Search Results (89)

Bentonite is widely used as a sorbent due to its high specific surface area and ion-exchange capacity; however, its properties can be significantly influenced by the presence of additional mineral phases and chemical modification. In this study, the influence of manganese oxides and quartz sand on the sorption properties of bentonite from the Stará Kremnička was systematically investigated, with particular attention to surface characterization by X-ray photoelectron spectroscopy (XPS). The materials were also characterized by X-ray diffraction, FTIR spectroscopy, and zeta potential measurements. XPS analysis revealed that manganese in all modified samples was predominantly present in the Mn(IV) oxidation state, with Mn 2p₃/₂ binding energies of 642.5–642.7 eV, corresponding to MnO₂-type phases. Deconvolution of the O 1s spectra confirmed the presence of lattice oxygen, silicate oxygen, and surface hydroxyl groups. The reason for the modification of mainly natural materials with manganese oxides is their higher affinity for the adsorption of heavy metal cations. The maximum adsorption capacity of natural bentonite was 63.29 mg/g. In bentonite samples modified with manganese oxides, the value increased to 103.09 mg/g for BMn, and to 116.28 mg/g for the MMn mixture. The results demonstrate that sorption behavior is governed by a combination of ion exchange on bentonite and interactions with Mn oxide surface phases, providing new insight into the role of Mn(IV) species in surface-controlled metal binding processes. These findings highlight the importance of surface chemical states in designing efficient bentonite-based sorbents. Full article

This study investigates the influence of inside-trapped water and remedial grouting on the vertical bearing behaviour of suction bucket foundations in sand through 1 g laboratory model tests. The tests were designed to compare the relative responses of different trapped-water and grouting conditions under the same model scale, sand preparation procedure, and loading protocol. Two target trapped-water conditions were considered: a condition without an observable continuous water layer beneath the bucket lid and a condition with an initial trapped-water thickness of approximately 2 cm. These conditions were controlled and verified before loading using the scale attached to the transparent bucket wall and the underwater camera monitoring system. The results show that inside-trapped water modifies the vertical load-transfer path between the bucket lid and the internal soil plug. When a water layer exists beneath the lid, direct lid–soil plug contact is weakened, and the foundation resistance relies more strongly on skirt-side resistance and the resistance mobilized near the bucket rim. Under cyclic vertical loading, the trapped-water case exhibited larger cumulative displacement and a lower post-cyclic bearing response than the no-trapped-water case. The secant cyclic stiffness showed a continuous increase in the no-trapped-water case, whereas a rise-then-fall trend was observed in the trapped-water case, which may be associated with cyclic densification, soil plug disturbance, changes in lid–soil plug contact, and possible local pore pressure development. Remedial grouting filled the trapped-water space beneath the bucket lid and partially restored the lid–soil plug load-transfer path. Under the present model test conditions, the post-cyclic dimensionless bearing capacity of the grouted cases increased by approximately 13–16% relative to the ungrouted trapped-water case. The grouting cases with different bentonite contents showed similar recovery trends within the limited dataset, suggesting that the improvement was mainly related to filling and sealing the trapped-water space rather than to the intrinsic strength of the grout material. Full article

Aiming to address the problems of shield chamber blockage and poor muck discharge faced by earth pressure balance shields during tunneling in sandy strata, bentonite slurry is used for muck improvement. Using a multi-scale approach combining macro-scale experiments, micro-scale analysis, and molecular dynamics simulations, this study systematically investigates the interface interactions between particles of sandy soil in shield tunneling and the improvement mechanism of sodium-based bentonite slurry additives. Through the macroscopic experiment, the sodium bentonite slurry soil–water ratio of 1:7 and injection ratio of 25% showed the best improvement effect. After improvement, the permeability coefficient decreased by 99.72%; the cohesion of the excavated soil increased from 3.055 kPa to 11.458 kPa, representing a 275.06% increase; and the angle of internal friction decreased from 42.318° to 36.985°, a decrease of 12.60%. The improvement was significant. Through SEM, XRD, and FTIR microanalysis, it is found that bentonite slurry forms a flexible film on the surface of sandy soil. By coating sand particles, filling voids in the soil, and enhancing interparticle cohesion, it improves the properties of the soil. On the nanoscale, a Na-MMT/SiO₂ system model is established based on molecular dynamics simulations to elucidate the interactions between bentonite slurry and sand particle interfaces. The results indicate the presence of van der Waals forces and hydrogen bonds between Na-MMT and SiO₂. Interlayer water molecules form a hydrogen bond network that strengthens interfacial bonding, enabling bentonite slurry to tightly adhere to soil particle surfaces. This improves the microstructure of the soil, thereby enhancing its macroscopic properties. Full article

Rapid urbanization has increased the demand for building materials, depleting natural resources used in cement production and prompting the use of alternative and waste materials. This research verifies that eggshell powder waste can fully replace limestone in clinker synthesis. Five clinkers were produced using eggshell powder, aluminum sources (bentonite, zeolite, fly ash, and kaolinitic–illitic clay), Fe-slag, and quartz sand, with mechanical preprocessing (10–30 min) before sintering at 1300 °C. Experimental tests assessed the effects of mix design and mechanical activation on clinkerization, phase formation, temperature, and mechanical properties. XRD, FTIR, and SEM/EDS confirmed consistent phase compositions and primary cement minerals. Aluminum source raw materials contributed significantly to tricalcium aluminate and tetracalcium aluminoferrite formation. Eggshell and fly ash promoted tricalcium silicate and dicalcium silicate synthesis, enhancing cement strength at early and late ages. Longer mechanical pretreatments hindered clinkerization. Eggshell-based cements untreated or pretreated for 10 min are suitable for structural concrete; 20–30 min pretreatment is appropriate for low-demand or non-structural applications. The proposed methodology reduces clinker manufacturing temperature by about 100 °C from the typical range of 1400–1450 °C while maintaining mechanical properties comparable to ordinary Portland cement. Full article

This paper presents the results of a laboratory-based treatability study conducted for a confidential former wood treating site heavily impacted by a creosote non-aqueous-phase liquid (NAPL) containing pentachlorophenol (PCP). PCP impacts in the silty sands extended to approximately 33 ft (10 m) below the ground surface (bgs), with discrete soil samples containing PCP concentrations up to 14,500 mg/kg, and groundwater PCP concentrations forming a main plume exceeding 1 mg/L over 2.16 acres (0.87 ha). Treatability testing was performed on unspiked and NAPL-spiked site soils with total PCP concentrations ranging from 10 to 100 mg/kg, respectively, and leachable PCP concentrations of approximately 3 to 8 mg/L. Stabilization/solidification (S/S) mix designs using 5 to 10 weight percent (wt%, dry-reagent-to-wet-soil mass basis) of a Portland cement (PC) blend and 1 wt% powdered bentonite met the minimum unconfined compressive strength (UCS) and maximum hydraulic conductivity (K) performance criteria of 50 lb/in2 (345 kPa) and 1 × 10⁻⁶ cm/s, respectively, within the specified 28-day cure time. Long-term semi-dynamic leach testing was performed on S/S-treated soils using a modified United States Environmental Protection Agency (EPA) Method 1315 test incorporating a polydimethylsiloxane (PDMS) liner to improve the data reliability for hydrocarbons. Results showed that adding 1 wt% organoclay (OC) to the S/S mix designs did not substantially reduce leaching of common semi-volatile organic compounds (SVOCs) such as naphthalene, acenaphthene, phenanthrene and benzo(a)anthracene compared to mixes using only the PC blend with bentonite, consistent with previous studies. However, the inclusion of OC had a decisive effect on PCP immobilization, providing an order-of-magnitude (10×) reduction in the cumulative mass release of PCP over the test duration. This benefit diminished with decreasing degree of chlorination for other phenolic compounds. Full article

Model tests are effective for studying the entire deformation and evolution process of reservoir landslides. The sensitivity of similar materials to seepage effects is crucial to the accuracy of landslide model testing. Based on a fuzzy evaluation of in situ sliding zone soil, this study compared three similar materials, using shear tests and microscopic SEM to assess the similarity. The optimal similar material (sliding zone soil: bentonite: standard sand = 50%: 20%: 30%) with a water content of 13.5% and a permeability coefficient of 3.8 × 10⁻⁶ cm/s was identified, simultaneously matching physical–mechanical properties and seepage effects. When the proportion of in situ sliding zone soil exceeds that of bentonite, the in situ sliding zone soil dominates the strength. Cohesion depends on interparticle cementation force and water film viscosity. Bentonite modifies these forces in stages, leading to a trend where cohesion (c′) first increases and then decreases with rising water content, while the internal friction angle (φ’) decreases continuously. Model test results indicate the failure mode of reservoir landslides is a three-stage traction-braking failure, evolving from initial shallow deformation to deep progressive failure and finally to overall large-scale instability. The proposed similar material exhibits reliable physical–mechanical and seepage similarity and can be directly applied in physical model tests of reservoir-induced landslides to reproduce the hydro-mechanical coupling behavior of sliding zones. Full article

The production route for cement clinker, including the clinkerization protocol and temperature, is highly dependent on the selection of raw materials. Natural resource reserves used in cement manufacturing are steadily declining due to rapid urbanization and the growing demand for building materials. Consequently, there is an urgent need to identify alternative resources, potentially from cost-effective primary raw materials or waste products. This study aims to evaluate the feasibility of incorporating recycled concrete as construction and demolition waste (C&DW) with unconventional clayey materials (bentonite and zeolite) into clinker synthesis at a reduced temperature of 1300 °C. The effect of mechanical pretreatment of the clinker raw meal, applied for durations of 10 to 30 min, was investigated. Mix designs combining traditional and alternative raw materials, along with different mechanical pretreatment durations, were systematically tested to assess their impact on raw meal clinkerization and the resulting cement mechanical properties. Despite variations in raw meal composition, the produced clinkers consistently exhibited phase compositions comprising C₃S, C₂S, C₃A, and C₄AF, as confirmed by XRD, FTIR, and SEM/EDS analyses. Among the studied raw materials, clayey components played a dominant role in controlling the formation of the main cement minerals, demonstrating that zeolite and bentonite can effectively substitute standard clays. Additionally, C&DW did not impede clinkerization; rather, it functioned as a silica source, replacing quartz sand. Short mechanical pretreatments (10 min) enhanced the content of cement minerals, whereas longer treatments adversely affected clinkerization. This study offers new insights into cement clinker production at reduced temperatures through the use of C&DW combined with unconventional clayey materials. The clinkerization temperature was reduced by approximately 100 °C from the conventional 1400–1450 °C, while still producing cements with mechanical performance comparable to ordinary Portland cement (OPC). The resulting zeolite- and bentonite-based cements, either mechanically untreated or subjected to short pretreatment, are potentially suitable for structural concrete applications, while cements produced with longer mechanical pretreatments may be more appropriate for lower-demand or non-structural uses. Full article

The safe disposal of high-level radioactive waste (HLW) is a significant challenge in the nuclear industry. As the buffer backfill material for deep geological disposal engineering barriers, the shrinkage characteristics of bentonite–sand mixtures are critical to the long-term stability of repositories. This study systematically conducted drying shrinkage tests using an improved thin-film technique under varying sand contents R_s (0–50%), salt solution concentrations (0–1.5 mol/L), and ion types (Na⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻). The mechanisms of the effects of sand content and salt solutions on the shrinkage behavior of bentonite were revealed based on the results. In addition, the rationality of the MCG-B model in simulating the shrinkage characteristics of mixtures was also discussed. The results show that a sand content of 30% is the minimum sand content for inhibiting the shrinkage behavior of bentonite–sand mixtures observed in this work: below this ratio, bentonite dominates the shrinkage process, and samples are prone to cracking due to uneven matrix suction; above this ratio, quartz sand forms a rigid skeleton that significantly inhibits volume shrinkage and accelerates water evaporation. Salt solutions suppress shrinkage by compressing the thickness of the diffuse double layer and inducing ion crystallization. Higher cation concentrations and valences (Mg²⁺ > Na⁺ > Ca²⁺) enhance the inhibitory effect. Crystalline salts such as Na₂SO₄ cause measurement deviations in water content due to hydration and delay the shrinkage process. However, NaCl solutions effectively inhibit shrinkage with minimal impact on shrinkage time. Fitting results with the MCG-B model (Coefficient of determination > 0.97) demonstrate that the MCG-B model can empirically describe the results of thin-film technique experiment, though the model’s prediction accuracy decreases for the residual shrinkage stage at high sand contents (>40%). This study provides a theoretical basis for optimizing buffer material proportions and curing processes, with significant implications for the long-term safety of HLW repositories. Full article

Substrate amendment is a promising strategy to enhance phytoremediation in degraded coastal wetlands, yet the selection of optimal materials and their incorporation ratios remains challenging. This study systematically investigated the effects of five amendments, viz., manganese sand, maifan stone, bentonite, iron–carbon (Fe-C), and vermiculite, across an incorporation ratio gradient (5–40%) on the growth of the mangrove, Kandelia obovata, and the physicochemical properties of coastal wetland substrate. Results demonstrated material-specific and dose-dependent responses. Four amendments (vermiculite, Fe-C, manganese sand, and maifan stone) promoted Kandelia obovata growth to varying degrees, while bentonite exhibited significant inhibition. All amendments ensured the physical stability of the substrate. Nutrient removal efficiency followed the order: Fe-C > vermiculite > maifan stone > manganese sand, with 10% Fe-C showing the highest comprehensive nutrient removal. Conversely, bentonite functioned as a nutrient enrichment agent. The amendments differentially influenced redox potential, CO₂ emissions, and electrical conductivity, yet all maintained a stable substrate pH. A comprehensive evaluation considering plant growth, nutrient removal, and CO₂ sequestration identified maifan stone as the optimal amendment, with the 40% incorporation ratio delivering the most favorable integrated performance. This study provides critical, ratio-specific guidance for selecting and applying substrate amendments in coastal wetland restoration. This study provides critical, ratio-specific guidance for selecting and applying environmentally sustainable amendments, supporting the development of nature-based solutions for long-term coastal wetland restoration. Full article

To promote energy efficiency, emission reduction, and green low-carbon development, this study investigates the influence of cellulose ether (CE) content and its interactions with supplementary materials, including stone powder (SP), manufactured sand (MS), polyvinyl alcohol (PVA), and bentonite (BT), on the performance of premixed mortar using an L16(4⁵) orthogonal experimental design. The effects of five factors at four levels were analyzed, focusing on mortar workability and compressive strength. Results showed that CE content significantly affected consistency, water retention, and compressive strength (p < 0.01). A 60% increase in CE led to a 4.7% reduction in flowability, a 2.05% improvement in water retention, and an 18.49% decrease in compressive strength. Response surface methodology identified optimal compositions for each property. The CE-BT interaction influenced consistency (R² = 0.6894), while CE-PVA interactions affected water retention (R² = 0.9336). A ternary model for compressive strength (CE-SP-MS) showed that SP and MS replacements had significant negative effects, with optimal SP replacement at 10%. PVA at 0.04% effectively inhibited plastic shrinkage cracking. The study provides predictive models for mortar performance, aiding in the optimization of premixed mortar formulations. Full article

Oil contamination in subsurface soils caused by leaks from underground storage tanks (USTs) and industrial facilities has become a significant geo-environmental concern. Total petroleum hydrocarbons (TPH) migrate through the ground and are difficult to remediate once dispersed; thus, prevention of migration is critical. This study experimentally investigated a hybrid liner system combining three barrier mechanisms—physical, reactive, and absorptive—to prevent TPH migration in the subsurface. Laboratory-scale experiments were conducted using a soil box simulating groundwater flow, in which Type A (100% polynorbornene powder) and Type B (mixed bentonite–sand–polyolefin–polynorbornene) liners were embedded under different soil types and spill distances. Results showed that permeability decreased rapidly after oil contact, reaching the transition zone within 120 H. Type A responded more quickly and achieved lower permeability, while Type B provided comparable but slower reduction owing to its mixed composition. These findings demonstrate that hybrid liners effectively block oil migration without hindering groundwater flow and that soil condition and spill location should be considered when selecting liner type for field applications. Full article

It is well known that the operation of a Borehole Heat Exchanger (BHE) can thermally induce groundwater convection in aquifers, enhancing the thermal performance of the BHE. However, the effect on the thermal performance of BHEs installed in low-permeable rock formations remains unclear. In this study, two BHEs were installed in a silty sandstone formation, one backfilled with high-permeable materials and the other grouted with sand–bentonite slurry. A Thermal Response Test (TRT) showed that the fluid outlet temperature of the high-permeable-material backfilled BHE was about 2.5 °C lower than that of the BHE refilled with sand–bentonite slurry, implying a higher thermal efficiency. The interpreted borehole thermal parameters also show a lower borehole thermal resistance in the high-permeable-material backfilled BHE. Physical model tests reveal that groundwater convective flow was induced in the high-permeable-material backfilled BHE. A test of BHEs with different borehole diameters shows that the larger the borehole diameter, the higher the thermal efficiency is. Thus, the thermal performance enhancement was attributed to two factors. First, the induced groundwater flow accelerates heat transfer by convection. Additionally, the increment of the thermal volumetric capacity of the groundwater stored inside a high-permeable-material refilled borehole stabilized the borehole’s temperature, which is key to sustaining high thermal efficiency in a BHE. The thermal performance enhancement demonstrated here shows potential for reducing reliance on fossil-fuel-based energy resources in challenging geological settings, thereby contributing to developing more sustainable geothermal energy solutions. Further validation in diverse field conditions is recommended to generalize these findings. Full article

Conventional slurry wall protection exhibits reduced film performance upon exposure to water in saturated sand layers with high permeability, frequently resulting in hole wall instability. Optimizing the slurry ratio to enhance film performance is thus critical for borehole stability. A multiple regression model was developed to determine the optimal slurry ratio for saturated sand. Slurry permeability tests assessed filtration loss, film formation time, and film morphology changes. Scanning electron microscopy (SEM) further elucidated the film formation mechanism. Bentonite, clay, Na₂CO₃, and sodium carboxymethyl cellulose (CMC) significantly affected the slurry’s properties: specific gravity and sand content increased with bentonite/clay; viscosity increased with CMC; and pH increased with Na₂CO₃. The optimized slurry (water–bentonite–Na₂CO₃–clay–CMC = 1000:220:32:110:1; specific gravity, 1.20 g/cm³; viscosity, 29 s) demonstrated low filtration loss and stable film morphology. SEM revealed that simultaneous CMC and clay addition (ratio of 1:110) improved film surface flatness, reduced porosity and pore size, enhanced formation surface filling, and produced a denser film. The optimized slurry ratio significantly enhanced film performance in saturated sand layers. The findings provide a theoretical and engineering framework for bored pile wall protection slurry design and film formation mechanisms. Full article

The influence of temperature on soil behavior has traditionally attracted attention for geotechnical engineers, especially in the design of engineering works and nuclear facilities located in regions with severe cold climates. This research emphasizes exploring how temperature variations affect essential soil properties that are significant for the resilience and long-term stability of geotechnical structures. For this reason, the influence of temperature on the soil’s mechanical and physical attributes was comprehensively evaluated. To achieve this, soil mixtures consisting of two blends prepared as 70% bentonite with 30% sand and 70% sand with 30% bentonite (70B30S and 70S30B) were exposed to temperatures ranging from –45 °C to +105 °C for durations of 24 and 48 h. The study examined how temperature variations affect the mechanical, physical, and mineralogical features of soil through consistency limit tests, direct shear tests, swelling pressure tests, and X-ray diffraction (XRD) analysis. It was observed that the internal friction angle (Φ) declined as temperature increased in both mixtures, particularly in specimens with higher sand content. Similarly, cohesion (c) values decreased with increasing temperature, more significantly in mixtures with higher bentonite content. Additionally, the consistency limits and swelling pressure decreased as temperature rose. This trend was evident in both mixtures. Swelling pressure results showed that from 20 °C to 105 °C, the pressure rose with temperature in bentonite-rich soils, while it decreased in sand-rich soils. Conversely, at subzero conditions (–10 to –45 °C), swelling pressure increased as temperature decreased in mixtures dominated by bentonite, while it dropped in those rich in sand. Full article

Aeolian sand is the primary geological material for construction in desert regions, and its stabilization with industrial solid wastes-based geopolymer (ISWG) provides an eco-friendly treatment replacing cement. This study comparatively investigated the enhancement effects of chemical activators and expansive agents on compressive strength of aeolian sand stabilized by ISWG (ASIG). Three chemical activators—NaOH, Ca(OH)₂, and CaCl₂—along with two expansive agents—desulfurized gypsum and bentonite—were considered. Through X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, mercury intrusion porosimetry and pH values tests, the enhancement mechanisms of the additives on ASIG were elucidated. Results demonstrate that the expansive agent exhibits significantly superior strengthening effects on ASIG compared to the widely applied chemical activators. Chemical activators promoted ISWs dissolution and hydration product synthesis, thereby densifying the hydration product matrix but concurrently enlarged interparticle pores. Desulfurized gypsum incorporation induced morphological changes in ettringite, and excessive desulfurized gypsum generated substantial ettringite that disrupted gel matrix. In contrast, bentonite demonstrated superior pore-filling efficacy while densifying gel matrix through a compaction effect. These findings highlight bentonite superior compatibility with the unique microstructure of aeolian sand compared to conventional alkaline activators or expansive agents, and better effectiveness in enhancing the strength of ASIG. Full article