 106 Bq/kg, 125 ± 48 nGy/h, 1.23 ± 0.48 mSv/y, 0.74 ± 0.29, and 0.94 ± 0.37, for Ra_eq, D, AEDE, H_ex, and l_γ, respectively. The mean values of Ra_eq and H_ex were in good agreement with the international limits, while the means of D and lγ were higher than the universal values. Calculated AEDE in about 60% of the samples exceeded the universal limit of 1 mSv/y for the public exposure (maximum value of 2.16 mSv/y). The investigated parameters were in the same range for the majority of imported samples; however, they were slightly higher than the locally produced ceramic, highlighting the importance of monitoring imported materials for their radioactivity contents. Full article

The present work is the first systematic and large scale study on radioactive materials and heavy metals in surface soil around the Bayanwula prospective uranium mining area in China. In this work, both natural and anthropogenic radionuclides and heavy metals in 48 surface soil samples were analyzed using High Purity Germanium (HPGe) γ spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS). The obtained mean activity concentrations of ²³⁸U, ²²⁶Ra, ²³²Th, ⁴⁰K, and ¹³⁷Cs were 25.81 ± 9.58, 24.85 ± 2.77, 29.40 ± 3.14, 923.0 ± 47.2, and 5.64 ± 4.56 Bq/kg, respectively. The estimated average absorbed dose rate and annual effective dose rate were 76.7 ± 3.1 nGy/h and 83.1 ± 3.8 μSv, respectively. The radium equivalent activity, external hazard index, and internal hazard index were also calculated, and their mean values were within the acceptable limits. The estimated lifetime cancer risk was 3.2 × 10⁻⁴/Sv. The heavy metal contents of Cr, Ni, Cu, Zn, As, Cd, and Pb from the surface soil samples were measured and their health risks were then assessed. The concentrations of all heavy metals were much lower than the average backgrounds in China except for lead which was about three times higher than that of China’s mean. The non-cancer and cancer risks from the heavy metals were estimated, which are all within the acceptable ranges. In addition, the correlations between the radionuclides and the heavy metals in surface soil samples were determined by the Pearson linear coefficient. Strong positive correlations between radionuclides and the heavy metals at the 0.01 significance level were found. In conclusion, the contents of radionuclides and heavy metals in surface soil around the Bayanwula prospective uranium mining area are at a normal level. Full article