Search Results (429)

Given that the stock of coal gangue is increasing annually, and especially considering the problem of resource utilization after the spontaneous combustion of coal gangue accumulations with large thickness, the post-spontaneous combustion of coal gangue (SC coal gangue) from Yangquan, Shanxi, was selected as a research object. After crushing and screening, SC coal gangue was used as a coarse and fine aggregate, and through concrete mix design and a trial mix of concrete and mix ratio adjustment, concrete of strength grade C20 was obtained. Through experiments, the strength, elastic modulus, frost resistance, carbonation depth and other performance indicators of the concrete were measured. Using the SC coal gangue concrete, a 20 mm thick SC coal gangue panel was designed and manufactured. Through experimental tests, the bearing capacity, hanging force, impact resistance, impermeability and other properties of the board met the requirements of the relevant standards for building wallboard. For the SC coal gangue panel composite rock wool, its heat transfer coefficient decreased by 34.0%, air sound insulation was $\ge 45 \mathrm{d}\mathrm{B}$, and the self-weight of the external wallboard was reduced by 37.5%, so the related performance was better than the requirements of the current standard. The research results have been successfully applied to an office building project in Shanxi, China. Using SC coal gangue to make the external wallboard of the building, the reduction and recycling of solid waste are realized. In addition, the production of wall panels has been industrialized, thereby improving the construction efficiency. Full article

New energy vehicles face a critical challenge in balancing the thermal safety management of high-specific-energy battery systems with the simultaneous improvement of energy density. With the large-scale application of high-energy-density systems such as silicon-based anodes and solid-state batteries, their inherent thermal runaway risks pose severe challenges to battery thermal management systems (BTMS). Currently, the thermal insulation performance, temperature resistance, and fire protection capabilities of flame-retardant materials (e.g., foam cotton, fiber felts) used in automotive batteries are inadequate to meet the demands of intense combustion and high temperatures generated during thermal failure in high-energy-density batteries. Against this backdrop, thermal insulation and fireproof aerogel materials are emerging as a revolutionary solution for the next generation of power battery thermal protection systems. Leveraging their nanoporous structure’s exceptional thermal insulation properties (thermal conductivity of 0.013–0.018 W/(m·K) at room temperature) and extreme fire resistance (temperature resistance > 1100 °C/UL94 V-0 flame retardancy), aerogels are gaining prominence. This article provides a systematic review of thermal runaway phenomena in automotive batteries and corresponding protective measures. It highlights recent breakthroughs in the selection of material systems, optimization of preparation processes, and fiber–matrix composite technologies for automotive fireproof aerogel composites. The core engineering values of these materials, such as blocking thermal runaway propagation, reducing system weight, and improving volumetric efficiency, are quantitatively validated. Furthermore, the paper explores future research directions, including the development of low-cost aerogel composites and the design of organic–inorganic hybrid composite structures, aiming to provide a foundation and industrial pathway for the research and development of next-generation high-performance battery thermal management systems. Full article

The applicability of biochar as a coarse aggregate substitute in concrete to increase sustainability and multifunctionality was investigated. Biochar, a porous carbon-rich byproduct from biomass pyrolysis, was incorporated at various replacement ratios (5–20%) under four water-to-binder (w/b) conditions (0.25–0.40). The key physical, mechanical, thermal, and microstructural properties, including the unit weight, porosity, compressive strength, flexural strength, and thermal conductivity, were evaluated via SEM and EDS analyses. The results revealed that although increasing the biochar content reduced the mechanical strength, it significantly improved the thermal insulation performance because of the porous structure of the biochar. At low w/b ratios and 5–10% biochar content, sufficient mechanical properties were retained, indicating a viable design range. Higher replacement ratios (>15%) led to excessive porosity, reduced hydration, and impaired durability. This study quantitatively analyzed the interproperty correlations, confirming that the strength and thermal performance are closely linked to the internal matrix density and porosity. These findings suggest that biochar-based concrete has potential for use in thermal energy storage systems, high-temperature insulation, and low-carbon construction. The low-carbon effect is achieved both by sequestering stable carbon within the concrete matrix and by partially replacing cement, thereby reducing CO₂ emissions from cement production. Moreover, the results highlight a strong correlation between increased porosity, enhanced thermal insulation, and reduced strength, thereby offering a solid foundation for sustainable material design. In particular, the term ‘high temperature’ in this context refers to exposure conditions above approximately 200~400 °C, as reported in previous studies. However, this should be considered as a potential application to be validated in future experiments rather than a confirmed outcome of this study. Full article

In SF₆ gas-insulated equipment, solid dielectrics critically degrade insulation performance by reducing the electric field’s ability to withstand gas gaps. To investigate the critical role played by solid dielectric surfaces during the initial phase of gas–solid interface discharge phenomena, this paper experimentally measures the AC breakdown voltage (U_bd) of both dielectric surface-initiated breakdown (DIBD) and electrode surface-initiated breakdown (EIBD) across eight types of post insulator samples. Tests are conducted in 36 mm SF₆ gas gaps under pressures ranging from 0.1 to 0.4 MPa. Combined with electrostatic field simulations, the results reveal that DIBD requires substantially lower U_bd than EIBD under comparable maximum electric field (E_max) conditions. As gas pressure increases, this difference becomes more pronounced. This phenomenon can be explained by three key mechanisms: First, due to the regulatory effect of dielectric materials and shielding electrodes on the electric field distribution, the high-electric-field zone along the gas–solid interface exhibits a longer effective discharge path compared to that in a pure gas gap. This configuration creates more favorable conditions for discharge initiation and subsequent propagation toward the opposite electrode. Second, microscopic irregularities on the dielectric surface induce stronger local electric field enhancement than comparable features on metallic electrodes. Third, in high-electric-field regions adjacent to the dielectric surface, desorption processes significantly enhance electron multiplication during gas discharge, and this enhancement effect becomes more pronounced as gas pressure increases, further lowering the discharge inception threshold. As a result, discharge initiation at dielectric interfaces requires less stringent electric field conditions compared to breakdown in a gas gap, especially at high gas pressure. This conclusion not only accounts for the saturation behavior in the U_bd-p characteristic of SF₆ gas–solid interface discharges but also explains why surface contaminants/defects disproportionately degrade interfacial insulation performance relative to their impact on gas gaps. Full article

The molten salt reactor (MSR) is a prominent Generation IV nuclear reactor concept that offers substantial advantages over conventional solid-fueled systems, including enhanced fuel utilization, inherent passive safety features, and significant reductions in long-lived radioactive waste. Central to its safety strategy is a reliance on natural circulation (NC) mechanisms, which eliminate the need for active pumping systems and enhance system reliability during normal and off-normal conditions. However, the challenges associated with molten salts, such as their high melting points, corrosivity, and material compatibility issues, render experimental investigations inherently complex and demanding. Therefore, the use of high-Pr-number surrogate fluids represents a practical alternative for studying molten salt behavior under safer and more accessible experimental conditions. In this study, a single-phase natural circulation loop setup at the University of Idaho’s Thermal–Hydraulics Laboratory was employed to investigate NC behavior under various operating conditions. The RELAP5-3D code was initially validated against water-based experiments before employing Therminol-66, a high-Prandtl-number surrogate for molten salts, in the natural circulation loop for the first time. The RELAP5-3D results demonstrated good agreement with both steady-state and transient experimental results, thereby confirming the code’s ability to model NC behavior in a single-phase flow regime. The results also highlighted certain experimental limitations that should be addressed to enhance the NC loop’s performance. These include increasing the insulation thickness to reduce heat losses, incorporating a dedicated mass flow measurement device for improved accuracy, and replacing the current heater with a higher-capacity unit to enable testing at elevated power levels. By identifying and addressing the main causes of these limitations and uncertainties during water-based experiments, targeted improvements can be implemented in both the RELAP5 model and the experimental setup, thereby ensuring that tests using a surrogate fluid for MSR analyses are conducted with higher accuracy and minimal uncertainty. Full article

Accurate thermal characterization of closed mesoporous metal gels is vital for high-temperature uses, yet microscale effects often ignored in macroscopic models significantly impact heat transfer. This study introduces a new predictive method based on an equivalent Voronoi model, accounting for the Knudsen effect and microscale electromagnetic interactions. Predicted thermal conductivity closely matched experimental results, with an average error of 5.35%. The results demonstrate that thermal conductivity decreases with porosity, increases with temperature, and varies with pore size, with a minimum of 17.47 W/(m·K) observed at ~1 μm. Variations in refractive index, extinction coefficient, and specific surface area exert negligible influence. Conductive heat transfer is suppressed under Knudsen-dominated conditions at small pore sizes. Electromagnetic analysis around the pore size corresponding to minimum conductivity reveals localized surface plasmon resonances and magnetic coupling at the gas–solid interface, which enhance radiative dissipation and further reduce thermal conductivity. Radiation dissipation efficiency increases with decreasing porosity and pore size. This model thus serves as a predictive tool for designing high-performance thermal insulation systems for elevated-temperature applications. Full article

In high-humidity environments, the epoxy resin solid insulation materials of high-frequency transformers are prone to aging, resulting in varying degrees of deterioration in the material’s dielectric properties and other aspects. To enhance the adaptability of epoxy resin in high humidity environments, this paper, based on the molecular dynamics simulation method, establishes epoxy resin-based nanocomposites with doped nanofillers: a pure epoxy resin model and three epoxy resin models, respectively, doped with carbon nanotubes, graphene(GR), and SiO₂. Based on the above models, using LAMMPS-17Apr2024, the thermal diffusion coefficients (thermal conductivity and specific heat capacity), glass transition temperatures, and dielectric constants under different moisture contents are calculated. The results show that the various properties of the epoxy resin nanocomposites doped with nanofillers have been improved to varying degrees. Among them, the GR/epoxy resin composite model shows the most significant improvements in thermal conductivity, thermal diffusivity, and glass transition temperature, and the SiO₂/epoxy resin composite model has the best dielectric properties. Considering the high-temperature operation conditions and heat dissipation requirements of the high-frequency transformer, the GR-enhanced epoxy resin becomes the optimal filler choice. Full article

This study evaluates the impact of different flame retardants on the mechanical and thermal properties of rigid polyisocyanurate (PIR) foams, focusing on formulations with isocyanate indexes of 335 and 400. The flame retardants tested include triethyl phosphate (TEP), ammonium polyphosphate (APP), aluminium hydroxide (Al(OH)₃), and a combination of APP and Al(OH)₃. FOAMAT^® was used to analyse the foaming kinetics, while further tests assessed density, thermal conductivity, and compression strength. TEP, a liquid flame retardant, was found to reduce peak heat release rate (pHRR) and total heat release significantly, outperforming solid flame retardants. Although solid flame retardants like APP slightly increase start times and gel times due to their non-reactive, filler role, they increase the foam’s density and somewhat limit the effectiveness in reducing flammability. The uneven dispersion and lower compatibility of solid additives may lead to suboptimal improvements in fire resistance. APP displayed dual-phase decomposition, aiding char formation to a degree. Overall, TEP proved most effective in enhancing PIR foam’s fire resistance, demonstrating the advantage of liquid over solid flame retardants in achieving uniform distribution and better integration with the foam matrix, thus optimising thermal insulation and mechanical performance. Full article

Practical applications such as solar power energy systems, electronic cooling, and the convective drying of vented enclosures require continuous developments to enhance fluid and heat flow. Numerous studies have investigated the enhancement of heat transfer in L-formed vented cavities by inserting heat-generating components, filling the cavity with nanofluids, providing an inner rotating cylinder and a phase-change packed system, etc. Contemporary work has examined the thermal performance of L-shaped porous vented enclosures, which can be augmented by using metal foam, using nanofluids as a saturated fluid, and increasing the wall surface area by corrugating the cavity’s heating wall. These features are not discussed in published articles, and their exploration can be considered a novelty point in this work. In this study, a vented cavity was occupied by a copper metal foam with $PPI=10$ and saturated with a copper–water nanofluid. The cavity walls were well insulated except for the left wall, which was kept at a hot isothermal temperature and was either non-corrugated or corrugated with rectangular waves. The Darcy–Brinkman–Forchheimer model and local thermal non-equilibrium models were adopted in momentum and energy-governing equations and solved numerically by utilizing commercial software. The influences of various effective parameters, including the Reynolds number ($20\le Re\le 1000$), the nanoparticle volume fraction ($0\%\le \phi \le 20\%$), the inflow and outflow vent aspect ratios ($0.1\le D/H\le 0.4$), the rectangular wave corrugation number ($N=5$ and $N=10$), and the corrugation dimension ratio ($CR=1$ and $CR=0.5$) were determined. The results indicate that the flow field and heat transfer were affected mainly by variations in $Re$, $D/H$, and $\phi$ for a non-corrugated left wall; they were additionally influenced by $N$ and $CR$ when the wall was corrugated. The fluid- and solid-phase temperatures of the metal foam increased with an increase in $Re$ and $D/H$. The fluid-phase Nusselt number near the hot left sidewall increased with an increase in $\phi$ by $\left(25–60\right)\%$, while the solid-phase Nusselt number decreased by $\left(10–30\right)\%$, and these numbers rose by around $3.5$ times when the Reynolds number increased from $20$ to $1000$. For the corrugated hot wall, the Nusselt numbers of the two metal foam phases increased with an increase in $Re$ and decreased with an increase in $D/H$, $CR$, or $N$ by $10\%$, $19\%$, and $37\%$. The original aspect of this study is its use of a thermal, non-equilibrium, nanofluid-saturated metal foam in a corrugated L-shaped vented cavity. We aimed to investigate the thermal performance of this system in order to reinforce the viability of applying this material in thermal engineering systems. Full article

In solid rocket propulsion systems, overload effects induced by aircraft maneuvers can lead to gas accumulation in the afterburning chamber, resulting in severe localized ablation of thermal insulation layers and significantly compromising overall operational stability. Traditional ablation experimental methods (e.g., oxyacetylene and plasma ablation) exhibit poor correlation with the actual thermal environments in solid rocket ramjets, thereby posing substantial challenges for simulating real operational conditions. To address this issue, an oxygen-kerosene engine-based ablation device was developed. Methodologically, the CEA-optimized oxygen-to-fuel ratio (3.5) enabled authentic combustion simulation, while 3D compressible flow modeling (Ansys Fluent 2020 R2) quantified critical parameters such as chamber pressure and achieved precise control of surface temperature. Ablation experiments were conducted on diverse ablative materials using this device, yielding a maximum error in mass ablation rate of only 5.67%. This demonstrates the high accuracy of the device, which meets the requirements for ablation experiments. This reliable simulator (with an error <6%) provides a validated platform for high-fidelity evaluation of ablation performance in maneuverable solid rocket ramjets. Full article

This study aimed to determine optimal forming conditions by comparing the compaction behavior and microstructural characteristics of two Fe-based Soft Magnetic Composite (SMC) powders, Somaloy 700HR 5P and Somaloy 130i 5P. A full factorial design was employed with powder type, compaction temperature, and punch speed as variables. Finite element modeling (FEM) using experimentally derived properties predicted density and stress distributions in toroidal geometries. 700HR 5P exhibited higher stress under most conditions, while both powders showed similar axial density gradients. Experimental results validated the simulations. SEM analysis revealed that 130i 5P had fewer microvoids and clearer particle boundaries. As revealed by TEM-EDS analyses, after heat treatment, both powders exhibited a tendency for the insulation layers to become more uniform and continuous. The insulation layer of 700HR 5P was relatively thicker but retained some pores, whereas that of 130i 5P was thinner yet exhibited smoother and more continuous coverage. XRD analysis indicated that both powders retained an α-Fe solid solution. These results demonstrate that powder properties, composition, and insulation stability significantly influence compaction and microstructural evolution. This work systematically compares the formability and insulation stability of two commercial Somaloy powders and elucidates process–structure–property relationships through an application-oriented evaluation integrating experimental design, FEM, and microstructural characterization, providing practical insights for optimal process design. Full article

Perfluoroisobutyronitrile (C₄F₇N) has emerged as a promising SF₆ alternative due to its superior dielectric properties and acceptable environmental impact. However, the gas–solid interfacial charge accumulation behavior in such gas mixtures requires in-depth and systematic investigation. This study investigated the surface charge accumulation behavior on scaled disc insulators in C₄F₇N/CO₂/O₂ mixtures under AC voltage. By constructing a high-precision surface charge measurement platform, the influence mechanisms of varying gas composition ratios of C₄F₇N (2–14%) with fixed O₂ content and O₂ (2–14%) with fixed C₄F₇N content on charge accumulation were analyzed. The results demonstrated that increasing C₄F₇N content significantly suppresses surface charge accumulation. When the C₄F₇N concentration rises from 2% to 14%, the maximum positive/negative charge densities decrease by 46.58% and 22.22% in the absence of metal particles. The suppression effect is more pronounced with the metal particle present, where the reductions in positive/negative charge densities reach 61.90% and 23.71% under the same conditions. In contrast, variations in O₂ content exhibit a weaker impact on charge accumulation, showing no consistent regulatory effect within the 2–14% range. By comparing charge distribution patterns under different gas compositions, it is revealed that C₄F₇N suppresses gas ionization primarily by enhancing electronegativity, while O₂ exhibits negligible influence on charge transport. This study provides critical experimental evidence for optimizing gas ratios and insulation design in AC GIS equipment. Full article

This study offers a detailed environmental, energy, and economic evaluation of thermal modernisation options for an existing single-family home in southern Poland. A total of 24 variants, combining different heat sources (solid fuel, biomass, natural gas, and heat pumps) with various levels of building insulation, were analysed using energy performance certification methods. Results show that, from an energy perspective, the most advantageous scenarios are those utilising brine-to-water or air-to-water heat pumps supported by photovoltaic systems, reaching final energy demands as low as 43.5 kWh/m²year and primary energy demands of 41.1 kWh/m²year. Biomass boilers coupled with solar collectors delivered the highest renewable energy share (up to 99.2%); however, they resulted in less notable reductions in primary energy. Environmentally, all heat pump options removed local particulate emissions, with CO₂ reductions of up to 87.5% compared to the baseline; biomass systems attained 100% CO₂ reduction owing to renewable fuels. Economically, biomass boilers had the lowest unit energy production costs, while PV-assisted heat pumps faced the highest overall costs despite their superior environmental benefits. The findings highlight the trade-offs between ecological advantages, energy efficiency, and investment costs, offering a decision-making framework for the modernisation of sustainable residential heating systems. Full article

The interest in synthesizing new dielectric materials is caused by their potential application in various electronic and sensor devices as well as in a large variety of electronic components. The present work reports the synthesis of glasses in the Na₂O/Al₂O₃/BaO/ZrO₂/TiO₂/B₂O₃/SiO₂ system prepared by melt-quenching. These glasses were then crystallized to glass–ceramics by a controlled thermal treatment. X-ray diffraction experiments reveal the precipitation of Ba₂TiSi₂O₈ (fresnoite) and BaTiO₃, which probably forms a BaZr_xTi_1−xO₃ solid solution. The microstructure is studied by scanning electron microscopy and shows the presence of mulberry-shaped, crystallized structures with a densely-branching morphology. Microcomputed X-ray tomography is used to gather information on the volume fraction and average size of the crystallized volume as an effect of the applied temperature–time schedule. Longer annealing times lead to a higher volume fraction and increasing average size of the crystallization structures obtained. The dielectric properties analyzed by impedance spectroscopy are insulating and show relatively high dielectric constants ≥ 100 and moderate loss tangent values at 10 kHz. Full article

Space exploration and the prospect of developing permanent lunar settlements in the near future will require the need for innovative building construction techniques using locally sourced materials, without the need for excessive input of simple, reusable energy. The Moon’s surface is covered by regolith, a superficial layer of unconsolidated heterogeneous dusty aggregate that covers solid bedrock. This material needs to be agglomerated to create a cohesive composite that can be used as building blocks or bricks. In this study, the OPRH2N’s Lunar Regolith Simulant (LRS) was used and agglomerated with Potato (Solanum tuberosum) Starch (PS) polymer aerogel. Starch was chosen because of its excellent binding properties at very low concentrations. The resulting low-starch-containing LRS/PS aerogel composite bricks (2 and 4 wt%) were tested for their mechanical and thermal insulation performance to evaluate their potential application in lunar building structures. The composite resistance to intense beta-radiation and very large thermal amplitude was investigated to test the bricks’ resistance. This new lightweight and porous material shows promising mechanical and thermal performance, making it a potential candidate for the construction of larger structures, especially in low gravity. Full article